FR3026006A1 - COMPOSITION FOR COLORING KERATIN FIBERS COMPRISING AT LEAST TWO DIFFERENT OXIDATION BASES - Google Patents

Abstract

The present invention relates to a composition for the dyeing of keratinous fibers, comprising at least two different oxidation bases, of which a first oxidation base (a) is 2- (methoxymethyl) benzene-1,4-diamine salts thereof. addition and its solvates, and a second oxidation base (b) is pyrazolo-pyridine or pyrazolo-pyrazolone type. This composition is intended for dyeing keratinous fibers, and in particular hair.

Description

The present invention relates to a composition for dyeing keratinous fibers, comprising at least two different oxidation bases, a first oxidation base (a) of which is at least two oxidation bases. 2- (methoxymethyl) benzene-1,4-diamine and a second oxidation base (b) is pyrazolo-pyridine or pyrazolo-pyrazolone type. The invention also relates to a method for dyeing keratin fibers using this composition. The invention finally relates to the use of such a composition for dyeing keratinous fibers, and in particular the hair. The present invention relates to the field of dyeing keratinous fibers, and more particularly to that of hair dyeing. For a long time, many people seek to change the color of their hair, and in particular to hide their white hair. It is known to dye keratinous fibers, in particular human keratinous fibers such as the hair to obtain so-called permanent dyes with dyeing compositions containing oxidation dye precursors, generally called oxidation bases such as orthoacids. or para-phenylenediamines, ortho- or para-aminophenols or heterocyclic compounds such as pyrazoles, pyrazolinones or pyrazolopyridines. These oxidation bases are colorless or weakly colored compounds which, when combined with oxidizing products, can give rise to colored compounds by a process of oxidative condensation.

It is also known that the shades obtained with these oxidation bases can be varied by combining them with couplers or color modifiers, the latter being chosen in particular from aromatic meta-diamines, meta-aminophenols, meta-aminophenols and meta-aminophenols. diphenols and certain heterocyclic compounds such as indole or pyridine compounds. The variety of molecules involved in oxidation bases and couplers, allows to obtain a rich palette of colors.

The oxidation dyeing process therefore consists in applying to the keratin fibers a dye composition comprising oxidation bases or a mixture of oxidation bases and couplers with hydrogen peroxide as an oxidizing agent, let it diffuse, then rinse the fibers.

However, the implementation of these dye compositions may have a number of disadvantages. Indeed, after application to the keratinous fibers, the obtained dye power may not be entirely satisfactory, or even low, and lead to a restricted range of colors. The colorations may also not be sufficiently stubborn against external agents such as light, shampoos, perspiration and also be too selective, that is to say that the color difference is too important along the same keratin fiber which is differently sensitized between its tip and its root. 2- (Methoxymethyl) benzene-1,4-diamine, as described in CA2576189, is known to be an interesting color precursor. However, this compound does not fulfill most of the above requirements, especially in terms of selectivity. Indeed, it does not ensure good coverage of keratinous fibers, especially depigmented keratinous fibers, such as white hair. Moreover, its dyeing power is still limited, thus leading to a limited color field. Thus, there is a real need to provide a coloring composition for keratinous fibers, in particular human keratin fibers such as the hair, which do not have the drawbacks mentioned above, that is to say which is capable of to lead to a wide range of colors while having low selectivity and good toughness. These and other objects are achieved by the present invention which therefore relates to a composition for dyeing keratin fibers, comprising: at least two different oxidation bases, including: a first oxidation base (a) is chosen from 2- (methoxymethyl) benzene-1,4-diamine of formula (I), its addition salts and its solvates: o, CH3 NH2 (I) and a second oxidation base (b) is chosen among: (i) the compounds of formula (II), their addition salts and their solvates: in which, R 1 represents an amino group, a C 1 -C 4 alkyl group, optionally substituted by one or more hydroxyl or amino groups, a C1-C4 alkoxy group, optionally substituted by one or more hydroxyl or amino groups, (ii) the compounds of formula (III), their addition salts and their solvates: in which, R2 represents an amino group, a grouping C1 to C4 alkyl, optionally substituted with one or more hydroxy or amino elements, a C1-C4 alkoxy group, optionally substituted with one or more hydroxy or amino groups, and (iii) mixtures thereof.

In other words, the composition according to the invention comprises at least one mixture of different oxidation bases comprising at least 2- (methoxymethyl) benzene-1,4-diamine or one of its addition salts or solvates and at least one oxidation base (b) selected from compounds (i) and (ii) as described above.

The present invention also relates to a process for dyeing keratinous fibers in which the composition according to the invention is applied to said fibers. The invention also relates to the use of said composition for dyeing keratinous fibers, and in particular the hair.

The invention also relates to a device with at least two compartments comprising: a) in a first compartment, a composition (A) comprising: at least two different oxidation bases, of which: a first oxidation base (a) is chosen from 2- (methoxymethyl) benzene-1,4-diamine of formula (I), its addition salts and its solvates: o, CH3 NH2 (I) a second oxidation base (b) is chosen from: (i) the compounds of formula (II), their addition salts and their solvates: in which, R 1 represents an amino group, a C 1 -C 4 alkyl group, optionally substituted with one or more hydroxyl or amino groups, a group C1-C4 alkoxy, optionally substituted by one or more hydroxy or amino groups, (ii) the compounds of formula (III), their addition salts and their solvates: wherein R2 represents an amino group, an alkyl group, C1 to C4, optionally substituted by one or more groups hydroxy or amino groups, a C 1 -C 4 alkoxy group, optionally substituted by one or more hydroxyl or amino groups, and (iii) their mixtures and b) in a second compartment, a composition (B) comprising at least one oxidizing agent chemical, preferably hydrogen peroxide. By "chemical oxidizing agent" according to the invention is meant an oxidizing agent other than oxygen in the air. The composition according to the invention makes it possible to lead to powerful, intense and not very selective staining, that is to say to stains which are homogeneous along the fiber. This composition also makes it possible to cover particularly well depigmented keratin fibers, such as white hair.

The composition according to the invention also makes it possible to achieve different shades in a very wide range of colors. Furthermore, the colorations obtained with the composition according to the invention are resistant to various attacks that may occur in the hair, such as light, weather, washing, perspiration. Other objects, features, aspects and advantages of the invention will emerge even more clearly on reading the description and examples which follow. In what follows, and unless otherwise indicated, the boundaries of a domain of values are included in this field, especially in the expressions "between" and "from ... to". Moreover, the expression "at least one" used in the present description is equivalent to the expression "one or more".

Similarly, the expression "at least two" is equivalent to the expression "two or more". The composition according to the invention comprises at least two different oxidation bases of which a first oxidation base (a) is chosen from 2- (methoxymethyl) benzene-1,4-diamine of formula (I), its salts of addition and its solvates: o, CH3 NI-12 (I) The addition salts of the first oxidation base (a), present in the composition according to the invention, are chosen in particular from the addition salts with an acid such as hydrochlorides, hydrobromides, sulphates, citrates, succinates, tartrates, lactates, tosylates, benzenesulfonates, methanesulphonates, phosphates and acetates, and addition salts with a base such as as soda, potash, ammonia, amines or alkanolamines. Furthermore, the solvates of the first oxidation base (a) more particularly represent the hydrates of said oxidation base (a) and / or the combination of said oxidation base (a) with a linear or branched alcohol C 1 -C 4 such as methanol, ethanol, isopropanol, n-propanol. Preferably, the solvates are hydrates.

The amount of the first oxidation base (a), present in the composition according to the invention, can range from 0.0001 to 20% by weight, preferably from 0.005 to 10% by weight, and more preferably from 0, 01 to 6% by weight, relative to the total weight of the composition. The composition according to the invention comprises at least two different oxidation bases of which a second oxidation base (b), different from the first oxidation base (a) of formula (I), is chosen from: (i) the compounds of formula (II), their addition salts and their solvates: in which, R 1 represents an amino group, a C 1 -C 4 alkyl group, optionally substituted with one or more hydroxyl or amino groups, a C 1 -C 4 alkoxy group; at C4, optionally substituted by one or more hydroxyl or amino groups, (ii) the compounds of formula (III), their addition salts and their solvates: in which, R2 represents an amino group, a C1-C4 alkyl group; optionally substituted by one or more hydroxy or amino groups, a C1-C4 alkoxy group, optionally substituted with one or more hydroxyl or amino groups, and (iii) their mixtures.

Preferably, in the compounds of formula (II), R 1 represents an amino group. Preferably, in the compounds of formula (M), R 2 represents a C 1 -C 4 alkoxy group, optionally substituted by one or more hydroxyl groups, and preferably a hydroxyethoxy group. Of the compounds of formula (II), it is preferred to use 2,3-diamino-6,7-dihydro-1H, 5H-pyrazolo [1,2-a] pyrazol-1-one, one of its addition or one of its solvates.

