FR2959750A1 - Procede de production de kerosene a partir de bio-ethanol. - Google Patents

Procede de production de kerosene a partir de bio-ethanol. Download PDF

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Publication number
FR2959750A1
FR2959750A1 FR1001952A FR1001952A FR2959750A1 FR 2959750 A1 FR2959750 A1 FR 2959750A1 FR 1001952 A FR1001952 A FR 1001952A FR 1001952 A FR1001952 A FR 1001952A FR 2959750 A1 FR2959750 A1 FR 2959750A1
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FR
France
Prior art keywords
effluent
feedstock
oligomerization
catalyst
amorphous
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR1001952A
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English (en)
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FR2959750B1 (fr
Inventor
Emmanuelle Guillon
Nicolas Cadran
Natacha Touchais
Laurent Bournay
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IFP Energies Nouvelles IFPEN
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IFP Energies Nouvelles IFPEN
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Priority to FR1001952A priority Critical patent/FR2959750B1/fr
Priority to PCT/FR2011/000265 priority patent/WO2011138520A2/fr
Publication of FR2959750A1 publication Critical patent/FR2959750A1/fr
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Publication of FR2959750B1 publication Critical patent/FR2959750B1/fr
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/42—Catalytic treatment
    • C10G3/44—Catalytic treatment characterised by the catalyst used
    • C10G3/48—Catalytic treatment characterised by the catalyst used further characterised by the catalyst support
    • C10G3/49—Catalytic treatment characterised by the catalyst used further characterised by the catalyst support containing crystalline aluminosilicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C07C1/24—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by elimination of water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/62—Catalyst regeneration
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G50/00—Production of liquid hydrocarbon mixtures from lower carbon number hydrocarbons, e.g. by oligomerisation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1011—Biomass
    • C10G2300/1014—Biomass of vegetal origin
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/30—Physical properties of feedstocks or products
    • C10G2300/301—Boiling range
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4018—Spatial velocity, e.g. LHSV, WHSV
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4081—Recycling aspects
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/04—Diesel oil
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/08—Jet fuel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

L'invention décrit un procédé de production de bases hydrocarbonées distillats moyens à partir d'une charge issue de la biomasse, ledit procédé comprenant une étape de purification de ladite charge, une étape de déshydratation de ladite charge purifiée en un effluent majoritairement éthylènique comprenant de l'eau, ladite étape opérant en présence d'un catalyseur acide amorphe ou zéolithique, au moins une étape de séparation de l'eau et/ou purification, une première étape d'oligomérisation en au moins un effluent oléfinique léger comprenant au moins 50% poids d'oléfines ayant un nombre d'atomes de carbone supérieur ou égal à 4, en présence d'un catalyseur comprenant au moins un élément du groupe VIII et un support réfractaire oxyde poreux, une deuxième étape d'oligomérisation produisant des bases hydrocarbonées distillats moyens en présence d'un catalyseur amorphe ou zéolithique ayant au moins des ouvertures de pores contenant 10 ou 12 atomes d'oxygène et une étape de fractionnement de l'effluent issu de l'étape d'oligomérisation.
FR1001952A 2010-05-06 2010-05-06 Procede de production de kerosene a partir de bio-ethanol. Active FR2959750B1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
FR1001952A FR2959750B1 (fr) 2010-05-06 2010-05-06 Procede de production de kerosene a partir de bio-ethanol.
PCT/FR2011/000265 WO2011138520A2 (fr) 2010-05-06 2011-04-29 Procede de production de kerosene a partir de bio-ethanol

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR1001952A FR2959750B1 (fr) 2010-05-06 2010-05-06 Procede de production de kerosene a partir de bio-ethanol.

Publications (2)

Publication Number Publication Date
FR2959750A1 true FR2959750A1 (fr) 2011-11-11
FR2959750B1 FR2959750B1 (fr) 2013-02-15

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
FR1001952A Active FR2959750B1 (fr) 2010-05-06 2010-05-06 Procede de production de kerosene a partir de bio-ethanol.

