FR3060323A1 - COMPOSITION COMPRISING AT LEAST TWO ANIONIC SURFACTANTS, NON-IONIC SURFACTANT AND AMPHOTERIC SURFACTANT, AND SOLID PARTICLES - Google Patents

Abstract

The present invention relates to a composition for the cosmetic treatment of keratinous fibers, in particular hair, comprising at least two anionic surfactants, at least one nonionic surfactant, at least one amphoteric surfactant, and solid particles. The invention also relates to a process for the cosmetic treatment of keratinous fibers, in particular for washing and / or conditioning and / or styling and / or hair dyeing, with the aid of such a composition, as well as a use implementing said composition.

Description

® FRENCH REPUBLIC

NATIONAL INSTITUTE OF INDUSTRIAL PROPERTY © Publication number:

(to be used only for reproduction orders)

©) National registration number

060 323

62579

COURBEVOIE © Int Cl ⁸ : A 61 K8 / 33 (2017.01), A 61 K8 / 46, 8/60, 8/92, 8/72, A 61 Q 5/00

A1 PATENT APPLICATION

©) Date of filing: 16.12.16. (© Priority: (© Applicant (s): L'OREAL Société anonyme— FR. @ Inventor (s): MATHONNEAU ESTELLE. ©) Date of public availability of the request: 06.22.18 Bulletin 18/25. ©) List of documents cited in the preliminary search report: See the end of this booklet (© References to other related national documents: ©) Holder (s): L'OREAL Société anonyme. ©) Extension request (s): (© Agent (s): L'OREAL Société anonyme.

COMPOSITION COMPRISING AT LEAST TWO ANIONIC SURFACTANTS, A NON - IONIC SURFACTANT AND AN AMPHOTERIC SURFACTANT, AND SOLID PARTICLES.

FR 3 060 323 - A1 (6 /) The present invention relates to a composition intended for the cosmetic treatment of keratin fibers, in particular hair, comprising at least two anionic surfactants, at least one nonionic surfactant, at least one amphoteric surfactant, and solid particles.

The invention also relates to a cosmetic treatment process for keratin fibers, in particular for washing and / or conditioning and / or styling and / or coloring hair, using such a composition, as well as a use using said composition.

i

The present invention relates to a composition intended for the cosmetic treatment of keratin fibers, in particular human keratin fibers such as the hair, comprising at least two distinct anionic surfactants, at least one nonionic surfactant, at least one amphoteric surfactant, and one or more types of solid particles. The invention also relates to a method of cosmetic treatment of keratin fibers using such a composition, as well as to a use using said composition.

It is known to use care and / or washing compositions for keratin fibers using solid particles in order to improve the cosmetic properties of the hair, for example the styling, coloring or anti-greasy properties. .

However, these hair compositions are not necessarily entirely satisfactory and can still be improved, in particular concerning the deposition of these solid particles on the keratin fibers.

Furthermore, the hair compositions of the prior art generally do not give complete satisfaction in terms of foaming power and / or in terms of cosmetic properties, generally expected for compositions for washing keratin fibers.

There is therefore a real need to develop hair compositions intended for cleaning and conditioning keratin fibers which are also capable of imparting improved cosmetic and / or styling and / or coloring and / or anti-grease properties to the hair, after one or more applications, without load or weighing down the hair, while retaining good washing power, in particular good foaming power (abundant foam, generated quickly) and satisfactory qualities of use (ease of spreading the composition over the especially wet hair, good rinsability).

This object is achieved by the present invention which relates in particular to a cosmetic composition, preferably a hair composition, in particular intended for the cosmetic treatment of keratin fibers, in particular human keratin fibers such as the hair, comprising:

(i) one or more anionic surfactants chosen from polyoxyalkylenated alkyl (amido) ether carboxylic acids and / or their salts;

(ii) one or more anionic surfactants different from the polyoxyalkylenated alkyl (amido) ether carboxylic acid anionic surfactant (s) (i);

(iii) one or more nonionic surfactants;

(iv) one or more amphoteric surfactants; and (v) one or more types of solid particles.

It has been found that the composition according to the invention has a satisfactory foaming power. It provides an abundant foam, quickly generated, which spreads easily on the keratin fibers and which is easily removed on rinsing.

Some users of shampoos may have more or less sensitized hair, that is to say hair which is generally damaged or weakened by the action of external atmospheric agents such as light and bad weather, and / or the action of mechanical or chemical treatments such as brushing, combing, dyeing, bleaching, perms and / or straightening. Also, the composition according to the invention also makes it possible to improve the cosmetic properties imparted to keratin fibers, in particular to the hair, preferably sensitized. In particular, the composition according to the invention makes it possible to improve the contribution of body, mass and texture, as well as the suppleness and the feel of the hair, without build-up effect.

Furthermore, the compositions according to the invention have a relatively non-aggressive character, their application in the long term to the hair fiber resulting in little damage linked in particular to the progressive elimination of the lipids or proteins contained in or on the surface of the latter. .

In addition, the composition according to the invention allows good deposition of solid particles on the keratin fibers and thus makes it possible to obtain better effectiveness in terms of styling, coloring and / or anti-grease effects.

In addition, the composition according to the invention can confer residual cosmetic and / or styling and / or coloring and / or anti-greasy properties to shampoos.

The composition according to the invention also has the advantage of being stable in storage both at room temperature (20-25 ° C) and at 45 ° C, especially in terms of its visual appearance and / or its viscosity.

By "stable" is meant within the meaning of the present invention a composition which, after two months of storage has no change in appearance, color, odor, viscosity or pH.

In what follows, and unless otherwise indicated, the limits of a domain of values are included in this domain, in particular in the expressions "included between" and "going from ... to ...".

Furthermore, the expression "at least one" used in the present description is equivalent to the expression "one or more" and may be substituted for it.

Anionic surfactants

As indicated above, the composition according to the invention comprises at least one anionic surfactant of alkyl (amido) polyoxyalkylenated carboxylic ether type (i) and at least one anionic surfactant (ii) different from the anionic surfactant (s) (i).

Thus, within the meaning of the invention, the cosmetic composition comprises at least two distinct anionic surfactants.

The term “anionic surfactant” is intended to mean a surfactant comprising, as a group, ionic or ionizable elements only anionic groups.

In the present description, an entity is qualified as being anionic when it has at least one permanent negative charge or when it can be ionized into a negatively charged entity, under the conditions of use of the composition of the invention (medium , pH for example) and not comprising a cationic charge.

Polvoxyalkylenated alkyl (amido) ether carboxylic acids (i)

The composition of the invention contains at least one anionic surfactant chosen from polyoxyalkylenated alkyl (amido) ether carboxylic acids and their salts, in particular those comprising from 2 to 50 alkylene oxide groups, in particular ethylene.

The polyoxyalkylenated alkyl (amido) ether carboxylic acids capable of being used are preferably chosen from those of formula (1):

^ - (OC.HJ — OCH ₂ COOA (1) in which:

- R1 represents a linear or branched C6-C24 alkyl or alkenyl radical, a (C8-C9) phenyl alkyl radical, an R2CONH-CH2-CH2- radical with R2 denoting a linear or branched C9-C21 alkyl or alkenyl radical;

preferably R1 is a C8-C20, preferably C8-C18 alkyl radical, and aryl preferably denotes phenyl,

- n is an integer or decimal number (average value) varying from 2 to 24, preferably from 2 to 10,

- A denotes H, ammonium, Na, K, Li, Mg, Ca or a monoethanolamine or triethanolamine residue.

It is also possible to use mixtures of compounds of formula (1), in particular mixtures of compounds having different R1 groups.

Particularly preferred polyoxyalkylenated alkyl (amido) ether carboxylic acids are those of formula (1) in which:

- R1 denotes a C12-C14 alkyl, cocoyl, oleyl, nonylphenyl or octylphenyl radical,

- A denotes a hydrogen or sodium atom, and

- n varies from 2 to 20, preferably 2 to 10.

Even more preferably, compounds of formula (1) are used in which R denotes a C 12 alkyl radical, A denotes a hydrogen or sodium atom and n varies from 2 to 10.

Polyoxyalkylenated alkyl ether (C6-C24) ether carboxylic acids and their salts are preferably used, polyoxyalkylenated alkyl (C6-C24) amido ether carboxylic acids, in particular those containing from 2 to 15 alkylene oxide groups, and their salts and their mixtures.

When the anionic surfactant is in the form of a salt, said salt can be chosen from alkali metal salts such as the sodium or potassium salt, ammonium salts, salts of amines and in particular amino alcohols, and alkaline earth metal salts such as the magnesium salt.

As examples of amino alcohol salts, mention may be made of the mono-, di- and triethanolamine salts, the mono-, di- or tri-isopropanolamine salts, the 2amino 2-methyl 1-propanol, 2-amino 2 salts -methyl 1,3-propanediol and tris (hydroxymethyl) amino methane.

The alkali or alkaline earth metal salts are preferably used, and in particular the sodium or magnesium salts.

Among the commercial products, it is possible to use preferably the products sold by the company KAO under the names:

ΑΚΥΡΟ® NP 70 (Ri = nonylphenyl, n = 7, A = H)

ΑΚΥΡΟ® NP 40 (Ri = nonylphenyl, n = 4, A = H)

AKYPO®OP 40 (Ri = octylphenyl, n = 4, A = H)

ΑΚΥΡΟ® OP 80 (Ri = octylphenyl, n = 8, A = H)

ΑΚΥΡΟ® OP 190 (Ri = octylphenyl, n = 19, A = H)

ΑΚΥΡΟ® RLM 38 (Ri = C12-C14 alkyl, n = 4, A = H)

ΑΚΥΡΟ® RLM 38 NV (Ri = C12-C14 alkyl, n = 4, A = Na)

ΑΚΥΡΟ® RLM 45 CA (Ri = C12-C14 alkyl, n = 4.5, A = H)

ΑΚΥΡΟ® RLM 45 NV (Ri = C12-C14 alkyl, n = 4.5, A = Na)

ΑΚΥΡΟ® RLM 100 (Ri = C12-C14 alkyl, n = 10, A = H)

ΑΚΥΡΟ® RLM 100 NV (Ri = C12-C14 alkyl, n = 10, A = Na)

ΑΚΥΡΟ® RLM 130 (Ri = C12-C14 alkyl, n = 13, A = H)

ΑΚΥΡΟ® RLM 160 NV (Ri = C12-C14 alkyl, n = 16, A = Na), or by the company SANDOZ under the names:

SANDOPAN DTC-Acid (Ri = C13 alkyl, n = 6, A = H)

SANDOPAN DTC (Ri = C13 alkyl, n = 6, A = Na)

SANDOPAN LS 24 (Ri = C12-C14 alkyl, n = 12, A = Na)

SANDOPAN JA 36 (Ri = C13 alkyl, n = 18, A = H), and more particularly, the products sold under the following names: ΑΚΥΡΟ® RLM 45 (INCI: Laureth-5 carboxylic acid)

AKYPO®RLM100

ΑΚΥΡΟ® RLM 38.

The composition according to the invention preferably comprises said polyoxyalkylenated alkyl (amido) ether carboxylic acid (s) and / or their salts, in a total amount ranging from 0.05 to 30% by weight, preferably from 0.1 to 25% by weight, better still from 0.5 to 20% by weight and preferably from 1 to 10% by weight relative to the total weight of the composition.

Additional anionic surfactants (ii)

As indicated above, the composition according to the invention comprises at least one additional anionic surfactant, different from the polyoxyalkylenated alkyl (amido) ether carboxylic acids and their salts (i) described above.

