FR2966726A1 - FOAM COLORING COMPOSITION COMPRISING MONO OR SACCHARIDE - Google Patents

Abstract

The present invention relates to a coloring composition of human keratinous fibers such as hair, in the form of a foam comprising: (a) one or more mono or di saccharides; (b) one or more alkaline agents; (c) one or more surfactants; (d) one or more oxidizing agents, (e) one or more oxidation dye precursors. It also relates to a process for treating human keratin fibers from this composition in the form of foam and aerosol or non-aerosol devices for the generation of this foam.

Description

FOAM COLORING COMPOSITION COMPRISING MONO OR SACCHARIDE

The present invention relates to a method of dyeing hair in the form of foam from a composition comprising oxidation dye precursors and a composition in the form of foam. Among the methods for staining human keratinous fibers, such as the hair, mention may be made of oxidation or permanent staining. More particularly, this mode of staining uses one or more oxidation dyes, usually one or more oxidation bases possibly associated with one or more couplers. In general, the oxidation bases are chosen from ortho- or para-phenylenediamines, ortho- or para-aminophenols as well as heterocyclic compounds. These oxidation bases are colorless or weakly colored compounds which, combined with oxidizing products, allow access to colored species. Very often, the shades obtained with these oxidation bases are varied by combining them with one or more couplers, the latter being chosen in particular from aromatic meta-diamines, meta-aminophenols, meta-diphenols and certain heterocyclic compounds, such as indole compounds. The variety of molecules involved in the oxidation bases and couplers allows a rich palette of colors to be obtained. The permanent coloring processes thus consist in using with the dyeing composition, an aqueous composition comprising at least one oxidizing agent such as hydrogen peroxide, under alkaline pH conditions in the vast majority of cases. The alkaline agent conventionally used is ammonia or other alkaline agents, such as alkanolamines. The coloring compositions may be in various forms such as lotions, gels, emulsions, creams or foams. The coloring foams are pleasant to use however they often have poor durability over time. For example, a rapid disappearance of the foam after application or a non-homogeneous application along the fibers may be observed. There is a real constant need to develop oxidation dye compositions in foam form that are easy to prepare and apply, which remain sufficiently stable over time while retaining effective dyeing properties. This and other objects are achieved by the present invention which therefore relates to a coloring composition of human keratinous fibers such as hair, in the form of foam comprising: a) at least one monosaccharide or saccharide; b) at least one alkaline agent; c) at least one surfactant; d) at least one oxidizing agent; e) at least one oxidation dye precursor. It also relates to a process for staining human keratin fibers from this composition. The subject of the invention is also a device with two compartments comprising in one, a first composition containing one or more surfactants, one or more oxidation dye precursors, one or more alkaline agents, in a second one a second composition containing one or more oxidizing agents and in a third a container provided with an element allowing the delivery in the form of a foam of the composition of the invention resulting from the mixture of the two preceding compositions, at least one of the first and a second composition comprising one or more monosaccharides. The invention also relates to a device for staining keratin fibers, comprising the composition of the invention in liquid form and a foam dispenser for delivering the composition in the form of a foam. The composition of the invention is in the form of a foam which is particularly pleasant to apply. It has a light and airy texture, which makes them particularly pleasant to use. The qualities of the foam are sufficiently persistent over time to allow application of the product of homogeneous color and without sagging. The composition of the invention makes it possible to retain dyeing properties such as the power of color, resistance to external agents (shampoos, perspiration, light) and selectivity, which are particularly effective. Other characteristics and advantages of the invention will emerge more clearly on reading the description and examples which follow. In what follows, and unless otherwise indicated, the boundaries of a domain of values are included in this field. The term "at least one" associated with an ingredient in the composition means "one or more". The human keratinous fibers treated by the process according to the invention are preferably the hair. The composition of the invention comprises at least one mono or di saccharide.

The monosaccharides of the invention can be of two types: aldoses and ketoses. The monosaccharides of the invention preferably have from 3 to 8 carbon atoms, more preferably from 5 to 6 carbon atoms.

The monosaccharides are preferably chosen from ribulose, xylulose, psicose, fructose, sorbose, tagatose, ribose, arabinose, xylose, lyxose, allose, altrose, glucose, mannose , gulose, idose, galactose, talose., best among fructose, xylose, glucose, galactose and mannose. Preferably, the monosaccharides of the invention are in D form. The disaccharides are the product resulting from the combination of 2 monosaccharides by a covalent bond, called glucoside bonding. The disaccharides of the invention preferably have from 10 to 16 more preferably from 10 to 12 carbon atoms. The disaccharides are preferably selected from sucrose, trehalose, raffinose, lactose, cellobiose, maltose, isomaltulose, lactulose, better from lactose and sucrose. Preferably the mono or disaccharides are selected from fructose, xylose, glucose, galactose, mannose, lactose and sucrose, more preferably from glucose or sucrose. By way of example, mention may be made of sucrose (or sucrose) powder such as SUCROSE ULTRA PURE GRADE or ORGANIC EVAPORATED CANE JUICE sucrose or CRYSTAL SUGAR NUMBER 1 PURE CANE 1500 or GOLDEN SUGAR 500 sucrose. The monosaccharide or monosaccharides are present in the composition in an amount ranging preferably from 0.01 to 10%, better still from 0.1 to 5%, and still more preferably from 0.2 to 2% relative to the total weight of the composition. the composition. The composition comprises at least one alkaline agent. This agent may be chosen from inorganic or organic or hybrid alkaline agents or mixtures thereof. The inorganic alkaline agent (s) is (are) preferably chosen from ammonia, alkali carbonates or bicarbonates, such as sodium or potassium carbonates and sodium or potassium bicarbonates, sodium or potassium hydroxides, or mixtures thereof.

The organic alkaline agent (s) is (are) preferably chosen from organic amines whose pKb at 25 ° C. is less than 12, and preferably less than 10, and even more advantageously less than 6. It should be noted that this is pKb corresponding to the highest basicity function. As hybrid compounds, mention may be made of the salts of the amines mentioned above with acids such as carbonic acid and hydrochloric acid. The organic alkaline agent (s) are, for example, chosen from alkanolamines, oxyethylenated and / or oxypropylenated ethylenediamines, amino acids and compounds of the following formula (I): ## STR2 ## in which W is a C 1 -C 6 alkylene residue optionally substituted by a hydroxyl group or a C 1 -C 6 alkyl radical; Rx, Ry, Rz and Rt, which may be identical or different, represent a hydrogen atom, a C 1 -C 6 alkyl or C 1 -C 6 hydroxyalkyl or C 1 -C 6 aminoalkyl radical. Examples of such amines include 1,3-diaminopropane, 1,3-diaminopropanol, spermine and spermidine. By alkanolamine is meant an organic amine comprising a primary, secondary or tertiary amine function, and one or more linear or branched C 1 -C 8 alkyl groups carrying one or more hydroxyl radicals. Alkanolamines, such as mono-, di- or trialkanolamines comprising one to three identical or different C1-C4 hydroxyalkyl radicals, are particularly suitable for carrying out the invention.

