FR2910288A1 - Cosmetic process useful for makeup to skin, lips, eyelashes, eyebrows or nails involves application to keratin materials, via at least one composition having silicon compounds; and catalyst - Google Patents

Abstract

Cosmetic process involves application to the keratin materials, via at least one composition of compounds X1 and Y1, at least one of which is silicone compound; and of catalyst, compounds X1 and Y1; at least one tacky oil whose tack index is >= 0.05 J/m2>. An independent claim is included for cosmetic kit comprises at least two compositions, compound X1, compound Y1, and optionally catalyst; the compounds X1 and Y1 and the compounds Xand Yreacting together via a hydrosilylation reaction or condensation reaction, at least one of first and second compositions containing tacky oil whose tack index is >= 0.05 J/m2>.

Description

The present invention relates to a kit comprising two compositions

  cosmetics separately packaged for use on keratin materials, each comprising a compound X or a compound Y, which are capable of reacting together at the time of deposition on the keratin materials; at least one of the compounds X and Y is silicone.  One of the two compositions additionally contains at least one sticky oil.  The invention also relates to a makeup process consisting of the application of compounds X and Y and the sticky oil.  The compositions may in particular be applied to the skin, the lips, the eyelashes, the eyebrows or the nails.  Each composition can be a free or compacted powder, a foundation, a blush, an anti-ring product, a blush, a lipstick, a lip balm, a lip gloss, a pencil. lips or eyes, a mascara, an eyeliner or a product of body make-up or skin coloring.  Makeup compositions, when applied to the skin, often have the disadvantage of transferring, that is to say, of being deposited at least in part, leaving traces, on certain supports with which they can be put in contact and in particular a glass, a cup, a cigarette, a garment or the skin.  It follows a poor persistence of the applied film, requiring regular renewal of the application of the foundation composition or lipstick.  We therefore seek make-up compositions for the lips and the so-called non-transfer skin which have the advantage of forming a deposit which does not deposit, at least in part, on the supports with which they are put in contact (glass, clothing , cigarette, tissues).  We also seek a composition whose deposit on keratin materials is as adherent as possible, to increase its resistance to friction.  The aim of the present invention is to provide a novel way of formulating make-up compositions, making it possible to obtain a film deposited on keratin materials, having good non-transfer properties, and good friction-holding properties, which result in by a better adhesion of said film to keratin materials.  The inventors have discovered that it is possible to obtain such properties using a system comprising silicone compounds which polymerize in situ and sticky oils.  This is why, according to a first aspect, the subject of the present invention is a kit comprising two cosmetic compositions packaged separately and intended to be applied to keratin materials: at least one first composition comprising a compound X; at least one second composition comprising a compound Y; At least one of the compounds X and Y being a silicone compound, said compounds X and Y being capable of reacting together by a hydrosilylation, condensation or crosslinking reaction in the presence of a peroxide, when they are contacted with each other - at least one of the first and second composition containing at least one oil whose adhesive is greater than or equal to 0.05 J / m2.  The compounds X and Y may react together on the keratin materials or on a support so as to form, on the keratin materials, in the presence of the sticky oil, an adherent and non-transfer film.  Before being applied to keratin materials, compounds X and Y may be present in the same composition or in two different compositions called first and second compositions.  According to an embodiment, the subject of the present invention is a cosmetic kit comprising at least two compositions packaged separately, the kit comprising at least one silicone compound X, at least one silicone compound Y, and optionally at least one catalyst with the proviso that compounds X and Y - and the catalyst when present - are not simultaneously in one of said compositions, - said compounds X and Y being capable of reacting together by a hydrosilylation reaction when they are brought into contact with each other, at least one of the first and second compositions containing at least one oil whose adhesive is greater than or equal to 0.05 J / m 2.  Preferably, the first composition comprising the compound X and the second composition comprising the compound Y are packaged in separate packages.  Each composition may be packaged separately in the same packaging article, for example in a bi-compartmentalized pen, the base composition being delivered by one end of the pen and the composition of the top being delivered by the other end of the pen, each end being closed particularly tightly by a cap.  Each composition may also be packaged in a compartment within the same packaging article, the mixture of the two compositions being effected at the end or ends of the packaging article during the delivery of each composition.  Alternatively, each of the first and second compositions may be packaged in a different packaging article.  The invention also relates to the use of a kit as described above, to obtain a film deposited on keratin materials, having non-transfer properties while having improved friction resistance properties.  Of course, each composition comprises a cosmetically acceptable medium, ie a non-toxic medium that can be applied to keratin materials of human beings and of pleasant appearance, odor and feel.  According to an advantageous embodiment, the compounds X and Y are mixed extemporaneously and then the mixture is applied to the keratin materials.  The subject of the invention is also a cosmetic process comprising the application on said keratin materials, via at least one composition, of compounds X and Y at least one of which is silicone, the compounds X and Y being suitable, when they are brought into contact with each other, to react together by hydrosilylation, condensation, or crosslinking in the presence of a peroxide, and of at least one oil whose adhesive is greater than or equal to 0.05 J / m2.  Alternatively, compound X and compound Y are applied via at least two separate compositions, each comprising one of the compounds.  This is why the present invention relates to a cosmetic process for coating keratin materials, the process comprising the application to said keratinous materials:  at least one layer of a first composition comprising a compound X; b.  at least one layer of a second composition comprising a compound Y; At least one of the compounds X and Y being a silicone compound, said compounds X and Y being capable of reacting together by a hydrosilylation, condensation or crosslinking reaction in the presence of a peroxide, when they are set in contact with each other.  According to this method, it is possible to apply at least one layer of the first composition comprising the compound X to the keratin materials and then to deposit on the layer or layers of said first composition at least one layer of the second composition comprising the compound Y .  According to a variant, the process consists in applying to the keratin materials at least one layer of the second composition comprising the compound Y, and then depositing on the layer or layers of said second composition at least one layer of the first composition comprising the compound X.  Alternatively, several layers of each of the first and second compositions may alternatively be applied to the keratin materials.  In another aspect, the compounds X and Y as well as the sticky oil may be present in the same composition, which then comprises at least one compound X and at least one compound Y, at least one of the compounds X and Y being a silicone compound, said compounds X and Y being capable of reacting together by a hydrosilylation reaction, condensation or crosslinking in the presence of a peroxide, and - at least one sticky oil.  In this embodiment, at least one of the compounds X and Y may be present in an encapsulated form.  According to one variant, the two compounds X and Y are both present in separate encapsulated forms.  More particularly, the compounds X and / or Y may be present in the form of microcapsules and in particular nanocapsules of the heart / shell type, the core of lipophilic nature containing the compound X or the compound Y.  The adhesive oil is preferably an oil whose adhesive is greater than or equal to 0.05 J / m 2.  For example, the sticky oil has a tack greater than or equal to 0.10, or greater than or equal to 0.11, or greater than or equal to 0.12, or greater than or equal to 0.13, or even greater than or equal to 0.13. equal to 0.15, or greater than or equal to 0.16, or greater than or equal to 0.17, more preferably greater than or equal to 0.18 J / m2.  The measurement of the oil tack can be done with a texturometer, similar to that used to measure the adhesion index of the deposit, such as a Rheo TAXT2i texturometer.  0.5 ml of the oil whose sticky size is to be measured is deposited in a 10 ml beaker.  The texturometer is surmounted by a clamp clamping a tip AU4G cylindrical (3 15 mm in diameter) covered at its end with a Bioskin film of the same diameter.  A new tip is used for each measurement.  Once cleaned, it can be reused after 24 hours of drying.  With the aid of the texturometer, a compression measurement with time keeping is carried out, setting the following parameters: controlled pre-speed: 1 mm / s - speed: 0.1 mm / s - force: 0.283 N ( a pressure of 0.01 MPa) constant for a time of 10 s - post-speed (speed of removal of the tip): 10 mm / s.  The beaker is placed under conditions thermostated at 25 ° C for the measurement.  The oil tack is chosen as the separation work measured during the discharge phase (tensile phase).  More precisely, it corresponds to the area under the curve of the pressure measured as a function of the displacement during this discharge phase.  The tacky oil may be selected from polybutylenes such as INDOPOL H-100, INDOPOL H-300, INDOPOL H-1500 marketed or manufactured by AMOCO.  The tacky oil may comprise from 1 to 99%, preferably from 10 to 80%, by weight of the total weight of the composition containing it.  The tacky oil may represent for example from 5 to 70% and more preferably from 10 to 30% of the total weight of the first and / or second composition, for example from 5 to 15% by weight of the weight of the composition that contains.  The tacky oil is present in an amount such that the ratio of sticky oil / compound X and / or the ratio of sticky oil / compound Y is preferably between 1/20 and 1/1, preferably between 1/10 and 1 / 4.  Silicone oil The composition may contain in addition to the sticky oil, a silicone oil, which is preferably non-volatile.  By "non-volatile oil" is meant an oil remaining on the keratin materials at ambient temperature and atmospheric pressure for at least several hours and in particular having a vapor pressure of less than 10 -3 mmHg (0.13 Pa).  By silicone oil is meant an oil comprising at least one silicon atom.  The non-volatile silicone oils may be: non-volatile polydimethylsiloxanes (PDMS), polydimethylsiloxanes comprising alkyl or alkoxy groups, during and / or at the end of the silicone chain, groups each having from 3 to 40 carbon atoms, phenyl silicones such as phenyl trimethicones, phenyl dimethicones, phenyl trimethylsiloxy diphenylsiloxanes, diphenyl dimethicones, diphenyl methyldiphenyl trisiloxanes, 2-phenylethyl trimethylsiloxysilicates, trimethylpentaphenyltrisiloxane; Polyalkylmethylsiloxanes, optionally fluorinated, such as polymethyltrifluoropropyl dimethylsiloxanes; polyalkylmethylsiloxanes substituted with functional groups such as hydroxyl, thiol and / or amine groups; polysiloxanes modified with fatty acids, fatty alcohols or polyoxyalkylenes, and mixtures thereof.  The nonvolatile silicone oil may have a viscosity in the range of 10 to 10,000 cSt at 25 C and more preferably 10 to 5,000 cSt.  The non-volatile silicone oil may be selected from non-volatile polydimethylsiloxanes (PDMS); polydimethylsiloxanes comprising alkyl, alkoxy or phenyl groups, during or at the end of the silicone chain, groups having from 2 to 24 carbon atoms; phenyl silicones such as phenyl trimethicones, phenyl dimethicones, phenyl trimethylsiloxy diphenylsiloxanes, diphenyl dimethicones, diphenyl methyldiphenyl trisiloxanes; polysiloxanes modified with fatty acids (especially C8-C20), fatty alcohols (especially C8-C20) or polyoxyalkylenes (especially polyoxyethylene and / or polyoxypropylene); amino silicones; silicones containing a hydroxyl group; fluorinated silicones comprising a fluorinated group during or at the end of the silicone chain having from 1 to 12 carbon atoms, all or part of the hydrogen of which is substituted by fluorine atoms; and their mixtures.  