Preferably, the additional anionic surfactants (ii) used in the composition according to the invention are chosen from anionic surfactants comprising in their structure one or more sulphate and / or sulphonate and / or phosphates, and / or carboxylate groups, and / or their mixtures, preferably sulfates.

The anionic surfactant (s) (ii) can be oxyethylenated and / or oxypropylenated. The total average number of ethylene oxide (EO) and / or propylene oxide (OP) groups can then vary from 1 to 50 and in particular from 1 to 10.

The anionic carboxylic surfactants capable of being used therefore comprise at least one carboxylic or carboxylate function.

They can be chosen from the following compounds: acylglycinates, acyllactylates, acylsarcosinates, acylglutamates; alkyl-D-galactosideuronic acids; as well as the salts of these compounds; the alkyl and / or acyl groups of these compounds containing from 6 to 30 carbon atoms, in particular from 12 to 28, better still from 14 to 24, or even from 16 to 22, carbon atoms; these compounds possibly being polyoxyalkylenated, in particular polyoxyethylenated and then preferably comprising from 1 to 50 ethylene oxide units, better still from 1 to 10 ethylene oxide units.

It is also possible to use C6-C24 alkyl monoesters and polyglycoside-polycarboxylic acids such as C6-C24 alkyl polyglycoside-citrates, C6-C24 alkyl polyglycoside-tartrates and polyglycoside-sulfosuccinates of C6-C24 alkyl, and their salts.

Preferably, the anionic carboxylic surfactants are chosen from, alone or as a mixture:

- acylglutamates, in particular C6-C24, or even C12-C20, such as stearoylglutamates, and in particular disodium stearoylglutamate;

- acylsarcosinates, in particular C6-C24, or even C12-C20, such as palmitoylsarcosinates, and in particular sodium palmitoylsarcosinate;

- acyllactylates, in particular C12-C28, or even C14-C24, such as behenoyllactylates, and in particular sodium behenoyllactylate;

- C6-C24 acylglycinates, especially C12-C20;

in particular in the form of alkali or alkaline earth metal, ammonium or amino alcohol salts.

The anionic sulfonate surfactants capable of being used comprise at least one sulfonate function.

They can be chosen from the following compounds: alkylsulfonates, alkylamidesulfonates, alkylarylsulfonates, alpha-olefin sulfonates, paraffin sulfonates, alkylsulfosuccinates, alkylethersulfosuccinates, alkylamidesulfosuccinates, alkylsulfoacetates, N-acyltaurates; alkyl sulfolaurates; as well as the salts of these compounds;

the alkyl groups of these compounds containing from 6 to 30 carbon atoms, in particular from 12 to 28, even better from 14 to 24, or even from 16 to 22, carbon atoms; the aryl group preferably denoting a phenyl or benzyl group; these compounds possibly being polyoxyalkylenated, in particular polyoxyethylenated and then preferably comprising from 1 to 50 ethylene oxide units, better still from 2 to 10 ethylene oxide units.

Preferably, the anionic sulfonate surfactants are chosen from, alone or as a mixture:

- C6-C24 alkylsulfosuccinates, in particular C12-C20, in particular laurylsulfosuccinates.

- C6-C24 alkylethersulfosuccinates, especially C12-C20;

- (C6-C24) acylisethionates, preferably (C12-C18) acylisethionates, in particular in the form of alkali or alkaline-earth metal, ammonium or amino alcohol salts.

The anionic sulphate surfactants capable of being used comprise at least one sulphate function.

They can be chosen from the following compounds: alkyl sulphates, alkyl ether sulphates, alkylamidoether sulphates, alkylaryl polyethersulphates, monoglyceride sulphates; as well as the salts of these compounds;

the alkyl groups of these compounds containing from 6 to 30 carbon atoms, in particular from 12 to 28, even better from 14 to 24, or even from 16 to 22, carbon atoms; the aryl group preferably denoting a phenyl or benzyl group; these compounds possibly being polyoxyalkylenated, in particular polyoxyethylenated and then preferably comprising from 1 to 50 ethylene oxide units, better still from 2 to 10 ethylene oxide units.

Preferably, the anionic sulphate surfactants are chosen from, alone or as a mixture:

- alkyl sulfates, in particular C6-C24, or even C12-C20,

- alkyl ether sulfates, especially C6-C24, or even C12-C20, preferably comprising from 2 to 20 ethylene oxide units;

in particular in the form of alkali or alkaline earth metal, ammonium or amino alcohol salts.

When the anionic surfactant is in the form of a salt, said salt can be chosen from alkali metal salts such as the sodium or potassium salt, ammonium salts, salts of amines and in particular amino alcohols, and the alkaline earth metal salts such as the magnesium or calcium salt.

As examples of amino alcohol salts, mention may be made of the mono-, di- and triethanolamine salts, the mono-, di- or tri-isopropanolamine salts, the 2amino 2-methyl 1-propanol, 2-amino 2 salts -methyl 1,3-propanediol and tris (hydroxymethyl) amino methane.

The alkali or alkaline earth metal salts are preferably used, and in particular the sodium or magnesium salts.

Preferably, the additional anionic surfactants (ii) are chosen from, alone or as a mixture,

- C6-C24 alkyl sulphates, especially C12-C20,

- C6-C24 alkyl ether sulfates, especially C12-C20; preferably comprising from 2 to 20 ethylene oxide units;

- C6-C24 alkylsulfosuccinates, in particular C12-C20, in particular laurylsulfosuccinates.

- C6-C24 alkylethersulfosuccinates, especially C12-C20;

- (C6-C24) acylisethionates, preferably (C12-C18) acylisethionates,

- C6-C24 acylsarcosinates, especially C12-C20; in particular palmitoylsarcosinates;

- C6-C24 acylglutamates, in particular C12-C20;

- C6-C24 acylglycinates, especially C12-C20;

in particular in the form of alkali or alkaline earth metal, ammonium or amino alcohol salts.

Among the anionic surfactants (ii), it is preferred to use one or more sulphated anionic surfactants, preferably chosen from C8-C14 alkylsulphates and alkylsethersuliates and more particularly those of C12-C14, and very particularly lauryl (ether) sulphates.

Preferably, the anionic surfactant (s) (ii) are in the form of salts, and in particular of alkaline salts in particular of sodium salts, of ammonium salts, of amine salts including the amino alcohol salts, and / or magnesium salts. These salts preferably comprise from 2 to 5 groups of ethylene oxide.

More preferably used among these are sodium, triethanolamine, magnesium or ammonium (Ci2-Cu) alkyl sulfates, and / or sodium, ammonium or magnesium (Ci2Cu) alkyl sulfates , oxyethylenated, for example 1 to 10 moles of ethylene oxide.

Better still, the anionic surfactant (s) (ii) are chosen from alkyl (Ci2Cu) ethersulphates of sodium, ammonium or magnesium, oxyethylenated with 2.2 moles of ethylene oxide, as marketed under the name TEXAPON N702 by the company COGNIS.

The anionic surfactant (s) (ii) can be present in the composition according to the invention in a total content ranging from 0.05 to 30% by weight, preferably ranging from 0.1 to 25%, better still from 0.5 to 20% by weight. better from 1 to 15% by weight, relative to the total weight of the composition.

According to a particular embodiment, the total content of anionic surfactant (i) and (ii), of the composition according to the invention, is between 0.1 and 35% by weight, preferably between 1 and 25%, preferably between 5 and 15% by weight relative to the total weight of the composition.

Nonionic surfactants (iii)

As indicated above, the composition comprises one or more nonionic surfactants, preferably in a total content greater than or equal to 1% by weight relative to the total weight of the composition.

The nonionic surfactants can be chosen from:

- alcohols, alpha-diols and (C1-20) alkyl phenols, these compounds being polyethoxylated and / or polypropoxylated and / or polyglycerolated, the number of ethylene oxide and / or propylene oxide groups possibly ranging from 1 to 100, and the number of glycerol groups can range from 2 to 30; or else these compounds comprising at least one fatty chain comprising from 8 to 40 carbon atoms, in particular from 16 to 30 carbon atoms; in particular alcohols comprising at least one C8 to C40 alkyl chain, saturated or unsaturated, linear or branched, oxyethylenated comprising from 1 to 100 moles of ethylene oxide, preferably from 2 to 50, more particularly from 2 to 40 moles of ethylene oxide and having one or two fatty chains;

- condensates of ethylene oxide and propylene oxide on fatty alcohols;

- polyethoxylated fatty amides preferably having from 2 to 30 ethylene oxide units, polyglycerolated fatty amides comprising on average from 1 to 5 glycerol groups and in particular from 1.5 to 4;

- the ethoxylated sorbitan fatty acid esters preferably having from 2 to 40 ethylene oxide units,

- fatty acid esters of sucrose,

- esters of polyoxyalkylenated fatty acids, preferably polyoxyethylenated having from 2 to 150 moles of ethylene oxide including oxyethylenated vegetable oils,

- N- (C6-24 alkyl) glucamine derivatives,

- amine oxides such as oxides of (C10-14 alkyl) amines or oxides of N- (acyl C10-14) -aminopropylmorpholine.

Mention may also be made of nonionic surfactants of the alkyl (poly) glycoside type, in particular represented by the following general formula: R1O- (R2O) t- (G) v in which:

- R1 represents a linear or branched alkyl or alkenyl radical containing 6 to 24 carbon atoms, in particular 8 to 18 carbon atoms, or an alkylphenyl radical in which the linear or branched alkyl radical contains 6 to 24 carbon atoms, in particular 8 to 18 carbon atoms;

R2 represents an alkylene radical containing 2 to 4 carbon atoms,

- G represents a sugar unit comprising 5 to 6 carbon atoms,

-1 denotes a value ranging from 0 to 10, preferably from 0 to 4,

- v denotes a value ranging from 1 to 15, preferably from 1 to 4.

Preferably, the alkyl (poly) glycoside surfactants are compounds of formula described above in which:

- R1 denotes a saturated or unsaturated, linear or branched alkyl radical containing from 8 to 18 carbon atoms,

R2 represents an alkylene radical containing 2 to 4 carbon atoms,

-1 denotes a value ranging from 0 to 3, preferably equal to 0,

- G denotes glucose, fructose or galactose, preferably glucose;

- The degree of polymerization, that is to say the value of v, which can range from 1 to 15, preferably from 1 to 4; the average degree of polymerization being more particularly between 1 and 2.

The glucosidic bonds between the sugar units are generally of type 1-6 or 1-4, preferably of type 1-4. Preferably, the alkyl (poly) glycoside surfactant is an alkyl (poly) glucoside surfactant. Particularly preferred are C8 / C16- (poly) glucosides 1,4, and especially decylglucosides and caprylyl / capryl glucosides.

Among the commercial products, mention may be made of the products sold by the company COGNIS under the names PLANTAREN® (600 CS / U, 1200 and 2000) or PLANTACARE® (818, 1200 and 2000); the products sold by SEPPIC under the names ORAMIX CG 110 and ORAMIX® NS 10; the products sold by the company BASF under the name LUTENSOL GD 70 or the products sold by the company CHEM Y under the name AGIO LK.

Preferably, C8 / C16- (poly) glycoside 1,4 alkyls are used, in particular in a 53% aqueous solution, such as those sold by COGNIS under the reference PLANTACARE® 818 UP.

Preferably, the nonionic surfactants are chosen from, alone or as a mixture:

- oxyethylenated fatty alcohols, comprising at least one Cs to C40 alkyl chain, in particular C8-C20, even better in C10-C18, saturated or not, linear or branched, and comprising from 1 to 100 moles of oxide of ethylene, preferably from 2 to 50, more particularly from 2 to 40 moles, or even from 3 to 20 moles of ethylene oxide; in particular lauric alcohol with 4 moles of ethylene oxide (INCI name: LAURETH-4) and lauric alcohol with 12 moles of ethylene oxide (INCI name: LAURETH-12), and

- (C6-C24 alkyl) (poly) glycosides, and more particularly (alkyl C83060323 ίο

C18) (poly) glycosides.

