FR2998792A1 - ADHESIVE COMPOSITION FOR NAIL MAKE-UP - Google Patents

Abstract

The present invention relates to an adhesive composition for nail makeup article comprising: at least one polymer selected from the group consisting of: block copolymers comprising at least one polystyrene block and at least one block selected from the group consisting of polybutadiene blocks polyisoprene blocks and butadiene / isoprene copolymer blocks, and polychloroprenes, at least one tackifying resin having a number average molecular weight of less than or equal to 10,000 g / mol, selected from the group consisting of rosin and rosin esters, terpene resins, partially hydrogenated aromatic resins and mixed resins of aliphatic and aromatic hydrocarbon monomers, at least one plasticizer, and at least one volatile solvent.

Description

The present invention relates to an adhesive composition intended to be used for the make-up and / or care of the nails, as well as for use in the make-up and / or care of the nails. Nail makeup items such as false nails are commonly used by consumers for aesthetic reasons. The installation of false nails on the nails then requires the use of specific glues in order to obtain satisfactory holding of the false nail on the nail. Currently, the glues that are found on the market for gluing nail nails are traditionally based on ethylcyanoacrylate. Typically, ethylcyanoacrylate is used in combination with a polymer such as polymethyl methacrylate, resulting in the formation of a very solid polymerized system, as described in US 5,658,415. However, this type of glue has the disadvantage of having a high adhesion, allowing certainly a very good resistance to false nails on the nails, but making them in return difficult to remove when the consumer wants. In addition, ethylcyanoacrylate has the disadvantage of being relatively unstable and therefore difficult to convey. There is thus a need for a glue for makeup and / or care of the nails for gluing false nails on the nails effectively and whose physico-chemical properties allow easy removal. It is an object of the present invention to provide an adhesive composition for adhering makeup articles to the nails and removing them simply after the consumer wishes. Thus, the present invention relates to an adhesive composition for nail makeup article comprising: at least one polymer selected from the group consisting of: block copolymers comprising at least one polystyrene block and at least one block selected from the group consisting of polybutadiene blocks, polyisoprene blocks and butadiene / isoprene copolymer blocks, and polychloroprenes; at least one tackifying resin having a number average molecular weight of less than or equal to 10,000 g / mol selected from the group consisting of rosins and rosin esters, terpene resins, partially hydrogenated aromatic resins and mixed resins of aliphatic and aromatic hydrocarbon monomers, at least one plasticizer, and at least one volatile solvent.

The adhesive composition, once applied, forms an adhesive layer having a certain tackiness defined by its viscoelastic properties. The viscoelastic properties of a material are conventionally defined by two characteristic values which are the following: the elastic modulus which represents the elastic behavior of the material for a given frequency and which is classically denoted G ', and the viscous modulus which represents the viscous behavior of the material for a given frequency and which is classically denoted G. "These quantities are in particular defined in the" Handbook of Pressure Sensitive Adhesive Technology ", 3rd edition, D. Satas, chapter 9, pp. 155-157. Preferably, the adhesive materials usable according to the present invention have viscoelastic properties which are measured at a reference temperature of 35 ° C. and in a certain frequency range. polymer in a volatile solvent (such as water, a short ester, a short alcohol, acetone, etc.), o n measures the viscoelastic properties of this material under conditions in which it has a volatile solvent content of less than or equal to 30%, and in particular a volatile solvent content less than or equal to 20%. In particular, the elastic modulus of the material is measured at three different frequencies: at low frequency, ie at 2.10-2 Hz; at an intermediate frequency, ie at 0.2 Hz; - at high frequency, ie at 2 Hz; and the viscous modulus at the frequency of 0.2 Hz. These measurements make it possible to evaluate the evolution of the stickiness of the adhesive material over time. These viscoelastic properties are measured during dynamic tests under low amplitude sinusoidal stresses (small deformations) carried out at 35 ° C over a frequency range from 2.10-2 to 20 Hz on a "Haake RS5OR" type rheometer under a solicitation. torsion / shearing, for example in cone-plane geometry (for example with a cone angle of 1 °). Advantageously, said adhesive material meets the following conditions: G '(2 Hz, 35 ° C) k 103 Pa, and - G' (35 ° C) 108 Pa, in particular G '(35 ° C) 107 Pa, - G '(2.10-2 Hz, 35 ° C) 3.105 Pa, in which: - G' (2 Hz, 35 ° C) is the elastic modulus of shear of said adhesive material, measured at the frequency of 2 Hz and at temperature of 35 ° C, - G '(35 ° C) is the elastic modulus of shear of said adhesive material, measured at a temperature of 35 ° C, for any frequency between 2.10-2 and 2 Hz, - G' (2.10 -2 Hz, 35 ° C) is the elastic modulus of shear of said adhesive material, measured at a frequency of 2.10-2 Hz and at a temperature of 35 ° C. In a particular form of the invention, the adhesive material also satisfies the following condition: - G "/ G '(0.2 Hz, 35 ° C) k 0.35 in which: - G" (0.2 Hz , 35 ° C) is the viscous shear modulus of said adhesive material, measured at a frequency of 0.2 Hz and at a temperature of 35 ° C, - G '(0.2 Hz, 35 ° C) is the elastic modulus shearing said adhesive material, measured at a frequency of 0.2 Hz and at a temperature of 35 ° C.

