FR3030311B1 - METHOD AND REACTOR FOR PRODUCING A PHOTOCATALYTIC MEDIA AND ITS USE IN A FLUIDIZED BED - Google Patents

METHOD AND REACTOR FOR PRODUCING A PHOTOCATALYTIC MEDIA AND ITS USE IN A FLUIDIZED BED Download PDF

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Publication number
FR3030311B1
FR3030311B1 FR1463012A FR1463012A FR3030311B1 FR 3030311 B1 FR3030311 B1 FR 3030311B1 FR 1463012 A FR1463012 A FR 1463012A FR 1463012 A FR1463012 A FR 1463012A FR 3030311 B1 FR3030311 B1 FR 3030311B1
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Prior art keywords
fluid
reactor
fluidized bed
medium
producing
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FR1463012A
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French (fr)
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FR3030311A1 (en
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Razvan Vasile Garban
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/30Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/391Physical properties of the active metal ingredient
    • B01J35/392Metal surface area
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/063Titanium; Oxides or hydroxides thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08Silica
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/30Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/30Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/39Photocatalytic properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/40Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/30Treatment of water, waste water, or sewage by irradiation
    • C02F1/32Treatment of water, waste water, or sewage by irradiation with ultraviolet light
    • C02F1/325Irradiation devices or lamp constructions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/20Metals or compounds thereof
    • B01D2255/207Transition metals
    • B01D2255/20707Titanium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/30Silica
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/80Type of catalytic reaction
    • B01D2255/802Photocatalytic
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/70Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/708Volatile organic compounds V.O.C.'s
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/91Bacteria; Microorganisms
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
    • B01D2259/80Employing electric, magnetic, electromagnetic or wave energy, or particle radiation
    • B01D2259/804UV light
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00Apparatus for treatment of water, waste water or sewage
    • C02F2201/32Details relating to UV-irradiation devices
    • C02F2201/322Lamp arrangement
    • C02F2201/3223Single elongated lamp located on the central axis of a turbular reactor
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00Apparatus for treatment of water, waste water or sewage
    • C02F2201/32Details relating to UV-irradiation devices
    • C02F2201/322Lamp arrangement
    • C02F2201/3225Lamps immersed in an open channel, containing the liquid to be treated
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/001Upstream control, i.e. monitoring for predictive control
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/40Liquid flow rate
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/16Regeneration of sorbents, filters
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2305/00Use of specific compounds during water treatment
    • C02F2305/10Photocatalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Hydrology & Water Resources (AREA)
  • Water Supply & Treatment (AREA)
  • Environmental & Geological Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
  • Catalysts (AREA)

Abstract

Le réacteur pour la purification d'un fluide gazeux ou liquide, comporte une enceinte (1) comportant : i) en partie inférieure un conduit d'entrée (10) dudit fluide et en partie supérieure un conduit de sortie (20) dudit fluide, ii) entre lesdits conduits, une chambre interne (2) contenant une quantité de média photocatalytique (100) selon la revendication 13, la cloison inférieure de la chambre étant constituée d'un filtre (3) apte à retenir les particules dudit media et à laisser circuler ledit fluide, et iii) une lampe (4) émettrice de rayons UV, s'étendant dans ladite chambre à proximité dudit média, entre les conduits d'entrée (10) et de sortie (20) du fluide, de sorte que le média photocatalytique constitue un lit fluidisé éclairé par la lampe (4), qui est apte à purifier ledit fluide lorsque celui-ci traverse le réacteur.The reactor for the purification of a gaseous or liquid fluid comprises an enclosure (1) comprising: i) in the lower part an inlet conduit (10) of said fluid and in the upper part an outlet conduit (20) of said fluid, ii) between said ducts, an internal chamber (2) containing a quantity of photocatalytic medium (100) according to claim 13, the lower partition of the chamber consisting of a filter (3) able to retain the particles of said medium and to allowing said fluid to circulate, and iii) a lamp (4) emitting UV rays, extending in said chamber close to said medium, between the fluid inlet (10) and outlet (20) ducts, so that the photocatalytic medium constitutes a fluidized bed illuminated by the lamp (4), which is capable of purifying said fluid when the latter passes through the reactor.

FR1463012A 2014-12-19 2014-12-19 METHOD AND REACTOR FOR PRODUCING A PHOTOCATALYTIC MEDIA AND ITS USE IN A FLUIDIZED BED Active FR3030311B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
FR1463012A FR3030311B1 (en) 2014-12-19 2014-12-19 METHOD AND REACTOR FOR PRODUCING A PHOTOCATALYTIC MEDIA AND ITS USE IN A FLUIDIZED BED

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR1463012A FR3030311B1 (en) 2014-12-19 2014-12-19 METHOD AND REACTOR FOR PRODUCING A PHOTOCATALYTIC MEDIA AND ITS USE IN A FLUIDIZED BED

Publications (2)

Publication Number Publication Date
FR3030311A1 FR3030311A1 (en) 2016-06-24
FR3030311B1 true FR3030311B1 (en) 2022-03-11

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Application Number Title Priority Date Filing Date
FR1463012A Active FR3030311B1 (en) 2014-12-19 2014-12-19 METHOD AND REACTOR FOR PRODUCING A PHOTOCATALYTIC MEDIA AND ITS USE IN A FLUIDIZED BED

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Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6315870B1 (en) * 1998-04-10 2001-11-13 University Of Central Florida Method for high flux photocatalytic pollution control
FR2879479B1 (en) * 2004-12-17 2007-11-09 Armines Ass Loi De 1901 AMORPHOUS COMPOSITE STRUCTURES FOR PHOTOCATALYSIS

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FR3030311A1 (en) 2016-06-24

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