Even better, the nonionic surfactants are preferably chosen from alcohols comprising at least one C8-C20, better still CIOCI 8 alkyl chain, oxyethylenated comprising from 2 to 50, in particular from 3 to 20 moles of ethylene oxide.

According to a preferred embodiment of the invention, the composition comprises at least two nonionic surfactants, preferably chosen from alcohols comprising at least one C8-C20, better C10-C18 alkyl chain, oxyethylenated comprising from 2 to 50 , in particular from 3 to 20 moles of ethylene oxide; and (C6-C24 alkyl) (poly) glycosides, and more particularly (C8C18 alkyl) (poly) glycosides.

Preferably, the nonionic surfactant (s) are present in the composition according to the invention in a total content ranging from 0.05 to 30% by weight, preferably ranging from 0.1% to 25% by weight, in particular ranging from 0.5 to 20%, even better from 1 to 15% by weight, even better from 2 to 10% by weight, relative to the total weight of the composition.

Amphoteric surfactants (iv)

As indicated above, the composition comprises one or more amphoteric surfactants, preferably present in a total content greater than or equal to 3% by weight relative to the total weight of the composition.

In particular, the amphoteric or zwitterionic surfactant (s) are non-silicone. They may in particular be derivatives of secondary or tertiary aliphatic amines, optionally quaternized, in which the aliphatic group is a linear or branched chain containing from 8 to 22 carbon atoms, said amine derivatives containing at least one anionic group such as , for example, a carboxylate, sulfonate, sulfate, phosphate or phosphonate group.

Mention may in particular be made of alkyl (C8-C ₂ o) betaines, alkyl (CsC ₂ o) sulfobetaines, alkyl (C8-C ₂ o) amidoalkyl (C3-C8) betaines and alkyl (C8-C ₂ o ) amidalkyl (C6-C8) sulfobetaines.

Among the derivatives of secondary or tertiary aliphatic amines, optionally quaternized which can be used, as defined above, mention may also be made of the following compounds of respective structures (II) and (III):

R _a -CONHCH2CH2-N ⁺ (Rb) (R _c ) -CH ₂ COO ·, M ⁺ , X (II) in which:

- R _a represents a C10 to C30 alkyl or alkenyl group derived from an acid R _a . COOH, preferably present in hydrolyzed coconut oil, a heptyl, nonyl or undecyl group;

- R _b represents a beta-hydroxyethyl group; and

- R _c represents a carboxymethyl group;

M ⁺ represents a cationic counter ion derived from an alkaline, alkaline earth metal, such as sodium, an ammonium ion or an ion derived from an organic amine, and

- X ′ represents an organic or inorganic anionic counter ion, such as that chosen from halides, acetates, phosphates, nitrates, (Ci-C4) alkyl sulfates, (Ci-C4) alkyl - or (Ci-C4) alkyl aryl- sulfonates, in particular methylsulfate and ethylsulfate; or else M ⁺ and X 'are absent;

R _a -CONHCH ₂ CH ₂ -N (B) (B ') (III) in which:

- B represents the group -CH ₂ CH ₂ OX ';

- B 'represents the group - (CH ₂ ) _Z Y', with z = 1 or 2;

- X 'represents the group -CH ₂ COOH, -CH ₂ -COOZ', -CH ₂ CH ₂ COOH, CH ₂ CH ₂ COOZ ', or a hydrogen atom;

- Y 'represents the group -COOH, -COOZ', -CH ₂ CH (OH) SO3H or the group CH ₂ CH (OH) SO ₃ -Z ';

- Z ’represents a cationic counter ion from an alkali or alkaline earth metal, such as sodium, an ammonium ion or an ion from an organic amine;

- R _a 'represents a Cio to C30 alkyl or alkenyl group of an acid R _a -COOH preferably present in coconut oil or in hydrolysed linseed oil, an alkyl group, in particular C17 and its form iso, an unsaturated C17 group.

These compounds are classified in the CTFA dictionary, 5th edition, 1993, under the names disodium cocoamphodiacetate, disodium lauroamphodiacetate, disodium caprylamphodiacetate, disodium capryloamphodiacetate, disodium cocoamphodipropionate, disodium lauroamphodipropionate, capryl disodium propopropate lauroamphodipropionic, cocoamphodipropionic acid.

By way of example, mention may be made of cocoamphodiacetate sold by the company RHODIA under the trade name MIRANOL® C2M concentrate.

One can also use compounds of formula (IV):

Ra ”-NHCH (Y”) - (CH ₂ ) _n CONH (CH ₂ ) _n -N (R _d ) (R _e ) (IV) in which:

- Y ”represents the group -COOH, -COOZ”, -CH ₂ -CH (OH) SO3H or the group CH ₂ CH (OH) SO ₃ -Z ”;

- R _d and R _e , independently of one another, represent a C1 to C4 alkyl or hydroxyalkyl radical;

- Z ”represents a cationic counter ion derived from an alkali or alkaline earth metal, such as sodium, an ammonium ion or an ion derived from an organic amine;

- R _a ”represents a C10 to C30 alkyl or alkenyl group of an acid R _a ” -COOH preferably present in coconut oil or in hydrolyzed linseed oil;

- n and n ', independently of one another, denotes an integer ranging from 1 to 3. Among the compounds of formula (II), mention may be made of the compound classified in the CTFA dictionary under the name sodium diethylaminopropyl cocoaspartamide and marketed by CHIMEX under the name CHIMEXANE HB.

These compounds can be used alone or in mixtures.

Among the amphoteric or zwitterionic surfactants, use is preferably made of alkyl (C8-C2o) betaines such as cocobetaine, alkyl (C8-C2o) amidoalkyl (C ₃ Csjbetaines such as cocamidopropylbetaine, and their mixtures, and the compounds of formula (IV) such as the sodium salt of lauryl amino diethylaminopropyl succinamate (INCI name: sodium diethylaminopropyl cocoaspartamide). Preferably, the amphoteric or zwitterionic surfactants are chosen from alkyl (C8-C2o) amidoalkyl (C ₃ -C8) betaines such than cocamidopropyl betaine.

Preferably, the amphoteric surfactant (s) is or are present in the composition according to the invention at a total content ranging from 0.1 to 50% by weight, preferably ranging from 1 to 20% by weight, even better from 3 to 15 % by weight, very particularly from 3.5 to 10% by weight, relative to the total weight of the composition.

Solid particles

The composition according to the invention comprises at least one type of solid particles preferably insoluble in said composition; it can obviously include several different types of solid particles.

Said solid particles are generally insoluble in water. By water insoluble is meant within the meaning of the present invention a compound whose solubility in water at 25 ° C and at atmospheric pressure is less than 0.1%, better still less than 0.001% by weight.

Preferably, the solid particle or particles of the invention are chosen from solid solid particles. By solid particles is meant non-hollow particles, that is to say different from particles comprising at least one continuous envelope (or a surface layer) and at least one central cavity.

Advantageously, the particles according to the invention have a number-average primary size ranging from 0.001 to 1000 μm, preferably from 0.01 to 700 μm, preferably from 0.5 to 200 μm, in particular from 1 to 20 μm, and even better from 5 to 10 pm.

Within the meaning of the present invention, the term “primary particle size” is understood to mean the maximum dimension which it is possible to measure between two diametrically opposite points of an individual particle. The particle size can be determined by transmission electron microscopy or from the measurement of the specific surface by the BET method or from a laser granulometry.

The particles used in the composition according to the invention can have different shapes, for example a shape of spheres, flakes, needles or platelets; preferably they are substantially spherical.

The composition according to the invention preferably comprises particles of one or more organic compounds, which can be natural or synthetic, generally polymeric and / or particles of one or more mineral compounds.

The particles of natural organic compounds can in particular be micronized fruit nuclei.

The particles of polymeric organic compounds can be particles of crosslinked polymers or not.

These polymers are preferably in the glassy state, that is to say that they have a glass transition temperature significantly higher than the ambient temperature or the temperature of use (for example the temperature of the human body).

The particles of one or more organic compounds which can be used in the cosmetic composition according to the invention can in particular be chosen from polyamide powders; powders of acrylic polymers, in particular of crosslinked sodium polyacrylate, of polymethyl methacrylate; powders of acrylic copolymers, in particular of polymethyl methacrylate / ethylene glycol dimethacrylate, of allyl polymethacrylate / ethylene glycol dimethacrylate, of ethylene glycol dimethacrylate / lauryl methacrylate, of polyacrylate / alkylacrylate; polystyrene powders; polyethylene powders, in particular polyethylene / acrylic acid; microbeads of silicone resin.

Mention may more particularly be made, as particles of organic compounds according to the invention:

- polyamide powders (Nylon®), for example those sold under the names “ORGASOL® 4000” and “ORGASOL® 2002 UD NAT COS 204” by the company ATOCHEM,

- powders of acrylic polymers, in particular of crosslinked sodium polyacrylate, such as for example those sold under the name ASAP 2000 by the company CHEMOAL or HYSORB M7055 for the company BASF, of polymethyl methacrylate, such as, for example, those sold under the name " COVABEAD ® LH85 "" COVABEAD ® PMMA "by the company SENSIENT or those marketed under the name" MICROPEARL ® MHB "," MICROPEARL® M 100 "," MICROPEARL® M 310 "marketed by the company MATSUMOTO,

powders of acrylic copolymers, in particular of polymethyl methacrylate / ethylene glycol dimethacrylate, such as those marketed under the name of "DOW CORNING 5640 MICROSPONGE ® SKIN OIL ADSORBER" by the company DOW CORNING, or those marketed under the name "GANZPEARL ® GMP-0800 "by the company AICA KOGYO, of allyl polymethacrylate / ethylene glycol dimethacrylate, such as those sold under the name" POLYPORE ® L200 "or" POLYPORE ® E200 "sold by the company AMCOL, of dimethacrylate copolymer d ethylene glycol / lauryl methacrylate, such as those marketed by "POLYTRAP ® 6603" by the company DOW CORNING, of polyacrylate / ethylhexylacrylate such as those marketed under the name "TECHPOLYMER ® ACX 806C" by the company SEKISUI,

- polystyrene powders such as those sold under the name POLYSPHERE 3,000 SP by the company PRESPERESE,

- polystyrene / dinvinylbenzene powders such as those sold under the name "TECHPOLYMER ® SBX8" by the company SEKISUI,

- styrene / acrylate copolymer powders such as those sold under the name "SUNSPHERES POWDER" by the company ROHM & HAAS,

- polyethylene powders, especially polyethylene / acrylic acid marketed under the name "FLOBEADS ®" by the company SUMITOMO, or polyethylene beads marketed under the name "MICROPOLY 220 L" by the company MICRO POWDERS,

- silicone resin microbeads, such as those marketed under the names "TOSPEARL ®" by the company TOSHIBA SILICONE, in particular "TOSPEARL ® 240A" and "TOSPEARL ® 120A".

Preferably, the particles of organic compounds (or organic particles) are chosen from polyamide powders, crosslinked sodium polyacrylate powders, polyethylene powders and polymethylmethacrylate powders.

Said organic particles can optionally be treated at the surface with a hydrophobic treatment agent. Thus the organic particles can be made hydrophobic by coating or chemical grafting with products such as: silicones, such as methicones or dimethicones; amino acids, N-acylated amino acids or their salts; metallic soaps such as aluminum dimyristate, the aluminum salt of hydrogenated tallow glutamate; fluorinated derivatives, such as for example perfluoroalkylphosphates, perfluoroalkylsilanes, hexafluoropropylene polyoxides, polyorganosiloxanes comprising perfluroalkyl perfluoropolyethers groups; lecithin, isopropyl triisostearoyl titanate; fatty acids like stearic acid.