In a particular form of the invention, there is: G '(2 Hz, 35 ° C) 5.103 Pa, and in particular G' (2 Hz, 35 ° C) 104 Pa. In another particular form of In particular, the adhesive materials according to the invention have the following four conditions: - G '(2 Hz, 35 ° C) 104 - 5.104 Pa (2.10-2 Hz, 35 ° C) Pa, and - G '(35 ° C) 108 Pa, in particular G' (35 ° C) 107 Pa, - G '(2.10-2 Hz, 35 ° C) 5.104 Pa, and - G "/ G' ( 0.2 Hz, 35 ° C) 0.35.

Block Copolymer According to the invention, the adhesive composition comprises at least one polymer selected from the group consisting of: block copolymers comprising at least one polystyrene block and at least one block selected from the group consisting of polybutadiene blocks, polyisoprene blocks and butadiene / isoprene copolymer blocks, and polychloroprenes. It may be a single block copolymer, a mixture of block copolymers, a polychloroprene alone, a mixture of polychloroprenes or a mixture of block copolymers and polychloroprenes.

For the purposes of the present invention, the term "copolymer" means a polymer derived from at least two types of monomers. In the context of the present invention, the term "block copolymer" (or "block copolymer") denotes a copolymer consisting of blocks of different compositions, connected to each other in linear sequences. These copolymers may also be referred to as "block copolymers". Thus, these block copolymers or block copolymers are polymers comprising at least 2 distinct blocks or sequences. In the context of the present application, block copolymers also include diblock, triblock, multiblock, radial or star copolymers. In particular, the block copolymers consist of at least two blocks, preferably two or three blocks. These copolymers are therefore preferably chosen from diblock copolymers or triblock copolymers. They can for example be represented as follows: (block A) (block B) for the diblock copolymers and (block A) (block B) (block A) or (block B) (block A) (block B) for the 20 triblock copolymers. According to the invention, the multiblock copolymers designate copolymers comprising more than three blocks. The block copolymers according to the invention may also be chosen from star block copolymers or radial block copolymers. These copolymers have a single point of branching from which several blocks emanate. In particular, such a star copolymer having n blocks linked to the branch point is called a n-block star copolymer (or radial copolymer). The copolymers may have a linear structure or a non-linear structure such as, for example, a copolymer with branched, radial, star-shaped structure. The block copolymers according to the invention may be random or alternating. Examples of copolymers according to the invention are styrene-butadiene copolymers, styrene-isoprene copolymers, styrene-butadiene / isoprene copolymers, styrene-butadiene-styrene copolymers, styrene-isoprene-styrene copolymers and copolymers. styrene-butadiene / isoprene-styrene, such as those sold by the company KRATON.