Country Status (2)

Country Link
FR (1) FR2959750B1 (fr)
WO (1) WO2011138520A2 (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2018001920A1 (fr) * 2016-06-30 2018-01-04 IFP Energies Nouvelles Procede d'oligomerisation utilisant un catalyseur zeolithique et un catalyseur comprenant une silice alumine
FR3053265A1 (fr) * 2016-06-30 2018-01-05 IFP Energies Nouvelles Procede d'oligomerisation utilisant un catalyseur composite a base de silice-alumine et de zeolithe
FR3134110A1 (fr) 2022-04-05 2023-10-06 Axens Procédé amélioré de production de distillats moyens par oligomérisation d’une charge oléfinique

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AP2014008121A0 (en) * 2012-05-11 2014-12-31 Pet Oil & Gas Corp S Africa Conversion of alcohols to distillates
WO2014127436A1 (fr) * 2013-02-25 2014-08-28 Braskem S.A. Procédé de production d'oléfines à partir d'éthanol combustible
WO2014154801A1 (fr) * 2013-03-28 2014-10-02 Bp P.L.C. Production d'une composition d'hydrocarbure de distillat moyen
WO2014154802A1 (fr) * 2013-03-28 2014-10-02 Bp P.L.C. Production d'une composition d'hydrocarbure lourd liquide
WO2014154798A1 (fr) * 2013-03-28 2014-10-02 Bp P.L.C. Production d'une composition d'hydrocarbures de distillat moyen
WO2014154803A1 (fr) 2013-03-28 2014-10-02 Bp P.L.C. Production d'une composition d'hydrocarbures issus du distillat moyen
WO2014154799A1 (fr) * 2013-03-28 2014-10-02 Bp P.L.C. Production de composition d'hydrocarbures de distillat moyen
US9732285B2 (en) 2013-12-17 2017-08-15 Uop Llc Process for oligomerization of gasoline to make diesel
US9670425B2 (en) 2013-12-17 2017-06-06 Uop Llc Process for oligomerizing and cracking to make propylene and aromatics
US10815439B2 (en) 2018-08-22 2020-10-27 Exxonmobil Research And Engineering Company Manufacturing hydrocarbons
US10843980B2 (en) 2018-08-22 2020-11-24 Exxonmobil Research And Engineering Company Manufacturing a base stock from ethanol
SG11202100187PA (en) * 2018-08-22 2021-03-30 Exxonmobil Res & Eng Co Manufacturing hydrocarbon fluids
FR3090393B1 (fr) * 2018-12-20 2021-04-23 Ifp Energies Now Procédé de traitement d’une charge alcool pour la production d’oléfines
WO2022063992A1 (fr) 2020-09-25 2022-03-31 Haldor Topsøe A/S Procédé de conversion méthanol en oléfine (mto)
WO2022063995A1 (fr) * 2020-09-25 2022-03-31 Haldor Topsøe A/S Procédé de conversion méthanol en oléfine (mto)

Citations (10)

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Publication number Priority date Publication date Assignee Title
US3527839A (en) * 1969-01-13 1970-09-08 Shell Oil Co Ethylene oligomerization
US3992323A (en) * 1973-03-26 1976-11-16 Atlantic Richfield Company Olefin polymerization catalyst
US4542251A (en) * 1984-02-27 1985-09-17 Chevron Research Company Oligomerization of liquid olefin over a nickel-containing silicaceous crystalline molecular sieve
US4547601A (en) * 1980-12-23 1985-10-15 Mobil Oil Corporation Conversion of Fischer-Tropsch oxygenates to middle distillate
US4834949A (en) * 1985-09-13 1989-05-30 Mobil Oil Corporation Multistage system for converting olefins to heavier hydrocarbons
US5260501A (en) * 1991-06-21 1993-11-09 Mobil Oil Corporation Catalytic oligomerization process using modified mesoporous crystalline material
EP0734766A1 (fr) * 1995-03-29 1996-10-02 Koa Oil Company, Limited Catalyseur pour l'oligomérisation d'oléfines, procédé pour le préparer et procédé d'oligomérisation d'oléfines en utilisant ledit catalyseur
GB2326885A (en) * 1997-07-04 1999-01-06 Inst Francais Du Petrole Process for olefin oligomerisation
WO2009079213A2 (fr) * 2007-12-03 2009-06-25 Gevo, Inc. Compositions renouvelables
EP2123736A1 (fr) * 2008-05-19 2009-11-25 C.E.-Technology Limited Procédé de fabrication de carburants diesel et carburants d'avion à partir d'alcools C1-C5