The non-volatile phenyl silicone oil may be chosen from the phenyl silicones of formula (VI) below: ## STR1 ## in which - R 1 to R 10, independently of one another, are hydrocarbon radicals, saturated or unsaturated, linear, cyclic or branched, C 1 -C 30, - m, n, p and q are, independently of each other, integers between 0 and 900, provided that the sum 'm + n + q' is different from 0.  Preferably, the sum 'm + n + q' is between 1 and 100.  Preferably, the sum 'm + n + p + q' is between 1 and 900, more preferably between 1 and 800.  Preferably, q is equal to O.  Preferably, the non-volatile phenyl silicone oil is chosen from phenyl silicones of formula (VII) below: R6, independently of one another, are cyclic or branched, linear or branched C 1 -C 30 hydrocarbon radicals, 5 - m, n and p are, independently of one another, integers between 0 and 100; , provided that the sum 'n + m' is between 1 and 100.  Preferably, R1 to R6, independently of each other, represent a saturated hydrocarbon radical, linear or branched, C1-C30, especially C1-C12, and in particular a methyl, ethyl, propyl or butyl radical.  In particular, R1 to R6 may be identical, and may furthermore be a methyl radical.  Preferably, one can have m = 1 or 2 or 3, and / or n = 0 and / or p = 0 or 1.  The phenyl silicone oils may be chosen from phenyl trimethicones, phenyl dimethicones, phenyl trimethylsiloxy diphenylsiloxanes, diphenyl dimethicones, diphenyl methyldiphenyl trisiloxanes, and mixtures thereof.  Preferably, the weight-average molecular weight of the phenyl silicone oil is between 500 and 10,000 g / mol.  It is possible to use a phenyl silicone oil of formula (VI) having a viscosity at 25 ° C. of between 5 and 1500 mm 2 / s (ie 5 to 1500 cSt), preferably having a viscosity of between 5 and 1000 mm 2 / s (ie at 1000 cSt).  Non-volatile phenyltrimethicones such as Dow Corning DC556 (22.5 cSt), Rhône Poulenc Silbione 70663V30 oil (28 cSt), or diphenyldimethicones such as Belsil oils can be used as the non-volatile phenylated silicone oil. including Belsil PDM1000 (1000cSt), Belsil PDM 200 (200 cSt) and Belsil PDM 20 (20cSt) from Wacker.  Values in parentheses represent viscosities at 25 C.  The non-volatile silicone oil may be present in each of the compositions of the kit according to the invention in a content ranging from 10% to 60% by weight, relative to the total weight of the non-volatile liquid fatty phase, preferably ranging from 15% to 55% by weight, and preferably ranging from 20% to 40% by weight.  ESTER OIL In addition to the sticky oil, the composition may contain a preferably non-volatile ester oil.  This ester oil may be chosen from esters of monocarboxylic acids with monoalcohols and polyalcohols.  Advantageously, said ester corresponds to the following formula (I): R, -CO-O-R2 (I) in which R represents a linear or branched alkyl radical of 1 to 40 carbon atoms, preferably 7 to 19 carbon atoms. carbon, optionally comprising one or more ethylenic double bonds, and optionally substituted.  R2 represents a linear or branched alkyl radical of 1 to 40 carbon atoms, preferably of 3 to 30 carbon atoms and better still of 3 to 20 carbon atoms, optionally comprising one or more ethylenic double bonds, and optionally substituted.  Examples of the R groups are those derived from fatty acids selected from the group consisting of acetic, propionic, butyric, caproic, caprylic, pelargonic, capric, undecanoic, lauric, myristic, palmitic, stearic, isostearic, arachidic, behenic, oleic, linolenic, linoleic, eleostearic, arachidonic, erucic, and mixtures thereof.  Examples of esters are, for example, purcellin oil (cetostearyl octanoate), isononyl isononanoate, isopropyl myristate, 2-ethylhexyl palmitate, octyl stearate. 2-dodecyl, octyl 2-dodecyl erucate, isostearyl isostearate, and heptanoates, octanoates, decanoates or ricinoleates of alcohols or polyalcohols, for example fatty alcohols.  Advantageously, the esters are chosen from the compounds of formula (I) above, in which R represents an unsubstituted linear or branched alkyl group, optionally comprising one or more ethylenic double bonds, of 1 to 40 carbon atoms. preferably, from 7 to 19 carbon atoms, and R2 represents an unsubstituted linear or branched alkyl group, optionally comprising one or more ethylenic double bonds, of 1 to 40 carbon atoms, preferably of 3 to 30 carbon atoms. and better still from 3 to 20 carbon atoms.  Preferably, R 1 is an unsubstituted branched alkyl group of 4 to 14 carbon atoms, preferably 8 to 10 carbon atoms, and R 2 is an unsubstituted branched alkyl group of 5 to 15 carbon atoms, preferably from 9 to 11 carbon atoms.  Preferably in the formula (I), R, -CO- and R 2 have the same number of carbon atoms and are derived from the same radical, preferably unsubstituted branched alkyl, for example isononyl, i.e. that the ester oil molecule is advantageously symmetrical.  The ester oil will preferably be chosen from the following compounds: isononyl isononanoate, cetostearyl octanoate, isopropyl myristate, 2-ethylhexyl palmitate, octyl 2-dodecyl stearate, - octyl 2-dodecyl erucate, - isostearyl isostearate.  The proportion of the non-volatile ester oil in the composition is preferably between X and X by weight.  Other oils of the composition In addition to the oils described above, the liquid fatty phase may contain an oil chosen from volatile oils.  For the purposes of the invention, the term "volatile oil" means an oil capable of evaporating in contact with keratin materials in less than one hour at ambient temperature and atmospheric pressure.  The volatile organic solvent (s) and the volatile oils of the invention are organic solvents and volatile cosmetic oils which are liquid at ambient temperature and have a non-zero vapor pressure at ambient temperature and atmospheric pressure, in particular ranging from 0 to 13 Pa at 30 40 000 Pa (10-3 to 300 mm Hg), in particular ranging from 1.3 Pa to 13 000 Pa (0.01 to 100 mm Hg), and more particularly ranging from 1 to 3 Pa at 1300 Pa (0.01 to 10 mmHg).  These oils may be hydrocarbon oils, silicone oils, fluorinated oils, or mixtures thereof.  The term "hydrocarbon-based oil" means an oil containing mainly hydrogen and carbon atoms and optionally oxygen, nitrogen, sulfur and phosphorus atoms.  The volatile hydrocarbon oils may be chosen from hydrocarbon-based oils having from 8 to 16 carbon atoms, and especially C8-C16 branched alkanes such as C8-C16 isoalkanes of petroleum origin (also known as isoparaffins), such as isododecane (also called 2,2,4,4,6-pentamethylheptane), isodecane, isohexadecane, and for example the oils sold under the trade names Isopars' or permetyls, branched C8-C16 esters isohexyl neopentanoate, and mixtures thereof.  Other volatile hydrocarbon oils such as petroleum distillates, in particular those sold under the name ShelI or by Shell, may also be used.  Preferably, the volatile solvent is chosen from volatile hydrocarbon oils having from 8 to 16 carbon atoms and mixtures thereof.  Volatile silicones, such as, for example, volatile linear or cyclic silicone oils, especially those having a viscosity of 8 centistokes (8 10-6 m 2 / s) and in particular having from 2 to 7 atoms, can also be used as volatile oils. silicon, these silicones optionally having alkyl or alkoxy groups having from 1 to 10 carbon atoms.  As volatile silicone oil that can be used in the invention, there may be mentioned in particular octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, heptamethylhexyltrisiloxane, heptamethyloctyltrisiloxane, hexamethyl disiloxane, octamethyltrisiloxane, decamethyl tetrasiloxane, dodecamethyl pentasiloxane and mixtures thereof.  It is also possible to mention volatile alkyltrisiloxane linear oils of general formula (I): ## STR2 ## in which R represents an alkyl group comprising from 2 to 4 carbon atoms and one or more atoms of which hydrogen can be substituted with a fluorine or chlorine atom.  Among the oils of general formula (I), mention may be made of: 3-butyl-1,1,1,3,5,5,5-heptamethyltrisiloxane, 3-propyl-1,1,1,3,5, 5,5-heptamethyltrisiloxane, and 3-ethyl-1,1,1,3,5,5,5-heptamethyltrisiloxane, corresponding to the oils of formula (I) for which R is respectively a butyl group, a propyl group or an ethyl group.  Fluorinated volatile solvents such as nonafluoromethoxybutane or perfluoromethylcyclopentane can also be used.  The oil of formula (I) for which R is an ethyl group is sold especially under the name BAYSILONE TP 3886 and the oil for which R is a butyl group is sold, for example, under the name BAYSILONE TP 3887 by the company BAYER. SILICONES.  Preferably, the compositions used in the kit according to the invention each have a volatile oil content of less than or equal to 50% by weight, preferably less than or equal to 30% and better still less than or equal to 10% by weight relative to total weight of each first and second composition.  More preferably, the first and second composition (s) are free of volatile oil.  NON-TRANSFER OF DEPOSITION The film transfer index - obtained by depositing a composition containing compounds X and Y and the sticky oil, or obtained by successive deposition of a composition containing compound X and a composition containing compound Y - is preferably less than or equal to 40 out of 100.  More preferably, the transfer number is less than or equal to 30, preferably less than or equal to 20, more preferably less than or equal to 15, preferably less than or equal to 10, preferably less than or equal to 5, 100, preferably less than or equal to 2 in 100.  The transfer index can be measured according to the method below.  A support (rectangle of 40 mm × 70 mm and thickness 3 mm) of adhesive polyethylene foam is preheated on one of the faces having a density of 33 kg / m 3 (sold under the name RE40X70EP3 from the company JOINT TECHNIQUE LYONNAIS IND. ) on a heating plate maintained at a temperature of 40 C so that the surface of the support is maintained at a temperature of 33 C 1 C.  While leaving the support on the hot plate, the mixture of the compositions is applied to the entire non-adhesive surface of the support by spreading it with a brush to obtain a deposit of the composition of about 15 μm. then allowed to dry for 30 minutes.  After drying, the support is adhered by its adhesive side to an anvil with a diameter of 20 mm and provided with a thread.  The support / deposit assembly is then cut using a punch with a diameter of 18 mm.  The anvil is then screwed onto a press (MANAL STATIF IMADA SV-2 from SOMECO) equipped with a dynamometer (IMADA DPS-20 from SOMECO).  A white photocopy paper of 80 g / m 2 is placed on the base of the press and the support / deposit assembly is pressed on the paper at a pressure of 2.5 kg for 30 seconds.  After removal of the carrier / deposit assembly, a portion of the deposit was transferred to the paper.  The color of the deposit transferred onto the paper is then measured using a MINOLTA CR300 colorimeter, the color being characterized by the colorimetric parameters L *, a *, b *.  The colorimetric parameters L * 0, a * 0, b * 0 of the color of the bare paper used are determined.  The color difference AE1 is then determined between the color of the transferred deposit with respect to the color of the bare paper by the following relation.  AE1 = (L * _Lo *) 2 + (a * - ao *) 2 + (b * - bo *) 2 Furthermore, a total transfer reference is prepared by applying the mixture directly to a paper identical to that used. previously, at room temperature (25 ° C), spreading the composition with a brush and depositing the composition about 15 μm and then allowed to dry for 30 minutes at room temperature (25 ° C). VS).  After drying, the colorimetric parameters L * ', a *', b * 'of the color of the deposit placed on the paper, corresponding to the total transfer reference color, are measured directly.  The colorimetric parameters L * '0, a *' 0, b * '0 of the color of the bare paper used are determined.  The color difference ΔE 2 between the total transfer reference color with respect to the color of the naked paper is then determined by the following relationship.  AE2 = (L *, _ Lo *,) 2 + (a *, - ao *,) 2 + (b *, - bo *,) 2 The transfer of the composition, expressed as a percentage, is equal to the ratio: 100 X AE1 / AE2 2910288 14 The measurement is carried out on 4 supports in succession and the transfer value corresponds to the average of the 4 measurements obtained with the 4 supports.  