FR3087778B1 - Composition de polymere adaptee pour moulage par injection comprenant des particules et un colorant, son procede de preparation et son utilisation - Google Patents

Composition de polymere adaptee pour moulage par injection comprenant des particules et un colorant, son procede de preparation et son utilisation Download PDF

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Publication number
FR3087778B1
FR3087778B1 FR1859955A FR1859955A FR3087778B1 FR 3087778 B1 FR3087778 B1 FR 3087778B1 FR 1859955 A FR1859955 A FR 1859955A FR 1859955 A FR1859955 A FR 1859955A FR 3087778 B1 FR3087778 B1 FR 3087778B1
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France
Prior art keywords
polymer composition
injection molding
particles
colorant
preparation process
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
FR1859955A
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English (en)
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FR3087778A1 (fr
Inventor
Benoit Andre
Sylvain Queruel
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Trinseo Europe GmbH
Original Assignee
Arkema France SA
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Filing date
Publication date
Priority to FR1859955A priority Critical patent/FR3087778B1/fr
Application filed by Arkema France SA filed Critical Arkema France SA
Priority to JP2021522358A priority patent/JP2022505712A/ja
Priority to MX2021004557A priority patent/MX2021004557A/es
Priority to PCT/EP2019/079159 priority patent/WO2020084110A1/fr
Priority to US17/286,944 priority patent/US20210380796A1/en
Priority to KR1020217015227A priority patent/KR20210084514A/ko
Priority to EP19797206.0A priority patent/EP3870631A1/fr
Priority to CN201980086213.1A priority patent/CN113286845A/zh
Publication of FR3087778A1 publication Critical patent/FR3087778A1/fr
Application granted granted Critical
Publication of FR3087778B1 publication Critical patent/FR3087778B1/fr
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/20—Compounding polymers with additives, e.g. colouring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/10—Homopolymers or copolymers of methacrylic acid esters
    • C08L33/12—Homopolymers or copolymers of methyl methacrylate
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/0001—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor characterised by the choice of material
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/20—Compounding polymers with additives, e.g. colouring
    • C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/20—Compounding polymers with additives, e.g. colouring
    • C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
    • C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/0041—Optical brightening agents, organic pigments
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/07—Aldehydes; Ketones
    • C08K5/08—Quinones
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/17—Amines; Quaternary ammonium compounds
    • C08K5/18—Amines; Quaternary ammonium compounds with aromatically bound amino groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/22—Compounds containing nitrogen bound to another nitrogen atom
    • C08K5/23—Azo-compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3442—Heterocyclic compounds having nitrogen in the ring having two nitrogen atoms in the ring
    • C08K5/3462—Six-membered rings
    • C08K5/3465—Six-membered rings condensed with carbocyclic rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L101/00—Compositions of unspecified macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F21—LIGHTING
    • F21K—NON-ELECTRIC LIGHT SOURCES USING LUMINESCENCE; LIGHT SOURCES USING ELECTROCHEMILUMINESCENCE; LIGHT SOURCES USING CHARGES OF COMBUSTIBLE MATERIAL; LIGHT SOURCES USING SEMICONDUCTOR DEVICES AS LIGHT-GENERATING ELEMENTS; LIGHT SOURCES NOT OTHERWISE PROVIDED FOR
    • F21K9/00—Light sources using semiconductor devices as light-generating elements, e.g. using light-emitting diodes [LED] or lasers
    • F21K9/60—Optical arrangements integrated in the light source, e.g. for improving the colour rendering index or the light extraction
    • F21K9/66—Details of globes or covers forming part of the light source
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F21—LIGHTING
    • F21K—NON-ELECTRIC LIGHT SOURCES USING LUMINESCENCE; LIGHT SOURCES USING ELECTROCHEMILUMINESCENCE; LIGHT SOURCES USING CHARGES OF COMBUSTIBLE MATERIAL; LIGHT SOURCES USING SEMICONDUCTOR DEVICES AS LIGHT-GENERATING ELEMENTS; LIGHT SOURCES NOT OTHERWISE PROVIDED FOR
    • F21K9/00—Light sources using semiconductor devices as light-generating elements, e.g. using light-emitting diodes [LED] or lasers
    • F21K9/90—Methods of manufacture
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00—Optical elements other than lenses
    • G02B5/02—Diffusing elements; Afocal elements
    • G02B5/0205—Diffusing elements; Afocal elements characterised by the diffusing properties
    • G02B5/0236—Diffusing elements; Afocal elements characterised by the diffusing properties the diffusion taking place within the volume of the element
    • G02B5/0242—Diffusing elements; Afocal elements characterised by the diffusing properties the diffusion taking place within the volume of the element by means of dispersed particles
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00—Optical elements other than lenses
    • G02B5/02—Diffusing elements; Afocal elements
    • G02B5/0273—Diffusing elements; Afocal elements characterized by the use
    • G02B5/0278—Diffusing elements; Afocal elements characterized by the use used in transmission
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2033/00—Use of polymers of unsaturated acids or derivatives thereof as moulding material
    • B29K2033/04—Polymers of esters
    • B29K2033/12—Polymers of methacrylic acid esters, e.g. PMMA, i.e. polymethylmethacrylate
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2995/00—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
    • B29K2995/0018—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds having particular optical properties, e.g. fluorescent or phosphorescent
    • B29K2995/002—Coloured
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/002—Physical properties
    • C08K2201/003—Additives being defined by their diameter
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/18—Spheres
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2310/00—Masterbatches
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/04—Polysiloxanes