Among the compounds of formula (III), it is preferable to use 2- (2-hydroxyethoxy) -3-aminopyrazolo [1,5-a] pyridine, one of its addition salts or one of its solvates. The addition salts of the second oxidation base or bases (b), present in the composition according to the invention, are chosen especially from the addition salts with an acid such as hydrochlorides, hydrobromides, sulphates, citrates, succinates, tartrates, lactates, tosylates, benzenesulfonates, methanesulfonates, phosphates and acetates, and addition salts with a base such as sodium hydroxide, potassium hydroxide, ammonia, amines or the alkanolamines. Furthermore, the solvates of the second oxidation base (s) (b) more particularly represent the hydrates of said oxidation bases (b) and / or the combination of said oxidation bases (b) with a linear or branched alcohol C 1 -C 4 such as methanol, ethanol, isopropanol, n-propanol. Preferably, the solvates are hydrates. Preferably, the second or the second oxidation bases (b) are chosen from 2,3-diamino-6,7-dihydro-1H, 5H-pyrazolo [1,2-a] pyrazol-1-one, the 2 - (2-hydroxyethoxy) -3-aminopyrazolo [1,5-a] pyridine, their addition salts, solvates and mixtures thereof. The quantity of the second oxidation base (s) (b) present in the composition according to the invention may range from 0.0001% to 20% by weight, preferably from 0.005% to 10% by weight, and more preferably from 0.005% to 10% by weight. 0.01 to 6% by weight, relative to the total weight of the composition. The composition according to the invention may optionally also comprise one or more additional oxidation bases, conventionally used for dyeing keratinous fibers, and different from the oxidation bases of formula (I), (II) and (III), as defined above. By way of example, the additional oxidation base or bases are chosen from among the different para-phenylenediamines of the compound of formula (I), bis-phenylalkylenediamines, para-aminophenols, bis-para-aminophenols, ortho-aminophenols, the different heterocyclic bases of the compounds of formula (II) and (III), their addition salts and their solvates. Among the paraphenylenediamines different from the compound of formula (I), there may be mentioned, by way of example, para-phenylenediamine, paratoluylenediamine, 2-chloro-para-phenylenediamine, 2,3-dimethyl-para-phenylenediamine, 2,6-dimethyl-para-phenylenediamine, 2,6-diethyl paraphenylenediamine, 2,5-dimethyl paraphenylenediamine, N, N-dimethyl paraphenylenediamine, N, N-diethyl paraphenylenediamine, N, N-dipropyl paraphenylenediamine, 4-amino N, N-diethyl 3- methyl aniline, N, N-bis- (13-hydroxyethyl) paraphenylenediamine, 4-N, Nbis- (13-hydroxyethyl) amino-2-methylaniline, 4-N, N-bis- (13-hydroxyethyl) amino 2-chloroaniline, 2-13-hydroxyethyl paraphenylenediamine, 2-fluoro-para-phenylenediamine, 2-isopropyl-para-phenylenediamine, N- (13-hydroxypropyl) para-phenylenediamine, 2-hydroxymethyl-para-phenylenediamine, N, N-dimethyl-3- methyl paraphenylenediamine, N, N- (ethyl, 0-hydroxyethyl) paraphenyl N-phenylenediamine, N- (13'-dihydroxypropyl) paraphenylenediamine, N- (4'-aminophenyl) paraphenylenediamine, N-phenyl paraphenylenediamine, 2-13-hydroxyethyloxy para-phenylenediamine, 2-13-acetylaminoethyloxy-para-phenylenediamine, N-phenylenediamine, (13-methoxyethyl) paraphenylenediamine, 4-aminophenylpyrrolidine, 2-thienyl paraphenylenediamine, 2-13-hydroxyethylamino 5-amino toluene, 3-hydroxy 1- (4'-aminophenyl) pyrrolidine, their addition salts with an acid and their solvates. Among the bis-phenylalkylenediamines, mention may be made, by way of example, of N, N'-bis- (13-hydroxyethyl) N, NLbis- (4'-aminophenyl) -1,3-diaminopropanol, N, NLbis - (13-hydroxyethyl) -N, NLbis- (4'-aminophenyl) ethylenediamine, N, N'-bis (4-aminophenyl) tetramethylenediamine, N, N'-bis (13-hydroxyethyl) N, N Bis (4-aminophenyl) tetramethylenediamine, N, N'-bis (4-methylaminophenyl) tetramethylenediamine, N, N'-bis (ethyl) -N, N'-bis (4 ') amino, 3'-methylphenyl) ethylenediamine, 1,8-bis (2,5-diamino phenoxy) -3,6-dioxaoctane, their addition salts with an acid and their solvates. Among the para-aminophenols, para-aminophenol, 4-amino-3-methylphenol, 4-amino-3-fluoro phenol, 4-amino-3-chlorophenol, 4 amino-3-hydroxymethyl phenol, 4-amino-2-methylphenol, 4-amino-2-hydroxymethylphenol, 4-amino-2-methoxymethylphenol, 4-amino-2-aminomethylphenol, 4- amino-2- (13-hydroxyethylaminomethyl) phenol, 4-amino-2-fluoro phenol, their addition salts with an acid and their solvates. Among the ortho-aminophenols, mention may be made, for example, of 2-amino phenol, 2-amino-5-methylphenol, 2-amino-6-methylphenol and 5-acetamido-2-amino phenol. and their addition salts with an acid and their solvates. Among the different heterocyclic bases of the compounds of formulas (II) and (III), mention may be made, by way of example, of pyridine derivatives, pyrimidine derivatives and pyrazole derivatives. Among the pyridine derivatives, mention may be made of the compounds described for example in patents GB 1 026 978 and GB 1 153 196, such as 2,5-diaminopyridine, 2- (4-methoxyphenyl) amino-3-amino pyridine, 3,4-diamino pyridine, their addition salts with an acid and their solvates. Among the pyrimidine derivatives, mention may be made of the compounds described, for example, in DE 2359399; JP 88 169571; JP 05-63124; EP 0770375 or patent application WO 96/15765 such as 2,4,5,6-tetraaminopyrimidine, 4-hydroxy 2,5,6-triaminopyrimidine, 2-hydroxy 4,5,6-triaminopyrimidine, , 4-dihydroxy-5,6-diaminopyrimidine, 2,5,6-triaminopyrimidine, and pyrazolopyrimidine derivatives such as those mentioned in the patent application FR A 2750048 and among which mention may be made of pyrazolo [1,5- 4-pyrimidine-3,7-diamine; 2,5-dimethyl pyrazolo [1,5-4-pyrimidine-3,7-diamine; pyrazolo [1,5-4-pyrimidine-3,5-diamine; 2,7-dimethyl pyrazolo [1,5-4-pyrimidine-3,5-diamine; 3-amino pyrazolo [1,5-4-pyrimidin-7-ol; 3-amino pyrazolo [1,5-4-pyrimidin-5-ol; 2- (3-amino pyrazolo [1,5-4-pyrimidin-7-ylamino] ethanol, 2- (7-amino pyrazolo [1,5-4-pyrimidin-3-ylamino] ethanol, 2 - [(3-amino-pyrazolo [1,5-4-pyrimidin-7-yl] - (2-hydroxyethyl) amino] ethanol, 2 - [(7-amino-pyrazolo- 1,5-4-pyrimidin-3-yl) - (2-hydroxyethyl) amino] ethanol, 5,6-dimethyl pyrazolo [1,5-4-pyrimidine-3,7-diamine, 2,6-dimethyl pyrazolo [1,5-4-pyrimidine3,7-diamine, 2,5, N7, N7-tetramethyl pyrazolo [1,5-4-pyrimidine3,7-diamine, 3-amino] 5-methyl-7-imidazolylpropylamino pyrazolo [1,5-4-pyrimidine, their addition salts and solvates. Among the pyrazole derivatives, there may be mentioned diaminopyrazole bases, in particular the compounds described in DE 3843892, DE 4133957 and patent applications WO 94/08969, WO 94/08970, FR-A-2 733 749 and DE 195 43 988. such as 4,5-diamino-methyl pyrazole, 4,5-diamino-1- (13-hydroxyethyl) pyrazole, 3,4-diamino pyrazole, 4,5-diamino-1- (4'-chlorobenzyl) pyrazole 4,5-diamino-1,3-dimethyl pyrazole, 4,5-diamino-3-methyl-1-phenyl pyrazole, 4,5-diamino-1-methyl-3-phenyl pyrazole, 4-amino-1,3 dimethyl 5-hydrazino pyrazole, 1-benzyl 4,5-diamino-3-methyl pyrazole, 4,5-diamino-3-tert-butyl-1-methyl pyrazole, 4,5-diamino-1-tert-butyl-3-methyl pyrazole, 4,5-diamino-1- (13-hydroxyethyl) 3-methyl pyrazole, 4,5-diamino-1-ethyl-3-methyl-pyrazole, 4,5-diamino-1-ethyl-3-yl methoxyphenyl) pyrazole, 4,5-diamino-1-ethyl-3-hydroxymethyl pyrazole, 4,5-diamino-3-hydroxymethyl-1-methyl pyrazole, 4,5-diamino-3-hydroxymethyl 1-isopropyl pyrazole, 4,5-diamino-3-methyl-1-isopropyl pyrazole, 4-amino-5- (2'-aminoethyl) amino-1,3-dimethyl pyrazole, 3,4,5-triamino pyrazole, 1-methyl-3,4,5-triamino pyrazole, 3,5-diamino-1-methyl-4-methylamino pyrazole, 3,5-diamino-4- (13-hydroxyethyl) amino-1-methyl pyrazole, 4-5-diaminol- (13-methoxyethyl) pyrazole, their addition salts and their solvates. The addition salts of the additional oxidation bases, different from the oxidation bases of formula (I), (II) and (III), present in the composition according to the invention are chosen especially from the addition salts with an acid such as hydrochlorides, hydrobromides, sulphates, citrates, succinates, tartrates, lactates, tosylates, benzenesulfonates, methanesulphonates, phosphates and acetates, and addition salts with a base such as as soda, potash, ammonia, amines or alkanolamines. Moreover, the solvates of the additional oxidation bases, different from the oxidation bases of formula (I), (II) and (III), represent more particularly the hydrates of said additional oxidation bases and / or the combination of said additional oxidation bases with a linear or branched C1-C4 alcohol such as methanol, ethanol, isopropanol, n-propanol. Preferably, the solvates are hydrates. Preferably, the additional oxidation base or bases, different from the oxidation bases of formulas (I), (II) and (III), are chosen from para-aminophenols, their addition salts and their solvates. The amount of the additional oxidation base (s), different from the oxidation bases of formulas (I), (II) and (III), present in the composition according to the invention may range from 0.001 to 10% by weight. and preferably from 0.005 to 6% by weight, based on the total weight of the composition. The composition according to the invention may optionally further comprise one or more couplers advantageously chosen from those conventionally used for dyeing keratinous fibers. Among these couplers, there may be mentioned meta-phenylenediamines, meta-aminophenols, meta-diphenols, naphthalenic couplers, heterocyclic couplers and their addition salts and solvates. Among the meta-aminophenols, mention may be made of the compounds of formula (IV), their addition salts and their solvates: (IV) in which R 3 represents a hydrogen atom or an optionally substituted C 1 -C 4 alkyl group with one or more hydroxy groups, and R4 represents a hydrogen or halogen atom. Other couplers, different from the compounds of formula (IV), can also be used in the composition according to the invention. 2,4-Dichloro-3-aminophenol, 5-amino-4-chloro-o-cresol, 4-chloro-1,3-dihydroxybenzene, 2,4-diamino-1- (13 hydroxyethyloxy) benzene, 2-amino 4- (13-hydroxyethylamino) -1-methoxybenzene, 1,3-bis (2,4-diaminophenoxy) propane, 3-ureido aniline, 3-ureido 1-dimethylamino benzene , sesamol, 1-13-hydroxyethylamino-3,4-methylenedioxybenzene, α-naphthol, 2-methyl-1-naphthol, 1,5-dihydroxy naphthalene, 2,7-naphthalenediol, acetoxy-2-methylnaphthalene, 6-hydroxyindole, 4-hydroxyindole, 4-hydroxy N-methylindole, 3,5-diamino-2,6-dimethoxypyridine, 2,6-dihydroxy-3-4 dimethyl pyridine, 3-amino-2-methylamino-6-methoxypyridine, 1-N- (13-hydroxyethyl) amino-3,4-methylene dioxybenzene, 2,6-bis- (13-hydroxyethylamino) toluene, 3-methyl-1-phenyl-5-pyrazolone, their addition salts with an acid and their solvates. The addition salts of the couplers present in the composition according to the invention are chosen especially from the addition salts with an acid such as hydrochlorides, hydrobromides, sulphates, citrates, succinates, tartrates, lactates, tosylates, benzenesulfonates, methanesulfonates, phosphates and acetates, and addition salts with a base such as sodium hydroxide, potassium hydroxide, ammonia, amines or alkanolamines.