Compounds X and Y Compounds X and Y may react together at a temperature ranging from room temperature to 180 ° C.  Advantageously, the compounds X and Y are capable of reacting together at room temperature (20 ° C.) and atmospheric pressure, advantageously in the presence of a catalyst, by a hydrosilylation reaction or a condensation reaction or a crosslinking reaction in the presence of a peroxide.  Preferably, these compounds X and Y are polymers.  By polymer is meant compounds having at least two repeating units, preferably at least three.  According to one embodiment, at least one of the compounds X and Y is a polymer whose main chain is formed mainly of organosiloxane units.  According to one particular embodiment, the compounds X and the compounds Y are silicone.  By silicone compound is meant a compound comprising at least two organosiloxane units.  The compound (s) X or the compound (s) Y may be applied to the keratin materials via different compositions containing the compound (s) X, the compound (s) Y, alone or as a mixture, or from a single composition containing the compound (s) X, the compound (s) Y.  According to a particular embodiment of the invention, a composition (A) comprising the compound (s) X, the compound (s) Y, and the sticky oil is applied to the keratin materials.  According to another particular embodiment of the invention, a composition (B) and a composition (C) comprising the compound (s) X and the compound (s) Y are applied to the keratin materials, the sticky oil being present in the composition (B) and / or the composition (C), the order of application of the compositions (B) and (C) being indifferent.  According to another particular embodiment of the invention, a composition (B), a composition (D) comprising the compound (s) X and a composition (E) comprising the compound (s) Y, are applied to the keratin materials. the sticky oil being present in the composition (B) and / or the composition (D) and / or the composition (E), the order of application of the compositions (B), (D) and (E) being indifferent.  According to another particular embodiment of the invention, a composition (F) comprising the compound (s) X and a composition (E) comprising the compound (s) Y, the sticky oil being present in the composition, is applied to the keratin materials. composition 10 (F) and / or composition (E), the order of application of compositions (F) and (E) being indifferent.  According to another particular embodiment of the invention, at least one catalyst as defined above is applied to the keratin materials to activate the reaction between the compound (s) X and the compound (s) Y.  For example, the catalyst or catalysts may be present in one or the other or in several of the compositions applied to the keratin materials or in an additional composition, in which case the order of application of the different compositions to the keratin materials is indifferent.  The silicone compounds X and Y mentioned hereinafter can exhibit both film-forming and adhesive properties, for example according to their proportion of silicone or according to whether they are used in admixture with a particular additive.  It is therefore possible to modulate the film-forming properties or the adhesive properties of such compounds according to the use envisaged, this is particularly the case for the so-called "room temperature vulcanization" reactive elastomeric silicones.  Polar groups According to a particular embodiment, at least one of the compounds X and Y carries at least one polar group capable of forming at least one hydrogen bond with the keratin materials.  According to one embodiment, the compounds X and Y may be amine or non-amino.  By polar group is meant a group comprising carbon and hydrogen atoms in its chemical structure and at least one heteroatom (such as O, N, S and P), such that said group is capable of establishing at least one hydrogen bond with keratin materials.  Compounds bearing at least one group capable of establishing a hydrogen bond are particularly advantageous since they provide the compositions containing them with better adhesion to keratin materials, thanks to the ability of these groups to establish a hydrogen bond with keratin materials.  The polar group (s) carried by at least one of the compounds X and Y is / are capable of establishing a hydrogen bond, and comprises (s) either a hydrogen atom bonded to an electronegative atom .  When the group comprises a hydrogen atom bonded to an electronegative atom, the hydrogen atom may interact with another electronegative atom carried, for example by another molecule, such as keratin, to form a hydrogen bond.  When the group comprises an electronegative atom, the electronegative atom may interact with a hydrogen atom bonded to an electronegative atom carried, for example by another molecule, such as keratin, to form a hydrogen bond.  Advantageously, these polar groups may be chosen from the following groups: carboxylic acid -COOH, alcohols, such as: -CH 2 OH or -CH (R) OH, R being an alkyl radical comprising from 1 to 6 carbon atoms - amino of formula -NR, R2, in which the R 1 and R 2, which are identical or different, represent an alkyl radical comprising from 1 to 6 carbon atoms, or one of R 1 or R 2 denotes a hydrogen atom, - pyridino, An amido of formula -NH-COR 'or -CO-NH-R' in which R 'represents a hydrogen atom or an alkyl radical comprising from 1 to 6 carbon atoms - pyrrolidino preferably chosen from groups of formula NNIIR, R, R being an alkyl radical having 1 to 6 carbon atoms, 30-carbamoyl of the formula -O-CO-NH-R 'or -NH-CO-OR', R 'being such that defined above, -thiocarbamoyl, such as -O-CS-NH-R 'or -NH-CS-O R', R 'being as defined above, 2910288 17 - ureyl such that -NR' -CO -N (R ') 2, the identical R' o u different as defined above, - sulfonamido such that -N R'-S (= O) 2- R ', R' as defined above.  Preferably, these polar groups are present at a content of less than or equal to 10% by weight relative to the weight of each compound X or Y, preferably less than or equal to 5% by weight, for example in a content ranging from 1 at 3% by weight The polar group (s) may be located in the main chain of the compound X 10 and / or Y or may be pendant to the main chain or located at the ends of the main chain of the compound X and / or Y.  1- X and Y compounds capable of reacting by hydrosilvlation According to this embodiment, compounds X and Y are capable of reacting by hydrosilylation, this reaction can be schematically simplified as follows: -Si-H + CH 2 -CH- W-Si-CH 2 CH 2 -W 1 with W representing a carbon and / or silicone chain containing one or more unsaturated aliphatic groups.  In this case, the compound X may be chosen from silicone compounds comprising at least two unsaturated aliphatic groups.  By way of example, the compound X may comprise a silicone main chain whose unsaturated aliphatic groups are pendant to the main chain (side group) or located at the ends of the main chain of the compound (terminal group).  In the remainder of the description, these particular compounds will be called polyorganosiloxanes with unsaturated aliphatic groups.  According to one embodiment, the compound X and / or the compound Y carries at least one polar group, as described above, capable of forming at least one hydrogen bond with the keratin materials.  This polar group is advantageously carried by the compound X which comprises at least two unsaturated aliphatic groups.  According to one embodiment, the compound X is chosen from polyorganosiloxanes comprising at least two unsaturated aliphatic groups, for example two or three vinyl or allylic groups, each bonded to a silicon atom.  According to an advantageous embodiment, the compound X is chosen from polyorganosiloxanes comprising siloxane units of formula: in which: R represents a monovalent hydrocarbon group, linear or cyclic, comprising from 1 to 30 carbon atoms, preferably from 1 to at 20, and more preferably 1 to 10 carbon atoms, such as, for example, a short-chain alkyl radical, for example comprising 1 to 10 carbon atoms, in particular a methyl radical or a phenyl group, preferably a radical. methyl, m is equal to 1 or 2 and R 'represents: an unsaturated aliphatic hydrocarbon group comprising from 2 to 10, preferably from 2 to 5 carbon atoms, for example a vinyl group or a group -R " -CH = CHR "'in which R" is a divalent aliphatic hydrocarbon chain, comprising from 1 to 8 carbon atoms, bonded to the silicon atom and R "' is a hydrogen atom or an alkyl radical comprising from 1 at 4 carbon atoms, preferably a hydrogen atom; mention may be made, as R 'group, of vinyl and allyl groups and mixtures thereof or of unsaturated cyclic hydrocarbon group comprising from 5 to 8 carbon atoms, for example a cyclohexenyl group. Preferably, R' is an unsaturated aliphatic hydrocarbon group, preferably a vinyl group.  According to a particular embodiment, the polyorganosiloxane also comprises units of formula (II) in which R is a group as defined above, and n is equal to 1, 2 or 3.  According to one variant, the compound X comprises a silicone resin comprising at least two ethylenic unsaturations, said resin being capable of reacting with the compound 5 (I) by means of hydrosilylation.  Mention may be made, for example, of resins of MQ or MT type bearing itself unsaturated reactive ends -CH = CH2.  These resins are crosslinked organosiloxane polymers.  The nomenclature of silicone resins is known as "MDTQ", the resin being described in terms of the different monomeric siloxane units it comprises, each of the letters "MDTQ" characterizing a type of unit.  The letter M represents the monofunctional unit of formula (CH 3) 3 SiO 2, the silicon atom being connected to a single oxygen atom in the polymer comprising this unit.  The letter D signifies a difunctional unit (CH 3) 2 SiO 2 12 in which the silicon atom is connected to two oxygen atoms. The letter T represents a trifunctional unit of formula (CH 3) SiO 3 12.  In the units M, D and T defined above, at least one of the methyl groups may be substituted by a group R other than the methyl group such as a hydrocarbon radical (in particular alkyl) having 2 to 10 carbon atoms or a group 15 phenyl or else a hydroxyl group.  Finally, the letter Q means a tetrafunctional unit SiO4 / 2 in which the silicon atom is bonded to four hydrogen atoms themselves linked to the rest of the polymer.  Examples of such resins that may be mentioned are MT silicone resins such as poly (phenyl-vinylsilsesquioxane), such as those sold under the reference SST-3PV1 by Gelest.  Advantageously, the compound X is chosen from polyorganopolysiloxanes, in particular those comprising the siloxane units (I) and optionally (II) units previously described.  The compound Y preferably comprises at least two free Si-H groups (hydrogenosilane groups).  The compound Y may advantageously be chosen from organosiloxanes comprising at least one alkylhydrogenosiloxane unit of the following formula:  in which: R represents a linear or cyclic monovalent hydrocarbon group comprising from 1 to 30 carbon atoms, for example an alkyl radical having from 1 to 30 carbon atoms, preferably from 1 to 20 and better still from 1 to 30 carbon atoms; 10 carbon atoms, in particular a methyl radical, or a phenyl group and p is 1 or 2.  Preferably R is a hydrocarbon group, preferably methyl.  These organosiloxane compounds Y with alkylhydrogenosiloxane units may further comprise units of formula: as defined above.  The compound Y may be a silicone resin comprising at least