Among compounds of this type, mention may be made of monoethanolamine, diethanolamine, triethanolamine, monoisopropanolamine, diisopropanolamine, N-dimethylaminoethanolamine, 2-amino-2-methyl-1-propanol, triisopropanolamine, 2-amino -2-methyl-1,3-propanediol, 3-amino-1,2-propanediol, 3-dimethylamino-1,2-propanediol, tris-hydroxymethylaminomethane. More particularly, the amino acids that can be used are of natural or synthetic origin, in their L, D, or racemic form, and comprise at least one acid function chosen more particularly from the carboxylic, sulphonic, phosphonic or phosphoric acid functions. Amino acids can be in neutral or ionic form. As amino acids that may be used in the present invention, mention may in particular be made of aspartic acid, glutamic acid, alanine, arginine, ornithine, citrulline, asparagine, carnitine and cysteine. , glutamine, glycine, histidine, lysine, isoleucine, leucine, methionine, N-phenylalanine, proline, serine, taurine, threonine, tryptophan, tyrosine and valine. Advantageously, the amino acids are basic amino acids comprising an additional amine function optionally included in a ring or in a ureido function. Such basic amino acids are preferably chosen from those corresponding to the following formula (II): ## STR2 ##

where R denotes a group chosen from: - (CH2) 2NH2 - (CH2) 2NHCONH2 - (CH2) 2NH1 -NH2 NH The compounds corresponding to formula (II) are histidine, lysine, arginine, ornithine, citrulline. The organic amine may also be chosen from heterocyclic organic amines. In addition to the histidine already mentioned in the amino acids, mention may in particular be made of pyridine, piperidine, imidazole, triazole, tetrazole and benzimidazole. . The organic amine may also be selected from amino acid dipeptides. As amino acid dipeptides that can be used in the present invention, mention may be made especially of carnosine, anserin and whale. The organic amine is chosen from compounds containing a guanidine function. As amino amines of this type which can be used in the present invention, mention may in addition be made of arginine already mentioned as amino acid, creatine, creatinine, 1,1-dimethylguanidine, 1,1 diethylguanidine, glycocyamine, metformin, agmatine, n-amidinoalanine, 3-guanidinopropionic acid, 4-guanidinobutyric acid and 2 - ([amino (imino) methyl] amino) ethane-1 sulfonic. As hybrid compounds, mention may in particular be made of guanidine carbonate or monoethanolamine hydrochloride.

According to one particular embodiment, the composition of the invention comprises as alkaline agent one or more alkanolamines. Preferably, the alkanolamine is monoethanolamine. In one variant of the invention, the composition of the invention comprises as alkaline agent one or more alkanolamines, preferably monoethanolamine and ammonia. In this variant, the alkanolamine (s) are present in a major amount relative to ammonia. ## STR1 ## Advantageously, the composition according to the invention has an alkaline agent (s) content ( s), ranging from 0.01 to 30% by weight, preferably from 0.1 to 20% by weight more preferably from 1 to 10% by weight relative to the weight of said composition. The composition according to the invention also comprises at least one oxidizing agent. The oxidizing agents are, for example, chosen from hydrogen peroxide, urea peroxide, alkali metal bromates or ferricyanides, peroxygenated salts such as, for example, persulfates, perborates, peracids and their precursors and metal percarbonates. alkaline or alkaline earth metals.

Advantageously, the oxidizing agent is hydrogen peroxide. The content of oxidizing agent (s) represents more particularly from 0.1 to 20% by weight, preferably from 0.5 to 10% by weight, relative to the weight of the composition. As indicated above, the composition according to the invention comprises one or more oxidation dye precursors. As oxidation dye precursors, oxidation bases and couplers may be used. By way of example, the oxidation bases are chosen from para-phenylenediamines, bis-phenylalkylenediamines, para-aminophenols, ortho-aminophenols, heterocyclic bases and their addition salts. Among the paraphenylenediamines, there may be mentioned, for example, para-phenylenediamine, paratoluylenediamine, 2-chloro-para-phenylenediamine, 2,3-dimethyl-para-phenylenediamine, 2,6-dimethyl-para-phenylenediamine, 2,6-diethyl paraphenylenediamine, 2,5-dimethyl-para-phenylenediamine, N, N-dimethyl-para-phenylenediamine, N, N-diethyl-para-phenylenediamine, N, N-dipropyl-para-phenylenediamine, 4-amino-N, N-diethyl-3-methylaniline, N, N- bis - ([3-hydroxyethyl) paraphenylenediamine, 4-N, N-bis - ([3-hydroxyethyl) amino-2-methylaniline, 4-N, N-bis - ((3-hydroxyethyl) amino 2-chloro aniline, 2- (3-hydroxyethyl) paraphenylenediamine, 2-fluoro-para-phenylenediamine, 2-isopropyl-para-phenylenediamine, N - ([3-hydroxypropyl) -paraphenylenediamine, 2-hydroxymethyl-para-phenylenediamine, N, N-dimethyl-3-methyl-para-phenylenediamine N, N- (ethyl, [3-hydroxyethyl) paraphenylenediamine, N- ((3, γ-dihydroxypropyl) paraphenylenediamine, N- (4'-aminophenyl) paraphenylenediamine, N-phenyl-para-phenylenediamine, 2- [3-hydroxyethyloxy-para-phenylenediamine, 2- [3-acetylaminoethyloxy-para-phenylenediamine, N - ((3-methoxyethyl) para-phenylenediamine) 4-aminophenylpyrrolidine, 2-thienyl paraphenylenediamine, 2- (3-hydroxyethylamino-5-amino-toluene, 3-hydroxy-1441-aminophenyl) pyrrolidine and their addition salts with an acid.

Among the para-phenylenediamines mentioned above, paraphenylenediamine, paratoluylenediamine, 2-isopropyl paraphenylenediamine, 2- [3-hydroxyethyl paraphenylenediamine, 2- [3-hydroxyethyloxy-para-phenylenediamine, 2,6-dimethyl-para-phenylenediamine, , 6-diethyl paraphenylenediamine, 2,3-dimethyl paraphenylenediamine, N, N-bis- (3-hydroxyethyl) paraphenylenediamine, 2-chloro-para-phenylenediamine, 2- [3-acetylaminoethyloxy-para-phenylenediamine, and their addition salts with an acid are particularly preferred. Among the bis-phenylalkylenediamines, mention may be made, by way of example, of N, N'-bis ((3-hydroxyethyl) N, N'-bis (4'-aminophenyl) -1,3-diamino propanol, N, N'-bis - ([3-hydroxyethyl) N, N'-bis- (4'-aminophenyl) ethylenediamine, N, N'-bis- (4-aminophenyl) tetramethylenediamine, N, N'-bis; - ([3-hydroxyethyl) N, N'-bis (4-aminophenyl) tetramethylenediamine, N, N'-bis- (4-methylaminophenyl) tetramethylenediamine, N, N'-bis (ethyl) N N, B- (4'-amino, 3'-methylphenyl) ethylenediamine, 1,8-bis (2,5-diamino phenoxy) -3,6-dioxaoctane, and their addition salts.

