FR3075809B1 - Procede de conversion de charges lourdes d’hydrocarbures avec recycle d’une huile desasphaltee - Google Patents

Procede de conversion de charges lourdes d’hydrocarbures avec recycle d’une huile desasphaltee Download PDF

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Publication number
FR3075809B1
FR3075809B1 FR1762868A FR1762868A FR3075809B1 FR 3075809 B1 FR3075809 B1 FR 3075809B1 FR 1762868 A FR1762868 A FR 1762868A FR 1762868 A FR1762868 A FR 1762868A FR 3075809 B1 FR3075809 B1 FR 3075809B1
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Prior art keywords
dao
hydroconversion
recycle
hydrocarbons
heavy loads
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FR1762868A
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FR3075809A1 (fr
Inventor
Joao Marques
Jan Verstraete
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IFP Energies Nouvelles IFPEN
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IFP Energies Nouvelles IFPEN
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Priority to FR1762868A priority Critical patent/FR3075809B1/fr
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Priority to US16/957,078 priority patent/US11149217B2/en
Priority to RU2020123948A priority patent/RU2801814C2/ru
Priority to PT188149041T priority patent/PT3728518T/pt
Priority to EP18814904.1A priority patent/EP3728518B1/fr
Priority to PL18814904.1T priority patent/PL3728518T3/pl
Priority to ES18814904T priority patent/ES2923131T3/es
Priority to CN201880090040.6A priority patent/CN111819268B/zh
Priority to PCT/EP2018/084052 priority patent/WO2019121073A1/fr
Publication of FR3075809A1 publication Critical patent/FR3075809A1/fr
Priority to SA520412257A priority patent/SA520412257B1/ar
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Publication of FR3075809B1 publication Critical patent/FR3075809B1/fr
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G67/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only
    • C10G67/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only
    • C10G67/04—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only including solvent extraction as the refining step in the absence of hydrogen
    • C10G67/0454—Solvent desasphalting
    • C10G67/0463—The hydrotreatment being a hydrorefining
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G21/00—Refining of hydrocarbon oils, in the absence of hydrogen, by extraction with selective solvents
    • C10G21/003—Solvent de-asphalting
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/14—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing with moving solid particles
    • C10G45/16—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing with moving solid particles suspended in the oil, e.g. slurries
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/22—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing with hydrogen dissolved or suspended in the oil
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
    • C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
    • C10G65/04—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1077—Vacuum residues
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/202—Heteroatoms content, i.e. S, N, O, P
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/205—Metal content
    • C10G2300/206—Asphaltenes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/30—Physical properties of feedstocks or products
    • C10G2300/301—Boiling range
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4006—Temperature
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4012—Pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4018—Spatial velocity, e.g. LHSV, WHSV
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4081—Recycling aspects
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/44—Solvents

Abstract

L'invention porte sur un procédé de conversion d'une charge lourde d'hydrocarbures contenant une fraction d'au moins 50% ayant une température d'ébullition d'au moins 300°C et contenant du soufre, du carbone Conradson, des métaux, et de l'azote, comportant au moins deux étapes d'hydroconversion successives, pouvant être séparées par une étape de séparation intermédiaire, et au moins une étape de désasphaltage d'une fraction lourde de l'effluent issu de l'hydroconversion, avec un recyclage d'au moins une partie de l'huile désasphaltée (DAO) lors de l'hydroconversion, en aval de la première étape d'hydroconversion. La DAO est soit recyclée à sa sortie du désasphalteur, soit après avoir subi une étape de fractionnement produisant une fraction lourde de la DAO qui constitue alors la partie de la DAO recyclée. Ce procédé permet d'améliorer simultanément le niveau de conversion et la stabilité des effluents liquides.
FR1762868A 2017-12-21 2017-12-21 Procede de conversion de charges lourdes d’hydrocarbures avec recycle d’une huile desasphaltee Active FR3075809B1 (fr)

Priority Applications (10)