  comprising at least one unit selected from the units M, D, T, Q as defined above and comprising at least one Si-H group such as the poly (methyl-hydridosilsesquioxane) sold under the reference SST-3MH1. These organosiloxane compounds Y preferably comprise from 0.5 to 2.5% by weight of Si-H groups.  Advantageously, the radicals R represent a methyl group in the above formulas. Preferably, these organosiloxanes Y comprise terminal groups of formula CH 3 SiO 2.  Advantageously, the organosiloxanes Y comprise at least two alkylhydrogenosiloxane units of formula H3CHSiO and optionally comprise (H3C) 2SiO units.  Such organosiloxane compounds Y having hydrogenosilane groups are described, for example, in document EP 0465744.  According to one variant, the compound X is chosen from oligomers or organic polymers (by organic means compounds whose main chain is non-silicone, preferably compounds containing no silicon atoms) or from polymers or organic / silicone hybrid oligomers, said oligomers or polymers bearing at least 2 reactive unsaturated aliphatic groups, the compound Y being selected from the hydrogenosiloxanes mentioned above.  According to one embodiment, the organic compounds X or hybrid organic / silicone bearing at least 2 reactive unsaturated aliphatic groups, carry at least one polar group as described above.  Compound X, of organic nature, may then be chosen from vinyl, (meth) acrylic polymers or oligomers, polyesters, polyurethanes and / or polyureas, polyethers, perfluoropolyethers, polyolefins such as polybutene. , polyisobutylene, dendrimers or organic hyperbranched polymers, or mixtures thereof.  In particular, the organic polymer or the organic part of the hybrid polymer may be chosen from the following polymers: a) polyesters with ethylenic unsaturation (s): This is a group of polyester-type polymers having at least 2 ethylenic double bonds, randomly distributed in the main chain of the polymer.  These unsaturated polyesters are obtained by polycondensation of a mixture of linear or branched or cycloaliphatic aliphatic dicarboxylic acids containing especially from 3 to 50 carbon atoms, preferably from 3 to 20 and better still from 3 to 10 carbon atoms, such as adipic acid or sebacic acid, of aromatic dicarboxylic acids having in particular from 8 to 50 carbon atoms, preferably from 8 to 20 and better still from 8 to 14 carbon atoms, such as phthalic acids, especially terephthalic acid, and / or dicarboxylic acids derived from dimers of ethylenically unsaturated fatty acids, such as the oleic or linoleic acid dimers described in application EP-A-959 066 (paragraph [0021)) sold under the names Pripol by Henkel, the company Unichema or Empol, all these diacids to be free of polymerizable ethylenic double bonds, - linear aliphatic diols or branched or cycloaliphatic having in particular from 2 to 50 carbon atoms, preferably from 2 to 20 and preferably from 2 to 10 carbon atoms, such as ethylene glycol, diethylene glycol, propylene glycol, 1,4-butanediol or cyclohexanedimethanol, aromatic diols having 6 to 50 carbon atoms, preferably 6 to 20 and more preferably 6 to 15 carbon atoms such as bisphenol A and bisphenol B, and / or diol dimers from the reduction fatty acid dimers as defined above, and one or more dicarboxylic acids or their anhydrides containing at least one polymerizable ethylenic double bond and having from 3 to 50 carbon atoms, preferably from 3 to 20, and preferably from 3 to 10 carbon atoms, such as maleic acid, fumaric acid or itaconic acid.  b) polyesters with (meth) acrylate groups and / or terminal: This is a group of polyester-type polymers obtained by polycondensation of a mixture of linear or branched aliphatic carboxylic or cycloaliphatic dicarboxylic acids including From 3 to 50 carbon atoms, preferably from 3 to 20 and more preferably from 3 to 10 carbon atoms, such as adipic acid or sebacic acid, of aromatic dicarboxylic acids having in particular from 8 to 50 carbon atoms, preferably from 8 to 20 and better still from 8 to 14 carbon atoms, such as phthalic acids, especially terephthalic acid, and / or dicarboxylic acids derived from ethylenically unsaturated fatty acid dimers such as the dimers of the acids Oleic or linoleic compounds described in application EP-A-959 066 (paragraph [0021]) marketed under the names Pripol by the company Unichema or Empol by the company Henkel, all these diacids to be ex- c) polymerizable ethylenic double bonds; - linear or branched or cycloaliphatic aliphatic diols having in particular from 2 to 50 carbon atoms, preferably from 2 to 20 and more preferably from 2 to 10 carbon atoms, such as ethylene glycol, diethylene glycol, propylene glycol, 1,4-butanediol or cyclohexanedimethanol, aromatic diols having from 6 to 50 carbon atoms, preferably from 6 to 20 and more preferably from 6 to 15 carbon atoms such as bisphenol A and bisphenol B, 25 and - at least one (meth) acrylic acid ester and a diol or polyol having 2 to 20 carbon atoms, preferably 2 to 6 carbon atoms, such as (meth) 2-hydroxyethyl acrylate, 2-hydroxypropyl (meth) acrylate and glycerol methacrylate.  These polyesters differ from those described above under a) in that the ethylenic double bonds are not located in the main chain but on side groups or at the end of the chains.  These ethylenic double bonds are those of (meth) acrylate groups present in the polymer.  Such polyesters are sold, for example, by the company UCB under the names EBECRYL (EBECRYL 450: molar mass 1600, on average 6 acrylate functions per molecule, EBECRYL 652: molar mass 1500, in average 2910 acrylate functions per molecule, EBECRYL 800: molar mass 780, on average 4 acrylate functions per molecule, EBECRYL 810: molar mass 1000, on average 4 acrylate functions per molecule, EBECRYL 50,000: molar mass 1500, on average 6 acrylate functions per molecule) c) polyurethanes and and / or polyureas with (meth) acrylate groups, obtained by polycondensation - aliphatic cycloaliphatic and / or aromatic diisocyanates, triisocyanates and / or polyisocyanates having in particular from 4 to 50, preferably from 4 to 30 carbon atoms, such as hexamethylene diisocyanate , isophorone diisocyanate, toluene diisocyanate, diphenylmethane diisocyanate or isocyanurates of the formula OIIC OCNiRuN ~ NURuNCO -CC Where R is a linear, branched or cyclic hydrocarbon radical having 2 to 30 carbon atoms; polyols, especially diols, free of polymerizable ethylenic unsaturations, such as 1,4-butanediol, ethylene glycol or trimethylolpropane, and / or polyamines, in particular diamines, aliphatic, cycloaliphatic and / or aromatic having in particular from 3 to 50 carbon atoms, such as ethylenediamine or hexamethylenediamine, and from at least one (meth) acrylic acid ester and a diol or polyol having from 2 to 20 carbon atoms preferably 2 to 6 carbon atoms, such as 2-hydroxyethyl (meth) acrylate, 2-hydroxypropyl (meth) acrylate and glycerol methacrylate.  Such acrylate-containing polyurethanes / polyureas are commercially available for example under the name SR 368 (tris (2-hydroxyethyl) isocyanuratetriacrylate) or CRAYNOR 435 by the company CRAY VALLEY, or under the name EBECRYL by the company UCB (EBECRYL 210: mass molar 5 10 2910288 24 1500, 2 acrylate functions per molecule, EBECRYL 230: 5000 molar mass, 2 acrylate functions per molecule, EBECRYL 270: 1500 molar mass, 2 acrylate functions per molecule, EBECRYL 8402: 1000 molar mass, 2 acrylate functions per molecule, EBECRYL 8804 molar mass 1300, 2 acrylate functions per molecule, EBECRYL 220: molar mass 1000, 6 acrylate functions per molecule, EBECRYL 2220: molecular weight 1200, 6 acrylate functions per molecule, EBECRYL 1290 molar mass 1000, 6 acrylate functions per molecule, EBECRYL 800: 800 molar mass, 6 acrylate functions per molecule).  The water-soluble aliphatic diacrylate polyurethanes sold under the names EBECRYL 2000, EBECRYL 2001 and EBECRYL 2002, and the polyurethanes diacrylate in aqueous dispersion sold under the trade names IRR 390, IRR 400, IRR 422 IRR 424 by the company UCB, can also be mentioned.  D) polyethers with (meth) acrylate groups obtained by esterification, with (meth) acrylic acid, terminal hydroxyl groups of homopolymers or copolymers of C1 alkylene glycols, such as polyethylene glycol, polypropylene glycol, copolymers ethylene oxide and propylene oxide preferably having a weight average molecular weight of less than 10,000, polyethoxylated or polypropoxylated trimethylolpropane.  Suitable molar mass polyoxyethylene di (meth) acrylates are commercially available, for example, under the names SR 259, SR 344, SR 610, SR 210, SR 603 and SR 252 by the company Cray Valley or under the name EBECRYL 11 by UCB. .  Polyethoxylated trimethylolpropane triacrylates are sold, for example, under the names SR 454, SR 498, SR 502, SR 9035, SR 415 by the company Cray Valley or under the name EBECRYL 160 by the company UCB.  Polypropoxylated trimethylolpropane triacrylates are commercially available, for example, under the names SR 492 and SR 501 by the company CRAY VALLEY.  e) epoxyacrylates obtained by reaction between - at least one diepoxide chosen for example from: (i) diglycidyl ether of bisphenol A (ii) a diepoxy resin resulting from the reaction between the diglycidyl ether of bisphenol A and the epichlorohydrin, (iii) an α, β-diepoxy terminated epoxyester resin resulting from the condensation of a dicarboxylic acid having 3 to 50 carbon atoms with a stoichiometric excess of (i) and / or (ii), 2910288 ( iv) an epoxy ether resin having α,--diepoxy ends resulting from the condensation of a diol having from 3 to 50 carbon atoms with a stoichiometric excess of (i) and / or (ii), (v) natural or synthetic materials bearing at least 2 epoxide groups, such as epoxidized soybean oil, epoxidized linseed oil and epoxidized vernonia oil, (vi) a phenol-formaldehyde polycondensate (Novolac resin), the ends and / or or the side groups have been epoxidized, and 10 - a or a plurality of carboxylic acids or polycarboxylic acids having at least one ethylenic double bond in α, β of the carboxylic group such as (meth) acrylic acid or crotonic acid or esters of (meth) acrylic acid and a diol or polyol having 2 to 20 carbon atoms, preferably 2 to 6 carbon atoms such as 2-hydroxyethyl (meth) acrylate.  Such polymers are sold, for example, under the names SR 349, SR 601, CD 541, SR 602, SR 9036, SR 348, CD 540, SR 480, CD 9038 by the company Cray Valley, under the names EBECRYL 600 and EBECRYL. 609, EBECRYL 150, EBECRYL 860, EBECRYL 3702 by the company UCB and under the names PHOTOMER 3005 and PHOTOMER 3082 by the company HENKEL.  f) poly (meth) acrylates of C 1-50 alkyl, said alkyl being linear, branched or cyclic, comprising at least two functions with ethylenic double bond borne by the side and / or terminal hydrocarbon chains.  Such copolymers are sold for example under the names IRR 375, OTA 480 and EBECRYL 2047 by the company UCB.  G) polyolefins such as polybutene, polyisobutylene; h) perfluoropolyethers containing acrylate groups obtained by esterification, for example with (meth) acrylic acid, of perfluoropolyethers bearing lateral and / or terminal hydroxyl groups.  Such α, β-diol perfluoropolyethers are described in particular in EP-A-1057849 and are marketed by AUSIMONT under the name FOMBLIN Z DIOL.  (I) hyperbranched dendrimers and polymers bearing terminal (meth) acrylate or (meth) acrylamide groups obtained respectively by esterification or amidification of dendrimers and hyperbranched polymers with hydroxyl or amino terminal functions, with (meth) acrylic acid; .  Dendrimers (from the Greek dendron = tree) are "tree", that is, highly branched, polymer molecules invented by D.  AT.  Tomalia and his team in the early 90s (Donald A.  Tomalia et al. , Angewandte Chemie, Int.  Engl.  Ed. , flight.  29, No. 2, pp. 138-175).  These are structures built around a generally versatile central pattern.  Around this central motif 10 are chained, according to a perfectly determined structure, branched chain extension units thus giving rise to symmetrical, monodisperse macromolecules having a well-defined chemical and stereochemical structure.  Dendrimers of polyamidoamine type are marketed for example under the name STARBUST by the company DENDRITECH.  The hyperbranched polymers are polycondensates, generally of the polyester, polyamide or polyethyleneamine type, obtained from multifunctional monomers, which have a tree structure similar to that of the dendrimers but much less regular than the latter (see, for example, WO-A-20). 93/17060 and WO 96/12754).  The company PERSTORP markets under the name BOLTORN hyperbranched polyesters.  Under the COMBURST name of the company DENDRITECH are hyperbranched polyethyleneamines.  Hyperramified poly (esteramide) with hydroxyl ends are marketed by DSM under the name HYBRANE.  These dendrimers and hyperbranched polymers esterified or amidified with acrylic and / or methacrylic acid are distinguished from the polymers described under points a) to h) above by the very large number of ethylenic double bonds present.  This high functionality, most often greater than 5, makes them particularly useful by allowing them to play a role of "crosslinking node", that is to say of multiple crosslinking site.  These dendritic and hyperbranched polymers can thus be used in combination with one or more of the polymers and / or oligomers a) to h) above.  According to one embodiment, the compositions comprising compound X and / or Y may further comprise an additional reactive compound such as organic or inorganic particles comprising on their surface at least 2 unsaturated aliphatic groups, mention may be made, for example, of silicas 5 surface-treated, for example with silicone compounds with vinyl groups such as, for example, cyclotetramethyltetravinylsiloxane-treated silica, and silazane compounds such as hexamethyldisilazane.  Catalyst The hydrosilylation reaction is advantageously carried out in the presence of a catalyst which may be present in one or other of the compositions comprising X and / or Y or in a separate composition, the catalyst being preferably based on platinum or tin.  