Among para-aminophenols, para-aminophenol, 4-amino-3-methylphenol, 4-amino-3-fluoro-phenol, 4-amino-3-chlorophenol, 4-amino-3 are exemplified. -hydroxymethyl phenol, 4-amino-2-methylphenol, 4-amino-2-hydroxymethylphenol, 4-amino-2-methoxymethylphenol, 4-amino-2-aminomethylphenol, 4-amino-2 - ([3- hydroxyethyl aminomethyl) phenol, 4-amino-2-fluoro phenol, and their addition salts with an acid. Among the ortho-aminophenols, mention may be made, for example, of 2-amino phenol, 2-amino-5-methylphenol, 2-amino-6-methylphenol and 5-acetamido-2-aminophenol, and their addition salts. Among the heterocyclic bases that may be mentioned by way of example are pyridine derivatives, pyrimidine derivatives and pyrazole derivatives. Among the pyridine derivatives, mention may be made of the compounds described for example in patents GB 1 026 978 and GB 1 153 196, such as 2,5-diamino pyridine, 2- (4-methoxyphenyl) amino-3-amino pyridine, 3,4-diamino pyridine, and their addition salts.

Other pyridinic oxidation bases useful in the present invention are the 3-amino pyrazolo [1,5-a] pyridines oxidation bases or their addition salts described for example in the patent application FR 2801308. By way of example, mention may be made of pyrazolo [1,5-a] pyridin-3-ylamine; 2-acetylamino pyrazolo [1,5-a] pyridin-3-ylamine; 2-morpholin-4-yl-pyrazolo [1,5-a] pyridin-3-ylamine; 3-amino-pyrazolo [1,5-a] pyridin-2-carboxylic acid; 2-methoxy-pyrazolo [1,5-a] pyridin-3-ylamino; (3-amino-pyrazolo [1,5-a] pyridin-7-yl) -methanol; 2- (3-aminopyrazolo [1,5-a] pyridin-5-yl) -ethanol; 2- (3-Amino-pyrazolo [1,5-a] pyridin-7-yl) -ethanol; (3-Amino-pyrazolo [1,5-a] pyridin-2-yl) -methanol; 3,6-diaminopyrazolo [1,5-a] pyridine; 3,4-diamino-pyrazolo [1,5-a] pyridine; pyrazolo [1,5-a] pyridine-3,7-diamine; 7-morpholin-4-yl-pyrazolo [1,5-a] pyridin-3-ylamine; pyrazolo [1,5-a] pyridine-3,5-diamine; 5-morpholin-4-yl-pyrazolo [1,5-a] pyridin-3-ylamine; 2 - [(3-amino-pyrazolo [1,5-a] pyridin-5-yl) - (2-hydroxyethyl) amino] ethanol; 2 - [(3-Amino-pyrazolo [1,5-a] pyridin-7-yl) - (2-hydroxyethyl) amino] ethanol; 3-amino-pyrazolo [1,5-a] pyridin-5-ol; 3-amino-pyrazolo [1,5-a] pyridin-4-ol; 3-amino-pyrazolo [1,5-a] pyridin-6-ol; 3-amino-pyrazolo [1,5-a] pyridin-7-ol; as well as their addition salts. Among the pyrimidine derivatives, mention may be made of the compounds described, for example, in DE 2359399; JP 88-169571; JP 05-63124; EP 0770375 or patent application WO 96/15765 such as 2,4,5,6-tetraaminopyrimidine, 4-hydroxy 2,5,6-triaminopyrimidine, 2-hydroxy 4,5,6-triaminopyrimidine, , 4-dihydroxy-5,6-diaminopyrimidine, 2,5,6-triaminopyrimidine and their addition salts and tautomeric forms, when tautomeric equilibrium exists.

Among the pyrazole derivatives, mention may be made of the compounds described in DE 3843892, DE 4133957 and patent applications WO 94/08969, WO 94/08970, FR-A-2 733 749 and DE 195 43 988 as the 4.5 1-methyl pyrazole, 4,5-diamino 1 - ([3-hydroxyethyl) pyrazole, 3,4-diamino pyrazole, 4,5-diamino 1- (4'-chlorobenzyl) pyrazole, 4, 5-diamino 1,3-dimethyl pyrazole, 4,5-diamino-3-methyl-1-phenylpyrazole, 4,5-diamino-1-methyl-3-phenylpyrazole, 4-amino-1,3-dimethyl-5-hydrazino pyrazole, 1-benzyl 4,5-diamino-3-methyl pyrazole, 4,5-diamino-3-tert-butyl-1-methyl pyrazole, 4,5-diamino-1-tert-butyl-3-methyl pyrazole, 4 5-diamino 1 - ([3-hydroxyethyl) 3-methylpyrazole, 4,5-diamino-1-ethyl-3-methylpyrazole, 4,5-diamino-1-ethyl-3- (4'-methoxyphenyl) pyrazole, 4,5-diamino-1-ethyl-3-hydroxymethyl pyrazole, 4,5-diamino-3-hydroxymethyl-1-methyl pyrazole, 4,5-diamino-3-hydroxymethyl-1-isopropyl pyrazole, 4,5-diamino-3- meth 1-isopropyl pyrazole, 4-amino 5- (2'-aminoethyl) amino 1,3-dimethyl pyrazole, 3,4,5-triamino pyrazole, 1-methyl 3,4,5-triamino pyrazole, 3,5-diamino-1-methyl-4-methylamino pyrazole, 3,5-diamino 4 - ([3-hydroxyethyl) amino-1-methyl pyrazole, and their addition salts. It is also possible to use 4-5-diamino-1 - ([3-methoxyethyl) pyrazole. Preferably, a 4,5-diaminopyrazole and even more preferably 4,5-diamino-1 - ([3-hydroxyethyl) pyrazole and / or one of its salts will be used. As pyrazole derivatives, mention may also be made of diamino N, N-dihydropyrazolopyrazolones and especially those described in application FR-A-2,886,136 such as the following compounds and their addition salts: 2,3-diamino-6 7-Dihydro-1H, 5H-pyrazolo [1,2-a] pyrazol-1-one, 2-amino-3-ethylamino-6,7-dihydro-1H, 5H-pyrazolo [1,2-a] pyrazol-1-one, 2-amino-3-isopropylamino-6,7-dihydro-1H, 5H-pyrazolo [1,2-a] pyrazol-1-one, 2-amino-3- (pyrrolidin-1) yl) -6,7-dihydro-1H, 5H-pyrazolo [1,2-a] pyrazol-1-one, 4,5-diamino-1,2-dimethyl-1,2-dihydro-pyrazol-3-one 4,5-diamino-1,2-diethyl-1,2-dihydro-pyrazol-3-one, 4,5-diamino-1,2-di- (2-hydroxyethyl) -1,2-dihydro-pyrazole 3-one, 2-amino-3- (2-hydroxyethyl) amino-6,7-dihydro-1H, 5H-pyrazolo [1,2-a] pyrazol-1-one, 2-amino-3-dimethylamino- 6,7-dihydro-1H, 5H-pyrazolo [1,2-a] pyrazol-1-one, 2,3-diamino-5,6,7,8-tetrahydro-1H, 6H-pyridazino [1, 2-a] pyrazol-1-one, 4-amino-1,2-diethyl-5- (pyrrolidin-1-yl) -1,2-dihydro-pyrazol-3-one, 4-amino-5- (3) -diméth ylamino-pyrrolidin-1-yl) -1,2-diethyl-1,2-dihydro-pyrazol-3-one, 2,3-diamino-6-hydroxy-6,7-dihydro-1H, 5H-pyrazolo [1 , 2-a] pyrazol-1-one. It is preferred to use 2,3-diamino-6,7-dihydro-1H, 5H-pyrazolo [1,2-a] pyrazol-1-one and / or a salt thereof. As heterocyclic bases, use will preferably be made of 4,5-diamino-1 - ([3-hydroxyethyl) pyrazole and / or 2,3-diamino-6,7-dihydro-1H, 5H-pyrazolo [1,2 a] pyrazol-1-one and / or a salt thereof.