Advantageously, the polymer is a mixture of block copolymers comprising at least one diblock copolymer and at least one triblock copolymer. Preferably, the polymer is a mixture of styrene-butadiene-styrene linear triblock copolymers and styrene-butadiene diblock copolymers, in particular available from KRATON under the reference KRATON® D-1102 (SBS). Furthermore, "polychloroprene" is understood to mean a compound of the following formula: ## STR1 ## where n is an integer of 1 to 10,000. Advantageously, the polymer content is from 1% to 50%, advantageously from 5% to 30%, preferably 10% to 20%, by weight relative to the total weight of the composition. The block copolymers according to the invention are highly polar and thus have good compatibility with the tackifying resins according to the invention, described below, which contributes to the tackiness of the adhesive composition of the invention.

For the purposes of the present invention, the term "polar" a compound whose negative and positive charges are distributed asymmetrically. Tackifying Resin In the context of the present invention, the adhesive composition comprises at least one tackifying resin as defined above. In the context of the present description, the term "tackifying resin" means a thermoplastic resin of low molecular weight used in the composition of glues. The tackifying resins according to the invention have a number average molecular weight of less than or equal to 10,000 g / mol. Advantageously, this number-average molecular weight ranges from 250 g / mol to 10,000 g / mol, preferably from 250 g / mol to 5,000 g / mol, more preferably from 250 g / mol to 2,000 g / mol, or even from 250 g / mol to 1000 g / mol. The number average molecular weights (Mn) are determined by liquid gel permeation chromatography (THF solvent, calibration curve established with linear polystyrene standards, refractometric detector). The tackifying resins according to the invention are chosen from the group consisting of rosin and rosin esters, optionally hydrogenated, terpene resins, optionally styrenated, partially hydrogenated aromatic resins and mixed resins of aliphatic and aromatic hydrocarbon monomers. Rosin is a mixture comprising mainly organic acids called rosin acids (mainly abietic and pimaric type acids). There are three types of rosin: rosin ("gum rosin") obtained by incision on live trees, wood rosin extracted from stumps or pine wood, and tall oil ("Tall oil rosin") which is obtained from a by-product from the production of paper. The rosin esters are derived from the esterification (for example with polyhydric alcohols such as ethylene glycol, glycerol, pentaerythritol) of rosin acids. There may be mentioned, for example, the rosin esters marketed under the reference FORAL 85, PENTALYN H and STAYBELITE ESTER 10 by the company HERCULES; SYLVATAC 95 and ZONESTER 85 by the company ARIZONA CHEMICAL; 15 FORAL 105 Synthetic Resin by PINOVA or UNIREZ 3013 by UNION CAMP. The terpene resins are terpene-based resins which are hydrocarbons of formula (C5H8), where n is an integer at least equal to 1. These resins are said to be "styrenic" when they contain styrene groups. As styrenic terpenic resin, mention may be made in particular of the references SylvaresTM ZT 105LT Resin, SylvaresTM ZT 106LT Resin, and ZonatacTM NG 98, available from ARIZONA CHEMICAL. Preferably, the terpene resins used are styrene terpene resins. Furthermore, as partially hydrogenated aromatic resin, mention may be made of the hydrogenated indene / methylstyrene / styrene copolymers sold under the name "Regalite" by the company Eastman Chemical, in particular REGALITE C6100, REGALITE C6100L, REGALITE R7100, REGALITE R9100, REGALITE S5100, or under the name ARKON M-90, ARKON M-100, ARKON M-115 by Arakawa. Finally, as a mixed resin of aliphatic and aromatic hydrocarbon monomers, mention may be made of: mixed pentanediene and indene resins, which result from the polymerization of a mixture of pentanediene and indene monomers, such as those described above, such as, for example, the resins sold under the reference ESCOREZ 2101, ESCOREZ 2105, ESCOREZ 2173, ESCOREZ 2184, ESCOREZ 2203LC, ESCOREZ 2394, ESCOREZ 2510 by the company Emoen Chemicals, NORSOLENE A 100 by the company Cray Valley, the resins marketed under the reference VVINGTACK 86, VVINGTACK EXTRA and VVINGTACK PLUS by the company Cray Valley; and the diene resins of the dimers of cyclopentanediene resulting from the polymerization of the first monomer chosen from indene and styrene, and of the second monomer chosen from cyclopentanediene dimers such as dicyclopentanediene, methyldicyclopentanediene, the other dimers of pentanediene, and their mixtures. These resins generally have a molecular weight ranging from 500 to 800 g / mol, such as for example those sold under the reference ESCOREZ 5600, ESCOREZ 5615, ESCOREZ 5690, by the company E) (on Mobil Chem Advantageously, the tackifying resin is chosen from the group consisting of rosin and rosin esters, optionally hydrogenated, The tackifying resin is, for example, the hydrogenated rosin ester sold under the name FORAL 105 Synthetic Resin by the company Pl NOVA.