Application Number Priority Date Filing Date Title
FR1762868A FR3075809B1 (fr) 2017-12-21 2017-12-21 Procede de conversion de charges lourdes d’hydrocarbures avec recycle d’une huile desasphaltee
PCT/EP2018/084052 WO2019121073A1 (fr) 2017-12-21 2018-12-07 Procede de conversion de charges lourdes d'hydrocarbures avec recycle d'une huile desasphaltee
PT188149041T PT3728518T (pt) 2017-12-21 2018-12-07 Método de conversão de cargas pesadas de hidrocarbonetos com reciclagem de um óleo desasfaltado
EP18814904.1A EP3728518B1 (fr) 2017-12-21 2018-12-07 Procédé de conversion de charges lourdes d'hydrocarbures avec recyclage d'une huile désasphaltée
PL18814904.1T PL3728518T3 (pl) 2017-12-21 2018-12-07 Sposób konwersji ciężkich surowców węglowodorowych z recyklingem oleju odasfaltowanego
ES18814904T ES2923131T3 (es) 2017-12-21 2018-12-07 Procedimiento de conversión de cargas pesadas de hidrocarburos con reciclaje de un aceite desasfaltado
US16/957,078 US11149217B2 (en) 2017-12-21 2018-12-07 Method for converting heavy hydrocarbon feedstocks with recycling of a deasphalted oil
RU2020123948A RU2801814C2 (ru) 2017-12-21 2018-12-07 Способ конверсии тяжелого углеводородного сырья с рециркуляцией деасфальтированного масла
CN201880090040.6A CN111819268B (zh) 2017-12-21 2018-12-07 将脱沥青油再循环的转化重质烃原料的方法
SA520412257A SA520412257B1 (ar) 2017-12-21 2020-06-18 طريقة لتحويل خامات التغذية الهيدروكربونية الثقيلة مع إعادة تدوير زيت مُزال الأسفلت

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1762868 2017-12-21
FR1762868A FR3075809B1 (fr) 2017-12-21 2017-12-21 Procede de conversion de charges lourdes d’hydrocarbures avec recycle d’une huile desasphaltee

Publications (2)

Publication Number Publication Date
FR3075809A1 FR3075809A1 (fr) 2019-06-28
FR3075809B1 true FR3075809B1 (fr) 2020-09-11

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FR1762868A Active FR3075809B1 (fr) 2017-12-21 2017-12-21 Procede de conversion de charges lourdes d’hydrocarbures avec recycle d’une huile desasphaltee

Country Status (9)

Country Link
US (1) US11149217B2 (fr)
EP (1) EP3728518B1 (fr)
CN (1) CN111819268B (fr)
ES (1) ES2923131T3 (fr)
FR (1) FR3075809B1 (fr)
PL (1) PL3728518T3 (fr)
PT (1) PT3728518T (fr)
SA (1) SA520412257B1 (fr)
WO (1) WO2019121073A1 (fr)

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US10604709B2 (en) 2017-02-12 2020-03-31 Magēmā Technology LLC Multi-stage device and process for production of a low sulfur heavy marine fuel oil from distressed heavy fuel oil materials
FR3101082B1 (fr) 2019-09-24 2021-10-08 Ifp Energies Now Procédé intégré d’hydrocraquage en lit fixe et d’hydroconversion en lit bouillonnant avec une séparation gaz/liquide améliorée
FR3104606B1 (fr) 2019-12-17 2021-11-19 Ifp Energies Now Procédé intégré d’hydrocraquage en lit fixe et d’hydroconversion en lit bouillonnant avec un recyclage de l’hydrogène optimisé
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FR3130836A1 (fr) * 2021-12-20 2023-06-23 IFP Energies Nouvelles Hydroconversion en lit bouillonnant ou hybride bouillonnant-entraîné d’une charge comportant une fraction plastique

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WO2013067315A1 (fr) * 2011-11-04 2013-05-10 Saudi Arabian Oil Company Procédé d'hydrocraquage avec séparation et purification d'hydrogène intermédiaire intégrées
FR2999599B1 (fr) * 2012-12-18 2015-11-13 IFP Energies Nouvelles Procede de conversion d'une charge hydrocarbonee lourde integrant un desaphaltage selectif avec recyclage de l'huile desasphaltee
FR3014110B1 (fr) * 2013-12-03 2015-12-18 Ifp Energies Now Procede de conversion d'une charge hydrocarbonee lourde integrant un desasphaltage selectif en cascade avec recyclage d'une coupe desasphaltee
FR3014897B1 (fr) * 2013-12-17 2017-04-07 Ifp Energies Now Nouveau procede integre de traitement de charges petrolieres pour la production de fiouls a basse teneur en soufre et en sediments
FR3030568B1 (fr) * 2014-12-18 2019-04-05 Axens Procede de conversion profonde de residus maximisant le rendement en gazole
FR3033797B1 (fr) 2015-03-16 2018-12-07 IFP Energies Nouvelles Procede ameliore de conversion de charges hydrocarbonees lourdes

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PL3728518T3 (pl) 2022-09-26
US11149217B2 (en) 2021-10-19
RU2020123948A3 (fr) 2022-01-21
WO2019121073A1 (fr) 2019-06-27
CN111819268A (zh) 2020-10-23
RU2020123948A (ru) 2022-01-21
ES2923131T3 (es) 2022-09-23
EP3728518B1 (fr) 2022-05-18
SA520412257B1 (ar) 2023-03-05
FR3075809A1 (fr) 2019-06-28
PT3728518T (pt) 2022-07-22
CN111819268B (zh) 2022-12-13
US20200339894A1 (en) 2020-10-29

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