Among the couplers that may be used in the composition of the invention, there may be mentioned meta-phenylenediamines, meta-aminophenols, meta-diphenols, naphthalenic couplers, heterocyclic couplers and their addition salts. By way of example, mention may be made of 1,3-dihydroxybenzene, 1,3-dihydroxy-2-methylbenzene, 4-chloro-1,3-dihydroxybenzene and 2,4-diamino-1- (3-dihydroxybenzene). hydroxyethyloxy) benzene, 2-amino 4- (13-hydroxyethylamino) 1-methoxybenzene, 1,3-diamino benzene, 1,3-bis (2,4-diaminophenoxy) propane, 3-ureido aniline, 3-ureido 1-dimethylamino benzene, sesamol, 1-13-hydroxyethylamino-3,4-methylenedioxybenzene, α-naphthol, 2-methyl-1-naphthol, 6-hydroxyindole, 4-hydroxyindole, 4-hydroxy N-methylindole, 2-amino-3-hydroxypyridine, 6-hydroxybenzomorpholine 3,5-diamino-2,6-dimethoxypyridine, 1-N- (3-hydroxyethyl) amino-3 , 4-methylene dioxybenzene, 2,6-bis- (13-hydroxyethylamino) toluene, 6-hydroxy indoline, 2,6-dihydroxy-4-methyl pyridine, 1-H 3 -methyl pyrazole 5-one, 1-phenyl-3-methyl pyrazole-5-one, 2,6-dimethyl pyrazolo [1,5-b] -1,2,4-triazole, 2,6-dimethyl [3,2-c] -1, 2,4-triazole, 6-methyl pyrazol [1,5-a] benzimidazole, their addition salts with an acid, and mixtures thereof. The addition salts of the oxidation bases and the couplers are in particular chosen from acid addition salts such as hydrochlorides, hydrobromides, sulphates, citrates, succinates, tartrates, lactates and tosylates. , benzenesulfonates, phosphates and acetates. The oxidation base (s) are generally present each in an amount of between 0.0001% and 10% by weight relative to the total weight of the composition, and preferably from 0.005% to 5% by weight relative to the total weight of the composition. composition. The coupler or couplers are each in general from 0.0001 to 10% by weight relative to the total weight of the composition, and preferably from 0.005 to 5% by weight relative to the total weight of the composition. The composition according to the invention may contain synthetic or natural direct dyes, cationic or nonionic. By way of example of particularly suitable direct dyes, mention may be made of the nitro dyes of the benzene series; azo direct dyes; azomethines; methinic; azacarbocyanines such as tetraazacarbocyanines (tetraazapentamethines); quinone direct dyes and in particular anthraquinone, naphthoquinone or benzoquinone dyes; direct azine dyes; xanthenics; triarylmethanics; indoamines; indigoids; phthalocyanines, porphyrins and natural direct dyes, alone or in mixtures. In particular, mention may be made of azo direct dyes; methinic; carbonyls; azinic; nitro (hetero) aryl; tri- (hetero) aryl methanes; porphyrins; phthalocyanines and natural direct dyes, alone or in mixtures. When present, the direct dye (s) more particularly represent from 0.0001 to 10% by weight of the total weight of the composition, and preferably from 0.005 to 5% by weight. The composition according to the invention comprises one or more surfactants. The surfactant (s) may be cationic, amphoteric, nonionic and / or anionic surfactants. The surfactants useful in the composition of the invention are surfactants which are known per se in the field of dyeing keratinous fibers. The amphoteric or zwitterionic surfactant (s) that may be used in the present invention may be in particular derivatives of secondary or tertiary aliphatic amines, optionally quaternized, in which the aliphatic group is a linear or branched chain containing from 8 to 22 carbon atoms. said amine derivatives containing at least one anionic group such as, for example, a carboxylate, sulfonate, sulfate, phosphate or phosphonate group. Mention may in particular be made of (C 8 -C 20) alkylbenzines, sulphobetaines, (C 8 -C 20) alkylamido (C 3-8 alkyl) betaines or (C 8 -C 20) alkylamido (C6-C8 alkyl) sulfobetaines. Among the derivatives of secondary or tertiary aliphatic amines optionally quaternized utilizable, as defined above, there may also be mentioned compounds of respective structures (III) and (III '):

Ra-CONHCH2CH2-N + (Rb) (Rc) (CH2COO-) (III) in which: Ra represents a C10-C30 alkyl or alkenyl group derived from an acid Ra-0000H preferably present in hydrolysed coconut oil heptyl, nonyl or undecyl, Rb is beta-hydroxyethyl, and Rc is carboxymethyl;

and Ra'-CONHCH2CH2-N (B) (B ') (III')

wherein: B represents -CH2CH2OX ', B' represents - (CH2) z-Y ', with z = 1 or 2, X' represents the group -CH2-0OOH, CH2-COOZ ', -CH2CH2-0OOH, -CH2CH2 -COOZ ', or a hydrogen atom, Y' represents -000H, -COOZ ', the group -CH2-CHOH-SO3H or -CH2-CHOH-SO3Z', Z 'represents an ion derived from an alkali metal or alkaline earth such as sodium, an ammonium ion or an ion derived from an organic amine. Ra 'represents a C10-C30 alkyl or alkenyl group of a Ra'-O00H acid, preferably present in coconut oil or in hydrolysed linseed oil, an alkyl group, in particular a C17 and its iso form, unsaturated C17 group.