Moreover, the solvates of the couplers more particularly represent the hydrates of said couplers and / or the combination of said couplers with a linear or branched C1 to C4 alcohol such as methanol, ethanol, isopropanol, n-propanol. Preferably, the solvates are hydrates. Preferably, the coupler or couplers present in the composition according to the invention are chosen from the compounds of formula (IV), their addition salts and their solvates. More particularly, the coupler or couplers present in the composition according to the invention are chosen from 2-methyl-5-hydroxyethylaminophenol, 4-amino-2-hydroxytoluene and 5-amino-6-chloro-o-cresol. , their addition salts, their solvates and their mixtures The amount of the coupler or couplers, present in the composition according to the invention, can range from 0.001 to 10% by weight, and preferably from 0.005 to 6% by weight, by relative to the total weight of the composition. The composition according to the invention may optionally further comprise one or more fatty substances. By "fatty substance" is meant an organic compound which is insoluble in water at ordinary temperature (25 ° C.) and at atmospheric pressure (760 mmHg) (solubility less than 5%, preferably less than 1%, and more preferably less than 0.1%). They have in their structure at least one hydrocarbon chain comprising at least 6 carbon atoms or a chain of at least two siloxane groups. In addition, the fatty substances are generally soluble in organic solvents under the same conditions of temperature and pressure, such as, for example, chloroform, dichloromethane, carbon tetrachloride, ethanol, benzene, toluene, tetrahydrofuran ( THF), petrolatum oil or decamethylcyclopentasiloxane.

Preferably, the fatty substances of the invention do not contain salified or non-salified carboxylic acid groups (-C (O) OH or -C (O) O-). In particular, the fatty substances of the invention are neither polyoxyalkylenated nor polyglycerolated.

More particularly, the fatty substances are chosen from C 6 to C 16 hydrocarbons, hydrocarbons containing more than 16 carbon atoms, non-silicone oils of animal origin, vegetable oils of the triglyceride type, synthetic triglycerides, and fluorinated oils. fatty alcohols, esters of fatty acids and / or fatty alcohol different from triglycerides and vegetable waxes, non-silicone waxes, silicones. It is recalled that for the purposes of the invention, the alcohols, esters and fatty acids more particularly have one or more linear or branched hydrocarbon groups, saturated or unsaturated, comprising 6 to 30 carbon atoms, which are optionally substituted, in particular by one or more hydroxyl groups (in particular 1 to 4). If unsaturated, these compounds may comprise one to three carbon-carbon double bonds, conjugated or otherwise. With regard to the C6 to C16 hydrocarbons, the latter are linear, branched, optionally cyclic and preferably alkanes. By way of example, mention may be made of hexane, dodecane and isoparaffins, such as isohexadecane and isodecane.

As hydrocarbon oils of animal origin, mention may be made of perhydrosqualene. Triglyceride oils of vegetable or synthetic origin are preferably chosen from liquid triglycerides of fatty acids containing from 6 to 30 carbon atoms, for instance triglycerides of heptanoic or octanoic acids or else, for example, sunflower seed oils. corn, soy, squash, grape seed, sesame, hazelnut, apricot, macadamia, arara, castor, avocado, tea seed, passionflower seed, seed molefoam, triglycerides of caprylic / capric acids such as those sold by the company Stearineries Dubois or those sold under the names Miglyole 810, 812 and 818 by the company Dynamit Nobel, jojoba oil, shea butter oil and their mixtures. The linear or branched hydrocarbons, of mineral or synthetic origin, of more than 16 carbon atoms, are preferably chosen from paraffin oils, petroleum jelly, vaseline oil, polydecenes, hydrogenated polyisobutene such as Parlé am The fluorinated oils may be chosen from perfluoromethylcyclopentane and perfluoro-1,3-dimethylcyclohexane, sold under the names "FLUTECe PC1" and "FLUTECe PC3" by BNFL Fluorochemicals; perfluoro-1,2-dimethylcyclobutane, perfluoroalkanes such as dodecafluoropentane and tetradecafluorohexane, sold under the names "PF 5050®" and "PF 5060®" by the company 3M, or bromoperfluorooctyl sold under the name "FORALKYL" "by the Atochem Company; nonafluoromethoxybutane and nonafluoroethoxyisobutane; perfluoromorpholine derivatives, such as 4-trifluoromethyl perfluoromorpholine sold under the name "PF 5052®" by the company 3M. The fatty alcohols that can be used in the composition according to the invention are saturated or unsaturated, linear or branched, and contain from 6 to 30 carbon atoms and more particularly from 8 to 18 carbon atoms. For example, cetyl alcohol, stearyl alcohol and their mixture (cetylstearyl alcohol), octyldodecanol, 2-butyloctanol, 2-hexyldecanol, 2-undecylpentadecanol, oleic alcohol or linoleic alcohol may be mentioned; . The wax or waxes that may be used in the composition according to the invention are chosen in particular from Carnauba wax, Candelila wax, and Alfa wax, paraffin wax, ozokerite and waxes. vegetable oils such as olive wax, rice wax, hydrogenated jojoba wax or absolute waxes of flowers such as the essential wax of blackcurrant flower sold by the company BERTIN (France), animal waxes such as waxes bees, or modified beeswaxes (cerabellina); other waxes or waxy raw materials that can be used according to the invention are, in particular, marine waxes, such as the one sold by SOPHIM under the reference M82, and polyethylene or polyolefin waxes in general. With regard to the fatty acid esters and / or fatty alcohols, advantageously different from the triglycerides mentioned above, mention may in particular be made of saturated or unsaturated, linear or branched C 1 -C 26 aliphatic mono or poly acid esters and of saturated or unsaturated, linear or branched C1 to C26 aliphatic mono or polyalcohols, the total number of carbon of the esters being more particularly greater than or equal to 10.

Among the monoesters, mention may be made of dihydroabiethyl behenate; octyldodecyl behenate; isoketyl behenate; cetyl lactate; C12 to C15 alkyl lactate; isostearyl lactate; lauryl lactate; linoleyl lactate; oleyl lactate; (iso) stearyl octanoate; isocetyl octanoate; octyl octanoate; cetyl octanoate; decyl oleate; isocetyl isostearate; isocetyl laurate; isocetyl stearate; isodecyl octanoate; isodecyl oleate; isononyl isononanoate; isostearyl palmitate; methyl ricinoleate acetyl; myristyl stearate; octyl isononanoate; 2-ethylhexyl isononanoate; octyl palmitate; octyl pelargonate; octyl stearate; octyldodecyl erucate; oleyl erucate; ethyl and isopropyl palmitates, ethyl-2-hexyl palmitate, 2-octyldecyl palmitate, alkyl myristates such as isopropyl, butyl, cetyl, 2-octyldodecyl myristate; , styryl, hexyl stearate, butyl stearate, isobutyl stearate; dioctyl malate, hexyl laurate, 2-hexyldecyl laurate. Still within the scope of this variant, it is also possible to use esters of C 4 to C 22 di or tricarboxylic acids and of C 1 to C 22 alcohols and esters of mono di or tricarboxylic acids and di, tri, alcohols. C2 to C26 tetra or pentahydroxy. These include: diethyl sebacate; diisopropyl sebacate; diisopropyl adipate; di-propyl adipate; dioctyl adipate; diisostearyl adipate; dioctyl maleate; glyceryl undecylenate; octyldodecyl stearoyl stearate; pentaerythrityl monoricinoleate; pentaerythrityl tetraisononanoate; pentaerythrityl tetrapelargonate; pentaerythrityl tetraisostearate; pentaerythrityl tetraoctanoate; propylene glycol dicaprylate; propylene glycol dicaprate, tridecyl erucate; triisopropyl citrate; triisotearyl citrate; glyceryl trilactate; glyceryl trioctanoate; trioctyldodecyl citrate; trioleyl citrate, propylene glycol dioctanoate; neopentyl glycol diheptanoate; diethylene glycol diisanonate; and polyethylene glycol distearates. Among the esters mentioned above, it is preferred to use ethyl, isopropyl, myristyl, cetyl, stearyl palmitates, ethyl-2-hexyl palmitate, 2-octyldecyl palmitate, sodium myristates and the like. alkyls such as isopropyl, butyl, cetyl, 2-octyldodecyl myristate, hexyl stearate, butyl stearate, isobutyl stearate; dioctyl malate, hexyl laurate, 2-hexyldecyl laurate and isononyl isonononate, cetyl octanoate.

The composition may also comprise, as fatty ester, esters and diesters of C 6 to C 30, preferably C 12 to C 22, fatty acid sugars. It is recalled that "sugar" is understood to mean oxygenated hydrocarbon compounds which have several alcohol functions, with or without an aldehyde or ketone function, and which contain at least 4 carbon atoms. These sugars can be monosaccharides, oligosaccharides or polysaccharides. Suitable sugars include, for example, sucrose (or sucrose), glucose, galactose, ribose, fucose, maltose, fructose, mannose, arabinose, xylose, lactose, and their derivatives. especially alkyls, such as methyl derivatives such as methylglucose. The esters of sugars and of fatty acids may be chosen in particular from the group comprising the esters or mixtures of esters of sugars described previously and of C 6 to C 30, preferably C 12 to C 22 fatty acids, linear or branched, saturated or unsaturated. If unsaturated, these compounds may comprise one to three carbon-carbon double bonds, conjugated or otherwise. The esters according to this variant may also be chosen from mono-, di-, tri- and tetraesters, polyesters and mixtures thereof. These esters may be for example oleate, laurate, palmitate, myristate, behenate, cocoate, stearate, linoleate, linolenate, caprate, arachidonates, or mixtures thereof, such as in particular the mixed oleo-palmitate, oleostearate and palmito-stearate esters. More particularly, the mono- and di-esters are used, and especially the mono- or dioleate, stearate, behenate, oleopalmitate, linoleate, linolenate, oleostearate, sucrose, glucose or methylglucose.