Family Cites Families (6)

* Cited by examiner, † Cited by third party
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US4134926A (en) 1977-04-18 1979-01-16 The Lummus Company Production of ethylene from ethanol
BR7705256A (pt) 1977-08-09 1979-04-03 Petroleo Brasileiro Sa Processo e preparacao de eteno
US4234752A (en) 1979-09-28 1980-11-18 Phillips Petroleum Company Dehydration of alcohols
BR8101487A (pt) 1981-03-13 1982-10-26 Petroleo Brasileiro Sa Processo de desidratacao de um alcool de baixo peso molecular
US4698452A (en) 1986-10-02 1987-10-06 Institut Nationale De La Recherche Scientifique Ethylene light olefins from ethanol
FR2905122B1 (fr) 2006-08-24 2009-07-24 Inst Francais Du Petrole Procede de production de propylene en presence d'un catalyseur macroporeux se presentant sous forme de billes spheriques

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3527839A (en) * 1969-01-13 1970-09-08 Shell Oil Co Ethylene oligomerization
US3992323A (en) * 1973-03-26 1976-11-16 Atlantic Richfield Company Olefin polymerization catalyst
US4547601A (en) * 1980-12-23 1985-10-15 Mobil Oil Corporation Conversion of Fischer-Tropsch oxygenates to middle distillate
US4542251A (en) * 1984-02-27 1985-09-17 Chevron Research Company Oligomerization of liquid olefin over a nickel-containing silicaceous crystalline molecular sieve
US4834949A (en) * 1985-09-13 1989-05-30 Mobil Oil Corporation Multistage system for converting olefins to heavier hydrocarbons
US5260501A (en) * 1991-06-21 1993-11-09 Mobil Oil Corporation Catalytic oligomerization process using modified mesoporous crystalline material
EP0734766A1 (fr) * 1995-03-29 1996-10-02 Koa Oil Company, Limited Catalyseur pour l'oligomérisation d'oléfines, procédé pour le préparer et procédé d'oligomérisation d'oléfines en utilisant ledit catalyseur
GB2326885A (en) * 1997-07-04 1999-01-06 Inst Francais Du Petrole Process for olefin oligomerisation
WO2009079213A2 (fr) * 2007-12-03 2009-06-25 Gevo, Inc. Compositions renouvelables
EP2123736A1 (fr) * 2008-05-19 2009-11-25 C.E.-Technology Limited Procédé de fabrication de carburants diesel et carburants d'avion à partir d'alcools C1-C5

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2018001920A1 (fr) * 2016-06-30 2018-01-04 IFP Energies Nouvelles Procede d'oligomerisation utilisant un catalyseur zeolithique et un catalyseur comprenant une silice alumine
FR3053355A1 (fr) * 2016-06-30 2018-01-05 IFP Energies Nouvelles Procede d'oligomerisation utilisant un catalyseur zeolithique et un catalyseur comprenant une silice alumine
FR3053265A1 (fr) * 2016-06-30 2018-01-05 IFP Energies Nouvelles Procede d'oligomerisation utilisant un catalyseur composite a base de silice-alumine et de zeolithe
CN109312240A (zh) * 2016-06-30 2019-02-05 Ifp 新能源公司 使用沸石催化剂和包含二氧化硅-氧化铝的催化剂的低聚方法
CN109312240B (zh) * 2016-06-30 2021-12-24 Ifp 新能源公司 使用沸石和包含二氧化硅-氧化铝的催化剂的低聚方法
FR3134110A1 (fr) 2022-04-05 2023-10-06 Axens Procédé amélioré de production de distillats moyens par oligomérisation d’une charge oléfinique
WO2023194337A1 (fr) 2022-04-05 2023-10-12 Axens Procédé amélioré de production de distillats moyens par oligomérisation d'une charge oléfinique

Also Published As

Publication number Publication date
WO2011138520A2 (fr) 2011-11-10
FR2959750B1 (fr) 2013-02-15
WO2011138520A3 (fr) 2012-10-26

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