FR3112774B1 - Device and process for the production of aromatics by biomass pyrolysis and reverse water gas conversion. - Google Patents

Device and process for the production of aromatics by biomass pyrolysis and reverse water gas conversion. Download PDF

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Publication number
FR3112774B1
FR3112774B1 FR2007915A FR2007915A FR3112774B1 FR 3112774 B1 FR3112774 B1 FR 3112774B1 FR 2007915 A FR2007915 A FR 2007915A FR 2007915 A FR2007915 A FR 2007915A FR 3112774 B1 FR3112774 B1 FR 3112774B1
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gas
pyrolysis
producing
unit
aromatics
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FR2007915A
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French (fr)
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FR3112774A1 (en
Inventor
Jean-François Joly
Frederic Feugnet
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IFP Energies Nouvelles IFPEN
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IFP Energies Nouvelles IFPEN
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
    • C10B53/02—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/04—Purification; Separation; Use of additives by distillation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/10—Purification; Separation; Use of additives by extraction, i.e. purification or separation of liquid hydrocarbons with the aid of liquids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/002—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal in combination with oil conversion- or refining processes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/02—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by distillation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/08—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal with moving catalysts
    • C10G1/086—Characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/002—Removal of contaminants
    • C10K1/003—Removal of contaminants of acid contaminants, e.g. acid gas removal
    • C10K1/005—Carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
    • C10K3/02—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment
    • C10K3/026—Increasing the carbon monoxide content, e.g. reverse water-gas shift [RWGS]
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/16—Integration of gasification processes with another plant or parts within the plant
    • C10J2300/164—Integration of gasification processes with another plant or parts within the plant with conversion of synthesis gas
    • C10J2300/1656—Conversion of synthesis gas to chemicals
    • C10J2300/1659—Conversion of synthesis gas to chemicals to liquid hydrocarbons
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Abstract

Dispositif et procédé de conversion de composés aromatiques, comprenant/utilisant : un train de fractionnement (4-7) ; une unité de séparation des xylènes ; une unité d’isomérisation (11) ; une unité de pyrolyse (13) pour traiter de la biomasse (30) et produire un effluent de pyrolyse (31) envoyé vers le train de fractionnement, et produire un gaz de pyrolyse (32) ; une section réactionnelle de conversion de gaz à l'eau inversée (RWGS) (50) pour traiter le gaz de pyrolyse (32) et produire un gaz de RWGS (51) ; une unité de séparation (52) pour séparer de l’eau et du CO2 non converti du gaz de RWGS (51) et produire un gaz de séparation (53) ; une section réactionnelle de synthèse Fischer-Tropsch (14) pour traiter au moins en partie le gaz de séparation (53), produire un effluent de synthèse (35) envoyé au moins en partie vers l’unité de pyrolyse (13). Figure 1 à publierApparatus and method for the conversion of aromatic compounds, comprising/using: a fractionation train (4-7); a xylene separation unit; an isomerization unit (11); a pyrolysis unit (13) for processing biomass (30) and producing pyrolysis effluent (31) sent to the fractionation train, and producing pyrolysis gas (32); a reverse water gas conversion (RWGS) reaction section (50) for treating the pyrolysis gas (32) and producing an RWGS gas (51); a separation unit (52) for separating water and unconverted CO2 from the RWGS gas (51) and producing a separation gas (53); a Fischer-Tropsch synthesis reaction section (14) for at least partially treating the separation gas (53), producing a synthesis effluent (35) sent at least partially to the pyrolysis unit (13). Figure 1 to be published

FR2007915A 2020-07-27 2020-07-27 Device and process for the production of aromatics by biomass pyrolysis and reverse water gas conversion. Active FR3112774B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
FR2007915A FR3112774B1 (en) 2020-07-27 2020-07-27 Device and process for the production of aromatics by biomass pyrolysis and reverse water gas conversion.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR2007915 2020-07-27
FR2007915A FR3112774B1 (en) 2020-07-27 2020-07-27 Device and process for the production of aromatics by biomass pyrolysis and reverse water gas conversion.

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FR3112774A1 FR3112774A1 (en) 2022-01-28
FR3112774B1 true FR3112774B1 (en) 2023-06-02

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Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4678860A (en) * 1985-10-04 1987-07-07 Arizona Board Of Regents Process of producing liquid hydrocarbon fuels from biomass
US4962258A (en) 1988-12-15 1990-10-09 Amoco Corporation Liquid-phase xylene isomerization
US6180550B1 (en) 1998-12-22 2001-01-30 Mobile Oil Corporation Small crystal ZSM-5, its synthesis and use
FR2862638B1 (en) 2003-11-26 2005-12-30 Inst Francais Du Petrole PROCESS FOR THE PRODUCTION OF PARAXYLENE COMPRISING AN ADSORPTION STEP AND TWO STEPS OF ISOMERIZATION
WO2006083409A2 (en) * 2004-12-22 2006-08-10 Exxonmobil Chemical Patents, Inc. Production of liquid hydorocarbons from methane
US7371913B2 (en) 2005-06-30 2008-05-13 Uop Llc Selective aromatics isomerization process
MY162584A (en) 2010-04-21 2017-06-30 Exxonmobil Chemical Patents Inc Xylene isomerization process and catalyst therefor
FI20105503A (en) * 2010-05-10 2011-11-11 Neste Oil Oyj A process for producing a hydrocarbon composition
FR3023840B1 (en) 2014-07-18 2016-07-15 Ifp Energies Now PROCESS FOR THE PRODUCTION OF HIGH PURITY PARAXYLENE FROM XYLENE CUTTING USING TWO SERIES MOBILE BED SEPARATION UNITS OPERATING IN SERIES AND TWO ISOMERIZING UNITS
FR3023841B1 (en) 2014-07-18 2016-07-15 Ifp Energies Now PROCESS FOR PRODUCING PARAXYLENE COMPRISING TWO SIMUL MOBILE BED SEPARATION UNITS AND TWO ISOMERIZING UNITS, ONE OF WHICH IS GAS PHASE
US20160304788A1 (en) * 2015-04-16 2016-10-20 Anellotech, Inc. Biomass-derived chemical intermediates
TWI746476B (en) * 2015-11-13 2021-11-21 美商艾克頌美孚硏究工程公司 Separation of mixed xylenes
KR102423926B1 (en) * 2017-07-27 2022-07-20 아넬로테크, 인코퍼레이티드 Efficient recovery of useful components from biomass catalytic pyrolysis effluent

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