By way of example, mention may be made of the product sold under the name Glucatee DO by the company Amerchol, which is a methylglucose dioleate. Mention may also be made, by way of examples, of esters or mixtures of esters of fatty acid sugar: the products sold under the names F160, F140, F110, F90, F70 and 5L40 by the company Crodesta, respectively denoting sucrose palmito-stearates of 73% monoester and 27% di- and tri-ester, 61% monoester and 39% di-, tri- and tetraester, 52% monoester and 48% monoester; % di-, tri- and tetraester, 45% monoester and 55% di-, tri- and tetraester, 39% monoester and 61% di-, tri-, and tetra. -ester, and sucrose mono-laurate; the products sold under the name Ryoto Sugar Esters, for example referenced B370 and corresponding to sucrose behenate formed from 20% monoester and 80% di-triester-polyester; the sucrose mono-di-palmito-stearate marketed by Goldschmidt under the name Tegosofte PSE. The silicones that can be used in accordance with the invention can be in the form of oils, waxes, resins or gums.

Preferably, the silicone is chosen from polydialkylsiloxanes, especially polydimethylsiloxanes (PDMS), and organomodified polysiloxanes comprising at least one functional group chosen from amino groups, aryl groups and alkoxy groups. Organopolysiloxanes are further defined in Walter Noll's "Chemistry and Technology of Silicones" (1968), Academie Press. They can be volatile or nonvolatile. When they are volatile, the silicones are more particularly chosen from those having a boiling point of between 60 ° C. and 260 ° C., and even more particularly from: (i) cyclic polydialkylsiloxanes containing from 3 to 7, preferably from 4 to 5 silicon atoms. It is, for example, octamethylcyclotetrasiloxane sold in particular under the name VOLATILE SILICONE® 7207 by UNION CARBIDE or SILBIONE® 70045 V2 by RHODIA, decamethylcyclopentasiloxane marketed under the name VOLATILE SILICONE® 7158 by UNION CARBIDE, and SILBIONE ® 70045 V5 by RHODIA, as well as their mixtures.

Mention may also be made of cyclocopolymers of the dimethylsiloxane / methylalkylsiloxane type, such as the VOLATILE® SILICONE FZ 3109 marketed by UNION CARBIDE, of formula: ## STR2 ## C8I-117 CH3 with D ': Cyclic polydialkylsiloxane mixtures can also be mentioned with organic compounds derived from silicon, such as the mixture of octamethylcyclotetrasiloxane and tetramethylsilylpentaerythritol (50/50) and the mixture of octamethylcyclotetrasiloxane and oxy-1,1 '- (hexa-2,2,2', 2 ', 3,3'-trimethylsilyloxy) bis-neopentane (ii) linear volatile polydialkylsiloxanes having 2 to 9 silicon atoms and having a lower viscosity or equal to 5.10-6 m2 / s at 25 ° C. It is, for example, decamethyltetrasiloxane marketed in particular under the name "SH 200" by the company Toray Silicone, silicones entering this class are also described in US Pat. ar article published in Cosmetics and Toiletries, Vol. 91, Jan. 76, p. 27-32 - TODD & BYERS "Volatile Silicone fluids for cosmetics". Non-volatile polydialkylsiloxanes, polydialkylsiloxane gums and resins, polyorganosiloxanes modified with the above organofunctional groups and mixtures thereof are preferably used.

These silicones are more particularly chosen from polydialkylsiloxanes, among which may be mentioned mainly polydimethylsiloxanes with trimethylsilyl end groups. The viscosity of the silicones is measured at 25 ° C. according to ASTM 445 Appendix C.

Among these polydialkylsiloxanes, mention may be made, without limitation, of the following commercial products: SILBIONE® oils of the 47 and 70 047 series or the MIRASIL® oils marketed by RHODIA, such as, for example, the 70 047 V 500 000 oil; the oils of the MIRASIL® series marketed by RHODIA; the oils of the 200 series of Dow Corning, such as DC200 having a viscosity of 60,000 mm 2 / s; - VISCASIL® oils from GENERAL ELECTRIC and some oils from SF series (SF 96, SF 18) from GENERAL ELECTRIC. Mention may also be made of polydimethylsiloxane dimethylsilanol end groups known under the name of dimethiconol (CTFA), such as the oils of the 48 series from Rhodia.

In this class of polydialkylsiloxanes, mention may also be made of the products sold under the names "ABIL WAX® 9800 and 9801" by GOLDSCHMIDT, which are polydialkyl (C 1 -C 20) siloxanes.

The silicone gums that can be used in accordance with the invention are in particular polydialkylsiloxanes, preferably polydimethylsiloxanes having high average molecular weights of between 200,000 and 1,000,000 used alone or in a mixture in a solvent. This solvent may be chosen from volatile silicones, polydimethylsiloxane (PDMS) oils, polyphenylmethylsiloxane (PPMS) oils, isoparaffins, polyisobutylenes, methylene chloride, pentane, dodecane, tridecane or their mixtures. More particularly useful products according to the invention are mixtures such as: - mixtures formed from a hydroxyl end-of-the-chain polydimethylsiloxane, or dimethiconol (CTFA) and a cyclic polydimethylsiloxane also called cyclomethicone (CTFA) such that the product Q2 1401 marketed by the company Dow Corning; mixtures of a polydimethylsiloxane gum and a cyclic silicone such as the product SF 1214 Silicone Fluid from the company General Electric, this product is an SF 30 gum corresponding to a dimethicone, having a number average molecular weight of 500,000 solubilized in oil SF 1202 Silicone Fluid corresponding to decamethylcyclopentasiloxane; mixtures of two PDMSs of different viscosities, and more particularly of a PDMS gum and a PDMS oil, such as the product SF 1236 from the company General Electric. The product SF 1236 is the mixture of an SE 30 gum defined above having a viscosity of 20 m 2 / s and an SF 96 oil with a viscosity of 5.10-6 m 2 / s. This product preferably comprises 15% of SE 30 gum and 85% of an SF 96 oil.

The organopolysiloxane resins used in accordance with the invention are crosslinked siloxane systems containing the units: R 2 SiO 2/2, R 3 SiO 1/2, RSiO 3/2 and SiO 4/2 in which R represents an alkyl having 1 to 16 carbon atoms. Among these products, those that are particularly preferred are those in which R denotes a lower C 1 -C 4 alkyl group, more particularly methyl. Among these resins may be mentioned the product marketed under the name "Dow Corning 593" or those sold under the names "Silicone Fluid SS 4230 and SS 4267" by the company General Electric and which are silicones of dimethyl / trimethyl siloxane structure. Mention may also be made of the trimethylsiloxysilicate type resins sold in particular under the names X22-4914, X21-5034 and X21-5037 by the company Shinet Su. The organomodified silicones that may be used according to the invention are silicones as defined above and comprising in their structure one or more organofunctional groups attached via a hydrocarbon-based group. The organomodified silicones may be polydiaryl siloxanes, especially polydiphenylsiloxanes, and polyalkylarylsiloxanes functionalized with the organofunctional groups mentioned above. The polyalkylarylsiloxanes are particularly chosen from polydimethyl / methylphenylsiloxanes, linear and / or branched polydimethyl / diphenylsiloxanes with a viscosity ranging from 1 × 10 -5 to 5 × 10 -2 m 2 / s at 25 ° C.

Among these polyalkylarylsiloxanes, mention may be made by way of example of the products sold under the following names: SILBIONE® oils of the 70 641 series from RHODIA; - the RHODORSIL® 70 633 and 763 RHODIA series of oils; - DOW CORNING 556 COSMETIC GRAD FLUID oil from Dow Corning; the silicones of the PK series of BAYER, such as the product PK20; the silicones of the PN, PH series of BAYER, such as the PN1000 and PH1000 products; certain oils of the SF series of GENERAL ELECTRIC such as SF 1023, SF 1154, SF 1250 and SF 1265. Among the organomodified silicones, mention may also be made of polyorganosiloxanes comprising: substituted or unsubstituted amino groups, such as the products sold under the name GP 4 Silicone Fluid and GP 7100 by the company GENESEE or the products sold under the names Q2 8220 and Dow Corning 929 or 939 by Dow Corning. The substituted amino groups are, in particular, C1-C4 aminoalkyl groups; alkoxylated groups, such as the product sold under the name "Silicone Copolymer F-755" by SWS Silicones and Abil Wax® 2428, 2434 and 2440 by the company GOLDSCHMIDT. Preferably, the fatty substances that can be used in the composition according to the invention are non-silicone.

More particularly, the fatty substances are chosen from liquid or pasty compounds at room temperature (25 ° C.) and at atmospheric pressure. Preferably, the fatty substances that can be used in the composition according to the invention are non-silicone oils.

By "oil" is meant a "fat" which is liquid at room temperature (25 ° C), and at atmospheric pressure (760 mm Hg).

