FR2992954A1 - Procede catalytique de production de monoxyde de carbone et reacteur associe. - Google Patents

Procede catalytique de production de monoxyde de carbone et reacteur associe. Download PDF

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Publication number
FR2992954A1
FR2992954A1 FR1256434A FR1256434A FR2992954A1 FR 2992954 A1 FR2992954 A1 FR 2992954A1 FR 1256434 A FR1256434 A FR 1256434A FR 1256434 A FR1256434 A FR 1256434A FR 2992954 A1 FR2992954 A1 FR 2992954A1
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FR
France
Prior art keywords
carbon monoxide
reactor
producing carbon
catalytic process
producing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR1256434A
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English (en)
Other versions
FR2992954B1 (fr
Inventor
Jean-Marc Borgard
Phuangphet Vibhatavata
Michel Tabarant
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Commissariat a lEnergie Atomique et aux Energies Alternatives CEA
Original Assignee
Commissariat a lEnergie Atomique CEA
Commissariat a lEnergie Atomique et aux Energies Alternatives CEA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Commissariat a lEnergie Atomique CEA, Commissariat a lEnergie Atomique et aux Energies Alternatives CEA filed Critical Commissariat a lEnergie Atomique CEA
Priority to FR1256434A priority Critical patent/FR2992954B1/fr
Priority to US14/412,812 priority patent/US20150306576A1/en
Priority to PCT/FR2013/051586 priority patent/WO2014006335A1/fr
Priority to EP13747435.9A priority patent/EP2870105A1/fr
Publication of FR2992954A1 publication Critical patent/FR2992954A1/fr
Application granted granted Critical
Publication of FR2992954B1 publication Critical patent/FR2992954B1/fr
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/894Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8906Iron and noble metals
    • B01J35/40
    • B01J35/613
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0201Impregnation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/03Precipitation; Co-precipitation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/03Precipitation; Co-precipitation
    • B01J37/031Precipitation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/04Mixing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08Heat treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08Heat treatment
    • B01J37/082Decomposition and pyrolysis
    • B01J37/088Decomposition of a metal salt
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/06Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
    • C01B3/12Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide
    • C01B3/16Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide using catalysts
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10KPURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K3/00Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
    • C10K3/02Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment
    • C10K3/026Increasing the carbon monoxide content, e.g. reverse water-gas shift [RWGS]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Combustion & Propulsion (AREA)
  • Thermal Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Inorganic Chemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Carbon And Carbon Compounds (AREA)

Abstract

Procédé de production d'un gaz de synthèse, dans lequel un mélange gazeux comprenant du dioxyde de carbone et de l'hydrogène est mis en contact avec un catalyseur afin de produire du monoxyde de carbone, le procédé étant caractérisé en ce que le catalyseur comprend du fer et de l'argent selon un rapport masse d'argent/masse de fer qui est de 0,05 à 0,95. Réacteur catalytique destiné à la mise en oeuvre du procédé de production d'un gaz de synthèse.
FR1256434A 2012-07-04 2012-07-04 Procede catalytique de production de monoxyde de carbone et reacteur associe. Expired - Fee Related FR2992954B1 (fr)

Priority Applications (4)

Application Number Priority Date Filing Date Title
FR1256434A FR2992954B1 (fr) 2012-07-04 2012-07-04 Procede catalytique de production de monoxyde de carbone et reacteur associe.
US14/412,812 US20150306576A1 (en) 2012-07-04 2013-07-04 Catalytic method for the production of carbon monoxide and associated reactor
PCT/FR2013/051586 WO2014006335A1 (fr) 2012-07-04 2013-07-04 Procede catalytique de production de monoxyde de carbone et reacteur associe
EP13747435.9A EP2870105A1 (fr) 2012-07-04 2013-07-04 Procede catalytique de production de monoxyde de carbone et reacteur associe

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR1256434A FR2992954B1 (fr) 2012-07-04 2012-07-04 Procede catalytique de production de monoxyde de carbone et reacteur associe.

Publications (2)

Publication Number Publication Date
FR2992954A1 true FR2992954A1 (fr) 2014-01-10
FR2992954B1 FR2992954B1 (fr) 2015-05-29

Family

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FR1256434A Expired - Fee Related FR2992954B1 (fr) 2012-07-04 2012-07-04 Procede catalytique de production de monoxyde de carbone et reacteur associe.

Country Status (4)

Country Link
US (1) US20150306576A1 (fr)
EP (1) EP2870105A1 (fr)
FR (1) FR2992954B1 (fr)
WO (1) WO2014006335A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3375513A1 (fr) * 2017-03-16 2018-09-19 Commissariat à l'Energie Atomique et aux Energies Alternatives Catalyseur pour reaction de gaz a l'eau inverse (rwgs), reaction rwgs associee et procede de regeneration in-situ du catalyseur

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112758932A (zh) * 2020-02-18 2021-05-07 上海电力大学 一种以氢气与二氧化碳为原料制备一氧化碳的装置及方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3857921A (en) * 1972-09-27 1974-12-31 Asahi Chemical Ind Method for eliminating nitrogen oxides and catalyst composition for use in practicing said method
WO2004058634A2 (fr) * 2002-12-20 2004-07-15 Honda Giken Kogyo Kabushiki Kaisha Formulations de catalyseur contenant des metaux du groupe 11 pour le production d'hydrogene
JP2005305363A (ja) * 2004-04-23 2005-11-04 Toyota Motor Corp 排ガス浄化用触媒
US20110105630A1 (en) * 2009-11-04 2011-05-05 The Government Of The United States Of America, As Represented By The Secretary Of The Navy Catalytic Support for use in Carbon Dioxide Hydrogenation Reactions

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4265868A (en) * 1978-02-08 1981-05-05 Koppers Company, Inc. Production of carbon monoxide by the gasification of carbonaceous materials

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3857921A (en) * 1972-09-27 1974-12-31 Asahi Chemical Ind Method for eliminating nitrogen oxides and catalyst composition for use in practicing said method
WO2004058634A2 (fr) * 2002-12-20 2004-07-15 Honda Giken Kogyo Kabushiki Kaisha Formulations de catalyseur contenant des metaux du groupe 11 pour le production d'hydrogene
JP2005305363A (ja) * 2004-04-23 2005-11-04 Toyota Motor Corp 排ガス浄化用触媒
US20110105630A1 (en) * 2009-11-04 2011-05-05 The Government Of The United States Of America, As Represented By The Secretary Of The Navy Catalytic Support for use in Carbon Dioxide Hydrogenation Reactions

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3375513A1 (fr) * 2017-03-16 2018-09-19 Commissariat à l'Energie Atomique et aux Energies Alternatives Catalyseur pour reaction de gaz a l'eau inverse (rwgs), reaction rwgs associee et procede de regeneration in-situ du catalyseur
FR3063917A1 (fr) * 2017-03-16 2018-09-21 Commissariat A L'energie Atomique Et Aux Energies Alternatives Catalyseur pour reaction de gaz a l'eau inverse (rwgs), reaction rwgs associee et procede de regeneration in-situ du catalyseur

Also Published As

Publication number Publication date
WO2014006335A1 (fr) 2014-01-09
FR2992954B1 (fr) 2015-05-29
EP2870105A1 (fr) 2015-05-13
US20150306576A1 (en) 2015-10-29

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