These compounds are classified in the CTFA dictionary, 5th edition, 1993, under the names cocoamphodiacétate disodium, lauroamphodiacétate disodium, caprylamphodiacétate disodium, capryloamphodiacétate disodium, cocoamphodipropionate disodium, lauroamphodipropionate disodium, caprylamphodipropionate disodium, capryloamphodipropionate disodium, acid lauroamphodipropionic, cocoamphodipropionic acid. By way of example, mention may be made of cocoamphodiacetate marketed by Rhodia under the trade name MIRANOL® C2M concentrate. Among the amphoteric or zwitterionic surfactants mentioned above, use is preferably made of betaines comprising at least one saturated or unsaturated C8-C30 fatty chain and in particular the compounds of formula (A): R1- (CONH) x -A1-N + (R2) (R3) -A2-Z (A) With x denoting 0 or 1 Al and A2 denoting independently of each other a linear or branched C1-C10 alkylene radical optionally substituted by a hydroxyl radical R1 denoting a linear or branched C6-C30 alkyl or alkenyl radical R2 and R3 denoting, independently of one another, a linear or branched C1-C4 alkyl radical. Z denoting a CO2- or SO3- group. Preferably R2 and R3 denote a methyl radical. The amphoteric surfactant (s) of betaine type used in the cosmetic composition according to the present invention may be in particular alkyl (C8-20) betaines, alkyl (C8-20) sulphobetaines, (C8-20 alkyl) amido. (C2-C8 alkyl) betaines or (C8-20 alkyl) amido (C6-8 alkyl) sulfobetaines. Among the amphoteric surfactants mentioned above, use is preferably made of (C 8-20 alkyl) betaines, (C 8-20 alkyl) amido (C 2-8 alkyl) betaines, and mixtures thereof. More particularly, betaine-type amphoteric surfactants are chosen from cocobetaine and cocamidopropylbétaine. The term "anionic surfactant" is understood to mean a surfactant comprising as ionic or ionizable groups only anionic groups. These anionic groups are preferably chosen from the groups CO2H, CO2-, SO3H, SO3-, OSO3H, OSO3-, H2PO3, HPO3-, PO3 2-, H2PO2 HPO2, HPO2-, PO2-, POH, PO-. Examples of anionic surfactants that can be used in the composition according to the invention include alkyl sulphates, alkyl ether sulphates, alkyl amido ether sulphates, alkylaryl polyether sulphates, monoglyceride sulphates, alkyl sulphonates, alkyl amide sulphonates, alkyl aryl sulphonates and alpha sulphonates. olefin-sulfonates, paraffin-sulfonates, alkylsulfosuccinates, alkylethersulfosuccinates, alkylamide-sulfosuccinates, alkylsulfoacetates, acylsarcosinates, acylglutamates, alkylsulfosuccinamates, acylisethionates and N-acyltaurates, alkyl monoester salts and polyglycoside-polycarboxylic acids, acyllactylates, D-galactoside-uronic acid salts, alkyl ether-carboxylic acid salts, alkyl acid salts aryl ether carboxylic acids, alkyl amidoether carboxylic acid salts; and the corresponding non-salified forms of all these compounds; the alkyl and acyl groups of all these compounds having from 6 to 24 carbon atoms and the aryl group denoting a phenyl group. These compounds may be oxyethylenated and then preferably comprise from 1 to 50 ethylene oxide units.

The salts of C6-24 alkyl monoesters and of polyglycosidepolycarboxylic acids may be chosen from C6-24 alkyl polyglycoside citrates, C6-24 alkyl polyglycoside tartrates and alkyl polyglycoside sulphosuccinates. 6-24. When the agent or the anionic surfactants are in the salt form, they may be chosen from alkali metal salts such as the sodium or potassium salt and preferably sodium salt, ammonium salts, amine salts and in particular aminoalcohols or alkaline earth metal salts such as magnesium salt. By way of example of aminoalcohol salts, mention may be made in particular of the salts of mono-, di- and triethanolamine, the salts of mono-, di- or tri-isopropanolamine, the salts of 2-amino-2-methyl 1-propanol, 2-amino-2-methyl-1,3-propanediol and tris (hydroxymethyl) amino methane. The alkali metal or alkaline earth metal salts and in particular the sodium or magnesium salts are preferably used.

Among the anionic surfactants, it is preferred to use, according to the invention, the alkyl sulphate and alkyl ether sulfate salts and their mixtures. The term "cationic surfactant" means a positively charged surfactant when it is contained in the composition according to the invention. This surfactant may carry one or more positive permanent charges or contain one or more cationizable functions within the composition according to the invention. The cationic surfactant or surfactants that can be used as conditioning agents according to the present invention are preferably chosen from primary, secondary or tertiary fatty amines, optionally polyoxyalkylenated, or their salts, quaternary ammonium salts, and mixtures thereof. Fatty amines generally comprise at least one C8-C30 hydrocarbon chain. Among the fatty amines that can be used according to the invention, mention may be made, for example, of stearylamidopropyl dimethylamine and distearylamine.

As quaternary ammonium salts, mention may be made, for example: - those corresponding to the following general formula (IV): + X (IV) in which the groups R 8 to R 11, which may be identical or different, represent an aliphatic group, linear or branched, having from 1 to 30 carbon atoms, or an aromatic group such as aryl or alkylaryl, at least one of the groups R8 to R11 denoting a group comprising from 8 to 30 carbon atoms, preferably from 12 to 24 carbon atoms. The aliphatic groups can comprise heteroatoms such as in particular oxygen, nitrogen, sulfur and halogens. The aliphatic groups are, for example, chosen from C1-30 alkyl, C1-30 alkoxy, polyoxyalkylene (C2-C6), C1-30 alkylamide, (C1-C22) alkylamido (C2-C6) alkyl, alkyl ( C12-C22) acetate, and C1-30 hydroxyalkyl; X- is an anion selected from the group of halides, phosphates, acetates, lactates, (C1-C4) alkyl sulfates, (C1-C4) alkyl or (C1-C4) alkylsulphonates. Among the quaternary ammonium salts of formula (IV), tetraalkylammonium salts are preferred, for example, dialkyldimethylammonium or alkyltrimethylammonium salts in which the alkyl group comprises from about 12 to 22 carbon atoms. carbon, in particular the salts of behenyltrimethylammonium, distearyldimethylammonium, cetyltrimethylammonium, benzyldimethylstearylammonium or, on the other hand, the salt of palmitylamidopropyltrimethylammonium, stearamidopropyltrimethylammonium, the salt of staramidopropyldimethylcétéaryl ammonium, or the salt of staramidopropyldimethyl (myristyl acetate) ammonium. sold under the name CERAPHYL® 70 by VAN DYK. It is particularly preferred to use the chloride salts of its compounds. the quaternary ammonium salts of imidazoline, such as, for example, those of the following formula (V): + Ris C / CH 2 CH 2 -N (R 15) -CO-R 12 N-N-R 4 O -C 2 H 2 (V)

wherein R12 is alkenyl or alkyl having 8 to 30 carbon atoms, for example fatty acid derivatives of tallow, R13 represents a hydrogen atom, a C1-C4 alkyl group or an alkenyl or alkyl group having 8 to 30 carbon atoms, R14 represents a C1-C4 alkyl group, R15 represents a hydrogen atom, a C1-C4 alkyl group, X- is an anion chosen from the group of halides, phosphates, acetates, lactates alkyl, sulphates, alkyl or alkylaryl sulphonates, the alkyl and aryl groups of which preferably comprise 1 to 20 carbon atoms and 6 to 30 carbon atoms, respectively. Preferably, R12 and R13 denote a mixture of alkenyl or alkyl groups containing from 12 to 21 carbon atoms, for example fatty acid derivatives of tallow, R14 denotes a methyl group, R15 denotes a hydrogen atom. Such a product is for example marketed under the name REWOQUAT® W 75 by the company REWO;

the quaternary di or triammonium salts, in particular of the formula ## STR1 ## in which R16 denotes an alkyl radical comprising approximately of 16 to 30 carbon atoms optionally hydroxylated and / or interrupted by one or more oxygen atoms, R17 is chosen from hydrogen or an alkyl radical containing from 1 to 4 carbon atoms or a group (R16a) (R17a) (R18a) N- (CH2) 3, R16a, R17a, R18a, R18, R19, R20 and R21, which are identical or different, are chosen from hydrogen or an alkyl radical containing from 1 to 4 carbon atoms, and X- is an anion selected from the group of halides, acetates, phosphates, nitrates and methylsulfates. Such compounds are for example X (VI): Finquat CT-P proposed by FINETEX (Quaternium 89), Finquat CT proposed by FINETEX (Quaternium 75), - Quaternary ammonium salts containing at least an ester function, such as those of the following formula (VII): ## STR2 ##