The term alkyl mentioned in the above-mentioned compounds can denote in particular an alkyl group, linear, branched or cyclic comprising from 1 to 30 carbon atoms, in particular from 5 to 16 carbon atoms.

The N-acylated amino acids can comprise an acyl group comprising from 8 to 22 carbon atoms, such as for example a 2-ethyl hexanoyl, caproyl, lauroyl, myristoyl, palmitoyl, stearoyl and cocoyl group.

The salts of these compounds can be the salts of aluminum, magnesium, calcium, zirconium, zinc, sodium or potassium.

The amino acid can be, for example, lysine, glutamic acid or alanine.

By way of example, mention may be made of poly (methyl methacrylate) microspheres coated with isopropyl triisostearyl titanate of size 2-15 μm sold by Kobo under the reference BPA-5I5.

The particles of one or more mineral compounds (or mineral particles) capable of being used in the cosmetic composition according to the invention can be chosen from metal particles, oxides, inorganic salts, carbides, nitrides, borides and hydroxides.

By metallic particles is meant particles formed by metals, in particular chosen from alkaline earth metals, transition metals, rare earth metals and alloys of these metals.

Preferably, the metals used are boron, aluminum, copper, cadmium, silver, gold, indium, iron, platinum, nickel, molybdenum, silicon, titanium, tungsten, antimony, palladium, zinc, tin and the alloys of these metals. Among these metals, gold, silver, platinum, cadmium and the alloys of these metals are particularly preferred.

The particles of one or more mineral compounds can also be oxides. Mention may be made of the oxides of the elements of columns 1 to 14 of the periodic table of elements. In particular, there may be mentioned in particular the oxides of titanium, zinc, cerium, zirconium, aluminum and bismuth oxychloride. Among these compounds, zinc oxide is particularly preferred. The particles of one or more mineral compounds can be inorganic salts. Mention may in particular be made of barium sulfate, calcium carbonate, calcium sulfate, calcium phosphate, magnesium hydrocarbonate. Among these compounds, calcium carbonate is preferred.

Among the particles of one or more mineral compounds belonging to the species described above, mention may also be made of clays, silicates, alumina, silica, kaolin and hydroxyapatite.

In particular, the usable silicas can be natural and untreated. Mention may therefore be made of the silicas proposed under the names SILLITIN N85, SILLITIN N87, SILLITIN N82, SILLITIN V85 and SILLITIN V88 by the company HOFFMANN MINERAL, or SUNSIL 130 by the company SUNJIN CHEMICAL, MSS-500-3 H by the company Kobo, SUNSPHERE H 51 by the company AGC SI-TECH, the hollow particles of amorphous silica of ellipsoidal shape marketed by Kobo under the reference silica shells. They can be pyrogenic. Pyrogenic silicas can be obtained by high-temperature hydrolysis of a volatile silicon compound in an oxyhydrogen flame, producing a finely divided silica. This process makes it possible in particular to obtain hydrophilic silicas which have a large number of silanol groups on their surface.

It is possible to chemically modify the surface of said silica, by chemical reaction generating a reduction in the number of silanol groups. Silanol groups can in particular be substituted by hydrophobic groups; a hydrophobic silica is then obtained. The hydrophobic groups can be:

(a) trimethylsiloxyl groups, which are obtained in particular by treatment of fumed silica in the presence of hexamethyldisilazane. Silicas thus treated are called Silica silylate according to the CTFA (6th edition, 1995).

(b) dimethylsilyloxyl or polydimethylsiloxane groups, which are obtained in particular by treatment of fumed silica in the presence of polydimethylsiloxane or dimethyldichlorosilane. Silicas thus treated are called Silica dimethyl silylate according to the CTFA (6th edition, 1995).

In particular, among hydrophobic silicas, mention may be made of silica aerogels. Aerogels are ultra-light porous materials, the first of which were produced by Kristler in 1932. They are generally synthesized by a sol-gel process in a liquid medium and then dried by extraction of a supercritical fluid. The most commonly used supercritical fluid is supercritical CO2. This type of drying helps prevent contraction of the pores and material. Other types of drying also make it possible to obtain porous materials from gel, namely (i) freeze-drying, which consists in solidifying the gel at low temperature and then subliming the solvent and (ii) drying by evaporation . The materials thus obtained are called cryogels and xerogels respectively. The sol-gel process and the different dryings are described in detail in Brinker CJ., And Scherer G.W., Sol-Gel Science: New York: Academie Press, 1990.

The term “hydrophobic silica” means any silica whose surface is treated with silylating agents, for example with halogenated silanes such as alkyl chlorosilanes, siloxanes, in particular dimethylsiloxanes such as hexamethyldisiloxane, or silazanes, so as to functionalize the OH groups with silyl Si-Rn groups, for example trimethylsilyl groups.

Preferably, the hydrophobic airgel particles which can be used in the present invention advantageously have a specific surface area per unit mass (SM) ranging from 500 to 1500 m2 / g, preferably from 600 to 1200 m2 / g and better still from 600 at 800 m2 / g and / or have an oil absorption capacity measured at the WET POINT ranging from 5 to 18 ml / g of particles, preferably from 6 to 15 ml / g and better still from 8 to 12 ml / g .

The absorption capacity measured at the Wet Point, and noted Wp, corresponds to the amount of oil that must be added to 100 g of particles to obtain a homogeneous paste. It is measured according to the so-called Wet Point method or method for determining the intake of powder oil according to the principle described in standard NF T 30-022. It corresponds to the quantity of oil adsorbed on the available surface of the powder and / or absorbed by the powder by measuring the Wet Point, described below: a quantity m = 2 g of powder is placed on a glass plate and then added drip oil (isononyl isononanoate). After adding 4 to 5 drops of oil to the powder, mix with a spatula and continue adding oil until the oil and powder conglomerates form. From this point, add the oil one drop at a time and then triturate the mixture with the spatula. The addition of oil is stopped when a firm and smooth paste is obtained. This paste should be allowed to spread on the glass plate without cracks or lump formation. The volume Vs (expressed in ml) of oil used is then noted. The oil intake corresponds to the Vs / m ratio.

The hydrophobic silica airgel particles used according to the present invention are preferably silylated silica airgel particles (INCI name silica silylate).

The preparation of hydrophobic silica airgel particles modified on the surface by silylation is described further in document US Pat. No. 7,470,725. In particular, hydrophobic silica airgel particles modified on the surface by trimethylsilyl groups will be used.

The hydrophobic airgel particles which can be used in the present invention advantageously have a size, expressed in mean diameter (D [0.5 d), of less than 1500 μm and preferably ranging from 1 to 30 μm, preferably from 5 to 25 pm, better from 5 to 20 pm and even better still from 5 to 15 pm ..

The sizes of airgel particles according to the invention can be measured by static light scattering using a commercial granulometer of the MasterSizer 2000 type from Malvern. The data is processed on the basis of Mie diffusion theory. This theory, exact for isotropic particles, makes it possible to determine in the case of non-spherical particles, an "effective" diameter of particles. This theory is particularly described in the work of Van de Hulst, H.C., Light Scattering by Small Particles, Chapters 9 and 10, Wiley, New York, 1957.

According to an advantageous embodiment, the hydrophobic airgel particles used in the present invention have a specific surface per unit of mass (SM) ranging from 600 to 800 m2 / g and a size expressed in mean diameter by volume (D [0 , 5j) ranging from 5 to 20 pm, better from 5 to 15 pm.

According to a preferred embodiment, use will be made more particularly of VM-2270, the particles of which have an average size ranging from 5 to 15 microns and a specific surface per unit of mass ranging from 600 to 800 m2 / g.

The hydrophobic airgel particles used in the present invention may advantageously have a packed density p ranging from 0.04 g / cm3 to 0.10 g / cm3, preferably from 0.05 g / cm3 to 0.08 g / cm3 .

In the context of the present invention, this density can be assessed according to the following protocol, known as the packed density protocol: 40 g of powder are poured into a graduated cylinder and then the cylinder is placed on a STAV 2003 device from STAMPF VOLUMETER . The test piece is then subjected to a series of 2,500 settlements (this operation is repeated until the difference in volume between 2 consecutive tests is less than 2%); then the final volume Vf of packed powder is measured directly on the test piece. The packed density is determined by the mass (m) A / f ratio, in this case 40 / Vf (Vf being expressed in cm3 and m in g).

According to one embodiment, the hydrophobic airgel particles used in the present invention have a specific surface area per unit of volume SV ranging from 5 to 60 m2 / cm3, preferably from 10 to 50 m2 / cm3 and better still from 15 to 40 m2 / cm3.

The specific surface per unit of volume is given by the relation: SV = SM * p where p is the packed density expressed in g / cm3 and SM is the specific surface per unit of mass expressed in m2 / g, as defined above .

According to a preferred embodiment, the hydrophobic airgel particles according to the invention have a specific surface per unit mass (SM) ranging from 500 to 1500 m2 / g, preferably from 600 to 1200 m2 / g and better still from 600 at 800 m2 / g, and a size expressed in mean diameter (D [0.5 d) ranging from 1 to 30 μm and / or an oil absorption capacity measured at the WET POINT ranging from 5 to 18 ml / g of particles, preferably from 6 to 15 ml / g and better still from 8 to 12 ml / g.

As hydrophobic silica aerogels which can be used in the invention, mention may be made, for example, of the airgel marketed under the name VM-2260 (name INCI Silica silylate) by the company Dow Corning, the particles of which have an average size d '' about 1000 microns and a specific surface per unit of mass ranging from 600 to 800 m2 / g.

We can also cite the aerogels marketed by Cabot under the references AEROGEL TLD 201, AEROGEL OGD 201 and AEROGEL TLD 203, ENOVA AEROGEL MT 1100, ENOVA AEROGEL MT 1200.

Use will be made more particularly of the airgel marketed under the name VM-2270 (name INCI Silica silylate), by the company Dow Corning, whose particles have an average size ranging from 5 to 15 microns and a specific surface area per unit mass ranging from 600 to 800 m2 / g.

The mineral particles according to the invention can also be clay particles.

Clays are products already well known in themselves, which are described for example in the book Mineralogy of clays, S. Caillère, S. Hénin, M. Rautureau, 2 ^nd edition 1982, Masson.

The clays are silicates containing a cation which can be chosen from calcium, magnesium, aluminum, sodium, potassium, lithium cations and their mixtures.

Mention may in particular be made of clays of the smectite family such as montmorillonites, hectorites, bentonites, beidellites, saponites, as well as of the family of vermiculites, stevensite and chlorites.

Clays can be of natural or synthetic origin. Preferably, clays are used which are cosmetically compatible and acceptable with keratin fibers such as the hair.

The clay can be chosen from montmorillonite, bentonite, hectorite, attapulgite, sepiolite, and their mixtures. Preferably, the clay is a bentonite or a hectorite.

The clays can be chosen from organophilic clays. Organophilic clays are clays modified with a chemical compound chosen from quaternary amines, tertiary amines, amino acetates, imidazolines, amino soaps, fatty sulfates, alkyl aryl sulfonates, amine oxides, and mixtures thereof. Preferably, the organophilic clays according to the invention are clays modified with a chemical compound chosen from quaternary amines. As organophilic clays, mention may be made of quaternium-18 bentonites such as those sold under the names Bentone 3, Bentone 38, Bentone 38V by the company Elementis, Tixogel VP by the company United catalyst, Claytone 34, Claytone 40, Claytone XL by Southern Clay company; stearalkonium bentonites such as those sold under the names Bentone 27V by the company Elementis, Tixogel LG by the company United Catalyst, Claytone AF, Claytone APA by the company Southern Clay and the quaternium-18 / benzalkonium bentonite such as those sold under the names Claytone HT, Claytone PS by the company Southern Clay. The organophilic clay is in particular chosen from modified hectorites such as hectorite modified with ammonium chloride of C10-C12 fatty acid, in particular distearyl dimethylammonium chloride and benzyldimethylammonium stearyl chloride.

