FR2983484B1 - Copolymerisation radicalaire controlee de monomeres fluores par un xanthate ou trithiocarbonate - Google Patents

Copolymerisation radicalaire controlee de monomeres fluores par un xanthate ou trithiocarbonate

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Publication number
FR2983484B1
FR2983484B1 FR1161017A FR1161017A FR2983484B1 FR 2983484 B1 FR2983484 B1 FR 2983484B1 FR 1161017 A FR1161017 A FR 1161017A FR 1161017 A FR1161017 A FR 1161017A FR 2983484 B1 FR2983484 B1 FR 2983484B1
Authority
FR
France
Prior art keywords
trithiocarbonate
xanthate
controlled radical
radical control
fluorinated
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
FR1161017A
Other languages
English (en)
Other versions
FR2983484A1 (fr
Inventor
Bruno Ameduri
Yogesh Patil
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Arkema France SA
Ecole Nationale Superieure de Chimie de Montpellier ENSCM
Original Assignee
Arkema France SA
Ecole Nationale Superieure de Chimie de Montpellier ENSCM
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Arkema France SA, Ecole Nationale Superieure de Chimie de Montpellier ENSCM filed Critical Arkema France SA
Priority to FR1161017A priority Critical patent/FR2983484B1/fr
Priority to US13/689,816 priority patent/US9184461B2/en
Publication of FR2983484A1 publication Critical patent/FR2983484A1/fr
Application granted granted Critical
Publication of FR2983484B1 publication Critical patent/FR2983484B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1069—Polymeric electrolyte materials characterised by the manufacturing processes
    • H01M8/1072—Polymeric electrolyte materials characterised by the manufacturing processes by chemical reactions, e.g. insitu polymerisation or insitu crosslinking
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/18—Monomers containing fluorine
    • C08F214/22—Vinylidene fluoride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1023—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having only carbon, e.g. polyarylenes, polystyrenes or polybutadiene-styrenes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1039—Polymeric electrolyte materials halogenated, e.g. sulfonated polyvinylidene fluorides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00—Living radical polymerisation
    • C08F2438/03—Use of a di- or tri-thiocarbonylthio compound, e.g. di- or tri-thioester, di- or tri-thiocarbamate, or a xanthate as chain transfer agent, e.g . Reversible Addition Fragmentation chain Transfer [RAFT] or Macromolecular Design via Interchange of Xanthates [MADIX]
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M2008/1095—Fuel cells with polymeric electrolytes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Electrochemistry (AREA)
  • Sustainable Energy (AREA)
  • Sustainable Development (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Graft Or Block Polymers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

L'invention concerne un procédé de préparation d'un copolymère fluoré, comprenant une étape de copolymérisation d'un monomère fluorure de vinylidène avec un monomère acide a-trifluorométhacrylique ou dérivé d'acide a-trifluorométhacrylique, en présence d'un composé xanthate ou trithiocarbonate. L'invention concerne également les copolymères obtenus par ce procédé ainsi que les copolymères à blocs comportant un bloc copolymère préparé selon ce procédé.
FR1161017A 2011-12-01 2011-12-01 Copolymerisation radicalaire controlee de monomeres fluores par un xanthate ou trithiocarbonate Active FR2983484B1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
FR1161017A FR2983484B1 (fr) 2011-12-01 2011-12-01 Copolymerisation radicalaire controlee de monomeres fluores par un xanthate ou trithiocarbonate
US13/689,816 US9184461B2 (en) 2011-12-01 2012-11-30 Controlled radical copolymerization of fluorinated monomers by xanthate or trithiocarbonate

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR1161017A FR2983484B1 (fr) 2011-12-01 2011-12-01 Copolymerisation radicalaire controlee de monomeres fluores par un xanthate ou trithiocarbonate

Publications (2)

Publication Number Publication Date
FR2983484A1 FR2983484A1 (fr) 2013-06-07
FR2983484B1 true FR2983484B1 (fr) 2015-02-20

Family

ID=46062343

Family Applications (1)

Application Number Title Priority Date Filing Date
FR1161017A Active FR2983484B1 (fr) 2011-12-01 2011-12-01 Copolymerisation radicalaire controlee de monomeres fluores par un xanthate ou trithiocarbonate

Country Status (2)

Country Link
US (1) US9184461B2 (fr)
FR (1) FR2983484B1 (fr)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10377843B2 (en) 2014-05-12 2019-08-13 Solvay Specialty Polymers Italy S.P.A. Method for the controlled polymerization of fluoromonomers
WO2016149238A1 (fr) * 2015-03-16 2016-09-22 Arkema Inc. Fluoropolymères modifiés
US10717861B2 (en) * 2015-04-28 2020-07-21 Dankook University Cheonan Campus Industry Academic Cooperation Foundation Perfluorinated ionomer nanoparticle dispersion solution, and preparation method therefor
KR101688625B1 (ko) * 2015-04-28 2016-12-21 단국대학교 천안캠퍼스 산학협력단 이오노머 나노 분산액
FR3054225B1 (fr) * 2016-07-21 2019-12-27 Total Marketing Services Copolymere utilisable comme additif detergent pour carburant
JP6933478B2 (ja) 2017-03-21 2021-09-08 株式会社クレハ ゲル状電解質
WO2019014661A1 (fr) * 2017-07-14 2019-01-17 Arkema Inc Composite de fluorure de polyvinylidène à haute résistance
US11655325B2 (en) 2017-12-19 2023-05-23 Solvay Specialty Polymers Italy S.P.A. Fluorinated block copolymers and application thereof
KR20210107019A (ko) 2018-12-20 2021-08-31 솔베이 스페셜티 폴리머스 이태리 에스.피.에이. 비닐리덴 플루오라이드 중합체 분산물
JP6989792B2 (ja) * 2019-12-25 2022-01-12 ダイキン工業株式会社 フルオロポリマーの製造方法

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008214420A (ja) * 2007-03-01 2008-09-18 Tosoh F-Tech Inc 乳化剤を用いずに制御されたラジカル重合法によるフッ化ビニリデン系共重合体

Also Published As

Publication number Publication date
US20140154611A1 (en) 2014-06-05
FR2983484A1 (fr) 2013-06-07
US9184461B2 (en) 2015-11-10

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