There may be mentioned, for example, platinum catalysts deposited on a silica gel or charcoal powder support, platinum chloride, platinum and chloroplatinic acid salts.  The chloroplatinic acids are preferably used in hexahydrate or anhydrous form, which is easily dispersible in organosilicone media.  Platinum complexes such as those based on chloroplatinic acid hexahydrate and divinyl tetramethyldisiloxane may also be mentioned. The catalyst may be present in one or the other of the compositions useful in the present invention in a content of 0.0001. % to 20% by weight relative to the total weight of the composition comprising it.  It is also possible to introduce polymerization inhibitors or retarders, and more particularly catalyst inhibitors, into the compositions of the invention, in order to increase the stability of the composition over time or to retard the polymerization.  In a nonlimiting manner, mention may be made of cyclic polymethylvinylsiloxanes, and in particular tetravinyl tetramethylcyclotetrasiloxane, acetylenic alcohols, which are preferably volatile, such as methylisobutynol.  The presence of ionic salts, such as sodium acetate, in one and / or the other of the first and second compositions may influence the rate of polymerization of the compounds.  By way of example of such compounds X and Y reacting by hydrosilylation, mention may be made of the following references proposed by Dow Corning: DC 7-9800 Soft Skin Adhesive parts A & B.  Advantageously, the compounds X and Y are chosen from silicone compounds capable of reacting by hydrosilylation; in particular, compound X is chosen from polyorganosiloxanes comprising units of formula (I) described above and compound Y is chosen from organosiloxanes comprising alkylhydrogenosiloxane units of formula (III) described above.  According to a particular embodiment, the compound X is a polydimethylsiloxane with terminal vinyl groups, and the compound Y is a methylhydrogensiloxane.  By way of example, the following two mixtures X 'and Y' containing compounds X and Y are used.  These mixtures can be supplied by Dow Corning.  MIXTURE X ': Ingredient (INCI name) N CAS Content (%) Function Compound X: Dimethyl 68083-19-2 55-95 End Siloxane Polymer Dimethylvinyl Siloxy Silica Silylate 68909-20-6 10-40 Charge 1,3-Diethylen -1,1,3,3- 68478-92-2 Trace Catalyst tetramethyldisiloxane complex Tetramethyldivinyldisiloxane 2627-95-4 0. 1-1 Polymer MIXTURE Y ': 20 2910288 29 Ingredient (INCI name) N CAS Level (%) Function Compound X: Dimethyl 68083-19-2 55-95 Polymer Siloxane endings Dimethylvinylsiloxy Silica Silylate 68909-20-6 10-40 Filler Compound Y: Dimethyl, 68037-59-2 1-10 Polymer Methylhydrogen siloxane, trimethylsiloxy-terminated 2 / X and Y compounds capable of reacting by condensation According to this embodiment, compounds X and Y are capable of reacting by condensation or in the presence of water (hydrolysis) by reaction of 2 compounds bearing alkoxysilane groups, or by direct condensation by reaction of a compound carrying alkoxysilane group (s) and a group-bearing compound ( s) silanol (s) or by reaction of 2 compounds bearing group (s) silanol (s).  When the condensation is done in the presence of water, it can be in particular the ambient humidity, the residual water of the skin, the lips of the eyelashes and / or the nails, or the water brought by an external source for example by pre-moistening eyelashes (for example by misting, natural or artificial tears).  In this condensation reaction mode, the compounds X and Y, which are identical or different, may therefore be chosen from silicone compounds whose main chain comprises at least two alkoxysilane groups and / or at least two silanol groups (Si-OH). , side and / or at the end of the chain.  According to one embodiment, the compound X and / or the compound Y carries at least one polar group, as described above, capable of forming at least one hydrogen bond with the keratin materials.  According to an advantageous embodiment, the compounds X and / or Y are chosen from polyorganosiloxanes comprising at least two alkoxysilane groups.  By alkoxysilane group is meant a group comprising at least a -Si-OR moiety, where R is an alkyl group having 1 to 6 carbon atoms.  The compounds X and Y are in particular chosen from polyorganosiloxanes comprising alkoxysilane end groups, more specifically those which comprise at least 2 terminal alkoxysilane groups, preferably terminal trialkoxysilanes.  These compounds X and / or Y preferably comprise, in a majority manner, units of formula "(IV) in which R 9 independently represent a radical chosen from alkyl groups comprising from 1 to 6 carbon atoms, phenyl and alkyl groups. fluorinated, and S is 0, 1, 2 or 3.  Preferably the R 9 represent alkyl groups comprising from 1 to 6 carbon atoms.  As alkyl group, there may be mentioned in particular methyl, propyl, butyl, hexyl and mixtures thereof, preferably methyl or ethyl.  As the fluoroalkyl group, 3,3,3-trifluoropropyl may be mentioned.  According to a particular embodiment, the compounds X and Y, which may be identical or different, are polyorganosiloxanes comprising units of the formula ## STR2 ## in which R 9 is as described above, preferably R 9 is a radical. methyl, and f is such that the polymer has a viscosity at 25 C ranging from 0.5 to 3000 Pa. s, preferably ranging from 5 to 150 Pa. s.  For example, f may range from 2 to 5000, preferably from 3 to 3000, and preferably from 5 to 1000.  These polyorganosiloxane compounds X and Y comprise at least 2 terminal trialkoxysilane groups per polymer molecule, said groups having the following formula in which the radicals R independently represent methyl, ethyl, n-propyl, isopropyl, n-butyl, and dry groups. butyl, isobutyl, preferably a methyl or ethyl group, R 'is a methyl or ethyl group, x is 0 or 1, preferably x is 0 and Z is selected from: divalent hydrocarbon groups having no ethylenic unsaturation and comprising from 2 to 18 carbon atoms (alkylene groups), the combinations of divalent hydrocarbon radicals and siloxane segments of formula R 9 R 9 -G- (Si (.  ZUT, if R9 R9 being as described above, G is a divalent hydrocarbon radical having no ethylenic unsaturation and comprising from 2 to 18 carbon atoms and c is an integer ranging from 1 to 6.  Z and G may especially be chosen from alkylene groups such as ethylene, propylene, butylene, pentylene, hexylene, arylene groups such as phenylene. Preferably Z is an alkylene group, and better is ethylene. .  These polymers may have on average at least 1.2 trialkoxysilane end groups or terminal chains per molecule, and preferably on average at least 1.5 trialkoxysilane end groups per molecule.  Since these polymers may have at least 1.2 trialkoxysilane end groups per molecule, some may comprise other types of end groups such as terminal groups of formula CH 2 = CH-SiR92- or of formula R 63 -Si-, in which R 9 is as defined above and each R6 group is independently selected from R9 or vinyl groups.  Examples of such end groups include trimethoxysilane, triethoxysilane, vinyldimethoxysilane and vinylmethyloxyphenylsilane groups.  Such polymers are described in particular in US Pat. No. 3,175,993, US Pat. No. 4,772,675, US Pat. No. 4,871,827, US Pat. No. 4,888,380, US Pat. No. 4,898,910, US Pat. No. 4,906,719 and US Pat. No. 4,962,174, the contents of which are incorporated by reference. reference to this application.  Compound X and / or Y may be mentioned in particular the polymer of formula lx R9 R9 ix (R. 0). Wherein R, R ', R9, Z, x and f are as described above.  Compounds X and / or Y may also comprise a polymer mixture of formula (VII) above with polymers of formula (VIII) below: R 9 9 f. Wherein R, R ', R9, Z, x and f are as described above.  When the compound X and / or Y polyorganosiloxanes with alkoxysilane group (s) comprises such a mixture, the various polyorganosiloxanes are present in contents such that the terminal organosilyl chains represent less than 40%, preferably less than 25% by weight. number of terminal chains Particularly preferred compounds X and / or Y polyorganosiloxanes are those of formula (VII) described above.  Such compounds X and / or Y are described, for example, in WO 01/96450.  As indicated above, the compounds X and Y may be the same or different.  According to one variant, one of the two reactive compounds X or Y is of a silicone nature and the other is of organic nature.  For example, the compound X is chosen from organic oligomers or polymers or oligomers or hybrid organic / silicone polymers, said polymers or oligomers comprising at least two alkoxysilane groups and Y is chosen from silicone compounds such as the polyorganosiloxanes described above. .  In particular, the organic oligomers or polymers are chosen from vinyl, (meth) acrylic, polyesters, polyamides, polyurethanes and / or polyureas, polyethers, polyolefins, perfluoropolyethers, dendrimers and organic hyperbranched polymers, and mixtures thereof. .  The organic polymers of vinyl nature or (meth) acrylic, bearing alkoxysilane side groups, may in particular be obtained by copolymerization of at least one vinyl organic monomer or (meth) acrylic with (meth) acryloxypropyltrimethoxysilane, vinyl trimethoxysilane, vinyltriethoxysilane, allyltrimethoxysilane, etc. .  For example, mention may be made of the (meth) acrylic polymers described in the KUSABE document. M, Pitture e Verniei - European Coating; 12-B, pages 43-49, 2005, and 2910288 33 in particular the alkoxysilane polyacrylates referenced Kaneka MAX or those described in the publication PROBSTER, M, Adhesion-Kleben & Dichten, 2004, 481 (1-2), pages 12-14.  The organic polymers resulting from a polycondensation or a polyaddition, such as polyesters, polyamides, polyurethanes and / or polyureas, polyethers, and bearing side and / or terminal alkylsilanes groups, may result for example from the reaction of an oligomeric prepolymer as described above with one of the following silane co-reactants bearing at least one alkoxysilane group: aminopropyltrimethoxysilane, aminopropyltriethoxysilane, aminoethylaminopropyltrimethoxysilane, glycidoxypropyltrimethoxysilane, glycidoxypropyltriethoxysilane, epoxycyclohexylethyltrimethoxysilane, mercaptopropyltrimethoxysilane.  Examples of polyethers and polyisobutylenes with alkoxysilane groups are described in the KUSABE publication. Mr. , Pitture e Verniei - European Coating; 12-B, 15 pp. 43-49, 2005.  As an example of polyurethanes with terminal alkoxysilane groups, mention may be made of those described in the document PROBSTER, M. , Adhesion-Kleben & Dichten, 2004, 481 (1-2), pages 12-14 or those described in the document LANDON, S. , Pitture e Verniei Vol.  73, No. 11, pages 18-24, 1997 or in the document HUANG, Mowo, Pitture e Verniei Vol.  5, 2000, pp. 61-67, there may be mentioned polyurethanes with alkoxysilane groups of OSI-WITCO-GE.  As compounds X and / or Y polyorganosiloxane, there may be mentioned resins of MQ or MT type itself bearing alkoxysilane ends and / or silanols such as poly (isobutylsilsesquioxane) resins functionalized with silanol groups proposed under the reference SST-S7C41 (3 Si-OH groups) by Gelest.  Additional Reagent Compound One of the compositions useful in the present invention may further comprise an additional reactive compound comprising at least two alkoxysilane or silanol groups.  For example, mention may be made of: • an organic or inorganic particle or particles comprising, on their surface, alkoxysilane and / or silanol groups, for example fillers surface-treated with such groups.  Catalyst The condensation reaction may be carried out in the presence of a metal catalyst which may be present in one or other of compositions comprising X and / or Y or 2910288 in a separate composition.  The catalyst useful in this type of reaction is preferably a titanium-based catalyst.  There may be mentioned in particular tetraalkoxytitanium-based catalysts of formula 5 in which R2 is chosen from tertiary alkyl radicals such as tert-butyl, tert-amyl and 2,4-dimethyl-3-pentyl; R3 represents an alkyl radical comprising from 1 to 6 carbon atoms, preferably an ethyl methyl group, n-propyl, isopropyl, n-butyl, sec-butyl, hexyl and y is a number ranging from 3 to 4, better still 3 , 4 to 4.  The catalyst may be present in any one of the compositions useful in the present invention in a content of from 0.0001% to 20% by weight based on the total weight of the composition (s) containing it. .  2c Diluent Useful compositions comprising X and / or Y may further comprise a volatile silicone oil (or diluent) for decreasing the viscosity of the composition.  This oil may be chosen from linear short chain silicones such as hexamethyldisiloxane, octamethyltrisiloxane, cyclic silicones such as octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane and mixtures thereof.  