Preferably, the tackifying resin content is from 5% to 50%, preferably from 10% to 30%, by weight relative to the total weight of the composition. Plasticizer According to the invention, the adhesive composition comprises at least one plasticizer.

For the purposes of the present invention, the term "plasticizer" is intended to denote a compound, in the liquid state more or less viscous, which, added to a formulation of a given material, makes it more tacky, more adherent, more flexible, more resistant and / or easier to handle. As plasticizer, mention may be made in particular of the usual plasticizers such as glycols and their derivatives, such as diethylene glycol ethyl ether, diethylene glycol methyl ether, diethylene glycol butyl ether or diethylene glycol hexyl ether, ethylene glycol ethyl ether, ethylene glycol methyl ether, ethylene glycol butyl ether, ethylene glycol hexyl ether, glycol esters, propylene glycol derivatives and in particular propylene glycol phenyl ether, propylene glycol diacetate, dipropylene glycol butyl ether, tripropylene glycol butyl ether, propylene glycol methyl ether, dipropylene glycol ethyl ether, tripropylene glycol methyl ether and diethylene glycol methyl ether, propylene glycol butyl ether, especially carboxylic acid esters such as citrates, especially triethyl citrate, tributyl citrate, triethyl acetylcitrate, tri-acetylcitrate butyl, triethyl-2-hexyl acetyl citrate; phthalates, especially dimethoxyethyl phthalate; phosphates, especially tricresyl phosphate, tributyl phosphate, triphenyl phosphate, tributoxyethyl phosphate; tartrates, especially dibutyl tartrate; adipates; carbonates; sebacates; benzyl benzoate, butyl acetylricinoleate, glyceryl acetylricinoleate, butyl glycolate, camphor, glycerol triacetate, N-ethyl-o, p-toluenesulfonamide, oxyethylenated derivatives such as oxyethylenated oils, in particular vegetable oils, such as castor oil, and more generally non-volatile oils, in particular nonvolatile silicone oils, non-volatile hydrocarbon oils, and mixtures thereof. Advantageously, the plasticizer is chosen from non-volatile hydrocarbon oils, in particular from liquid paraffins, polyisobutenes, hydrogenated or non-hydrogenated polyisobutenes. By "non-volatile oil" is meant an oil, or solvent, remaining on the nails at ambient temperature and atmospheric pressure for at least several hours and having in particular a vapor pressure of less than or equal to 10 -3 mmHg (0.13 Pa ). For example, the plasticizer marketed under the name PRIMOL 352 by the company EXXONMOBIL is used. Preferably, the plasticizer content is from 1% to 15%, preferably from 1% to 7%, by weight relative to the total weight of the composition. Solvent According to the invention, the adhesive composition comprises at least one volatile solvent (or oil). For the purposes of the present invention, the term "volatile solvent" means a solvent capable of evaporating on contact with keratin materials in less than one hour, at room temperature and atmospheric pressure. The volatile solvents of the invention are volatile organic solvents, liquid at room temperature, having a non-zero vapor pressure, at ambient temperature and atmospheric pressure, in particular from 0.13 Pa to 40 000 Pa (10-3 to 300 mmHg), preferably 1.3 Pa to 13 000 Pa (0.01 to 100 mmHg), preferably 1.3 Pa to 1300 Pa (0.01 to 10 mmHg). Advantageously, the volatile solvent is chosen from polar volatile solvents. By "polar" solvent, within the meaning of the present invention, is meant a solvent, or an oil, whose solubility parameter calculated beyond its melting point δ, is different from 0 (J / cm 3)%. In particular, by "polar" solvent is meant a solvent whose chemical structure is formed essentially or even consisting of carbon and hydrogen atoms, and comprising at least one strongly electronegative heteroatom such as an atom of oxygen, nitrogen, silicon or phosphorus. The definition and calculation of the solubility parameters in the HANSEN three-dimensional solubility space are described in the article by C. M. Hansen: "The three dimensional solubility parameters", J. Paint Technol. 39, 105 (1967). According to this Hansen space: - 613 characterizes the dispersion forces of LONDON resulting from the formation of dipoles induced during molecular shocks; 8p characterizes the DEBYE interaction forces between permanent dipoles as well as the KEESOM interaction forces between induced dipoles and permanent dipoles; - 6h characterizes the specific interaction forces (hydrogen bond type, acid / base, donor / acceptor, etc.); and - δ, is determined by the equation: δ = (81.2 + 61-12)%. The parameters 8p, 6h, 6D and 0, are expressed in (J / cm3)%. Advantageously, the volatile solvent is selected from the group consisting of 03-06 esters and ketones and mixtures thereof. Examples of volatile solvents that may be mentioned include acetone, methyl ethyl ketone, methyl isobutyl ketone, cyclohexanone and alkyl acetates in which the alkyl group comprises from 2 to 5 carbon atoms, such as methyl acetate, ethyl acetate, propyl acetate, n-propyl acetate, isopropyl acetate, n-butyl acetate, isobutyl acetate, and tert-butyl acetate. butyl. More particularly, the volatile solvent is selected from the group consisting of methyl acetate, ethyl acetate, n-propyl acetate, isopropyl acetate, acetone and the like. their mixtures. The volatile solvent is, for example, ethyl acetate. Preferably, the solvent content is at least 40%, preferably 50% to 90%, preferably 60% to 75%, by weight relative to the total weight of the composition. According to a preferred embodiment of the invention, the tackifying resin is a hydrogenated rosin ester and the volatile solvent is ethyl acetate. Additives The adhesive composition may further comprise other ingredients commonly used in cosmetic compositions and known to those skilled in the art as being capable of being incorporated into an adhesive composition for nail makeup article.