The term "non-silicone oil" means an oil containing no silicon atom (Si) and a "silicone oil" an oil containing at least one silicon atom. And more preferably, as indicated above, the fatty substances used in the dyeing composition according to the invention are liquid and non-silicone. Preferably, the fatty substance (s) present in the composition according to the invention are chosen from fatty alcohols, esters of fatty acids and / or fatty alcohol different from triglycerides, oils of mineral origin, and vegetable oils. triglyceride type and mixtures thereof. In a first variant, the amount of the fat or fats present in the composition according to the invention is greater than or equal to 10% by weight, preferably greater than or equal to 15% by weight, more preferably greater than or equal to 20% by weight. % by weight, and better still or equal to 30% by weight, relative to the total weight of the composition. In a second variant, the amount of the fat or fats present in the composition according to the invention ranges from 0.01 to 10% by weight, preferably from 0.5 to 5% by weight, relative to the weight of the total composition. The composition according to the invention may optionally further comprise one or more surfactants. The surfactant or surfactants that may be used in the composition according to the invention may be chosen from nonionic, cationic, anionic and amphoteric or zwitterionic surfactants. The composition according to the invention may comprise one or more nonionic surfactants. Nonionic surfactants which can be used are described, for example, in "Handbook of Surfactants" by M. R. PORTER, Blackie & Son editions (Glasgow and London), 1991, pp. 116-178. By way of examples of nonionic surfactants, mention may be made of the following nonionic surfactants: oxyalkylenated (C 8 -C 24) alkyl phenols; - saturated or unsaturated C8 to C40 alcohols, linear or branched, oxyalkylenated or glycerolated, and having one or two fatty chains; saturated or unsaturated, linear or branched, oxyalkylenated C8 to C30 fatty acid amides; saturated or unsaturated linear or branched C 8 -C 30 acid esters of polyethylene glycols; saturated or unsaturated, linear or branched C 8 to C 30 acid esters, and preferably oxyethylenated sorbitol esters; esters of sucrose fatty acids, alkyl (C 8 -C 30) (poly) glucosides, (C 8 -C 30) alkenyls (poly) glucosides, optionally oxyalkylenated (0 to 10 oxyalkylenated units) and comprising from 1 to Glucose units, (C8-C30) alkyl esters (poly) glucosides, oxyethylenated vegetable oils, saturated or not; condensates of ethylene oxide and / or propylene oxide; derivatives of N-alkyl (C8-C3o) glucamine and N-acyl (C8-C30) methylglucamine; aldobionamides; amine oxides; oxyethylenated and / or oxypropylenated silicones, and mixtures thereof. The oxyalkylenated units are more particularly oxyethylenated units, oxypropylene, or their combination, preferably oxyethylenated. The number of moles of ethylene oxide and / or propylene oxide is preferably from 1 to 250, more preferably from 2 to 100; better from 2 to 50; the number of moles of glycerol ranges from 1 to 50, more preferably from 1 to 10. Advantageously, the nonionic surfactants according to the invention do not comprise oxypropylene units. As an example of glycerolated nonionic surfactants, it is preferable to use C 8 -C 40 mono- or polyglycerolated alcohols comprising from 1 to 50 moles of glycerol, preferably from 1 to 10 moles of glycerol. By way of example of compounds of this type, mention may be made of lauryl alcohol with 4 moles of glycerol (INCI name: P0LYGLYCERYL-4 LAURYL ETHER), lauric alcohol with 1.5 moles of glycerol, alcohol oleic acid with 4 moles of glycerol (INCI name: P0LYGLYCERYL-4 OLEYL ETHER), oleic alcohol with 2 moles of glycerol (INCI name: P0LYGLYCERYL-2 OLEYL ETHER), cetearyl alcohol with 2 moles of glycerol, alcohol 6 moles of glycerol, oleocetyl alcohol with 6 moles of glycerol, and octadecanol with 6 moles of glycerol. Among the glycerolated alcohols, it is more particularly preferred to use the C8 / C10 alcohol with one mole of glycerol, the C10 / C12 alcohol with 1 mole of glycerol and the C12 alcohol with 1.5 moles of glycerol.

The nonionic surfactant or surfactants that can be used in the composition according to the invention are preferably chosen from: oxyethylenated C 8 to C 40 alcohols comprising from 1 to 100 moles of ethylene oxide, preferably from 2 to 50, more particularly from 2 to 40 moles of ethylene oxide and having one or two fatty chains; saturated or unsaturated oxyethylenated vegetable oils comprising from 1 to 100 moles of ethylene oxide, preferably from 2 to 50; (C 8 -C 30) alkyl (poly) glucosides, optionally oxyalkylenated (0 to 10 OE) and comprising 1 to 15 glucose units; - C8 to C40 alcohols, mono- or poly-glycerolated, comprising from 1 to 50 moles of glycerol, preferably from 1 to 10 moles of glycerol; saturated or unsaturated, linear or branched, oxyalkylenated C8 to C30 fatty acid amides; saturated or unsaturated linear or branched C 8 -C 30 acid esters of polyethylene glycols; - and their mixtures.

The composition according to the invention may comprise one or more cationic surfactants. The term "cationic surfactant" means a positively charged surfactant when it is contained in the composition according to the invention. This surfactant may carry one or more positive permanent charges or contain one or more cationizable functions within the composition according to the invention. The cationic surfactant or surfactants are preferably chosen from primary, secondary or tertiary fatty amines, optionally polyoxyalkylenated, or their salts, quaternary ammonium salts, and mixtures thereof. The fatty amines generally comprise at least one Cs to C30 hydrocarbon chain. As quaternary ammonium salts, mention may be made, for example: - those corresponding to the following general formula (V): ## STR5 ## in which, groups R28 to R31, which may be identical or different, represent a linear or branched aliphatic group containing from 1 to 30 carbon atoms, or an aromatic group such as aryl or alkylaryl, at least one of the groups R28 to R31 denoting a group comprising from 8 to 30 carbon atoms, preferably from 12 to 24 carbon atoms The aliphatic groups may comprise heteroatoms such as, in particular, oxygen, nitrogen, sulfur and halogens, and the aliphatic groups may be chosen, for example, from alkyl groups. C1 to C30, C1 to C30 alkoxy, (C2-C6) polyoxyalkylene, C1 to C30 alkylamide, (C12-C22) alkyl (C2-C6) amidoalkyl, (C12-C22) alkyl, and C1 to C10 hydroxyalkyl. C30; X- is an anion selected from the group of halides, phosphates, ac tates, lactates, alkyl (Ci-C4) sulfates, alkyl (Ci-C4) - alkyl or (C C4) alkyl aryl sulphonates. Of the quaternary ammonium salts of formula (V), tetraalkylammonium salts, such as, for example, dialkyldimethylammonium or alkyltrimethylammonium salts in which the alkyl group comprises from about 12 to 22 carbon atoms, are preferred. carbon, in particular the salts of behenyltrimethylammonium, di stearyldimethylammonium, cetyltrimethylammonium, benzyldimethylstearylammonium or, on the other hand, palmitylamidopropyltrimethylammonium, stearamidopropyltrimethylammonium salts, stearamidopropyldimethylceararyl ammonium salts, or stearamidopropyldimethyl (myristylacetate) salts. ammonium marketed under the name CERAPHYLe 70 by VAN DYK. It is particularly preferred to use the chloride salts of its compounds. the quaternary ammonium salts of imidazoline, such as, for example, those of formula (VI) below: ## STR5 ## wherein R32 represents an alkenyl or alkyl group having 8 to 30 carbon atoms, for example fatty acid derivatives of tallow, R33 represents a hydrogen atom, a C1-C4 alkyl group or an alkenyl or alkyl group containing from 8 to 30 carbon atoms, R34 represents a C1-C4 alkyl group, R35 represents a hydrogen atom, a C1-C4 alkyl group, X- is an anion chosen from the group of halides, phosphates, acetates, lactates, alkyls sulfates, alkyl- or alkylarylsulphonates whose alkyl and aryl groups preferably comprise respectively 1 to 20 carbon atoms and 6 to 30 carbon atoms. Preferably, R 32 and R 33 denote a mixture of alkenyl or alkyl groups containing from 12 to 21 carbon atoms, for example fatty acid derivatives of tallow, R 34 denotes a methyl group and R 35 denotes a hydrogen atom. Such a product is for example marketed under the name REWOQUATe W 75 by the company REWO; - Quaternary di or triammonium salts, in particular of formula (VII): ## STR5 ## wherein R 36 denotes an alkyl radical having about 16 carbon atoms; to 30 carbon atoms optionally hydroxyl and / or interrupted by one or more oxygen atoms, R37 is selected from hydrogen or an alkyl radical having 1 to 4 carbon atoms or a group (R3 6 a) (R3 7 a) (R 38 a) N- (CH2) 3, R3 6a, R3 7a, R38a, R38, R39, R40 and R41, which are identical or different, are chosen from hydrogen or an alkyl radical containing from 1 to 4 carbon atoms, and X- is an anion selected from the group of halides, acetates, phosphates, nitrates and methylsulfates. Such compounds are, for example, the Finquat CT-P proposed by Finetex (Quaternium 89), the Finquat CT proposed by Finetex (Quaternium 75), the quaternary ammonium salts containing at least one ester function, such as those of the following formula (VIII): 2X X (VIII) O (C, 1-12s0) R 45 1 1 1 + R 44 C - (OC, 1-12dy-N- (CtH 2 O)) - R 43 R 42 in which: R 42 is chosen from C 1 to C 6 alkyl groups and C 1 to C 6 hydroxyalkyl or dihydroxyalkyl groups, R 43 is chosen from: O - the group R 46 C - - R 47 groups which are linear or branched C 1 to C 22 hydrocarbon groups saturated or unsaturated, - the hydrogen atom, R45 is chosen from: o - the group R48 C - the groups R49 which are C1-C6 hydrocarbon groups, linear or branched, saturated or unsaturated, - the atom of hydrogen, R44, R46 and R48, which are identical or different, are chosen from linear or branched C7 to C21 hydrocarbon groups, which are saturated, s or unsaturated; r, s and t, which are identical or different, are integers from 2 to 6; y is an integer from 1 to 10; x and z, which are identical or different, are integers ranging from 0 to 10; X- is a simple or complex anion, organic or inorganic; with the proviso that the sum x + y + z is from 1 to 15, that when x is 0, then R43 is R47 and that when z is 0 then R45 is R4 9.

The alkyl groups R42 may be linear or branched and more particularly linear. Preferably, R 42 denotes a methyl, ethyl, hydroxyethyl or dihydroxypropyl group, and more particularly a methyl or ethyl group. Advantageously, the sum x + y + z is from 1 to 10. When R43 is a hydrocarbon R47 group, it may be long and have from 12 to 22 carbon atoms, or short and have from 1 to 3 carbon atoms.