R22 wherein: R22 is selected from C1-C6 alkyl groups and C1-C6 hydroxyalkyl or dihydroxyalkyl groups; R23 is selected from: O

0-15 O - the group R28 C - the groups R29 which are linear or branched, saturated or unsaturated hydrocarbon groups C1-C6, - the hydrogen atom, R24, R26 and R28, which are identical or different, are chosen from linear or branched, saturated or unsaturated C7-C21 hydrocarbon groups; r, s and t, identical or different, are integers ranging from 2 to 6; r1 and t1 identical or different, being 0 or 1 and r2 + r1 = 2r and t1 + t2 = 2t

y is an integer from 1 to 10; x and z, which are identical or different, are integers ranging from 0 to 10; X- is a simple or complex anion, organic or inorganic; the group R 26 - the groups R 27 which are linear or branched, saturated or unsaturated C 1 -C 22 hydrocarbon-based groups, - the hydrogen atom, R 25 is chosen from: 20 with the proviso that the sum x + y + z is from 1 to 15, that when x is 0 then R23 is R27 and when z is 0 then R25 is R29. The alkyl groups R22 may be linear or branched and more particularly linear.

Preferably, R 22 denotes a methyl, ethyl, hydroxyethyl or dihydroxypropyl group, and more particularly a methyl or ethyl group. Advantageously, the sum x + y + z is from 1 to 10. When R 23 is a hydrocarbon R 27 group, it may be long and have 12 to 22 carbon atoms, or short and have from 1 to 3 carbon atoms.

When R 25 is a hydrocarbon R 29 group, it preferably has 1 to 3 carbon atoms. Advantageously, R24, R26 and R28, which are identical or different, are chosen from linear or branched, saturated or unsaturated C11-C21 hydrocarbon groups, and more particularly from linear or branched, saturated C11-C21 alkyl and alkenyl groups. or unsaturated. Preferably, x and z, which are identical or different, are equal to 0 or 1. Advantageously, y is equal to 1. Preferably, r, s and t, identical or different, are equal to 2 or 3, and even more particularly are equal to 2 .

The anion X- is preferably a halide (chloride, bromide or iodide) or an alkyl sulphate more particularly methyl sulphate. However, it is possible to use methanesulphonate, phosphate, nitrate, tosylate, an anion derived from an organic acid such as acetate or lactate or any other anion compatible with ammonium with an ester function.

The X- anion is even more particularly chloride or methylsulfate. In the composition according to the invention, the ammonium salts of formula (VII) are used more particularly in which: R 22 denotes a methyl or ethyl group, x and y are equal to 1; z is 0 or 1; r, s and t are 2; R23 is selected from: O - the group R26 0- - methyl, ethyl or C14-C22 hydrocarbon groups, - the hydrogen atom; the group R28 - the hydrogen atom; R24, R26 and R28, which are identical or different, are chosen from linear or branched, saturated or unsaturated C13-C17 hydrocarbon groups, and preferably from linear or branched, saturated or unsaturated C13-C17 alkyl and alkenyl groups; . Advantageously, the hydrocarbon groups are linear. There may be mentioned, for example, the compounds of formula (VI) such as the salts (especially chloride or methylsulfate) of diacyloxyethyl-dimethylammonium, diacyloxyethyl-hydroxyethyl-methylammonium, monoacyloxyethyldihydroxyethyl-methylammonium, triacyloxyethyl-methylammonium, monoacyloxyethyl-hydroxyethyl-dimethylammonium and their mixtures. The acyl groups preferably have from 14 to 18 carbon atoms and come more particularly from a vegetable oil such as palm oil or sunflower oil. When the compound contains more than one acyl group, the latter groups may be identical or different. These products are obtained, for example, by direct esterification of triethanolamine, triisopropanolamine, alkyldiethanolamine or alkyldiisopropanolamine, optionally oxyalkylenated, with C10-C30 fatty acids or with mixtures of C10-C30 fatty acids. plant or animal origin, or by transesterification of their methyl esters. This esterification is followed by quaternization using an alkylating agent such as an alkyl halide (preferably methyl or ethyl), a dialkyl sulphate (preferably methyl or ethyl), methanesulfonate. methyl, para-toluenesulfonate methyl, chlorohydrin glycol or glycerol. Such compounds are, for example, sold under the names DEHYQUARTO by the company HENKEL, STEPANQUATO by the company STEPAN, NOXAMIUMO by the company CECA, REWOQUATO WE 18 by the company REWO-WITCO. The composition according to the invention may contain, for example, a mixture of quaternary ammonium mono-, di- and triester salts with a majority by weight of diester salts. It is also possible to use the ammonium salts containing at least one ester function described in US-A-4874554 and US-A-4137180. R25 is selected from: O

C can be used behenoylhydroxypropyltrimethylammonium chloride proposed by KAO under the name Quatarmin BTC 131. Preferably the ammonium salts containing at least one ester function contain two ester functions.

Among the quaternary ammonium salts containing at least one useful ester function, it is preferred to use dipalmitoylethylhydroxyethylmethylammonium salts. The nonionic surfactants are more particularly chosen from mono or polyoxyalkylenated, mono- or polyglycerolated nonionic surfactants. The oxyalkylenated units are more particularly oxyethylenated units, oxypropylene, or their combination, preferably oxyethylenated. By way of examples of oxyalkylenated nonionic surfactants, mention may be made of: oxyalkylenated (C 8 -C 24) alkylphenols, saturated or unsaturated, linear or branched, oxyalkylenated C 8 -C 30 alcohols, amides, in C 6 -C 30, saturated or non-saturated, linear or branched, oxyalkylenated, - saturated or unsaturated, linear or branched C 8 -C 30 acid esters, and polyethylene glycols, - C 8 -acidic esters - C30, saturated or unsaturated, linear or branched, and polyoxyethylenated sorbitol, - oxyethylenated vegetable oils, saturated or not, - condensates of ethylene oxide and / or propylene oxide, inter alia, alone or in mixtures . Surfactants having a number of moles of ethylene oxide and / or propylene of between 1 and 100, preferably between 2 and 50, preferably between 2 and 30. According to a preferred embodiment of the invention, the oxyalkylenated nonionic surfactants are chosen from oxyethylenated C 8 -C 30 alcohols comprising from 1 to 100 moles of ethylene oxide; saturated or unsaturated linear or branched C 8 -C 30 esters of polyoxyethylenated sorbitol comprising from 1 to 100 moles of ethylene oxide. By way of example of mono- or poly-glycerolated nonionic surfactants, the C -C 40 alcohols, mono- or polyglycerolated, are preferably used. In particular, the mono- or poly-glycerolated C 8 -C 40 alcohols correspond to the following formula: ## STR2 ## in which R represents a linear or branched alkyl or alkenyl radical, in C 6 -C 30, preferably C 6 -C 30, and m represents a number ranging from 1 to 30 and preferably from 1 to 10.