Such ingredients may be chosen from pigments and dyes, plasticizers, coalescers, preservatives, oils, waxes, free radical scavengers, spreading agents, wetting agents, dispersing agents, anti-foams, preservatives, surfactants, perfumes, neutralizers, stabilizers, antioxidants, thickening agents, the active agents that may be chosen from essential oils, UV / solar filters, moisturizing agents, vitamins, proteins, ceramides, plant extracts, etc., and mixtures thereof. The composition according to the invention may furthermore comprise, as active ingredients, nail care agents such as hardeners for keratinous substances, active agents acting on the growth of the nail, for example methylsulfonyl methane and / or active agents for treating various conditions located at the level of the nail, such as onichomycosis. Of course, those skilled in the art will take care to choose this or these optional additional compounds, and / or their quantity, so that the advantageous properties of the composition for use according to the invention are not, or substantially not altered by the addition envisaged. The present invention also relates to a non-therapeutic makeup and / or nail care method using the adhesive composition as described above. More specifically, it relates to a nail makeup and / or care method comprising: a) a step of applying to a nail at least one layer of a composition according to the invention, to obtain a coated nail, b) a step of applying to a nail makeup article at least one layer of a composition according to the invention, to obtain a coated nail makeup article, and c) a step of contacting said makeup article with nails 30 obtained at the end of step b) with said coated nail obtained at the end of step a), to obtain a nail covered with a nail makeup article. Typically, the article of nail makeup is a false nail. Preferably, the method comprises a step of drying the adhesive composition layers prior to application of the nail makeup article to the nail.