This silicone oil may represent from 5% to 95%, preferably from 10% to 80% by weight relative to the weight of each composition.  By way of example of compounds X and Y bearing alkoxysilane groups and reacting by condensation, mention may be made of the following mixtures X 'and Y' prepared by the company Dow Corning: By way of example of compounds X and Y carrying alkoxysilane groups and reacting by condensation, mention may be made of the following mixtures X 'and Z' prepared by the company Dow Corning: Mixture X ': Ingredient (INCI name) N CAS Content (I' Function Bis-Trimethoxysiloxyethyl PMN87176 25-45 Polymer Tetramethyldisiloxyethyl Dimethicone (1) Silica Silylate 68909-20-6 5-20 Charge Disiloxane 107-46-0 30-70 Solvent (1) Mixture X 'contains identical compounds X and Y Mix Z': Ingredient (INCI name ) N CAS Level (%) Disiloxane function 107-46-0 80-99 Tetra T solvent Butyl Titanate - 1-20 Catalyst 3 / Crosslinking in the presence of peroxide: 10 This reaction is preferably by heating to a temperature greater than or equal to at 50 C, of meadow greater than or equal to 80 C, up to 120 C.  The compounds X and Y, which are identical or different, comprise in this case at least two side groups ûCH3 and / or at least two side chains bearing a group -CH3.  The compounds X and Y are preferably silicone and may be chosen, for example, from high molecular weight non-volatile linear polydimethylsiloxanes having a degree of polymerization of greater than 6 having at least two silicon-bonded side groups connected to the silicon atom and or at least two side chains bearing a -CH3 group.  Mention may be made, for example, of the polymers described in the Reactive Silicones Catalog of Gelest Inc. , Edition 2004, page 6, and in particular the copolymers (also called gums) of vinylmethylsiloxane-dimethylsiloxane molecular weight ranging from 500,000 to 900,000 and viscosity greater than 2,000,000 cSt.  Peroxides which may be used in the context of the invention include benzoyl peroxide, 2,4-dichlorobenzoyl peroxide and mixtures thereof.  According to one embodiment, the reaction of hydrosilylation, condensation or crosslinking in the presence of a peroxide between the compounds X and Y is accelerated by a heat input by raising for example the temperature of the system between 25 C and 180 vs.  The system will react especially on the skin.  In general, irrespective of the type of reaction by which compounds X and Y react together, the molar percentage of X with respect to all compounds X and Y, i.e. the ratio X / (X + Y) x 100 may range from 5% to 95%, preferably from 10% to 90%, more preferably from 20% to 80%.  Likewise, the molar percentage of Y relative to the set of compounds X and Y, ie the ratio Y / (X + Y) x 100, can vary from 5% to 95%, of preferably from 10% to 90%, more preferably from 20% to 80%.  Compound X may have a weight average molecular weight (Mw) of from 150 to 1,000,000, preferably from 200 to 800,000, more preferably from 200 to 250,000.  Compound Y can have a weight average molecular weight (Mw) of from 200 to 1,000,000, preferably from 300 to 800,000, more preferably from 500 to 250,000.  The compound X is preferably from 5 to 60% by weight of the weight of the composition containing it, and the compound Y is preferably from 0.5 to 5% by weight of the weight of the composition containing it.  The ratio between the compounds X and Y can be varied so as to modulate the reaction rate and thus the rate of formation of the film or to adapt the properties of the formed film (for example its adhesive properties) according to the application. sought.  One or less of the compositions forming the kit may comprise fillers.  By way of example, these fillers may be colloidal calcium carbonate which may or may not be treated with stearic acid or stearate, silica such as fumed silicas, precipitated silicas or silicas treated to render them hydrophobic. ground quartz, alumina, aluminum hydroxide, titanium dioxide, diatomaceous earth, iron oxide, carbon black, and graphite.  Synthetic slices whose surface is modified with silicone compounds to render them hydrophobic at the surface are particularly preferred.  These fillers are differentiated from one another by their surface properties, the silicone compounds used to treat the silica, and the way in which the surface treatment is carried out.  Such fillers make it possible to reduce the viscosity of the formulation obtained from compounds X and / or Y.  In addition, resin-based reinforcing fillers can also be used.  Filler silica, calcium carbonate, resin fillers are preferred.  By way of example, there may be mentioned the treated feeds Cab-O-Sil® TS-530, Aerosil® R8200 and Wacker HDX® H2000.  Aqueous Phase At least one of the compositions of the kit may comprise an aqueous phase.  The aqueous phase may consist essentially of water; it may also comprise a mixture of water and water-miscible solvent (miscibility in water greater than 50% by weight at 25 ° C.) such as lower monoalcohols having 1 to 5 carbon atoms such as ethanol, isopropanol, glycols having 2 to 8 carbon atoms such as propylene glycol, ethylene glycol, 1,3-butylene glycol, dipropylene glycol, C3-C4 ketones, C2 aldehydes; -C4 and mixtures thereof.  The aqueous phase (water and optionally the water-miscible solvent) may be present in a content ranging from 5 to 95% by weight relative to the total weight of each composition, preferably from 10% to 85% by weight. and preferably from 2 to 80% by weight. Unsaturated bodies At least one of the compositions of the kit may also comprise at least one fatty substance that is solid at room temperature (25 ° C.), preferably having a melting point greater than 25 ° C. , especially chosen from waxes, pasty fatty substances and mixtures thereof.  These fats can be of animal, vegetable, mineral or synthetic origin.  Wax A wax is understood to mean a lipophilic compound, solid at room temperature (25 ° C.), with a reversible solid / liquid state change, having a melting point of greater than or equal to 30 ° C. and up to 120 ° C.  In particular, the waxes that are suitable for the invention may have a melting point of greater than about 45, and in particular greater than 55 C.  The melting point of the wax can be measured using a differential scanning calorimeter (D. S. vs. ), for example the calorimeter sold under the name DSC 30 by the METLER company.  In particular, it is possible to use hydrocarbon waxes such as beeswax, lanolin wax and Chinese insect waxes; rice wax, Carnauba wax, Candelilla wax, Ouricurry wax, Alfa wax, cork fiber wax, sugar cane wax, Japanese wax and sumac wax ; montan wax, microcrystalline waxes, paraffins and ozokerite; polyethylene waxes, waxes obtained by Fisher-Tropsch synthesis and waxy copolymers and their esters.  Mention may also be made of waxes obtained by catalytic hydrogenation of animal or vegetable oils having linear or branched C8-C32 fatty chains.  Among these, there may be mentioned hydrogenated jojoba oil, isomerized jojoba oil such as trans isomerized partially hydrogenated jojoba oil manufactured or marketed by Desert Whale under the trade name ISOJOJOBA-50, hydrogenated sunflower oil, hydrogenated castor oil, hydrogenated coconut oil and hydrogenated lanolin oil, di- (1,1,1-trimethylolpropane) tetrastearate sold under the name HEST 2T- 4S by the company HETERENE, di- (1,1,1-trimethylolpropane) tetra-enehenate sold under the name HEST 2T-4B by the company HETERENE.  Mention may also be made of silicone waxes such as alkyl or alkoxy dimethicone containing from 16 to 45 carbon atoms and fluorinated waxes.  It is also possible to use the wax obtained by hydrogenation of olive oil esterified with the stearyl alcohol sold under the name PHYTOWAX Olive 18 L 57 or even the waxes obtained by hydrogenation of castor oil esterified with cetyl alcohol. sold under the name PHYTOWAX ricin 16L64 and 22L73, by the company SOPHIM.  Such waxes are described in application FR-A-2792190.  Paste The composition according to the invention may further comprise at least one pasty compound.  For the purposes of the present invention, the term "pasty" is understood to mean a lipophilic fat compound having a reversible solid / liquid state change, having in the solid state an anisotropic crystalline organization, and comprising at a temperature of 23 ° C. a liquid fraction. and a solid fraction.  By pasty, is also meant vinyl polylaurate.  The pasty compound is preferably chosen from synthetic compounds and compounds of plant origin.  A pasty compound can be obtained synthetically from starting materials of plant origin.  The pasty compound is advantageously chosen from lanolin and its derivatives - polyol ethers chosen from pentaerythritol ethers and polyalkylene glycol ethers, fatty alcohol and sugar ethers, and mixtures thereof.  the ether pentaerythritol and polyethylene glycol comprising 5 oxyethylenated units (50E) (CTFA name: PEG-5 Pentaerythrityl Ether), the pentaerythritol ether and polypropylene glycol comprising 5 oxypropylene units (5 PO) (CTFA name: PPG -5 Pentaerythrityl Ether), and their mixtures and more especially the mixture PEG-5 Pentaerythrityl Ether,

  PPG-5 Pentaerythrityl Ether and Soybean Oil, sold under the name Lanolide by the company Vevy, a mixture in which the constituents are in a ratio by weight of 46/46/8: 46% of PEG-5 Pentaerythrityl Ether, 46% of PPG-5 Pentaerythrityl Ether and 8% soybean oil.  polymeric or non-polymeric silicone compounds, or non-polymeric fluorinated compounds, in particular: homopolymers of olefins; copolymers of olefins; homopolymers and copolymers of hydrogenated dienes; linear or branched oligomers, homo or copolymers of alkyl (meth) acrylates preferably having a C8-C30 alkyl group • Homopolymeric and copolymeric oligomers of vinyl esters having C8-C30 alkyl groups • Homo- and copolymer oligomers of vinyl ethers having alkyl groups C8-C30, - the liposoluble polyethers resulting from the polyetherification between one or more C2-C100 diols, preferably C2-050 diols, - the esters, and mixtures thereof.  A preferred silicone and fluoro pasty compound is polymethyl trifluoropropyl methylalkyl dimethylsiloxane, manufactured under the name X22-1088 by SHIN ETSU.  Among the liposoluble polyethers, ethylene oxide and / or propylene oxide copolymers are particularly preferred with long-chain C 6 -C 30 alkylene oxides, more preferably such as the weight ratio of ethylene oxide. The oxide and / or propylene oxide with alkylene oxide in the copolymer is from 5:95 to 70:30.  In this family, mention will in particular be made of copolymers such as long-chain alkylene oxides are arranged in blocks having an average molecular weight of 1. 000 to 10. 000, for example a polyoxyethylene / polydodecyl glycol block copolymer such as the ethers of dodecanediol (22 mol) and polyethylene glycol (45 0E) marketed under the trademark ELFACOS ST9 by Akzo Nobel.  Among the esters, the esters of an oligomeric glycerol, in particular the esters of diglycerol, in particular the condensates of adipic acid and of glycerol, for which part of the hydroxyl groups of the glycerols have reacted with a mixture of fatty acids such as stearic acid, capric acid, stearic acid and isostearic acid and 12-hydroxystearic acid, especially in the image of those marketed under the trademark Softisan 649 by the company Sasol 15 arachidyl propionate sold under the trademark Waxenol 801 by Alzo; phytosterol esters; triglycerides of fatty acids and their derivatives; pentaerythritol esters; non-crosslinked polyesters resulting from the polycondensation between a dicarboxylic acid; or a C 4 -C 50 linear or branched polycarboxylic acid and a C2-050 diol or polyol; - the ester aliphatic esters resulting from the esterification of a hydroxycarboxylic acid ester aliphatic boxylic acid with an aliphatic carboxylic acid; The aliphatic carboxylic acid comprises from 4 to 30 and preferably from 8 to 30 carbon atoms.  It is preferably selected from hexanoic acid, heptanoic acid, octanoic acid, 2-ethyl hexanoic acid, nonanoic acid, decanoic acid, undecanoic acid, dodecanoic acid, acid tridecanoic acid, tetradecanoic acid, pentadecanoic acid, hexadecanoic acid, hexyldecanoic acid, heptadecanoic acid, octadecanoic acid, isostearic acid, nonadecanoic acid, eicosanoic acid, isoarachidic acid, octyldodecanoic acid, henicosanoic acid, docosanoic acid, and mixtures thereof.  The aliphatic carboxylic acid is preferably branched.  The aliphatic hydroxy carboxylic acid ester is advantageously derived from a hydroxylated aliphatic carboxylic acid having from 2 to 40 carbon atoms, preferably from 10 to 34 carbon atoms and better still from 12 to 28 carbon atoms, and from 1 to 20 hydroxyl groups, preferably 1 to 10 hydroxyl groups and more preferably 1 to 6 hydroxyl groups.  