Preferably, the particles of one or more mineral compounds are chosen from calcium carbonate, silica and in particular silica aerogels.

The solid particles, in particular insoluble in water, can also be chosen from pigments, in particular pearlescent pigments such as colored pearlescent pigments such as mica coated with titanium and iron oxides, mica coated with oxide of iron, mica coated with titanium and especially with ferric blue or chromium oxide, mica coated with titanium as well as pearlescent pigments based on bismuth oxychloride. As pearlescent pigments, mention may be made of Cellini nacres sold by Engelhard (Mica-TiO2-lacquer), Prestige sold by Eckart (Mica-TiC ^), Prestige Bronze sold by Eckart (Mica-Fe ₂ O3), Colorona sold by Merck ( Mica-TiO2-Fe2O3); the gold-colored nacres sold in particular by the ENGELHARD company under the name of Brillant gold 212G (Timica), Gold 222C (Cloisonne), Sparkle gold (Timica), Gold 4504 (Chromalite) and Monarch gold 233X (Cloisonne); the bronze nacres sold in particular by the company MERCK under the name Bronze fine (17384) (Colorona) and Bronze (17353) (Colorona) and by the company ENGELHARD under the name Super bronze (Cloisonne); the orange nacres, in particular commerc3060323, sold by the company ENGELHARD under the name Orange 363C (Cloisonne) and Orange MCR 101 (Cosmica) and by the company MERCK under the name Passion orange (Colorona) and Matte orange (17449) (Microna); the brown-colored mother-of-pearl in particular sold by the company ENGELHARD under the name Nu-antique copper 340XB (Cloisonne) and Brown CL4509 (Chromante); copper reflective nacres sold in particular by ENGELHARD under the name Copper 340A (Timica); the mother-of-pearl with a red reflection, in particular sold by the company MERCK under the name Sienna fine (17386) (Colorona); the yellow-reflective nacres sold in particular by the company ENGELHARD under the name Yellow (4502) (Chromalite); the red-colored pearls with a gold reflection, in particular sold by the company ENGELHARD under the name Sunstone G012 (Gemtone); pink mother-of-pearl, in particular sold by ENGELHARD under the name Tan opal G005 (Gemtone); black mother-of-pearl with gold reflection in particular marketed by ENGELHARD under the name Nu antique bronze 240 AB (Timica), blue mother-of-pearl in particular marketed by MERCK under the name Matte blue (17433) (Microna), white mother-of-pearl with reflection silvery in particular marketed by the company MERCK under the name Xirona Silver and the pinkish orange-pink gold-green nacres in particular marketed by the company MERCK under the name Indian summer (Xirona) and their mixtures.

Among the pearlescent agents, there may be mentioned more particularly:

- polyol esters having at least two carbon atoms and long chain fatty acids, preferably C10-C30 and even more preferably C16-C22; such as mono or diesters of polyols and fatty acids; preferably the polyols are ethylene glycol and the polyalkylene glycol having from 2 to 10 ethylene oxide units;

- ethers of long chain fatty alcohols solid at a temperature less than or equal to about 30 ° C such as for example the dialkyl ethers of formula: RO-R ', in which R and R', identical or different, denote a radical alkyl, saturated or unsaturated, linear or branched, containing from 10 to 30 carbon atoms and preferably from 14 to 24 carbon atoms, R and R 'being chosen such that the compound is solid at a temperature less than or equal to 30 ° C approximately.

More particularly, R and R ′ denote a stearyl radical. A distearyl ether which can be used in the context of the present invention is sold under the name CUTINA STE by the company HENKEL;

- cyclodextrins and in particular β-cyclodextrin.

The pearlescent agents are preferably chosen from ethylene glycol mono- or distearate (or glycol distearate), distearyl ether, 1- (hexadecyloxy) -2octadecanol, β-cyclodextrin and their mixtures.

Preferably, the composition according to the invention comprises solid particles chosen from silicas, clays, pigments, pearlescent agents, and very particularly from silicas, clays and pigments, and their mixtures.

The solid particles are preferably present in the composition in an amount ranging from 0.001 to 15% by weight, preferably from 0.1 to 10% by weight, better still from 0.5 to 8% by weight, relative to the total weight of the composition.

Cationic polymers

The cosmetic composition can also comprise one or more cationic polymers, preferably having a cationic charge density greater than or equal to 4 milliequivalents / gram (meq / g).

The cationic charge density of a polymer corresponds to the number of moles of cationic charges per unit mass of polymer under the conditions where it is fully ionized. It can be determined by calculation if the structure of the polymer is known, that is to say the structure of the monomers constituting the polymer and their molar or weight proportion. It can also be determined experimentally by the Kjeldahl method.

Within the meaning of the present invention, the expression cationic polymer designates any non-silicone polymer (not comprising a silicon atom) containing cationic groups and / or groups which can be ionized into cationic groups, and which does not contain anionic groups and / or groups which can be ionized into anionic groups.

The cationic polymers capable of being used preferably have a weight-average molar mass (Mw) of between 500 and 5.10 ⁶ approximately, preferably between 10 ³ and 3.10 ⁶ approximately.

Among the cationic polymers, there may be mentioned more particularly:

(1) homopolymers or copolymers derived from acrylic or methacrylic esters or amides and comprising at least one of the units of the following formula:

r ₃ ch ₂ -ç— o = c

I

NH

I - ch ₂ -c -

I o = c

I

NH

I

AT

R — N - ^R 6

N r T ³ - ^CH 2 ^- ç— —CH ₂ -C -

O = ç o4? ?

A TO ^x I i

NR ₄ —N + —R ₆ / \ I r ₂ r, r ₅ in which:

- R3, identical or different, denote a hydrogen atom or a CH3 radical;

- A, identical or different, represent a divalent alkyl group, linear or branched, from 1 to 6 carbon atoms, preferably 2 or 3 carbon atoms or a hydroxyalkyl group from 1 to 4 carbon atoms;

- R4, R5, R6, identical or different, represent an alkyl group having from 1 to 18 carbon atoms or a benzyl radical; preferably an alkyl group having 1 to 6 carbon atoms;

- R1 and R2, identical or different, represent a hydrogen atom or an alkyl group having from 1 to 6 carbon atoms, preferably methyl or ethyl;

- X denotes an anion derived from a mineral or organic acid such as a methosulfate anion or a halide such as chloride or bromide.

The copolymers of family (1) can also contain one or more units deriving from comonomers which can be chosen from the family of acrylamides, methacrylamides, diacetones, acrylamides, acrylamides and methacrylamides substituted on nitrogen by lower alkyls (C1-C4) , esters of acrylic or methacrylic acids, vinyllactams such as vinylpyrrolidone or vinylcaprolactam, vinyl esters.

Among these copolymers of family (1), there may be mentioned:

- copolymers of acrylamide and of dimethylaminoethyl methacrylate quaternized with dimethyl sulphate or with a dimethyl halide, such as that sold under the name HERCOFLOC by the company HERCULES,

- copolymers of acrylamide and methacryloyloxyethyltrimethylammonium chloride, such as those sold under the name BINA QUAT P 100 by the company CIBA GEIGY,

- the copolymer of acrylamide and methacryloyloxyethyltrimethylammonium methosulfate, such as that sold under the name RETEN by the company HERCULES,

- vinylpyrrolidone / acrylate or dialkylaminoalkyl acrylate or methacrylate, quaternized or not, such as the products sold under the name GAFQUAT by the company ISP, for example GAFQUAT 734 or GAFQUAT 755 or else the products called COPOLYMER 845, 958 and 937. These poly3060323 mothers are described in detail in French patents 2,077,143 and 2,393,573;

- dimethylaminoethyl methacrylate / vinylcaprolactam / vinylpyrrolidone terpolymers, such as the product sold under the name GAFFIX VC 713 by the company ISP,

- vinylpyrrolidone / methacrylamidopropyldimethylamine copolymers, such as those marketed under the name STYLEZE CC 10 by ISP;

- vinylpyrrolidone / methacrylamide dimethylaminopropyl quaternized copolymers, such as the product sold under the name GAFQUAT HS 100 by the company ISP,

- polymers, preferably crosslinked, of methacryloyloxyalkyl (C1-C4) trialkyl (C1-C4) ammonium salts such as the polymers obtained by homopolymerization of dimethylaminoethylmethacrylate quaternized with methyl chloride, or by copolymerization of acrylamide with dimethylaminoethylmethacrylate quaternized by methyl chloride, the homo- or copolymerization being followed by crosslinking with an olefinically unsaturated compound, in particular methylene bisacrylamide. One can more particularly use a crosslinked acrylamide / methacryloyloxyethyltrimethylammonium chloride copolymer (20/80 by weight) in the form of a dispersion comprising 50% by weight of said copolymer in mineral oil. This dispersion is marketed under the name of SALCARE® SC 92 by the company CIBA. It is also possible to use a crosslinked homopolymer of methacryloyloxyethyltrimethylammonium chloride comprising approximately 50% by weight of the homopolymer in mineral oil or in a liquid ester. These dispersions are marketed under the names SALCARE® SC 95 and SALCARE® SC 96 by the company CIBA.

(2) cationic polysaccharides, in particular celluloses and cationic galactomannan gums. Among the cationic polysaccharides, there may be mentioned more particularly the cellulose ether derivatives comprising quaternary ammonium groups, the cationic cellulose copolymers or the cellulose derivatives grafted with a water-soluble quaternary ammonium monomer and the cationic galactomannan gums.

The cellulose ether derivatives comprising quaternary ammonium groups are described in particular in FR1492597, and mention may be made of the polymers marketed under the name UCARE POLYMER JR (JR 400 LT, JR 125, JR 30M) or LR (LR 400, LR 30M ) by the Company AMERCHOL. These polymers are also defined in the CTFA dictionary as quaternary ammoniums of hydroxyethylcellulose having reacted with an epoxide substituted by a trimethylammonium group.

Cationic cellulose copolymers or cellulose derivatives grafted with a water-soluble quaternary ammonium monomer, are described in particular in patent US4131576, and there may be mentioned hydroxyalkylcelluloses, such as hydroxymethyl-, hydroxyethyl- or hydroxypropyl celluloses grafted in particular with a salt methacryloylethyl trimethylammonium, methacrylamidopropyl trimethylammonium, dimethyl-diallylammonium. The products sold meeting this definition are more particularly the products sold under the name Celquat L 200 and Celquat H 100 by the National Starch Company. The cationic galactomannan gums are described more particularly in patents US Pat. No. 3,589,578 and US Pat. No. 4,031,307, and there may be mentioned guar gums comprising cationic trialkylammonium groups. Guar gums modified with a salt (for example a chloride) of 2,3-epoxypropyl trimethylammonium are used, for example. Such products are sold in particular under the names JAGUAR C13 S, JAGUAR C 15, JAGUAR C 17 or JAGUAR C162 by the company RHODIA.

(3) polymers consisting of piperazinyl units and divalent alkylene or hydroxyalkylene radicals with straight or branched chains, optionally interrupted by oxygen, sulfur, nitrogen atoms or by aromatic or heterocyclic rings, as well as the products of oxidation and / or quaternization of these polymers.