More specifically, the consumer coating the surface of his nails with at least one layer of adhesive composition as described above, coating the false nails with at least one layer of this composition, and then typically waiting for a few seconds to a few minutes that the two layers of composition dry. He then puts the dry nails coated with dry adhesive composition in contact with his nails coated with dry adhesive composition as well. His nails are covered with false nails whose hold is satisfactory. Finally, the present invention also relates to a method of removing make-up from nails coated with nail makeup articles by means of such an adhesive composition. It is more specifically a method of removing make-up from a nail covered with a nail-makeup article that can be obtained by a method as described above, comprising removing said nail-makeup article from said nail. nail by coat. More particularly, the consumer can remove a nail-sticked false nail using the adhesive composition of the invention by pulling on the false nail and the adhesive layer consisting of adhesive composition located between the nail and the nail. the false-nails. The make-up removal of the nail is thus facilitated with respect to a case where the false nail is stuck in a conventional manner, thanks to the physicochemical properties of the adhesive composition of the invention. The weight percentages given in this application can be likened to the percentage by weight of dry matter of the compounds used. By "understand one" or "include one" should be understood "to include at least one" or "to include at least one", unless the contrary is explicitly specified. The invention will be better understood on reading the description which follows, given solely by way of example. EXAMPLES Example 1.1: Preparation of an adhesive composition according to the invention An adhesive composition according to the invention was prepared according to Table 1.

The constituents indicated in Table 1 were mixed and heated at 45 ° C. with stirring to the magnetic bar until a homogeneous mixture was obtained. Table 1 Compound Name Supplier% in commercial weight Ester of pentaerythritol rosin Foral 105 Pl NOVA 17.3 Hydrogenated Synthetic Resin Mixture of triblock copolymers KRATON D-KRATON 12 linear styrene-butadiene-styrene and 1102 (SBS) PO LYM ERS diblock copolymers styrene-butadiene Plasticizer PRIMOL 352 E) <XONMOBIL 4 Ethyl acetate - - 66.7 Example 1.2: Nail makeup process using an adhesive composition according to the invention A layer of the adhesive composition of Example 1.1 was coated on nails, as well as under false nails bearing the reference "EDGE FASHION NAILS" brand FING'RSO. After drying the adhesive layers, false nails are applied to the nails. The nail makeup thus obtained could be easily removed by peeling. Comparative Example 1: Preparation of an Adhesive Composition Comprising an Aliphatic Hydrocarbon Tacking Resin The constituents shown in Table 2 were mixed and heated at 45 ° C with stirring to the magnet bar until a homogeneous mixture was obtained. Table 2 Compound Name Supplier% in commercial weight Tackifying hydrocarbon resin REGALITE EASTMAN 17.3 aliphatic R1100 CHEMICAL Mixture of triblock copolymers KRATON D-1102 (SBS) KRATON 12 linear styrene-butadiene-styrene and POLYM ERS diblock copolymers styrene-butadiene Plasticizer PRIMOL 352 EXXONMOBIL 4 Ethyl acetate 66.7 This adhesive composition comprises an aliphatic hydrocarbon tackifier resin different from the tackifying resins according to the invention. The preparation of this composition is not possible because the aliphatic hydrocarbon tackifying resin does not solubilize properly in ethyl acetate, thus demonstrating a compatibility problem between the tackifying resin and the solvent. This therefore demonstrates the importance of using a tackifying resin as defined in the invention. COMPARATIVE EXAMPLE 2.1 Preparation of an Adhesive Composition Comprising an Aliphatic Hydrocarbon Tacking Resin and Cyclohexane The constituents shown in Table 3 were mixed and heated at 45 ° C. with stirring to the magnetized bar until a reaction was obtained. homogeneous mixture. Table 3 Compound Name Supplier% in commercial weight Hydrocarbon tackifier resin REGALITE EASTMAN 17.3 aliphatic R1100 CHEMICAL Mixture of triblock copolymers KRATON D-KRATON 12 linear styrene-butadiene-styrene and 1102 (SBS) POLYMERS diblock copolymers styrene-butadiene Plasticizer PRIMOL 352 EXXONMOBIL 4 Cyclohexane - - 50 Ethyl Acetate - - 16.7 This adhesive composition comprises an aliphatic hydrocarbon tackifier resin different from the tackifying resins according to the invention. Contrary to what was obtained in Comparative Example 1, the additional presence of cyclohexane made it possible to solubilize the aliphatic hydrocarbon tackifier resin. This composition could therefore be used in the context of the makeup process according to the invention, described in the following example. Comparative Example 2.2: Nail Makeup Method Using an Adhesive Composition According to the Invention A layer of the adhesive composition of Comparative Example 2.1 was coated on the nails, as well as under false nails bearing the reference "EDGE FASHION" NAILS "brand FING'RSO. After drying the adhesive layers, the false nails were applied to the nails.