Abstract

La présente invention concerne une composition de polymère adaptée pour moulage par injection comprenant des particules de polymère et un colorant. En particulier, la présente invention concerne une composition de polymère (méth) acrylique comprenant des particules de polymère et un mélange de colorants adaptée pour des composés moulés par injection avec un brillant élevé. La présente invention concerne en outre l'utilisation d'une telle composition de polymère ou composition de polymère (méth) acrylique comprenant des particules de polymère et un mélange de colorants dans des applications d'éclairage et dans le moulage par injection. La présente invention concerne en outre un procédé de fabrication d'une composition de polymère (méth) acrylique comprenant des particules de polymère et un mélange de colorants adaptée pour des composés moulés par injection avec un brillant élevé.
FR1859955A 2018-10-26 2018-10-26 Composition de polymere adaptee pour moulage par injection comprenant des particules et un colorant, son procede de preparation et son utilisation Active FR3087778B1 (fr)

Priority Applications (8)

Application Number Priority Date Filing Date Title
FR1859955A FR3087778B1 (fr) 2018-10-26 2018-10-26 Composition de polymere adaptee pour moulage par injection comprenant des particules et un colorant, son procede de preparation et son utilisation
MX2021004557A MX2021004557A (es) 2018-10-26 2019-10-25 Composicion polimerica adecuada para moldeo por inyeccion que comprende particulas y colorante, su metodo de preparacion y su uso.
PCT/EP2019/079159 WO2020084110A1 (fr) 2018-10-26 2019-10-25 Composition polymère appropriée pour moulage par injection comprenant des particules et un colorant, son procédé de préparation et son utilisation
US17/286,944 US20210380796A1 (en) 2018-10-26 2019-10-25 A polymer composition suitable for injection moulding comprising particles and colorant, its method of preparation and its use
JP2021522358A JP2022505712A (ja) 2018-10-26 2019-10-25 粒子及び着色剤を含む射出成形に適したポリマー組成物、その調製方法及びその使用
KR1020217015227A KR20210084514A (ko) 2018-10-26 2019-10-25 입자 및 착색제를 포함하는 사출 성형에 적합한 중합체 조성물, 이의 제조 방법 및 이의 용도
EP19797206.0A EP3870631A1 (fr) 2018-10-26 2019-10-25 Composition polymère appropriée pour moulage par injection comprenant des particules et un colorant, son procédé de préparation et son utilisation
CN201980086213.1A CN113286845A (zh) 2018-10-26 2019-10-25 包含颗粒和着色剂的适合注塑的聚合物组合物、其制备方法及其用途