When R45 is a hydrocarbon R49 group, it preferably has 1 to 3 carbon atoms. Advantageously, R44, R46 and R48, which are identical or different, are chosen from linear or branched, saturated or unsaturated C11 to C21 hydrocarbon groups, and more particularly from linear or branched, saturated C11 to C21 alkyl and alkenyl groups. or unsaturated. Preferably, x and z, which are identical or different, are equal to 0 or 1. Advantageously, y is equal to 1. Preferably, r, s and t, identical or different, are equal to 2 or 3, and even more particularly are equal to 2 The anion X- is preferably a halide (chloride, bromide or iodide) or an alkyl sulphate, more particularly methyl sulphate. However, it is possible to use methanesulphonate, phosphate, nitrate, tosylate, an anion derived from an organic acid such as acetate or lactate or any other anion compatible with ammonium with an ester function. The X- anion is even more particularly chloride or methylsulfate. In the composition according to the invention, the ammonium salts of formula (VIII) are used more particularly in which: R 42 denotes a methyl or ethyl group, x and y are equal to 1; z is 0 or 1; r, s and t are 2; R 43 is selected from: R 14 -C 46 - the group - methyl, ethyl or C 14 to C 22 hydrocarbon groups, - the hydrogen atom; R 45 is selected from: R 48 C - the group - the hydrogen atom; R44, R46 and R48, which are identical or different, are chosen from linear or branched, saturated or unsaturated C13-C17 hydrocarbon-based groups, and preferably from linear or branched, saturated or unsaturated C13-C17 alkyl and alkenyl groups; . Advantageously, the hydrocarbon groups are linear. There may be mentioned, for example, the compounds of formula (VIII) such as the salts (in particular chloride or methylsulfate) of diacyloxyethyl dimethylammonium, diacyloxyethylhydroxyethylmethylammonium, monoacyloxyethyl dihydroxyethylmethylammonium, triacyloxyethylmethylammonium, monoacyloxyethylhydroxyethyl dimethylammonium and mixtures thereof. The acyl groups preferably have from 14 to 18 carbon atoms and come more particularly from a vegetable oil such as palm oil or sunflower oil. When the compound contains more than one acyl group, the latter groups may be identical or different. These products are obtained, for example, by direct esterification of triethanolamine, triisopropanolamine, alkyldiethanolamine or alkyldiisopropanolamine, optionally oxyalkylenated, with C 10 -C 30 fatty acids or with mixtures of C 10 -C 30 fatty acids. plant or animal origin, or by transesterification of their methyl esters. This esterification is followed by quaternization using an alkylating agent such as an alkyl halide (preferably methyl or ethyl), a dialkyl sulphate (preferably methyl or ethyl), methanesulfonate. methyl, para-toluenesulfonate methyl, chlorohydrin glycol or glycerol. Such compounds are, for example, sold under the names DEHYQUARTe by the company HENKEL, STEPANQUATe by the company STEPAN, NOXAMIUMe by the company CECA, REWOQUATe WE 18 by the company REWO-WITCO. The composition according to the invention may contain, for example, a mixture of quaternary ammonium mono-, di- and triester salts with a majority by weight of diester salts. It is also possible to use the ammonium salts containing at least one ester function described in US-A-4874554 and US-A4137180. Behemoylhydroxypropyltrimethylammonium chloride proposed by KAO can be used under the name Quatarmin BTC 131. Preferably, the ammonium salts containing at least one ester function contain two ester functions. Of the quaternary ammonium salts containing at least one useful ester group, it is preferred to use dipalmitoylethylhydroxyethylmethylammonium salts. The cationic surfactants are preferably chosen from those of formula (V) and those of formula (VIII), and more preferably from those of formula (V). The composition according to the invention may comprise one or more anionic surfactants. The term "anionic surfactant" is understood to mean a surfactant comprising as ionic or ionizable groups only anionic groups. These anionic groups are preferably chosen from the groups -COOH, -000-, -503H, -503-, -0503H, -0503-, -PO2H2, -PO2H-, -PO2-, -P (OH) 2, = P (O) OH, -P (OH) O, = P (O) O-, = POH, = PO-, the anionic parts comprising a cationic counterion such as an alkali metal, an alkaline earth metal, or an ammonium.

As examples of anionic surfactants that can be used in the composition according to the invention, mention may be made of alkyl sulphates, alkyl ether sulphates, alkylamido ether sulphates, alkylaryl polyether sulphates, monoglyceride sulphates, alkyl sulphonates, alkyl amide sulphonates, alkyl aryl sulphonates, alpha-olefin-sulfonates, paraffin-sulfonates, alkylsulfosuccinates, alkylethersulfosuccinates, alkylamidesulfosuccinates, alkylsulfoacetates, acylsarcosinates, acylglutamates, alkylsulfosuccinamates, acylisethionates and N-acyltaurates, monoesters salts of alkyl and polyglucoside-polycarboxylic acids, acyllactylates, D-galactoside-uronic acid salts, alkyl ether-carboxylic acid salts, alkyl aryl ether carboxylic acid salts, alkyl acid salts amidoether carboxylic acids, and the corresponding non-salified forms of all these compounds, alkyl and acyl groups of These compounds have from 6 to 40 carbon atoms and the aryl group designates a phenyl group. These compounds may be oxyethylenated and then preferably comprise from 1 to 50 ethylene oxide units.

The salts of C 6 to C 24 alkyl monoesters and of polyglucoside-polycarboxylic acids may be chosen from C 6 to C 24 alkyl polyglucoside citrates, C 6 to C 24 alkyl polyglucosidestartrates and polyglucoside sulphosuccinates. C6 to C24 alkyl.

When the anionic surfactant (s) is in salt form, they may be chosen from alkali metal salts such as sodium or potassium salt and preferably sodium salt, ammonium salts, amine salts and aminoalcohols or alkaline earth metal salts such as magnesium salts.

By way of example of aminoalcohol salts, mention may be made in particular of the salts of mono-, di- and triethanolamine, the salts of mono-, di- or triisopropanolamine and the salts of 2-amino-2-methyl-1-one. propanol, 2-amino-2-methyl-1,3-propanediol methane. and tris (hydroxymethyl) amino. Alkali or alkaline earth metal salts, and in particular sodium or magnesium salts, are preferably used. Among the anionic surfactants mentioned, it is preferable to use (C6-C24) alkylsulphates, (C6-C24) alkylsulphates comprising from 2 to 50 ethylene oxide units, in particular in the form of alkali metal salts, ammonium salts, aminoalcohols, and alkaline earth metals, or a mixture of these compounds. In particular, it is preferred to use (C 12 -C 20) alkyl sulphates, C 12 -C 20 alkyl ether sulphates comprising from 2 to 20 ethylene oxide units, especially in the form of alkali metal salts, ammonium salts, aminoalcohol , and alkaline earth metals, or a mixture of these compounds. More preferably, it is preferred to use sodium lauryl ether sulfate with 2.2 moles of ethylene oxide. The composition according to the invention may comprise one or more amphoteric or zwitterionic surfactants. In particular, the amphoteric or zwitterionic surfactant (s), preferably non-silicone surfactants, that may be used in the composition according to the present invention may be in particular derivatives of secondary or tertiary aliphatic amines, optionally quaternized, in which the aliphatic group is a linear chain. or branched having from 8 to 22 carbon atoms, said amine derivatives containing at least one anionic group such as, for example, a carboxylate group, sulfonate, sulfate, phosphate or phosphonate.

Mention may in particular be made of (C8-C20) alkyl betaines, (C8-C20) alkylsulfobetaines, (C8-C20) alkylamido (C3-C8) alkylbetaines and (C8-C20) alkylamidalkyls (C6-C6). C8) sulphobetaines. Among the derivatives of secondary or tertiary aliphatic amines, optionally quaternized, which can be used, as defined above, there may also be mentioned the compounds of respective structures (IX) and (X): Ra-CONHCH2CH2-1 (rb) (R 1) - CH 2 CO 2 -, M, X- (IX) Formula wherein: Ra represents a C 10 -C 30 alkyl or alkenyl group derived from an acid RaCOOH, preferably present in hydrolysed coconut oil, a heptyl, nonyl or undecyl group; Rb represents a beta-hydroxyethyl group; and - R, represents a carboxymethyl group; M + represents a cationic counterion derived from an alkali metal, alkaline earth metal, such as sodium, an ammonium ion or an ion derived from an organic amine, and X represents an organic or inorganic anionic counterion, such as that selected from halides, acetates, phosphates, nitrates, (C 1 -C 4) alkyl sulphates, (C 1 -C 4) alkyl or (C 1 -C 4) alkylsulphonates, in particular methylsulphate and ethylsulphate; or else M + and X- are absent; Ra-CONHCH2CH2-N (B) (B ') (X) Formula wherein: - B represents the group -CH2CH2OX'; B 'represents the group - (CH2) zY', with z = 1 or 2; X 'represents the group -CH2COOH, -CH2-COOZ', -CH2CH2COOH, CH2CH2-COOZ ', or a hydrogen atom; Y 'represents the group -COOH, -COOZ', -CH2CH (OH) SO311 or the group CH2CH (OH) SO3-Z '; Z 'represents a cationic counterion derived from an alkaline or alkaline earth metal, such as sodium, an ammonium ion or an ion derived from an organic amine; Ra represents a C 10 to C 30 alkyl or alkenyl group of an Ra-COOH acid preferably present in coconut oil or in hydrolysed linseed oil, an alkyl group, in particular a C 17 and its iso form, unsaturated C17 group. These compounds are classified in the CTFA dictionary, 5th edition, 1993, under the names cocoamphodiacétate disodium, lauroamphodiacétate disodium, caprylamphodiacétate disodium, capryloamphodiacétate disodium, cocoamphodipropionate disodium, lauroamphodipropionate disodium, caprylamphodipropionate disodium, capryloamphodipropionate di sodium, lauroamphodipropionic acid, cocoamphodipropionic acid. By way of example, mention may be made of cocoamphodiacetate marketed by Rhodia under the trade name MIRANOLe C2M Concentrate. It is also possible to use compounds of formula (XI); Ra - NHCH (Y '') - (CH2) nCONH (CH2) n -N (Rd) (Re) (XI) Formula wherein: Y "represents the group -COOH, -COOZ", -CH2- CH (OH) SO 3 H or the group CH 2 CH (OH) SO 3 Z 2 - Rd and Re, independently of one another, represent a C 1 -C 4 alkyl or hydroxyalkyl radical; Z 2 represents a cationic counterion; derived from an alkaline or alkaline earth metal, such as sodium, an ammonium ion or an ion derived from an organic amine; - Ra- represents a C10 to C30 alkyl or alkenyl group of an acid Ra - COOH preferably present in coconut oil or in hydrolysed linseed oil; n and n ', independently of one another, denote an integer ranging from 1 to 3. Among the compounds of formula (XI), mention may be made of the compound classified in the CTFA dictionary under the name sodium diethylaminopropyl cocoaspartamide and marketed by CHIMEX under the name CHIMEXANE HB.