The aliphatic hydroxycarboxylic acid ester is chosen from: a) partial or total esters of linear, saturated, monohydroxylated aliphatic monocarboxylic acids; b) partial or total esters of unsaturated monohydroxylated aliphatic monocarboxylic acids; C) partial or total esters of saturated monohydroxylated aliphatic polycarboxylic acids; d) partial or total esters of saturated polyhydroxylated aliphatic polycarboxylic acids; e) partial or total esters of C2 to C16 aliphatic polyols reacted with mono or polyhydroxylated aliphatic mono or poly carboxylic acid, and mixtures thereof.  The ester aliphatic esters are advantageously chosen from: the ester resulting from the esterification reaction of hydrogenated castor oil with isostearic acid in the proportions 1 to 1 (1/1) or monoisostearate of hydrogenated castor oil, the ester resulting from the esterification reaction of hydrogenated castor oil with isostearic acid in the proportions 1 to 2 (1/2) or hydrogenated castor oil diisostearate, the ester resulting from the esterification reaction of hydrogenated castor oil with isostearic acid in proportions of 1 to 3 (1/3) or hydrogenated castor oil triisostearate, and mixtures thereof.  The nature and amount of the solid fatty substances are a function of the desired mechanical properties and textures.  As an indication, the waxes may represent from 0.1 to 70% by weight of, relative to the total weight of each composition, better from 1 to 40% and more preferably from 5 to 30% by weight.  Filmoqene The compositions may comprise a film-forming polymer.  According to one embodiment, the composition contains at least one polymer which may be chosen from film-forming polymers.  Some film-forming polymers may be gelling agents.  According to one mode of implementation, the polymer is not a nitrocellulose.  For the purposes of the invention, the term "polymer" means a compound having at least 2 repeating units, and preferably at least 3 repeating units.  By "film-forming" polymer is meant a polymer capable of forming, by itself or in the presence of an auxiliary film-forming agent, a macroscopically continuous film on a support, in particular on keratin materials, and preferably a cohesive film and more preferably, a film whose cohesion and mechanical properties are such that said film 5 can be isolated from said support.  The polymer may be present in the composition in a content ranging from 0.1% to 60% by weight, relative to the total weight of the composition, preferably ranging from 0.1% to 50% by weight, preferably ranging from 0.5 to 40% by weight, preferably ranging from 1% to 30% by weight, and more preferably ranging from 1% to 25% by weight.  In one embodiment, the film-forming organic polymer is at least one polymer selected from the group consisting of: film-forming polymers soluble in an organic liquid medium, in particular liposoluble polymers, when the organic liquid medium comprises at least one oil; dispersible film-forming polymers in an organic solvent medium, in particular polymers in the form of nonaqueous dispersions of polymer particles, preferably dispersions in silicone or hydrocarbon oils; In one embodiment, the nonaqueous polymer dispersions comprise polymer particles stabilized on their surface by at least one stabilizing agent; film-forming polymers in the form of aqueous dispersions of polymer particles, often called latexes; in this case, the composition comprises an aqueous phase; water-soluble film-forming polymers; in this case, the composition comprises an aqueous phase.  Among the film-forming polymers that may be used in the composition of the present invention, mention may be made of synthetic polymers, of free-radical type or of polycondensate type, polymers of natural origin, and mixtures thereof.  As film-forming polymer, mention may be made in particular of acrylic polymers, polyurethanes, polyesters, polyamides, polyureas, cellulose polymers such as nitrocellulose, silicone polymers, in particular silicone resins, silicone-grafted acrylic polymers, polyamide polymers and copolymers, polyisoprenes.  The film-forming polymer may be chosen from the film-forming polymers described in patent application WO 04/028487, the contents of which are incorporated herein by reference.  In particular, the film-forming polymer may be a crosslinked silicone compound as described in US 2003/0103918 and US 2003/0049216, the contents of which are incorporated by reference in the present application.  In particular, film-forming polymers are described in International Patent Application No. PCT / FR03 / 02849, the contents of which are incorporated by reference.  The film-forming polymer may be a film-forming linear ethylenic block polymer, advantageously free of styrene.  More preferably, the block polymer comprises less a first block and at least a second block having different glass transition temperatures (Tg), said first and second blocks being interconnected by an intermediate block comprising at least one monomer constituting the first sequence and at least one constituent monomer of the second sequence.  The film-forming polymer may also be in the form of a dispersion of particles, preferably solid, of an ethylene polymer grafted into a liquid fatty phase.  Such a dispersion is particularly described in the international patent application filed as PCT / FR / 03/03709, the contents of which are incorporated by reference.  Advantageously, the grafted ethylenic polymer comprises an ethylenic skeleton insoluble in said liquid fatty phase, and side chains covalently bonded to said backbone and soluble in said dispersion medium.  Amphiphilic Silicone The compositions may contain at least one amphiphilic silicone.  The usable amphiphilic silicones contain a portion of silicone which is compatible with a silicone medium, and a hydrophilic portion which may be, for example, the remainder of a compound chosen from alcohols and polyols having from 1 to 12 hydroxyl groups, polyoxyalkylenes containing at least two oxyalkylene units and having from 0 to 20 oxypropylene units and / or from 0 to 20 oxyethylene units.  This hydrophilic portion thus has an affinity for the hydrophilic particles and contributes to the dispersion of these in a silicone medium.  The amphiphilic silicone may be an oil with no gelling activity.  Such oils may be composed of: dimethicone copolyols, optionally containing phenyl groups, alkylmethicone copolyols, polyglycerol silicones, ie silicones having alkylglyceryl ether groups, silicones having perfluorinated side groups and having side groups of glycerol, silicones having polyoxyethylene / polyoxypropylene side groups and having perfluorinated side groups, silicone block copolymers and hydrophilic block copolymers other than polyether, for example polyoxazoline or polyethyleneimine, graft copolymers of the silicone-grafted polysaccharide type, silicone block copolymers, poly (ethylene oxide / propylene oxide) block.  The amphiphilic silicone that can be used can also be an at least partially crosslinked amphiphilic silicone resin.  Examples of such resins include: - cross-linked silicone resins having alkylpolyether groups, such as polyethylene oxide (POE) and polyethylene oxide / propylene oxide (POE / POP) described in US No. 5,412,004, and partially cross-linked silicone resins having hydrophilic POE / POP side chains as well as hydrophobic alkyl side chains, such as those described in EP-A- 1,048,686.  The hydrophilic side chains are obtained by reaction with a POE / POP at a single vinyl end, and the alkyl side chains are formed by reaction with an α-olefin having a fatty chain.  In the amphiphilic silicone resin, the silicone portion is advantageously composed of polydimethylsiloxane.  Polyamide Polymer or Copolymer The compositions may contain at least one polyamide polymer or copolymer which may be chosen from polyamide homopolymers, polyamides branched with fatty chains, polyamides-organosiloxanes, polyamide-polyester copolymers and polyamide-polyacrylic copolymers. , and their mixtures.  As the polyamide polymer that can be used in the invention, mention may be made of the polymers described in the application EP 1 343 458, the content of which is incorporated herein by reference, for example the polyamide resins resulting from the condensation of a di-carboxylic acid. aliphatic carboxylic acid and a diamine (including compounds having more than 2 carbonyl groups and 2 amine groups), the carbonyl and amine groups of adjacent unit units being fused by an amide bond.  These polyamide resins are especially those marketed under the Versamid brand by General Mills, Inc.  and Henkel Corp.  (Versamid 930, 744 or 1655) or by Olin Mathieson Chemical Corp. , under the brand Onamid including Onamid S or C.  These resins have a weight average molecular weight ranging from 6000 to 9000.  For more information on these polyamides, reference may be made to US-A-3645705 and US-A-3148125.  More specifically, Versamid 930 or 744 are used.  It is also possible to use the polyamides sold by the company Arizona Chemical under the references Uni-Rez (2658, 2931, 2970, 2621, 2613, 2624, 2665, 1554, 2623, 2662) and the product sold under the reference Macromelt 6212 by Henkel company.  For more information on these polyamides, reference may be made to US-A-5500209.  It is also possible to use polyamide resins from vegetables such as those described in US-A-5783657 and US-A-5998570.  Polyamide polymers which may be used in the invention include polyamides branched by pendant fatty chains and / or terminal fatty chains having from 6 to 120 carbon atoms and better still from 8 to 120 and especially from 12 to 68 carbon atoms. carbon, each terminal fatty chain being linked to the polyamide backbone by at least one linking group, in particular an ester group.  Preferably, these polymers comprise a fatty chain at each end of the polymer backbone and in particular the polyamide backbone.  Other linking groups include ether, amine, urea, urethane, thioester, thiurea, thiourethane.  These polymers are more especially those described in the document US-A-5783657 of the company Union Camp.  By way of example, mention may be made of the commercial products sold by Arizona Chemical under the names Uniclear 80 and Uniclear 100.  They are sold respectively in the form of 80% gel (active ingredient) in a mineral oil and 100% (active ingredient).  They have a softening point of 88 to 94 C.  These commercial products are a mixture of copolymers of a C36 di-acid condensed on ethylene diamine, with a weight average molecular weight of about 6000.  The terminal ester groups result from the esterification of the remaining acid termini with cetyl alcohol, stearyl alcohol or mixtures thereof (also referred to as cetylstearyl alcohol).  Polyamide polymers that can be used in the invention also include polyamides comprising at least one polyorganosiloxane group, consisting of 1 to 1000 organosiloxane units in the main chain or in the form of a graft.  The polymers are, for example, those described in US-A-5,874,069, US-A-5,919,444, US-A-6,051,216 US-A-5,981,680 and WO 04/054524, the contents of which are incorporated herein by reference. .  The silicone polyamide may be a polymer comprising at least one unit of formula (IV) or (V): CX-R4 SiO R6-m R5 Si XC NH Y NH R7 O-n or NH X-mn R5 Si X NH CYC R 4, R 5, R 6 and R 7, which may be identical or different, represent a group chosen from: linear or branched or cyclic hydrocarbon groups of C 1 to C 40, saturated or unsaturated, which may contain in their chain one or more oxygen, sulfur and / or nitrogen atoms, and which may be substituted in part or totally by fluorine atoms, - optionally substituted C6-C10 aryl groups; by one or more C 1 to C 4 alkyl groups, the polyorganosiloxane chains containing or not containing one or more oxygen, sulfur and / or nitrogen atoms, X, which may be identical or different, represent an alkylene di-yl group; , linear or branched C to Cao, may contain in its chain one or more oxygen and / or nitrogen atoms, Y is a gr divalent alkylene linear or branched alkylene, arylene, cycloalkylene, alkylarylene or arylalkylene, saturated or unsaturated, C 1 -C 5, which may comprise one or more oxygen, sulfur and / or nitrogen atoms, and / or carry as substituting one of the following atoms or groups of atoms: fluorine, hydroxy, C3-C8 cycloalkyl, C₁-C C alkyl, C5-C ar aryl, phenyl optionally substituted by 1 to 3 C-alkyl groups, C 3 to C 3, C 1 to C 3 hydroxyalkyl and C 1 to C 6 alkylamines, or n is an integer from 2 to 500, preferably from 2 to 200, and m is an integer from 1 to 1000, preferably from 1 to 700 and more preferably from 6 to 200.  Surfactants The compositions according to the invention may contain emulsifying surfactants present in particular in a proportion ranging from 0.1 to 30% by weight relative to the total weight of each composition, better from 1 to 15% and better still from 2 to 10% by weight. %.  