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR1859955A FR3087778B1 (fr) 2018-10-26 2018-10-26 Composition de polymere adaptee pour moulage par injection comprenant des particules et un colorant, son procede de preparation et son utilisation

Publications (2)

Publication Number Publication Date
FR3087778A1 FR3087778A1 (fr) 2020-05-01
FR3087778B1 true FR3087778B1 (fr) 2021-07-23

Family

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FR1859955A Active FR3087778B1 (fr) 2018-10-26 2018-10-26 Composition de polymere adaptee pour moulage par injection comprenant des particules et un colorant, son procede de preparation et son utilisation

Country Status (8)

Country Link
US (1) US20210380796A1 (fr)
EP (1) EP3870631A1 (fr)
JP (1) JP2022505712A (fr)
KR (1) KR20210084514A (fr)
CN (1) CN113286845A (fr)
FR (1) FR3087778B1 (fr)
MX (1) MX2021004557A (fr)
WO (1) WO2020084110A1 (fr)

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE60333162D1 (de) 2002-01-22 2010-08-12 Arkema France Izierten materialien mit blockcopolymeren hergestellt durch kontrollierte freiradikalpolymerisation in anwesenheit von nitroxiden
US6893147B2 (en) * 2002-04-05 2005-05-17 General Electric Company Lamp lens or bezel with visual effect
JP2004050607A (ja) * 2002-07-19 2004-02-19 Sumitomo Chem Co Ltd 光拡散性樹脂積層板
DE10320318A1 (de) 2003-05-06 2004-12-02 Röhm GmbH & Co. KG Verfahren zur Herstellung von lichtstreuenden Formteilen mit hervorragenden optischen Eigenschaften
EP1927098B1 (fr) 2005-03-25 2018-05-23 Arkema France Dispositif illumine a del blanche et feuille de diffusion
EP1864274B1 (fr) 2005-03-25 2019-04-24 Arkema France Dispositif d'eclairage combinant une del et une feuille de diffusion
WO2007058810A2 (fr) * 2005-11-15 2007-05-24 Arkema France Composition thermoplastique diffusant de la lumiere blanche
EP2010604B1 (fr) 2006-04-14 2015-02-18 PolyOne Corporation Concentre de couleur liquide
KR100756676B1 (ko) 2006-11-23 2007-09-07 제일모직주식회사 실리콘계 미립자, 그 제조 방법, 및 그 미립자가 함유된열가소성 수지 조성물
JP2010518426A (ja) * 2007-02-02 2010-05-27 アルケマ フランス 多層スクリーン複合体
EP2888319A1 (fr) * 2012-08-21 2015-07-01 SABIC Innovative Plastics IP B.V. Article en plastique transparent
EP3046959B1 (fr) * 2013-09-16 2017-07-19 INEOS Styrolution Group GmbH Matières à mouler thermoplastiques noir foncé à brillance élevée et leur production
US9557445B2 (en) 2015-02-24 2017-01-31 Arkema France Optical diffusion blend materials for LED lighting
FR3054550B1 (fr) * 2016-07-29 2020-03-27 Arkema France Composition (meth)acrylique comprenant des particules, son procede de preparation et son utilisation en tant que melange maitre
JP2018095722A (ja) * 2016-12-13 2018-06-21 ユーエムジー・エービーエス株式会社 熱可塑性樹脂組成物、その製造方法および成形品

Also Published As

Publication number Publication date
EP3870631A1 (fr) 2021-09-01
MX2021004557A (es) 2021-06-15
WO2020084110A1 (fr) 2020-04-30
KR20210084514A (ko) 2021-07-07
US20210380796A1 (en) 2021-12-09
CN113286845A (zh) 2021-08-20
JP2022505712A (ja) 2022-01-14
FR3087778A1 (fr) 2020-05-01

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