FR3043340B1 - PROCESS AND INSTALLATION FOR THE CHEMICAL CONVERSION OF CARBONACEOUS MATERIAL WITH HEATED GAS TEMPERATURE - Google Patents

PROCESS AND INSTALLATION FOR THE CHEMICAL CONVERSION OF CARBONACEOUS MATERIAL WITH HEATED GAS TEMPERATURE

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Publication number
FR3043340B1
FR3043340B1 FR1560616A FR1560616A FR3043340B1 FR 3043340 B1 FR3043340 B1 FR 3043340B1 FR 1560616 A FR1560616 A FR 1560616A FR 1560616 A FR1560616 A FR 1560616A FR 3043340 B1 FR3043340 B1 FR 3043340B1
Authority
FR
France
Prior art keywords
carbonaceous material
effluent
installation
subjecting
gas temperature
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
FR1560616A
Other languages
French (fr)
Other versions
FR3043340A1 (en
Inventor
Guillaume Boissonnet
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Commissariat a lEnergie Atomique et aux Energies Alternatives CEA
Original Assignee
Commissariat a lEnergie Atomique CEA
Commissariat a lEnergie Atomique et aux Energies Alternatives CEA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Commissariat a lEnergie Atomique CEA, Commissariat a lEnergie Atomique et aux Energies Alternatives CEA filed Critical Commissariat a lEnergie Atomique CEA
Priority to FR1560616A priority Critical patent/FR3043340B1/en
Priority to PCT/EP2016/076752 priority patent/WO2017077090A1/en
Priority to EP16791592.5A priority patent/EP3371275A1/en
Publication of FR3043340A1 publication Critical patent/FR3043340A1/en
Application granted granted Critical
Publication of FR3043340B1 publication Critical patent/FR3043340B1/en
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Anticipated expiration legal-status Critical

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46—Gasification of granular or pulverulent flues in suspension
    • C10J3/463—Gasification of granular or pulverulent flues in suspension in stationary fluidised beds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46—Gasification of granular or pulverulent flues in suspension
    • C10J3/466—Entrained flow processes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46—Gasification of granular or pulverulent flues in suspension
    • C10J3/48—Apparatus; Plants
    • C10J3/482—Gasifiers with stationary fluidised bed
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46—Gasification of granular or pulverulent flues in suspension
    • C10J3/48—Apparatus; Plants
    • C10J3/485—Entrained flow gasifiers
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/0475—Composition of the impurity the impurity being carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/048—Composition of the impurity the impurity being an organic compound
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/0485—Composition of the impurity the impurity being a sulfur compound
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/0495—Composition of the impurity the impurity being water
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06—Integration with other chemical processes
    • C01B2203/061—Methanol production
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06—Integration with other chemical processes
    • C01B2203/062—Hydrocarbon production, e.g. Fischer-Tropsch process
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/146—At least two purification steps in series
    • C01B2203/147—Three or more purification steps in series
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/16—Integration of gasification processes with another plant or parts within the plant
    • C10J2300/164—Integration of gasification processes with another plant or parts within the plant with conversion of synthesis gas
    • C10J2300/1656—Conversion of synthesis gas to chemicals
    • C10J2300/1659—Conversion of synthesis gas to chemicals to liquid hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/16—Integration of gasification processes with another plant or parts within the plant
    • C10J2300/164—Integration of gasification processes with another plant or parts within the plant with conversion of synthesis gas
    • C10J2300/1656—Conversion of synthesis gas to chemicals
    • C10J2300/1662—Conversion of synthesis gas to chemicals to methane
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/16—Integration of gasification processes with another plant or parts within the plant
    • C10J2300/164—Integration of gasification processes with another plant or parts within the plant with conversion of synthesis gas
    • C10J2300/1656—Conversion of synthesis gas to chemicals
    • C10J2300/1665—Conversion of synthesis gas to chemicals to alcohols, e.g. methanol or ethanol
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Carbon And Carbon Compounds (AREA)

Abstract

La présente invention concerne un procédé de transformation chimique d'une matière carbonée comprenant au moins les étapes consistant à (a) gazéifier ladite matière carbonée dans un réacteur à flux entraîné ou à lit fluidisé moyennant quoi un gaz de synthèse est produit ; (b) soumettre ce gaz de synthèse à une trempe en lui ajoutant un fluide de trempe ; (c) soumettre l'effluent trempé à un traitement de purification ; (d) soumettre l'effluent purifié à une réaction catalytique de synthèse utilisant comme réactifs du CO et du H2 moyennant quoi un effluent gazeux et un effluent liquide sont obtenus, tout ou partie de l'effluent gazeux obtenu lors de l'étape (d) étant utilisé comme fluide de trempe lors de l'étape (b). La présente invention concerne également une installation susceptible d'être mise en œuvre durant un tel procédé.The present invention relates to a process for chemically transforming a carbonaceous material comprising at least the steps of (a) gasifying said carbonaceous material in an entrained-flow or fluidized bed reactor whereby synthesis gas is produced; (b) subjecting this synthesis gas to quenching by adding a quench fluid thereto; (c) subjecting the quenched effluent to a purification treatment; (d) subjecting the purified effluent to a catalytic synthesis reaction using as reactants CO and H2 whereby a gaseous effluent and a liquid effluent are obtained, all or part of the gaseous effluent obtained during step (d) ) being used as quench fluid during step (b). The present invention also relates to an installation capable of being implemented during such a process.