(4) water-soluble polyaminoamides, prepared in particular by polycondensation of an acidic compound with a polyamine; these polyaminoamides can be crosslinked with an epihalohydrin, a diepoxide, a dianhydride, an unsaturated dianhydride, a bis-unsaturated derivative, a bis-halohydrin, a bis-azetidinium, a bis-haloacyldiamine, a bis-halide of alkyl or also with an oligomer resulting from the reaction of a bifunctional compound reactive with a bishalohydrin, a bis-azetidinium, a bis-haloacyldiamine, an alkyl bis-halide, a epilhalohydrin, a diepoxide or a bisunsaturated derivative; the crosslinking agent being used in proportions ranging from 0.025 to 0.35 mol per amine group of the polyaminoamide; these polyaminoamides can be alkylated or, if they contain one or more tertiary amine functions, quaternized.

(5) polyaminoamide derivatives resulting from the condensation of polyalkylene polyamines with polycarboxylic acids followed by alkylation by bifunctional agents. Mention may be made, for example, of the adipic acid-diacoylaminohydroxyalkoyldialoylene triamine polymers in which the alkyl radical contains from 1 to 4 carbon atoms and preferably denotes methyl, ethyl, propyl. Among these derivatives, there may be mentioned more particularly the adipic acid / dimethylaminohydroxypropyl / diethylene triamine polymers sold under the name Cartaretine F, F4 or F8 by the company Sandoz.

(6) polymers obtained by reaction of a polyalkylene polyamine comprising two primary amine groups and at least one secondary amine group with a dicarboxylic acid chosen from diglycolic acid and saturated aliphatic dicarboxylic acids having from 3 to 8 carbon atoms; the molar ratio between the polyalkylene polyamine and the dicarboxylic acid preferably being between 0.8: 1 and 1.4: 1; the resulting polyaminoamide being reacted with epichlorohydrin in a molar ratio of epichlorohydrin relative to the secondary amine group of the polyaminoamide preferably between 0.5: 1 and 1.8: 1. Polymers of this type are in particular sold under the name Hercosett 57 by the company Hercules Inc. or else under the name of PD 170 or Delsette 101 by the company Hercules in the case of the copolymer of adipic acid / epoxypropyl / diethylene-triamine .

(7) cyclopolymers of alkyl diallyl amine or dialkyl diallyl ammonium such as homopolymers or copolymers comprising, as main constituent of the chain, units corresponding to formulas (I) or (II):

, (CH ₂ ) k

- (CH ₂ ) t - CR ₁₂ C (R ₁₂ ) -CH ₂ h ₂ c (i) \ Z

N +, / \

CH.

Y- (CH ₂ ) t - CR ₁₂ (II) h ₂ c

Ίο (CH ₂ ) k \

'10

C (R ₁₂ ) -CH ₂ CH.

in which

- k and t are equal to 0 or 1, the sum k + t being equal to 1;

- R12 denotes a hydrogen atom or a methyl radical;

- R10 and R11, independently of one another, denote a C1-C6 alkyl group, a C1-C5 hydroxyalkyl group, an C1-C4 amidoalkyl group; or alternatively R10 and R11 can denote, jointly with the nitrogen atom to which they are attached, a heterocyclic group such as piperidinyl or morpholinyl; R10 and R11, independently of one another, preferably denote a C1-C4 alkyl group;

- Y 'is an anion such as bromide, chloride, acetate, borate, citrate, tartrate, bisulfate, bisulfite, sulfate, phosphate.

Mention may more particularly be made of the homopolymer of dimethyldiallylammonium salts (for example chloride), for example sold under the name MERQUAT 100 by the company NALCO, and the copolymers of salts (for example chloride) of diallyldimethylammonium and of acrylamide sold in particular under the name name MERQUAT 550 or MERQUAT 7SPR.

(8) quaternary diammonium polymers comprising repeating units of formula:

N + -Æ-N + -B, I ¹ I 1

R X “^ 16

X14 in which:

- R13, R14, R15 and R16, identical or different, represent aliphatic, alicyclic or arylaliphatic radicals comprising from 1 to 20 carbon atoms or C1-C12 hydroxyalkylaliphatic radicals, or alternatively R13, R14, R15 and R16, together or separately, constitute with the nitrogen atoms to which they are attached heterocycles optionally comprising a second heteroatom other than nitrogen or else R13, R14, R15 and R16 represent a linear or branched C1-C6 alkyl radical substituted by a group nitrile, ester, acyl, amide or -CO-O-R17-D or -CO-NH-R17-D where R17 is an alkylene and D a quaternary ammonium group;

- A1 and B1 represent divalent polymethylenic groups comprising from 2 to 20 carbon atoms, linear or branched, saturated or unsaturated, and which may contain, linked to or inserted in the main chain, one or more aromatic rings, or one or more atoms oxygen, sulfur or sulfoxide, sulfone, disulfide, amino, alkylamino, hydroxyl, quaternary ammonium, ureido, amide or ester groups, and

- X denotes an anion derived from a mineral or organic acid;

it being understood that A1, R13 and R15 can form with the two nitrogen atoms to which they are attached a piperazine ring;

in addition if A1 denotes a linear or branched, saturated or unsaturated alkylene or hydroxyalkylene radical, B1 can also denote a group (CH2) n-CO-DOC- (CH2) p-, with n and p, identical or different, being integers varying from 2 to 20, and D denoting:

a) a glycol residue of formula -OZO-, where Z denotes a linear or branched hydrocarbon radical or a group corresponding to one of the following formulas: - (CH2CH2O) x-CH2CH2- and - [CH2CH (CH3) O] y-CH2CH (CH3) - where x and y denote an integer from 1 to 4, representing a defined and unique degree of polymerization or any number from 1 to 4 representing an average degree of polymerization;

b) a bis-secondary diamine residue such as a piperazine derivative;

c) a bis-primary diamine residue of formula -NH-Y-NH- where Y denotes a linear or branched hydrocarbon radical, or else the divalent radical -CH2-CH2-SS-CH2-CH2-;

d) a ureylene group of formula -NH-CO-NH-.

Preferably, X is an anion such as chloride or bromide. These polymers have a number-average molar mass (Mn) generally between 1000 and 100,000.

Mention may more particularly be made of polymers which consist of recurring units corresponding to the formula:

R.

Η-N (CH ₂ ) - N— (CH ₂ ) i IXΜ-

'2 x (IV)' 4 in which R1, R2, R3 and R4, identical or different, denote an alkyl or hydroxyalkyl radical having from 1 to 4 carbon atoms, n and p are whole numbers varying from 2 to 20, and X- is an anion derived from a mineral or organic acid.

A particularly preferred compound of formula (IV) is that for which R1, R2, R3 and R4 represent a methyl radical, n = 3, p = 6 and X = Cl, called Hexadimethrine chloride according to the INCI nomenclature (CTFA).

(9) quaternary polyammonium polymers comprising units of formula (V):

R.

- N + - (CH ₂ ) _r - NH - CO - (CH ₂ ) _q - CO - NH (CH ₂ ) _S - N + - A -

X- I R (V) '20

in which :

- R18, R19, R20 and R21, identical or different, represent a hydrogen atom or a methyl, ethyl, propyl, β-hydroxyethyl, β-hydroxypropyl or -CH2CH2 (OCH2CH2) pOH radical, where p is equal to 0 or to an integer between 1 and 6, provided that R18, R19, R20 and R21 do not simultaneously represent a hydrogen atom,

- r and s, identical or different, are whole numbers between 1 and 6,

- q is equal to 0 or to an integer between 1 and 34,

- X- denotes an anion such as a halide,

- A denotes a divalent radical of a dihalide or represents rence -CH2-CH2-O-CH2-CH2-.

Mention may for example be made of the products Mirapol® A 15, Mirapol® AD1, Mirapo® AZ1 and Mirapol® 175 sold by the company Miranol.

(10) Quaternary polymers of vinylpyrrolidone and of vinylimidazole such as for example the products sold under the names Luviquat® FC 905, FC 550 and FC 370 by the company B.A.S.F.

(11) Polyamines such as Polyquart® H sold by COGNIS, referenced under the name of POLYETHYLENEGLYCOL (15) TALLOW POLYAMINE in the CTFA dictionary.

(12) polymers comprising in their structure:

(a) one or more motifs corresponding to the following formula (A):

—CH ₂ —CH— nh ₂ (b) optionally one or more units corresponding to the following formula (B):

—CH; —CH— ² I (B)

NH — C-H

II

O

In other words, these polymers can in particular be chosen from homo- or copolymers comprising one or more units originating from vinylamine and optionally one or more units originating from vinylformamide.

Preferably, these cationic polymers are chosen from polymers comprising, in their structure, from 5 to 100% by moles of units corresponding to formula (A) and from 0 to 95% by moles of units corresponding to formula (B) , preferably from 10 to 100 mol% of units corresponding to formula (A) and from 0 to 90 mol% of units corresponding to formula (B).

These polymers can be obtained for example by partial hydrolysis of polyvinylformamide. This hydrolysis can take place in an acidic or basic medium.

The weight average molecular weight of said polymer, measured by light diffraction, can vary from 1000 to 3,000,000 g / mole, preferably from 10,000 to 1,000,000 and more particularly from 100,000 to 500,000 g / mole.

The polymers comprising units of formula (A) and optionally units of formula (B) are sold in particular under the name LUPAMIN by the company BASF, such as for example, and without limitation, the products offered under the name LUPAMIN 9095 , LUPAMIN 5095, LUPAMIN 1095, LUPAMIN 9030 (or LUVIGUAT 9030) and LUPAMIN 9010.

Other cationic polymers which can be used in the context of the invention are cationic proteins or cationic protein hydrolysates, polyalkyleneimines, in particular polyethyleneimines, polymers comprising vinylpyridine or vinylpyridinium units, polyamine and epichlorohydrin condensates, quaternary polyureylenes and chitin derivatives.

Preferably, the cationic polymers are chosen from those of the families (1), (2), (7) and (10) mentioned above.

Among the cationic polymers mentioned above, it is preferably possible to use cationic polysaccharides, in particular celluloses and cationic galactomannan gums, and in particular quaternary cellulose ether derivatives such as the products sold under the name JR 400 by the company AMERCHOL, cationic cyclopolymers, in particular homopo3060323 lymers or copolymers of salts (for example chloride) of dimethyldiallylammonium, sold under the names MERQUAT 100, MERQUAT 550 and MERQUAT S by the company NALCO, the quaternary polymers of vinylpyrrolidone and of vinylimidazole , optionally crosslinked homopolymers or copolymers of methacryloyloxyalkyl (C1-C4) trialkyl (C1-C4) ammonium salts; and their mixtures.

The total content of cationic polymer (s) in the composition according to the invention can vary from 0.05 to 5% by weight relative to the total weight of the composition, preferably from 0.1 to 3% by weight , and preferably from 0.2 to 2% by weight, relative to the total weight of the composition.

Amphoteric polymers

The cosmetic composition can also comprise one or more amphoteric polymers.

Within the meaning of the present invention, the term amphoteric polymer designates any non-silicone polymer (not comprising a silicon atom) containing cationic groups and / or groups which can be ionized into cationic groups, as well as anionic groups and / or ionizable groups into anionic groups.

The amphoteric polymers can preferably be chosen from amphoteric polymers comprising the repetition of:

(i) one or more units from a (meth) acrylamide type monomer, (ii) one or more units from a (meth) acrylamidoalkyltrialkylammonium type monomer, and (iii) one or more units from a acid monomer of (meth) acrylic acid type.

Preferably, the units originating from a (meth) acrylamide type monomer are units with the following structure (la):

CH;

r s 2 X.