By way of example of suitable compounds in the context of the invention, mention may be made of lauryl alcohol with 4 moles of glycerol (INCI name: POLYGLYCERYL-4 LAURYL ETHER), alcohol (auric at 1.5 moles glycerol, oleic alcohol with 4 moles of glycerol (INCI name: POLYGLYCERYL-4 OLEYL ETHER), oleic alcohol with 2 moles of glycerol (INCI name: POLYGLYCERYL-2 OLEYL ETHER), cetyl alcohol with 2 moles of glycerol, cetearyl alcohol containing 6 moles of glycerol, oleocetyl alcohol containing 6 moles of glycerol, and octadecanol containing 6 moles of glycerol, and the alcohol may represent a mixture of alcohols in the same way as the value of m represents a statistical value, which means that in a commercial product several species of polyglycerolated fatty alcohols may coexist in the form of a mixture Among the mono- or polyglycerolated alcohols, it is more particularly preferred to use the C-alcohol. $ / C10 to one mole of glycerol, C1 to C12 alcohol to 1 mole glycerol and the Cu alcohol to 1.5 moles of glycerol.

Nonionic surfactants that may also be mentioned include non-oxyethylenated fatty acid and sorbitan esters, sucrose fatty acid esters, optionally oxyalkylenated alkylpolyglycosides, alkylglucoside esters, N-alkylglucamine derivatives and N-acyl-methylglucamine, aldobionamides and amine oxides.

The surfactant or surfactants are preferably chosen from amphoteric, nonionic and anionic surfactants. More preferentially, the surfactant or surfactants are chosen from amphoteric and anionic surfactants. Even more preferentially, the surfactant or surfactants are chosen from amphoteric surfactants. According to a particular embodiment, the composition of the invention comprises one or more amphoteric surfactants, one or more nonionic surfactants and one or more anionic surfactants. According to this embodiment, the nonionic surfactant is preferably chosen from oxyethylenated fatty alcohols and saturated oxyethylenated vegetable oils or. The anionic surfactant is chosen from alkyl sulphates or alkyl ether sulphates. The total content of surfactants in the composition of the invention is in general between 0.1 and 30% by weight, preferably between 1 and 20% and better still between 1 and 10% by weight relative to the weight of the composition.

The composition may also contain various adjuvants conventionally used in compositions for dyeing or lightening hair, such as anionic, cationic, nonionic polymers, or mixtures thereof; antioxidants; penetrants; sequestering agents; perfumes ; dispersants; film-forming agents; ceramides; preservatives; opacifying agents. The adjuvants above are generally present in an amount for each of them between 0.01 and 20% by weight relative to the weight of the composition.

Preferably, the composition according to the invention comprises one or more cationic polymers. The composition according to the invention may comprise water and / or one or more organic solvents. As organic solvent, there may be mentioned for example linear or branched, preferably saturated monoalcohols or diols, comprising 2 to 10 carbon atoms, such as ethyl alcohol, isopropyl alcohol, hexylene glycol (2 methyl 2,4-pentanediol), neopentyl glycol and 3-methyl-1,5-pentanediol, butylene glycol, dipropylene glycol and propylene glycol; aromatic alcohols such as benzyl alcohol, phenylethyl alcohol; polyols with more than two hydroxyl functions such as glycerol; polyol ethers such as, for example, ethylene glycol monomethyl, monoethyl and monobutyl ethers, propylene glycol or its ethers such as, for example, propylene glycol monomethyl ether, and diethylene glycol, especially C1-C4 alkyl ethers, for example, diethylene glycol monoethyl ether or monobutyl ether, alone or as a mixture. The organic solvents, when they are present, generally represent between 1 and 40% by weight relative to the total weight of the dye composition, and preferably between 5 and 30% by weight relative to the total weight of the dyeing composition.

Preferably the composition is aqueous. In this case it preferably comprises from 30 to 95% of water by weight, better still from 40 to 90% by weight of water, more preferably from 50 to 85% by weight relative to the total weight of the composition. . The pH of the composition according to the invention if it is aqueous is generally between 3 and 12, preferably between 5 and 11, preferably between 7 and 11 inclusive. It can be adjusted to the desired value by means of acidifying or basifying agents usually used for dyeing keratinous fibers and in particular the alkaline agents of the invention mentioned above. The composition before diffusion in the form of a foam may result from the mixing of two or more compositions. The composition according to the invention is applied to keratinous fibers in the form of a foam.

The foam composition according to the invention is formed from a mixture of air or an inert gas with the composition described above. According to a particularly preferred embodiment, the composition according to the invention is in the form of a temporary foam produced just before use. According to this embodiment, the composition can be packaged in a foam dispenser. It can be either products called "aerosols" distributed from a pressurized container, using a propellant gas and thus forming a foam at the time of their distribution, or compositions distributed from a container by means of a mechanical pump connected to a dispensing head, the passage of the composition in the dispensing head transforming foam at the latest outlet level of such a head. According to a first variant, the dispenser may be an aerosol containing, in addition to the base composition, generally divided into two parts, one with the oxidizing agent (s) and the other with the propellant gas precursor (s). In such a configuration the two parts are usually stored separately each in a pressure vessel. Thus the propellants selected in each of the containers can be adapted to the contained portion. The propellant gas that can be used can be chosen from carbon dioxide, nitrogen, nitrogen oxide, dimethyl ether, volatile hydrocarbons such as butane, isobutane, propane and pentane, and mixtures thereof. . In practice for this variant one will use either an aerosol container with a single container internally containing two bags or a double aerosol containing two containers. In both cases the dispensing head is such that what is sprayed in the form of foam is the composition according to the invention, that is to say the mixture of the composition with the oxidizing agent (s) and the composition with the or the oxidation dye precursors.

According to another embodiment, the composition can be in a foam dispenser type "pump flasks". These dispensers include a dispensing head for dispensing the composition, a pump and a dip tube for transferring the composition of the container into the head to deliver the product. The foam is formed by forcing the composition to pass through a

material comprising a porous substance such as a sintered material, a filtering grid made of plastic or metal, or similar structures. Such dispensers are well known to those skilled in the art and are described in U.S. Patent Pat. No. 3,709,437 (Wright), U.S. Pat. No. 3,937,364 (Wright), US Pat. No. 4,022,351 (Wright), US Pat No. 4,1147,306 (Bennett), US Pat No. 4,184,615 (Wright), US Pat No. 4,598,862 (Rice), US Pat No 4,615,467 (Grogan et al.) And US Pat No. 5,364,031 (Tamiguchi et al.). In practice for this variant, the oxidizing agent (s) are packaged in a first container equipped with a stopper, and the oxidation dye precursor (s) are packaged in a second container, distinct from the first one, and also closed by a closure member. The closure member may be a pump dispensing mechanism. The composition according to the invention is then formed by mixing before use of a composition with the oxidizing agent (s) and a composition with the oxidation dye precursor (s). For this purpose, to limit the number of containers provided, one of the first or the second container defines an interior volume sufficient to receive the entirety of the two compositions. The mixture of the compositions can be homogenized by closing the container and shaking the container. Closing the container is advantageously carried out directly with the dispensing head. This dispensing head comprises a mechanical pump retained in a hoop intended for mounting by snapping or screwing on the neck of the container containing the mixture. The pump comprises a pump body connected to a dip tube to allow a distribution of the entire mixture. The pump also comprises a push button for actuating the pump body, such that each actuation, a dose of composition is sucked into the interior of the plunger tube and ejected in the form of foam at the dispensing orifice of the pump. the head. In this example, the containers are preferably made of a thermoplastic material, and obtained by extrusion blow molding or blow molding processes. In particular, the container intended for conditioning the composition with the oxidation dye precursor (s) is made of a material comprising a non-zero proportion of EVOH. The pump is for example the standard model "F2 - L9" proposed by the company REXAM. According to this preferred embodiment, the subject of the invention is a non-aerosol device comprising the composition of the invention.