The adhesive layer thus obtained develops a weak stickiness after drying, and does not adhere properly to the nails, demonstrating the importance of the nature of the tackifying resin. This comparative example again demonstrates the essential role of tackifying resin, the nature of which influences the preparation of the composition, especially in terms of compatibility with the solvent used, and tackiness.

Claims (5)

REVENDICATIONS1. An adhesive composition for nail makeup article comprising: at least one polymer selected from the group consisting of: block copolymers comprising at least one polystyrene block and at least one block selected from the group consisting of polybutadiene blocks, polyisoprene blocks and butadiene / isoprene copolymer blocks, and polychloroprenes, at least one tackifying resin with a number average molecular weight of less than or equal to 10,000 g / mol, selected from the group consisting of rosin and rosin esters, terpene resins partially hydrogenated aromatic resins and mixed resins of aliphatic and aromatic hydrocarbon monomers; at least one plasticizer; and at least one volatile solvent. The composition of claim 1, wherein the solvent is selected from the group consisting of C3-C6 esters and ketones and mixtures thereof. The composition of claim 1 or 2, wherein the solvent is selected from the group consisting of methyl acetate, ethyl acetate, n-propyl acetate, ethyl acetate and the like. isopropyl, acetone and mixtures thereof. 4. Composition according to any one of claims 1 to 3, wherein the solvent content is at least 40% by weight relative to the total weight of the composition. 5. Composition according to any one of claims 1 to 4, wherein the polymer is a mixture of block copolymers comprising at least one diblock copolymer and at least one triblock copolymer.Composition according to any one of claims 1 to 5, wherein the polymer is a mixture of styrene-butadiene-styrene linear triblock copolymers and styrene-butadiene diblock copolymers. Composition according to any one of claims 1 to 6, wherein the polymer content is 1% to 40% by weight relative to the total weight of the composition. The composition of any one of claims 1 to 7, wherein the tackifying resin is a hydrogenated rosin ester. The composition of claim 8 wherein the solvent is ethyl acetate. Composition according to any one of Claims 1 to 9, in which the content of tackifying resin is from 5% to 50% by weight relative to the total weight of the composition. A method of making and / or caring for the nails comprising: a) a step of applying to a fingernail at least one layer of a composition according to any of claims 1 to 10 to obtain a coated fingernail, b) a step of applying to a nail makeup article at least one layer of a composition according to any one of claims 1 to 10 to obtain a coated nail makeup article, and c) a step of in contact with said coated nail makeup article obtained at the end of step b) with said coated nail obtained at the end of step a), to obtain a nail covered with a nail makeup article . The method of claim 11, wherein the nail makeup article is a false nail. 7. 8. io 9. 15 10. 11.13. A method of removing makeup from a nail covered with a nail makeup article obtainable by a process according to claim 11 or 12, comprising removing said makeup article from said nail by peeling.