OR „(la) in which Ri denotes H or CH ₃ , and R ₂ is chosen from an amino, dimethylamino, tert-butylamino, dodecylamino, or -NH-CH ₂ OH radical.

Preferably, said amphoteric polymer only comprises the repetition of a single unit of formula (la).

The unit derived from a (meth) acrylamide type monomer of formula (Ia) in which Ri denotes H and R ₂ is an amino radical (NH2) is particularly preferred. It corresponds to the acrylamide monomer proper.

Preferably, the units originating from a (meth) acrylamido alkyltrialkylammonium type monomer are units with the following structure (IIa):

CH

F * 3 2 ^ NH

* 4 (Ha)

r ₇ in which:

- R ₃ denotes H or CH ₃ ,

- R ₄ denotes a group (CH ₂ ) k, k being an integer ranging from 1 to 6, preferably from 2 to 4;

- R ₅ R ₆ and R ₇ , identical or different, denote a C1-C4 alkyl,

- Y 'is an anion such as bromide, chloride, acetate, borate, citrate, tartrate, bisulfate, bisulfite, sulfate, phosphate.

Preferably, said amphoteric polymer only comprises the repetition of a single unit of formula (IIa).

Among these units originating from a (meth) acrylamidoalkyltrialkylammonium monomer of formula (IIa), preference is given to those originating from the methacrylamidopropyltrimethylammonium chloride monomer, for which R ₃ denotes a methyl radical, k is 3, R ₅ , R ₆ and R ₇ denote a methyl radical, and Y ′ denotes a chloride anion.

Preferably, the units derived from a (meth) acrylic acid type monomer are units of formula (Ilia):

CH _ÏÏ

R ₈ Ί (Ilia)

O ^ R _n in which R ₈ denotes H or CH3, and R ₉ denotes a hydroxyl radical or a radical -NH-C (CH ₃ ) ₂ -CH ₂ -SO ₃ H.

The preferred units of formulas (Ilia) correspond to the monomers acrylic acid, methacrylic acid and 2-acrylamino 2-methyl propane sulfonic acid.

Preferably, the unit derived from a monomer of (meth) acrylic acid type of formula (IIa) is that derived from acrylic acid, for which R ₈ denotes a hydrogen atom and R ₉ denotes a hydroxyl radical.

The acid monomer (s) of (meth) acrylic acid type may be non-neutralized, partially or totally neutralized, with an organic or mined base.

Preferably, said amphoteric polymer only comprises the repetition of a single unit of formula (Ilia).

According to a preferred embodiment of the invention, the amphoteric polymer or polymers of this type comprise at least 30 mol% of units derived from a monomer of type (i) (meth) acrylamide. Preferably, they comprise from 30 to 70 mol% of units derived from a (meth) acrylamide type monomer, more preferably from 40 to 60 mol%.

The content of units derived from a monomer of type (ii) (meth) acrylamido alkyltrialkylammonium can advantageously be from 10 to 60%, preferably from 20 to 55% by moles.

The content of units originating from an acid monomer of type (iii) (meth) acrylic acid can advantageously be from 1 to 20%, preferably from 5 to 15% by moles. According to a particularly preferred embodiment of the invention, the amphoteric polymer of this type comprises:

- from 30 to 70 mol% of units originating from a (i) (meth) acrylamide type monomer, more preferably from 40 to 60 mol%,

- from 10 to 60 mol%, preferably from 20 to 55 mol%, of units derived from a monomer of type (ii) (meth) acrylamidoalkyltrialkylammonium, and

- from 1 to 20 mol%, preferably from 5 to 15 mol%, of units derived from a monomer of type (iii) (meth) acrylic acid.

This type of amphoteric polymer can also comprise additional units, different from the units derived from a (meth) acrylamide type monomer, (meth) acrylamidoalkyltrialkylammonium type and (meth) acrylic acid type as described above.

However, according to a preferred embodiment of the invention, said amphoteric polymers consist solely of units derived from monomers of type (i) (meth) acrylamide, of type (ii) (meth) acrylamidoalkyltrialkylammonium and of type (iii) acid. (meth) acrylic.

As an example of amphoteric polymers which are particularly preferred, mention may be made of the acrylamide / methacrylamidopropyltrimethylammonium chloride / acrylic acid terpolymers. Such polymers are listed in the CTFA dictionary (INCI) under the name Polyquaternium 53. Corresponding products are in particular marketed under the names MEROUAT 2003 and MERGUAT 2003 PR by the company NALCO.

As another type of amphoteric polymer capable of being used, mention may also be made of copolymers based on (meth) acrylic acid and a dialkyldiallylammonium salt, such as copolymers of (meth) acrylic acid and chloride of dimethyldiallyl ammonium. We can cite for example the Merquat 280 offered by the company NALCO.

The amphoteric polymer (s) may generally be present in the composition according to the invention in a total amount of between 0.05 and 5% by weight, preferably between 0.1 and 3% by weight, and more particularly between 0.2 and 2% by weight, relative to the total weight of the composition.

According to a preferred embodiment of the invention, the composition according to the invention comprises:

one or more anionic surfactants (i) chosen from polyoxyalkylenated carboxylic ether alkyl (amido) acids and their salts, preferably of formula (1) as defined above;

one or more anionic surfactants (ii) chosen from sodium, triethanolamine, magnesium or ammonium alkyl (C12C14) sulfates, and / or sodium, ammonium or magnesium alkyl (C12-C14) ether sulfates , oxyethylenated, for example from 1 to 10 moles of ethylene oxide;

- one or more nonionic surfactants, in a total content of at least 1% by weight relative to the total weight of the composition, chosen from, alone or as a mixture:

- oxyethylenated fatty alcohols, comprising at least one C8 to C40 alkyl chain, in particular C8 to C20, even better in C10 to C18, saturated or not, linear or branched, and comprising from 1 to 100 moles of ethylene oxide , preferably from 2 to 50, more particularly from 2 to 40 moles, or even from 3 to 20 moles of ethylene oxide; in particular lauric alcohol with 4 moles of ethylene oxide and lauric alcohol with 12 moles of ethylene oxide; and

- (C6-C24 alkyl) (poly) glycosides, and more particularly (C8C18 alkyl) (poly) glycosides;

one or more amphoteric surfactants, in a total content of at least 3% by weight relative to the total weight of the composition, comprising one or more surfactants chosen from alkyl (C8-C ₂ o) betaines, alkyl (C8 -C ₂ o) sulfobetaines, alkyl (C8-C2o) amidoalkyl (C3-C8) betaines and alkyl (C8-C ₂ o) -amidalkyl (C6Csjsulfobetaines,

- one or more types of solid particles, preferably chosen from silicas, clays, pigments and their mixtures;

optionally one or more cationic polymers preferably having a cationic charge density greater than or equal to 4 meq / g, preferably chosen from homopolymers of dialkyldiallylammonium halide, and

- Optionally one or more amphoteric polymers preferably consisting solely of units derived from monomers of type (i) acrylamide, of type (ii) acrylamidoalkyltrialkylammonium and of type (iii) (meth) acrylic acid.

The composition according to the invention may comprise water or a mixture of water and one or more cosmetically acceptable solvents chosen from C1-C4 alcohols, such as ethanol, isopropanol, tert-butanol or n-butanol; polyols such as glycerol, propylene glycol and polyethylene glycols; and their mixtures.

Preferably, the composition according to the invention has a total water content of between 20 and 95% by weight, preferably between 30 and 90%, preferably between 50 and 85% by weight, even better between 65 and 80% by weight. relative to the total weight of the composition.

The pH of the compositions according to the invention generally varies from 3 to 9, preferably from 3 to 7, preferably from 3.5 to 6, and better still from 4 to 5.5.

The composition according to the invention can also comprise one or more conventional additives well known in the art, such as C12-C30 fatty alcohols; ceramides; C12-C32 fatty esters, such as isopropyl myristate, myristyl myristate, cetyl palmitate and stearyl stearate; mineral, vegetable or synthetic oils; vitamins or provitamins; nonionic, anionic polymers; pH stabilizers, preservatives; dyes; perfumes ; anti-hair loss agents, anti-seborrheic agents, anti-dandruff agents.

A person skilled in the art will take care to choose the optional additives and their quantity so that they do not harm the properties of the compositions of the present invention.

These additives are generally present in the composition according to the invention in an amount ranging from 0 to 20% by weight relative to the total weight of the composition.

The compositions according to the invention can be used as shampoos for washing and conditioning the hair; they are applied in this case preferably on damp hair in amounts effective for washing them; the foam generated by massage or friction with the hands can then be eliminated after a possible pause time, by rinsing with water, the operation being able to be repeated one or more times.

Method and use according to the invention

Another object of the present invention relates to a process for washing and / or conditioning and / or styling and / or coloring of keratin fibers, in particular human keratin fibers such as the hair, comprising the application to said said fibers of a composition as defined above, followed by a possible exposure time and / or rinsing and / or drying.

The composition can be applied to dry or wet hair, and preferably to wet or damp hair.

According to one embodiment, the method consists in applying to the keratin fibers, an effective amount of the composition according to the invention, kneading the fibers evenly, possibly leaving the composition on said fibers, and rinsing.

The exposure time of the composition on the keratin fibers can be between a few seconds and 15 minutes and preferably between 30 seconds and 5 minutes. The composition is generally rinsed with water.

A possible step of drying the keratin fibers can be implemented.

The present invention also relates to the use of the composition according to the invention as described above for washing and / or conditioning and / or styling and / or coloring of keratin fibers, in particular human keratin fibers such as the hair.

The examples which follow serve to illustrate the invention without, however, being limiting in nature.

EXAMPLES

The cosmetic compositions according to the invention are prepared from the ingredients indicated in the table below, the amounts of which are expressed in% by weight of active material (MA).

Compositions (% MA) AT B VS D SODIUM LAURETH SULFATE 1.75 7 10 7 COCAMIDOPROPYL BE- TAINE 3.8 7 7 7 LAURETH-5 CARBOXYLIC ACID 6.3 6 1 6 LAURETH-12 4 4 5.7 - LAURETH-4 6 1 1 - POLYQUATERNIUM-6 0.3 0.3 0.3 0.3 Caprylyl / capryl glucoside - - - 3 Silica 0.5 - - 0.5 Boron nitride - 0.8 - -

Clay - - 0.3 PRESERVATIVES Qs Qs Qs Qs PH agent Qs pH 4.6 Qs pH 4.6 Qs pH 4.6 Qs pH 4.6 WATER Qsp 100% Qsp 100% Qsp 100% Qsp 100%

The compositions according to the invention can be used as shampoos.

1 g of composition was applied to locks of 2.5 g of natural hair, then the locks were rinsed and dried. It was found that the locks thus treated had good styling properties.