FR1560616A 2015-11-05 2015-11-05 PROCESS AND INSTALLATION FOR THE CHEMICAL CONVERSION OF CARBONACEOUS MATERIAL WITH HEATED GAS TEMPERATURE Active FR3043340B1 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
FR1560616A FR3043340B1 (en) 2015-11-05 2015-11-05 PROCESS AND INSTALLATION FOR THE CHEMICAL CONVERSION OF CARBONACEOUS MATERIAL WITH HEATED GAS TEMPERATURE
PCT/EP2016/076752 WO2017077090A1 (en) 2015-11-05 2016-11-04 Method and facility for chemically converting carbonaceous material by means of top gas quenching
EP16791592.5A EP3371275A1 (en) 2015-11-05 2016-11-04 Method and facility for chemically converting carbonaceous material by means of top gas quenching

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR1560616A FR3043340B1 (en) 2015-11-05 2015-11-05 PROCESS AND INSTALLATION FOR THE CHEMICAL CONVERSION OF CARBONACEOUS MATERIAL WITH HEATED GAS TEMPERATURE

Publications (2)

Publication Number Publication Date
FR3043340A1 FR3043340A1 (en) 2017-05-12
FR3043340B1 true FR3043340B1 (en) 2017-12-15

Family

ID=55236592

Family Applications (1)

Application Number Title Priority Date Filing Date
FR1560616A Active FR3043340B1 (en) 2015-11-05 2015-11-05 PROCESS AND INSTALLATION FOR THE CHEMICAL CONVERSION OF CARBONACEOUS MATERIAL WITH HEATED GAS TEMPERATURE

Country Status (3)

Country Link
EP (1) EP3371275A1 (en)
FR (1) FR3043340B1 (en)
WO (1) WO2017077090A1 (en)

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5433760A (en) 1993-05-13 1995-07-18 Shell Oil Company Method of quenching synthesis gas
US5431703A (en) 1993-05-13 1995-07-11 Shell Oil Company Method of quenching synthesis gas
FR2861402B1 (en) * 2003-10-24 2008-09-12 Inst Francais Du Petrole PRODUCTION OF LIQUID FUELS BY A PROCESSING PROCESS OF A HYDROCARBONATED LOAD
DE102005041931B4 (en) 2005-09-03 2018-07-05 Siemens Aktiengesellschaft Apparatus for producing synthesis gases by partial oxidation of ash-containing fuels under elevated pressure with partial quenching of the raw gas and waste heat recovery
DE102005043212A1 (en) 2005-09-09 2007-03-15 Future Energy Gmbh Solid fuel, e.g. anthracite or gasification, for e.g. fluidized bed reactor, involves taking water-washed raw gas for deposition of particulate matters of partial condensation, where raw gas is indirectly cooled at preset temperature
US20080098654A1 (en) * 2006-10-25 2008-05-01 Battelle Energy Alliance, Llc Synthetic fuel production methods and apparatuses
FR2910489B1 (en) * 2006-12-22 2009-02-06 Inst Francais Du Petrole PROCESS FOR PRODUCING A PURIFIED SYNTHESIS GAS FROM BIOMASS INCLUDING A PURIFICATION STEP BEFORE PARTIAL OXIDATION
US8614257B2 (en) * 2010-02-08 2013-12-24 Fulcrum Bioenergy, Inc. Product recycle loops in process for converting municipal solid waste into ethanol
FR2982857B1 (en) * 2011-11-21 2014-02-14 Gdf Suez PROCESS FOR PRODUCING BIOMETHANE
FR2994980B1 (en) * 2012-09-05 2014-11-14 Commissariat Energie Atomique METHOD FOR GASIFYING CHARGE OF CARBONACEOUS MATERIAL WITH IMPROVED YIELD
FR3009308B1 (en) * 2013-08-01 2015-09-11 Commissariat Energie Atomique PROCESS FOR THE THERMOCHEMICAL CONVERSION OF A CARBONIC CHARGE IN SYNTHESIS GAS CONTAINING MAJORITARILY H2 AND CO.

Also Published As

Publication number Publication date
FR3043340A1 (en) 2017-05-12
WO2017077090A1 (en) 2017-05-11
EP3371275A1 (en) 2018-09-12

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