These compounds can be used alone or in mixtures. Among the amphoteric or zwitterionic surfactants mentioned above, use is preferably made of alkyl (C 8 -C 20) betaines such as cocobetaine, (C 8 -C 20) alkylamido (C 3 -C 8) alkyl betaines such as cocamidopropylbetaine, and mixtures thereof. the compounds of formula (XIII) such as the sodium salt of diethylaminopropyl laurylamino succinamate (INCI name: sodium diethylaminopropyl cocoaspartamide). Preferably, the surfactant (s) present in the composition according to the invention are chosen from nonionic and cationic surfactants and mixtures thereof. The amount of the surfactant (s) present in the composition according to the invention may range from 0.1 to 25% by weight, and preferably from 0.5 to 20% by weight, relative to the total weight of the composition.

The composition according to the invention may optionally also comprise one or more alkaline agents. Preferably, the dye composition comprises one or more alkaline agents, organic or inorganic, preferably organic.

The inorganic alkaline agent (s) is (are) preferably chosen from ammonia, alkali carbonates or bicarbonates, such as sodium or potassium carbonates or bicarbonates, sodium or potassium hydroxides, or mixtures thereof. The organic alkaline agent (s) is (are) preferably chosen from organic amines whose pKb at 25 ° C. is less than 12, and preferably less than 10, and even more advantageously less than 6. It should be noted that this is pKb corresponding to the highest basicity function. In addition, the organic amines do not comprise a fatty chain, alkyl or alkenyl, comprising more than ten carbon atoms. The organic alkaline agent (s) are, for example, chosen from alkanolamines, ethoxylated and / or oxypropylenated ethylenediamines, amino acids and compounds of the following formula (XII): ## STR2 ## (XII) wherein W is a divalent C1 to C6 alkylene radical optionally substituted by one or more hydroxyl groups or a C1 to C6 alkyl radical, and / or optionally interrupted by one or more heteroatoms such as O, or NRu; Rx Ry, R, Rt and Ru, which may be identical or different, represent a hydrogen atom, a C1-C6 alkyl or C1-C6 hydroxyalkyl radical or a C1-C6 aminoalkyl radical. amines of formula (XII), 1,3 diaminopropane, 1,3 diamino propanol, spermine, spermidine Alkanolamine means an organic amine comprising a primary, secondary or tertiary amine function, and one or more alkyl groups , linear or branched, in C1 to Cs bearing one or more hydroxyl radicals.

In particular, the organic amines chosen from alkanolamines, such as mono-, di- or tri-alkanolamines, comprising one to three identical or different C1 to C4 hydroxyalkyl radicals are suitable in particular for carrying out the invention. Among compounds of this type, mention may be made of monoethanolamine (MEA), diethanolamine, triethanolamine, monoisopropanolamine, diisopropanolamine, N, N-dimethylethanolamine, 2-amino-2-methyl-1-propanol and triisopropanol. amine, 2-amino-2-methyl-1,3-propanediol, 3-amino-1,2-propanediol, 3-dimethylamino-1,2-propanediol, tris-hydroxymethylamino methane. More particularly, the amino acids that can be used are of natural or synthetic origin, in their L, D, or racemic form, and comprise at least one acid function chosen more particularly from the carboxylic, sulphonic, phosphonic or phosphoric acid functions. Amino acids can be in neutral or ionic form. As amino acids that may be used in the present invention, mention may in particular be made of aspartic acid, glutamic acid, alanine, arginine, ornithine, citrulline, asparagine, carnitine and cysteine. , glutamine, glycine, histidine, lysine, isoleucine, leucine, methionine, N-phenylalanine, proline, serine, taurine, threonine, tryptophan, tyrosine and valine. Advantageously, the amino acids are basic amino acids comprising an additional amine function optionally included in a ring or in a ureido function. Such basic amino acids are preferably chosen from those corresponding to the following formula (XIII), and also their R-CH 2 -CH (NH 2) -C (O) -OH (XIII) salts in which R represents a chosen group. from imidazolyl, preferably imidazolyl-4-yl; aminopropyl; aminoethyl; - (CH 2) 2 N (H) -C (O) -NH 2; and - (CH2) 2-N (H) -C (NH) -NH2.

The compounds corresponding to formula (XIII) are histidine, lysine, arginine, ornithine, citrulline. The organic amine may also be chosen from heterocyclic organic amines. In addition to the histidine already mentioned in the amino acids, mention may be made, in particular, of pyridine, piperidine, imidazole, triazole, tetrazole and benzimidazole. The organic amine may also be selected from amino acid dipeptides. As amino acid dipeptides that can be used in the present invention, mention may notably be made of carnosine, anserine and balenine. The organic amine may also be chosen from compounds containing a guanidine function. As amines of this type which can be used in the present invention, mention may in addition be made of the arginine already mentioned as amino acid, creatine, creatinine, 1,1-dimethylguanidine, 1,1-diethylguanidine, glycocyamine, metformin, agmatine, n-amidinoalanine, 3-guanidinopropionic acid, 4-guanidinobutyric acid and 2- gamino (imino) methyl] amino) ethane-1-sulfonic acid .

As hybrid compounds, mention may be made of the salts of the amines mentioned above with acids such as carbonic acid and hydrochloric acid. In particular, guanidine carbonate or monoethanolamine hydrochloride can be used. Preferably, the alkaline agent (s) present in the composition according to the invention are chosen from ammonia, alkanolamines, amino acids in neutral or ionic form, in particular basic amino acids, and preferably corresponding to those of formula (XIII). More preferentially, the alkaline agent (s) present in the composition according to the invention are chosen from ammonia, alkanolamines and mixtures thereof. More preferably, the alkaline agent (s) present in the composition according to the invention are chosen from alkanolamines, and especially monoethanolamine (MEA). The amount of alkali agent (s) present in the composition according to the invention may range from 0.01 to 30% by weight, and preferably from 0.1 to 20% by weight, relative to the total weight of the composition. . The composition according to the invention may optionally comprise one or more additives, different from the compounds of the invention and among which mention may be made of organic solvents, cationic, anionic, nonionic or amphoteric polymers, or mixtures thereof, anti-dandruff agents, antiseborrhoeic agents, agents for preventing and / or regrowing hair, vitamins and provitamines including panthenol, sunscreens, inorganic or organic pigments, sequestering agents, plasticizing agents, solubilizing agents, acidifying agents, agents inorganic or organic thickeners, especially polymeric thickeners, opacifying or pearlescent agents, antioxidants, hydroxy acids, perfumes, preservatives, pigments and ceramides.

Of course, those skilled in the art will take care to choose this or these optional additional compounds in such a way that the advantageous properties intrinsically attached to the composition according to the invention are not, or not substantially, impaired by the addition or additions envisaged . The above additives may generally be present in an amount for each of them ranging from 0 to 20% by weight, relative to the total weight of the composition.

Chemical Oxidizing Agent According to a particular embodiment of the invention, the composition according to the invention comprises at least one chemical oxidizing agent. By chemical oxidizing agent is meant an oxidizing agent different from the oxygen of the air. In particular, the chemical oxidizing agent (s) are, for example, chosen from hydrogen peroxide, urea peroxide, alkali metal bromates, peroxygenated salts such as, for example, persulfates, perborates, peracids and their precursors and alkali or alkaline earth metal percarbonates. Advantageously, the oxidizing agent is hydrogen peroxide. The oxidizing agent or agents generally represent from 0.1 to 50% by weight, preferably from 0.5 to 20%, better still from 1 to 15% by weight relative to the total weight of the dye composition. According to a preferred embodiment, the dye composition according to the invention does not comprise an oxidizing agent, the oxidizing agent is provided by an oxidizing composition.

Another object of the invention is a method for staining human keratinous fibers, in particular the hair comprising the application to the keratinous fibers of the composition according to the invention.

At the time of use, the composition according to the dyeing invention according to the invention (composition (A)) is mixed with an oxidizing composition (B) as described above. The mixture obtained is then applied to the keratinous fibers and left for about 3 to 50 minutes, preferably about 5 to 40 minutes, followed by a rinsing step, washing with shampoo, rinsing again and finally drying. The coloring composition and the oxidizing composition described can be applied sequentially, in any order, with or without intermediate rinsing. The keratinous fibers can be dried at a temperature ranging from 50 to 80 ° C or allowed to dry in the open air. The keratinous fibers may be dried using a hair dryer, a helmet or a straightener in order to perform a shaping step. Preferably, at least one of the compositions (A) or (B) is aqueous. More preferably, the two compositions (A) and (B) are aqueous.

By "aqueous composition" according to the present application is meant a composition comprising at least 5% water. Preferably, an aqueous composition comprises more than 10% by weight of water, and more preferably more than 20% by weight of water. In a first variant of the invention, the coloring composition (A) is aqueous. In a second variant of the invention, the coloring composition (A) comprises at least 10% by weight of fatty substances, preferably at least 15% by weight of fatty substances, and more preferably at least 15% by weight of fatty substances. non-silicone liquid at room temperature (25 ° C). More preferably, the coloring composition (A) comprises at least 20% by weight of fatty substances, and more preferably 20% by weight of non-silicone fatty substances that are liquid at room temperature (25 ° C.).

Even better, the dye composition (A) comprises at least 30% by weight of fatty substances, and more preferably 30% by weight of non-silicone fatty substances that are liquid at room temperature (25 ° C.). Preferably, the dye composition (A) comprises at least 10% by weight of fatty substances, more preferably 15% by weight of non-silicone fatty substances that are liquid at room temperature (25 ° C.) and the oxidizing composition (B) comprises at least 10% by weight of fatty substances, in particular non-silicone fatty substances that are liquid at room temperature (25 ° C.).

More preferably, the dye composition (A) comprises at least 20% by weight of fatty substances, in particular non-silicone fatty substances that are liquid at room temperature (25 ° C.), and the oxidizing composition (B) comprises at least 20% by weight of fatty substances, in particular non-silicone fatty substances that are liquid at room temperature (25 ° C.). More preferably, the coloring composition (A) comprises at least 30% by weight of fatty substances, in particular liquid non-silicone fatty substances at room temperature (25 ° C.) and the oxidizing composition (B) comprises at least 20% by weight of body fatty, in particular non-silicone fatty substances that are liquid at room temperature (25 ° C.). The compositions (A) and (B) are preferably mixed in a weight ratio (A) / (B) ranging from 0.2 to 10, preferably ranging from 0.5 to 2. According to this embodiment, the staining process therefore consists in applying to the keratin fibers the staining composition resulting from the mixture of the compositions (A) and (B) mentioned above. Multi-compartment device Another object of the invention is a device with several compartments, preferably two compartments, for dyeing keratinous fibers, at least one first compartment containing the coloring composition (A) according to the invention and at least one a second compartment containing the oxidizing composition (B) as described above. The present invention finally relates to the use of a composition as described above for the dyeing of keratin fibers, and in particular the hair. The term "keratinous fibers" according to the present application denotes human keratinous fibers, and in particular the hair. The following examples serve to illustrate the invention but are not limiting in nature. EXAMPLES In the examples which follow, all the quantities are indicated as a percentage by weight relative to the total weight of the composition. I. Compositions comprising a compound of formula (II) a. Tested compositions The following coloring compositions, Al and A2, according to the invention were prepared from the ingredients whose contents are indicated in the table below.