Claims (19)

1. Cosmetic composition, preferably a hair composition, comprising: (I) one or more anionic surfactants chosen from polyoxyalkylenated alkyl (amido) ether carboxylic acids and their salts; (ii) one or more anionic surfactants different from the anionic surfactant (s) alkyl (amido) carboxylic acid polÿoxÿalkylénénés (i); (iii) one or more nonionic surfactants; (Iv) one or more amphoteric surfactants; and (v) one or more types of solid particles. 2. Composition according to the preceding claim, characterized in that the polyoxyalkylenated alkyl (amido) ether carboxylic acids are chosen from those 15 of formula (1): R, “(Oe ₂ H ₄ ) - OCH ₂ COOA (i) in which: - R1 represents a linear or branched C6-C24 alkyl or alkenyl radical, a (C8-C9) alkyl phenyl radical, an R2GONH-CH2-CH2- radical with R2 denoting a linear or branched C9-C21 alkyl or alkenyl radical; preferably R1 is a C8-C20, preferably C8-C18 alkyl radical, - n is an integer or decimal number varying from 2 to 24, preferably from 2 to 10, - A denotes H, ammonium, Na, K, Li, Mg, Ca or a monoethanolamine residue or Triethanolamine. 3. Composition according to one of the preceding claims, in which the polyoxyalkylenated alkyi (amido) ether carboxylic acids are chosen from those of formula (1): R ^ OC ^) - OCH ₂ COOA (d in which: - R1 denotes a C12-C14 alkyl, cocoyl, oleyl, nonylphenyl or octylphenyl radical, 35 - A denotes a hydrogen or sodium atom, and - n varies from 2 to 20, preferably 2 to 10; preferably R1 denotes a C12 alkyl radical, A denotes a hydrogen or sodium atom and n varies from 2 to 10. 40 4. Composition according to one of the preceding claims, comprising said polyoxyalkylenated carboxylic ether (amido) ether (s) and / or their salts, in a total amount ranging from 0.05 to 30% by weight, preferably 0.1 at 25% by weight, better still from 0.5 to 20% by weight and preferably from 1 to 10% by weight relative to the total weight of the composition. 5. Composition according to one of the preceding claims, in which the anionic surfactants (ii) are chosen from alone or as a mixture, - C6-C24 alkyl sulphates, especially C12-C20, - C6-C24 alkyl ether sulfates, especially in 02-020; preferably comprising from 2 to 20 ethylene oxide units; - C6-C24 alkylsulfosuccinates, in particular C12-C20, in particular laurylsulfosuccinates. - C6-C24 alkylethersulfosuccinates, especially C12-C20; - (C6-C24) acylisethionates, preferably (C12-C18) acylisethionates, - C6-C24 acylsarcosinates, especially C12-C20; in particular palmitoylsarcosinates; - C6-C24 acylglutamates, in particular C12-C20; - C6-C24 acylglycinates, especially C12-C20; in particular in the form of alkali or alkaline-earth metal salts, of ammonium, or of aminôàlcoôl; preferably chosen from C8C14 alkylsulphates and alkylsethersulphates and more particularly those of C12-C14, and very particularly lauryl (ether) sulphates. 6. Composition according to one of the preceding claims, comprising the anionic surfactant (s) (ii) in a total content ranging from 0.05 to 30% by weight, preferably ranging from 0.1 to 25%, better still from 0.5 to 20% by weight , even better from 1 to 15% by weight, relative to the total weight of the composition. 7. Composition according to any one of the preceding claims, in which the nonionic surfactants are chosen from; - alcohols, alpha-diols and (C1-20) alkyl phenols, these compounds being polyethoxylated and / or polypropoxylated and / or polyglycerolated, the number of ethylene oxide and / or propylene oxide groups being able to range from 1 to 100, and the number of glycerol groups can range from 2 to 30; or else these compounds comprising at least one fatty chain comprising from 8 to 40 carbon atoms, in particular from 16 to 30 carbon atoms; in particular the C8 to C4O alcohols, saturated or unsaturated, linear or branched ^ oxyethylenated comprising from 1 to 100 moles of ethylene oxide, preferably from 2 to 50, more particularly from 2 to 40 moles of oxide ethylene and having one or two fatty chains; - condensates of ethylene oxide and propylene oxide on fatty alcohols; - polyethoxylated fatty amides preferably having from 2 to 30 ethylene oxide units, polyglycerolated fatty amides comprising on average from 1 to 5 glycerol groups and in particular from 1.5 to 4; - the ethoxylated sorbitan fatty acid esters preferably having from 2 to 40 ethylene oxide units, - fatty acid esters of sucrose, - esters of polyoxyalkylenated fatty acids, preferably polyoxyethylenated having from 2 to 150 moles of ethylene oxide including oxyethylenated vegetable oils, - N- (C6-24 alkyl) glucamine derivatives, - amine oxides such as oxides of (C10-14 alkyl) amines or oxides of N- (acyl C10-14) -aminopropylmorpholine. - nonionic surfactants of alkyî (poly) glycoside type, in particular represented by the following general formula: R1O- (R2O) t- (G) v in which: - R1 represents a linear or branched alkyl or alkenyl radical containing 6 to 24 carbon atoms, in particular 8 to 18 carbon atoms, or an alkylphenyl radical in which the linear or branched alkyl radical contains 6 to 24 carbon atoms, in particular 8 to 18 carbon atoms; R2 represents an alkylene radical containing 2 to 4 carbon atoms, - G represents a sugar unit comprising 5 to 6 carbon atoms, -1 denotes a value ranging from 0 to 10, preferably from 0 to 4, - v denotes a value ranging from 1 to 15, preferably from 1 to 4. 8. Composition according to any one of the preceding claims, in which the nonionic surfactants are chosen from, alone or as a mixture: - oxyethylenated fatty alcohols, comprising at least one C 6 to C 40, in particular C 8 -C 20 alkyl chain, even better in C 10 -C 18, saturated or not, linear or branched, and comprising from 1 to 100 moles of oxide of ethylene, preferably from 2 to 50, more particularly from 2 to 40 moles, or even from 3 to 20 moles of ethylene oxide; in particular lauric alcohol with 4 moles of ethylene oxide (name INCI; LAURETH-4) and lauric alcohol with 12 moles of ethylene oxide (name INCI: LAURETH-12), and - (C6-C24 alkyl) (poiy) glycosides, and more particularly (C8C18 alkyl) (poly) gJycosides; even better, among the alcohols comprising at least one C8C20, better C10-C18 alkyl chain, oxyethylenated comprising from 2 to 50, in particular from 3 to 20 moles of ethylene oxide. 9. Composition according to any one of the preceding claims, comprising the nonionic surfactants in a total content ranging from 0.05 to 30% by weight, preferably ranging from 0.1% to 25% by weight, in particular ranging from 0 , 5 to 20%, even better from 1 to 15% by weight, even better from 2 to 10% by weight, relative to the total weight of the composition. 10. Composition according to any one of the preceding claims, in which the amphoteric surfactants are chosen from alkyl (C8-C2o) betaines, alkyl (Ce-C2o) sulfobetaines, alkyl (C8-C2q) amidoaIkyl (C3-C & ) betaines and (C8-C2o) -amidalkyl (C6-C8) sulfobetaines alkyls, as well as: - the compounds of respective structures (II) and (III) below: R _a -CONHCH2CH2-N ⁺ (Rb) (Rc) -CH2COO-, M ⁺ , X '(II) in which: - Ra represents a C10 to C30 alkyl or alkenyl group derived from a Ra5 CQOH acid, preferably present in hydrolyzed coconut oil, a heptyl, nonyl or undecyl group; - Rb represents a beta-hydroxyethyl group; and - R _c represents a carboxymethyl group; - M ⁺ represents a cationic counter ion From an alkali metal, alkaline-fibrous, such 10 than sodium, an ammonium ion or an ion derived from an organic amine, and - X 'represents an organic or inorganic anionic counter ion, such as that chosen from halides, acetates, phosphates, nitrates, (Ci-C4) alkyl, sulphates, alkyi (Ci-C4) - or alkyl (Gi-C4) aryl- sulforiates, in particular methyl sulphate and ethyl sulphate; or else M ⁺ and X 'are absent; R _a -CONHGH2ÇH2-N (B) (B ') (III) ................. years which Y ............. - B represents the group -CH2CH2OX '; - B 'represents the group - (GH2) zY ’, with z = 1 or 2; 20 - X 'represents the group -CH2COOH, -Ctfc-COOZ ’, -CH2CH2COOH, CH2CH2GOOZ’, or a hydrogen atom; - Y 'represents the group -COOH, -COOZ', -CH2CH (OH) SO3H or the group CH2CH (OH) SO ₃ -Z '; - Z ’represents a cationic counter ion derived from an alkali or alkaline earth metal, 25 such as sodium, an ammonium ion or an ion derived from an organic amine; - R _a 'represents a C10 to C30 alkyl or alkenyl group of a Ra-COOH acid preferably present in coconut oil or in hydrolysed linseed oil, an alkyl group, in particular C17 and its iso form , an unsaturated C17 group. 30 - the compounds of formula (IV): Ra-NHCH (Y ”) - (CH2) nCONH (CH2) n-N (Rd) (Re) (IV) in which: - Y ”represents the group -COOH, -COOZ”, -CH2-CH (OH) SO ₃ H or the group CH2CH (OH) SO ₃ -Z ”; 35 - Rd and R _e , independently of one another, represent a C1 to C4 alkyl or hydroxyalkyl radical; - Z ”represents a cationic counter ion derived from an alkali or alkaline earth metal, such as sodium, an ammonium ion or an ion derived from an organic amine; - Ra represents a C10 to C30 alkyl or alkenyl group of a Ra'-COOH acid 40 preferably present in coconut oil or in hydrolyzed linseed oil; - n and n ’, independently of each other, denote an integer ranging from 1 to 3. 11. Composition according to any one of the preceding claims, comprising 3060323 amphoteric surfactants with a total content ranging from 0.1 to 50% by weight, preferably ranging from 1 to 20% by weight, even better from 3 to 15% by weight. weight, very particularly from 3.5 to 10% by weight, relative to the total weight of the composition. 12. Composition according to any one of the preceding claims, in which the solid particles are chosen from: - micronized fruit pits; - particles of crosslinked polymers or not; in particular chosen from polyamide powders, powders of crosslinked sodium polyacrylate, polyethylene powders and polymethylmethacrylate powders. - the particles of one or more mineral compounds (or mineral particles), in particular chosen from metallic particles, oxides, inorganic salts, carbides, nitrides, borides and hydroxides; clays, silicates, alumina, silica, kaolin and hydroxyapatite; pigments, pearlescent agents. 13. Composition according to any one of the preceding claims, in which the solid particles are chosen from silicas, clays, pigments, pearlescent agents, and very particularly from silicas, clays and pigments, and mixtures thereof. 14. Composition according to any one of the preceding claims, comprising the solid particles in an amount ranging from 0.001 to 15% by weight, preferably from 0.1 to 10% by weight, better still from 0.5 to 8% by weight , relative to the total weight of the composition. 15. Composition according to one of the preceding claims, further comprising one or more cationic polymers, preferably having a cationic charge density greater than or equal to 4 milliequivalents / gram (meq / g); preferably at a total content varying from 0.05 to 5% by weight, preferably from 0.1 to 3% by weight, and preferably from 0.2 to 2% by weight, relative to the total weight of the composition. 16. Composition according to the preceding claims, further comprising one or more amphoteric polymers, in particular chosen from amphoteric polymers comprising the repetition of: (i) one or more units from a (meth) acrylamide type monomer, (ii) one or more units from a (meth) acrylamidoalkyltrialkylammonium type monomer, and (iii) one or more units from a acid monomer of (meth) acrylic acid type; preferably in a total amount of between 0.05 and 5% by weight, of ferment between 0.1 and 3% by weight, and more particularly between 0.2 and 2% by weight, relative to the total weight of the composition. 17- Composition according to any one of the preceding claims, comprising water, in particular at a total content of between 20 and 95% by weight, preferably between 30 and 90%, preferably between 50 and 85% by weight, even better between 65 and 80% by weight relative to the total weight of the composition. 18. Process for washing and / or conditioning and / or styling and / or coloring keratin fibers, in particular human keratin fibers such as the hair, comprising the application to said fibers of a composition such as defined according to any one of claims 1 to 17, followed by a possible exposure time and / or rinsing and / or drying. 15 19. Use of the composition according to one of claims 1 to 17, for washing and / or conditioning and / or styling and / or coloring of keratin fibers, in particular human keratin fibers such as hair.