The dyeing method according to the invention consists in applying the composition according to the invention to human, dry or moist keratin fibers for a time sufficient to develop the desired coloration. According to the invention, the composition applied to the keratin fibers is in the form of a foam. The dyeing process is generally carried out at room temperature (between 15 to 25 ° C) and up to temperatures of up to 60 ° C to 80 ° C. After a pause of one minute to one hour, preferably from 5 minutes to 30 minutes, the keratin fibers are rinsed with water, optionally washed with a shampoo followed by rinsing with water.

The following examples serve to illustrate the invention without being limiting in nature.

EXAMPLES The following compositions are prepared (the amounts are expressed in g% of active ingredients) Composition AB Coco betaine 1 1 Sodium laureth sulfate 1 1 Sucrose (Saccharose) 0.5 0.5 Ammonia (expressed as NH3) 0.6 - Monoethanolamine 2 2 Sorbitol 4 4 POLYQUATERNIUM-6 0.5 0.5 POLYQUATERNIUM-39 0.05 0.05 Hydrogenated castor oil 40 oxyethylenated 0.4 0.4 Hydrogen peroxide 4.5 4.5 Glycerin 3 3 Cetearyl alcohol 0.2 0.2 Erythorbic acid 0.2 0.2 Sodium metabisulfite 0.2 0.2 Sodium salicylate 0.021 0.021 Tetrahedric pyrophosphate 0.024 0.024 Tetrasodium Etidronate 0.036 0.036 EDTA 0.08 0.08 Phosphoric acid Qsp. Qs. PH pH Water Qs. Qs.

The compositions E1 and E2 above are obtained by mixing before use of two compositions: Al and B for composition E1, A2 and B for composition E2: Composition Composition A1 A2 Precursors of oxidation dyes (base (s) ) Qs grade Qs grade and coupler (s) Coco betaine 2.5 2.5 Sucrose 1.25 1.25 Ammonia (expressed as NH3) 1.5 Monoethanolamine 5 5 Sorbitol 10 10 POLYQUATERNIUM-6 1.25 1.25 Hydrogenated castor oil 40-oxyethylenated 1 1 Erythorbic acid 0.5 0.5 Sodium metabisulfite 0.5 0.5 EDTA 0.2 0.2 Water Qs.

100 Qs.

100 Composition B% by weight Sodium laureth sulfate 1,666 POLYQUATERNIUM-39 0.083 Hydrogen peroxide 7.5 Glycerine 5 Cetearyl alcohol 0.333 Sodium salicylate 0.035 Tetrasodium pyrophosphate 0.04 Tetrasodium tetrasodium tetrasodium 0.06 Phosphoric acid Qsp. pH 2.2 Water Qs.

The mixture is introduced at a rate of 65 g (26 g of composition A + 39 g of composition B) into a pump bottle (L9 REXAM equipped with a dip tube) The device makes it possible, by pumping, to obtain a foam which is sufficiently compact. to be applied on gray hair with 90% white, natural or permed and not to disintegrate immediately.Comfort on application is very good.After 30 minutes of installation, the locks are rinsed, washed with a shampoo 15 standard , rinsed again and then dried to give the desired coloring.This coloration is powerful and selectively selective.5

Claims (17)

REVENDICATIONS1. A foam coloring composition comprising: (a) at least one monosaccharide or saccharide; (b) at least one alkaline agent; (c) at least one surfactant; (d) at least one oxidizing agent, (e) at least one oxidation dye precursor. 2. Composition according to Claim 1, in which the surfactant or surfactants are chosen from cationic, amphoteric, nonionic and anionic surfactants, preferably from amphoteric, nonionic and anionic surfactants and more preferably from amphoteric and anionic surfactants, and more preferably among amphoteric surfactants. 3. The composition according to claim 1, in which the surfactant is an amphoteric surfactant chosen from (C 8 -C 20) alkylbetaines, sulphobetaines, (C 8 -C 20) alkylamido (C 1 -C 6) alkylbetaines or alkyls. (C 8 -C 20) amidoalkyl (C 1 -C 6) sulfobetaines, preferably (C 8 -C 20) alkylamido (C 1 -C 6) alkylbetaines. 4. Composition according to any one of the preceding claims comprising one or more amphoteric surfactants, one or more nonionic surfactants and one or more anionic surfactants. 5. Composition according to any one of claims 1 to 4 wherein the surfactant or surfactants are present in a total amount ranging from 0.1 to 30% by weight, preferably from 1 to 20% by weight, preferably from 1 to 10% by weight. weight relative to the weight of the composition. 6. Composition according to any one of the preceding claims, in which the alkaline agent is chosen from ammonia, alkanolamines and amino acids. 7. Composition according to any one of the preceding claims wherein the alkaline agent is selected from alkanolamines and in particular is monoethanolamine. 8. Composition according to any one of the preceding claims wherein the alkaline agent or agents represent a content ranging from 0.01 to 30% by weight, preferably from 0.1 to 20% by weight, better still from 1 to 10% by weight. weight relative to the weight of said composition. 9. A composition according to any preceding claim wherein the monosaccharides are selected from ribulose, xylulose, psicose, fructose, sorbose, tagatose, ribose, arabinose, xylose, lyxose allose, altrose, glucose, mannose, gulose, idose, galactose, talose, better fructose, xylose, glucose, galactose and mannose. 10. Composition according to any one of claims 1 to 8 wherein the disaccharides are selected from sucrose, trehalose, raffinose, lactose, cellobiose, maltose, isomaltulose, lactulose, better from lactose and sucrose. 11. Composition according to any one of the preceding claims wherein the mono- or disaccharides are chosen from fructose, xylose, glucose, galactose, mannose lactose and sucrose better, from glucose or sucrose. 12. Composition according to any one of the preceding claims, in which the mono or disaccharide or monosaccharides are present in the composition in an amount ranging preferably from 0.01 to 10%, better still from 0.1 to 5%, and more preferably from 0.2 to 2% relative to the total weight of the composition. 13. Composition according to any one of the preceding claims wherein the oxidizing agent is hydrogen peroxide. . 14. Composition according to any one of the preceding claims, comprising one or more oxidation bases and one or more couplers. 15. An aerosol device comprising means for generating in the form of foam a composition as defined in any one of claims 1 to 14; 16. An aerosol device according to claim 15 comprising a single container provided with 2 bags or comprising two containers. 17. Non-aerosol device comprising a bottle equipped with a mechanical pumping system and comprising a composition as defined in any one of claims 1 to 14 and a dispensing system for delivering it in the form of foam.