Composition Composition Al A2 Ammonia (20% NH3) 7 7 Erythorbic acid 0.5 0.5 Ethanolamine 5.4 4.95 EDTA 0.2 0.2 Sodium sulphite 0.5 0.5 2-ol amine 1,3-octadecanediol 0.01 0.01 2- (methoxymethyl) benzene-1,4-diamine hydrochloride 0.33 0.18 Titanium dioxide 0.3 0.3 2-methyl-5-hydroxyethylaminophenol 0.31 0 4,4-amino-2-hydroxy-toluene 1.254 0.6 2,3-diamino-6,7-dihydro-1H, 5H-2,7-pyrazolo [1,2-a] pyrazol-1-one dimethanesulfonate p -aminophenol 0.25 0.34 C20 to C22 alcohols 3 Perfume 0.5 0.5 Hydroxypropyl methylcellulose 0.19 0.19 hexadimethrin chloride in 2 2 aqueous solution 60% Polyquaternium-6 in solution 5 5 aqueous 40 % Cetyl hydroxyethylcellulose 0.45 0.45 Oleic acid 3 3 Steareth-2 5.5 5.5 PEG-40 stearate (ethoxylated) 1.8 1.8 Monoethanolamine stearamide 4.8 4.8 Oleth-30 1.5 1 The following oxidizing composition, Bi, according to the invention was prepared from the ingredients whose contents are indicated in FIG. table below.

Composition B1 Pentasodium pentetate 0.15 40% aqueous solution Hydrogen peroxide 6 Sodium stannate 0.04 Sodium pyrophosphate 0.02 Glycerol 0.5 Trideceth-2 carboxamide MEA 0.85 Cetearyl alcohol mixture and 2.85 ceteareth -25 Phosphoric acid Qs pH = 2.2 ± 0.2 Water Qs 100 b. Procedure The coloring compositions, Al and A2, are mixed with the oxidizing composition Bi in a weight ratio of 1: 1.5. The mixtures thus obtained are applied to hair strands at 90% natural white. After an exposure time of 35 minutes, the locks are rinsed with clean water, then washed with shampoo, rinsed again. Finally, the locks are dried.

The color of the locks was evaluated visually. vs. Results The results of the coloring are given in the following table.20 Wicks Colored wicks colored with Al + B1 A2 + B1 Color Light brown Copper blond copper red mahogany II. Compositions comprising a compound of formula (III) a. Compositions tested The following coloring compositions, A3 and A4, according to the invention were prepared from the ingredients whose contents are indicated in the table below.

Composition Composition A3 A4 Sodium metabisulfite 0.45 0.45 Ethanolamine 4.43 4.43 EDTA 0.2 0.2 2- (Methoxymethyl) benzene-1,4-diamine hydrochloride 0.5 0.24 2-methyl 5-hydroxyethylaminophenol 0.11 1.06 4-amino-2-hydroxy-toluene 0.7 - 5-amino-6-chloro-o-cresol 0.052 - 2- (2-hydroxyethoxy) -3-aminopyrazolo [1, 5-a] pyridine hydrochloride 0.81 0.82 p-aminophenol 0.1 0.1 Mineral oil 59.7 59.7 Sunflower seed oil 0.1 0.1 Tea seed oil 0.1 0, 1 Passiflora seed oil 0.1 0.1 Meadowfoam seed oil 0.1 0.1 Perfume 0.95 0.95 Polyquaternium-67 0.2 0.2 Steareth-2 1.13 1.13 Steareth-1 3.88 3.88 Caprylyl / capryl glucoside in 4 4 60% aqueous solution Polysorbate 21 2.4 2.4 Ascorbic acid 0.25 0.25 Water Qsp 100 Qsp 100 The following oxidizing composition, B3, according to US Pat. The invention has been prepared from the ingredients whose contents are indicated in the table below. Composition B3 Pentasodium pentetate 0.15 40% aqueous solution Hydrogen peroxide 6 Sodium stannate 0.04 Sodium pyrophosphate 0.03 Mineral oil 20 Hexadimethrine chloride 0.25 60% aqueous solution Polyquaternium-6 solution 0.5 aqueous 40% Glycerol 0.5 Cetearyl alcohol 6 Steareth-20 5 PEG-4 rapeseedamide 1,2 Tocopherol 0.1 Phosphoric acid Qs pH = 2.2 ± 0.2 Water Qs 100 b. Procedure The coloring compositions, A3 and A4, are mixed with the oxidizing composition B3, in a weight ratio equal to 1. The mixtures thus obtained are applied to locks of hair at 90% natural white. After an exposure time of 35 minutes, the locks are rinsed with clear water, then washed with shampoo and rinsed again. Finally, the locks are dried. The color of the locks was assessed visually.15 c. Results The results of the staining are given in the following table. Colorful locks with colored strokes A3 + B3 A4 + B3 Color Dark brown Deep blond deep red deep red

Claims (18)

REVENDICATIONS1. Composition for the coloration of keratinous fibers, comprising: at least two different oxidation bases, of which: a first oxidation base (a) is chosen from 2- (methoxymethyl) benzene-1,4-diamine of formula (I), its addition salts and its solvates: o, CH3 NH2 (I) and a second oxidation base (b) is chosen from: (i) ) the compounds of formula (II), their addition salts and their solvates: in which, R 1 represents an amino group, a C 1 -C 4 alkyl group, optionally substituted with one or more hydroxyl or amino groups, an alkoxy group containing C1 to C4, optionally substituted by one or more hydroxyl or amino groups, (ii) the compounds of formula (III), their addition salts and their solvates: in which, R2 represents an amino group, a C1 to C4 alkyl group; C4, optionally substituted by one or more hydroxy or amino groups, a C1-C4 alkoxy group, optionally substituted by one or more hydroxyl or amino groups, and (iii) their mixtures. 2. Composition according to claim 1, characterized in that R1 represents an amino group in the compounds of formula (II). 3. Composition according to any one of the preceding claims, characterized in that R2 represents a C1-C4 alkoxy group, optionally substituted with one or more hydroxyl groups, preferably a hydroxyethoxy group, in the compounds of formula (III). 4. Composition according to any one of the preceding claims, characterized in that the amount of the first oxidation base (a) ranges from 0.0001 to 20% by weight, preferably from 0.005 to 10% by weight, and more preferably from 0.01 to 6% by weight, relative to the total weight of the composition. 5. Composition according to any one of the preceding claims, characterized in that the second or the second oxidation bases (b) are chosen from 2,3-diamino-6,7-dihydro-1H, 5H-pyrazolo [1,2 pyrazol-1-one, 2- (2-hydroxyethoxy) -3-aminopyrazolo [1,5-a] pyridine, their addition salts, solvates and mixtures thereof. 6. Composition according to any one of the preceding claims, characterized in that the amount of the one or two oxidation bases (b) ranges from 0.0001 to 20% by weight, preferably from 0.005 to 10% by weight. and more preferably from 0.01 to 6% by weight, relative to the total weight of the composition. 7. Composition according to any one of the preceding claims, characterized in that it comprises one or more additional oxidation bases, different from the oxidation bases of formula (I), (II) and (III). 8. Composition according to any one of the preceding claims, characterized in that it comprises one or more couplers. 9. Composition according to Claim 8, characterized in that the coupler or couplers are chosen from compounds of formula (IV), their addition salts and their solvates: (IV) in which R3 represents a hydrogen atom or a C1-C4 alkyl group, optionally substituted by one or more hydroxyl groups, and R4 represents a hydrogen or halogen atom. 10. A composition according to claim 8 or 9, characterized in that the coupler or couplers are chosen from 2-methyl-5-hydroxyethylaminophenol, 4-amino-2-hydroxytoluene, 5-amino-6-chloro-o- cresol, their addition salts, their solvates and their mixtures. 11. Composition according to any one of the preceding claims, characterized in that it further comprises one or more fatty substances. 12. The composition as claimed in claim 11, characterized in that the fatty substance or fats are chosen from fatty alcohols, esters of fatty acids and / or fatty alcohols other than triglycerides, oils of mineral origin and vegetable oils. triglyceride type and mixtures thereof. 13. Composition according to any one of the preceding claims, characterized in that it further comprises one or more surfactants, preferably chosen from nonionic, cationic surfactants and mixtures thereof. 14. Composition according to any one of the preceding claims, characterized in that it further comprises a chemical oxidizing agent, preferably hydrogen peroxide. 15. A method of dyeing keratinous fibers comprising applying to said keratin fibers the composition as defined in any one of the preceding claims. 16. A process for dyeing keratinous fibers according to claim 15, characterized in that the composition defined according to claim 14 is derived from the mixture of two compositions: - a dye composition (A) comprising at least two different oxidation bases including: a first oxidation base (a) is chosen from 220 (methoxymethyl) benzene-1,4-diamine of formula (I), its addition salts and its solvates: o, CH3 NI-12 (I) and a second oxidation base (b) is chosen from: (i) the compounds of formula (II), their addition salts and their solvates: in which, R 1 represents an amino group, a C 1 -C 4 alkyl group, optionally substituted by one or more hydroxyl or amino groups, a C 1 -C 4 alkoxy group, optionally substituted by one or more hydroxyl or amino groups, (ii) the compounds of formula (III), their addition salts and their solvates: wherein, R2 represents an amino group a C 1 -C 4 alkyl group, optionally substituted by one or more hydroxyl or amino groups, a C 1 -C 4 alkoxy group, optionally substituted by one or more hydroxyl or amino groups, and (iii) their mixtures, and oxidizing composition (B) comprising one or more chemical oxidizing agents. 17. Multi-compartment device, preferably two compartments, for dyeing keratinous fibers, at least a first compartment containing a coloring composition (A) as defined according to any one of claims 1 to 13, and at least one second compartment containing an oxidizing composition (B) comprising one or more chemical oxidizing agents. 10 18. Use of a composition as defined in any one of claims 1 to 14, for dyeing keratinous fibers, and in particular hair.