These surfactants may be chosen from anionic, nonionic, amphoteric or zwitterionic surfactants.  See Encyclopedia of Chemical Technology, KIRK-OTHMER, Vol. 22, p. 333-432, 3rd edition, 1979, WILEY, for the definition of the properties and functions (emulsifier) of surfactants, in particular p. 347-377 of this reference, for anionic and nonionic surfactants.  The surfactants preferably used in the first and second compositions according to the invention are chosen from: a) nonionic surfactants with a HLB greater than or equal to 8 at 25 ° C., used alone or as a mixture; mention may be made in particular of: oxyethylenated and / or oxypropylenated ethers (which may contain from 1 to 150 oxyethylenated and / or oxypropylenated groups) of glycerol; oxyethylenated and / or oxypropylenated ethers (which may contain from 1 to 150 oxyethylenated and / or oxypropylenated groups) of fatty alcohols (in particular of C 8 -C 24, and preferably C 12 -C 18), such as ether oxyethylenated oxyethylenated cetearyl alcohol (CTFA name "Ceteareth-30") and the oxyethylenated ether of the mixture of C12-C15 fatty alcohols having 7 oxyethylenated groups (CTFA name "C12-15 Pareth-7" marketed under the name NEODOL 25-7 by SHELL CHEMICALS; fatty acid esters (especially C8-C24, and preferably C16-C22) and polyethylene glycol (which may comprise from 1 to 150 ethylene glycol) such as PEG-50 stearate and PEG-40 monostearate sold under the name MYRJ 52P by the company ICI UNIQUEMA; fatty acid esters (especially C8-C24 acid esters); preferably C16-C22) and oxyethylenated and / or oxypropylenated glycerol ethers ( have from 1 to 150 oxyethylenated and / or oxypropylene groups), such as PEG-200 glyceryl monostearate sold under the name Simulsol 220 TM by the company SEPPIC; polyethoxylated glyceryl stearate with 30 ethylene oxide groups, such as the product TAGAT S sold by the company GOLDSCHMIDT, polyethoxylated glyceryl oleate with 30 ethylene oxide groups, such as the product TAGAT O sold by the company GOLDSCHMIDT, polyethoxylated glyceryl cocoate with 30 ethylene oxide groups, such as the product VARIONIC LI 13 sold by the company SHEREX, polyethoxylated glyceryl isostearate with 30 ethylene oxide groups, such as the product TAGAT L sold by the company GOLDSCHMIDT and polyethoxylated glyceryl laurate with 30 ethylene oxide groups, such as the product TAGAT I from GOLDSCHMIDT; fatty acid esters (in particular C8-C24 and preferably C16-C22 acids) and oxyethylenated and / or oxypropylenated sorbitol ethers (which can contain from 1 to 150 oxyethylene and / or oxypropylene groups), as the polysorbate 30 60 sold under the name Tween 60 by the company Uniquema; dimethicone copolyol, such as that sold under the name Q2-5220 by the company Dow Corning; dimethicone copolyol benzoate (FINSOLV SLB 101 and 201 from the company FINTEX); Copolymers of propylene oxide and of ethylene oxide, also called EO / Op polycondensates, for example the polyethylene glycol / polypropylene glycol / polyethylene glycol triblock polycondensates sold under the name "SYNPERONIC", such as "SYNPERONIC PE". L44 "and" SYNPERONIC PE / F127 "by ICI, and mixtures thereof.  - and their mixtures.  b) nonionic surfactants with a HLB of less than 8 to 25 ° C., optionally combined with one or more nonionic surfactants with a HLB of greater than 8 to 25 ° C., as mentioned above, such as: esters and ethers dies such as sucrose stearate, sucrose cocoate, sorbitan stearate and mixtures thereof such as Arlatone 2121 sold by the company ICI; Esters of fatty acids (in particular of C 8 -C 24, and preferably of C 16 -C 22) and of polyol, in particular glycerol or sorbitol, such as glyceryl stearate, glyceryl stearate, such as the product sold under the name TEGIN M by GOLDSCHMIDT, glyceryl laurate such as the product sold under the name IMWITOR 312 by the company HULS, polyglyceryl-2 stearate, sorbitan tristearate, glyceryl ricinoleate; the mixture of cyclomethicone / dimethicone copolyol sold under the name "Q2-3225C" by the company Dow Corning.  c) Anionic surfactants such as: - Cs-Cap fatty acid salts, especially those derived from amines, such as triethanolamine stearate; salts of polyoxyethylenated fatty acids, in particular those derived from amines or alkaline salts, and mixtures thereof; phosphoric esters and their salts, such as "DEA oleth-10 phosphate" (Crodafos N 10N from CRODA), cetyl phosphate (Amphisol K from DSM Nutritionnal Products); sulphosuccinates such as "Disodium PEG-5 citrate lauryl sulphosuccinate" and "Disodium ricinoleamido MEA sulphosuccinate" - alkyl ether sulphates such as sodium lauryl ether sulphate; isethionates; Acylglutamates, such as "Disodium hydrogenated tallow glutamate" (AMISOFT HS-21 R marketed by the company AJINOMOTO), and mixtures thereof.  Particularly suitable for the invention, triethanolamine stearate.  The latter is generally obtained by simple mixing of stearic acid and triethanolamine.  Gelling agent The compositions may contain at least one gelling agent.  An aqueous medium gelling agent may be chosen from: water-soluble cellulosic thickeners guar, xanthan, carob, scleroglucan, gellan, rhamsan, karaya and carrageenan gums alginates, maltodextrins, starch and its derivatives, hyaluronic acid and its salts, chitosans and their derivatives, glyceryl poly (metha) crylate polymers sold under the names "Hispagel" or "Lubragel" by the companies Hispano Quimica or Guardian, polyvinylpyrrolidone, polyvinyl alcohol, crosslinked polymers and copolymers of acrylamide, such as those sold under the names "PAS 5161" or "Bozepol C" by the company Hoechst, "Sepigel 305 by the company Seppic by the company Allied Colloid, or else the cross-linked homopolymers of methacryloyloxyethyltrimethylammonium chloride sold under the name "Salcare SC95" by the company Allied Collo d.  associative polymers and in particular associative polyurethanes; polyamides, such as Uniclear 100 sold by the company Arizona; semi-crystalline polymers previously described; organosiloxanes obtained by hydroxysilylation.  Such gelling agents are especially described in applications EP-A-1400234, the contents of which are incorporated by reference.  An oily medium gelling agent may be selected from: - alkylated guar gums (with C1-C6 alkyl group), such as those described in EP-A-708114; oil-forming polymers such as triblock or star polymers resulting from the polymerization or copolymerization of at least one monomer containing an ethylenic group, such as the polymers sold under the name Kraton; polymers having a weight average molecular weight of less than 100,000, comprising a) a polymeric backbone having hydrocarbon-based repeating units provided with at least one heteroatom, and optionally b) at least one pendant fatty chain and / or at least one terminal fatty chain optionally functionalized, having from 6 to 120 carbon atoms and being linked to these hydrocarbon-based units, as described in applications WO-A-02/056847, WO-A-02/47619, the contents of which are incorporated in reference title; in particular, polyamide resins (especially those comprising alkyl groups having 12 to 22 carbon atoms) such as those described in US-A-5783657, the contents of which are incorporated by reference.  The organogellators may be selected from those described in WO-A-03/037888, the contents of which are incorporated by reference.  As gelling agent that may be used in the invention, mention may also be made of crosslinked organopolysiloxanes obtained by hydroxysilylation.  Examples of resins obtained by hydroxysilylation that may be used according to the invention include those sold under the names KSG6 from Shin-Etsu, Trefil E-505C or Trefil E-506C from Dow-Corning, Gransil from Grant Industries (SR-CYC, SR DMF10, SR-DC556), or those marketed in the form of preconstituted gels (KSG15, KSG17, KSG16, KSG18, KSG20, KSG21, KSG31, KSG32 from Shin-Etsu, Gransil SR 5CYC gel, Gransil SR DMF 10 gel, Gransil SR DC556 gel, SF 1204 and JK 113 from 15 General Electric).  The products Dow Corning DC9010 and DC 9011 and Wacker EF199913 can also be used; these products include all oxyethylene groups, as do the products KSG20, KSG21, KSG31 and KSG32.  A mixture of these commercial products can also be used.  These products are especially obtained as described in US-A-5,236,986 to Shin-Etsu, US Pat. No. 5,412,004 to Kosé and Shin-Etsu, or also US-A-5,811,487 to Dow Corning.  Dyestuff The compositions may comprise at least one dyestuff chosen for example from pigments, nacres, dyes, effect materials and mixtures thereof.  These dyestuffs may be present in a content ranging from 0.01% to 50% by weight, preferably from 0.01% to 30% relative to the weight of each first and second composition or relative to the total weight of the composition. when X and Y are present within the same composition.  The pigments useful in the present invention may be in the form of a powder or a pigment paste.  By dyes are meant compounds, generally organic, soluble in at least one oil or in a hydroalcoholic phase.  By pigments must be understood white or colored particles, mineral or organic, insoluble in an aqueous medium, intended to color and / or opacify the resulting film.  By nacres or pearlescent pigments, it is necessary to include colored particles of any shape, iridescent or otherwise, in particular produced by certain shellfish in their shell or else synthesized and which exhibit a color effect by optical interference.  The pigment may be an organic pigment.  By organic pigment is meant any pigment which meets the definition of the Ullmann encyclopedia in the organic pigment chapter.  The organic pigment may especially be chosen from nitroso compounds, nitro, azo, xanthene, quinoline, anthraquinone, phthalocyanine, metal complex type, isoindolinone, isoindoline, quinacridone, perinone, perylene, diketopyrrolopyrrole, thioindigo, dioxazine, triphenylmethane, quinophthalone.  The organic pigment (s) may be chosen, for example, from carmine, carbon black, aniline black, melanin, azo yellow, quinacridone, phthalocyanine blue, and blue pigments codified in the Color Index under the references Cl 42090, 69800, 69825, 73000, 74100, 74160, the yellow pigments coded in the Color Index under the references Cl 11680, 11710, 15985, 19140, 20040, 21100, 21108, 47000, 47005, the green pigments codified in the Color Index under the references Cl 61565, 61570, 74260, the orange pigments coded in the Color Index under the references Cl 11725, 15510, 45370, 71105, the red pigments codified in the Color Index under the references Cl 12085, 12120, 12370, 12420, 12490, 14700, 15525, 15580, 15620, 15630, 15800, 15850, 15865, 15880, 17200, 26100, 45380, 45410, 58000, 73360, 73915, 75470, the pigments obtained by oxidative polymerization of indole derivatives, phenolic as they are described in the FR 2,679,771.  These pigments can also be in the form of composite pigments as described in patent EP 1 184 426.  These composite pigments may be composed in particular of particles comprising an inorganic core at least partially covered with an organic pigment and at least one binder for fixing the organic pigments on the core.  By way of example, mention may also be made of organic pigment pigment pastes such as the products sold by HOECHST under the name: YELLOW COSMENYL 10G: Pigment YELLOW 3 (Cl 11710); YELLOW COSMENYL G: Pigment YELLOW 1 (Cl 11680); COSMENYL GR ORANGE: ORANGE PIGMENT 43 (Cl 71105); COSMENYL RUG RED: Pigment RED 4 (Cl 12085), CARMIN COSMENYL FB: Pigment RED 5 (Cl 12490), 2910288 53 - VIOLET COSMENYL RL: Pigment VIOLET 23 (Cl 51319), - COSMENYL BLUE A2R: Pigment BLUE 15 . 1 (CI 74160); - GREEN COSMENYL GG: Pigment GREEN 7 (Cl 74260); - BLACK COSMENYL R Pigment BLACK 7 (Cl 77266).  The pigment may also be a lacquer.  By lacquer is meant insolubilized dyes adsorbed on insoluble particles, the assembly thus obtained remaining insoluble during use.  The inorganic substrates on which the dyes are adsorbed are, for example, alumina, silica, calcium and sodium borosilicate or calcium and aluminum borosilicate, and aluminum.  Among the organic dyes, mention may be made of cochineal carmine.  Mention may also be made of the products known under the following names: D & C Red 21 (Cl 45 380), D & C Orange 5 (Cl 45 370), D & C Red 27 (Cl 45 410), D & C Orange 10 (Cl 45,425), D & C Red 3 (Cl 45,430), D & C Red 4 (Cl 15,510), D & C Red 33 (Cl 17,200), D & C Yellow 5 (Cl 19,140) , D & C Yellow 6 (Cl 15,985), D & C Green (Cl 61,570), D & C Yellow 10 (Cl 77,002), D & C Green 3 (Cl 42,053), D & C Blue 1 (Cl 42 090).  As examples of lacquers, mention may be made of the product known under the following name: D & C Red 7 (Cl 15 850: 1).  The pigment can also be a special effects pigment.  By special effect pigments are meant pigments which generally create a colored appearance (characterized by a certain nuance, a certain liveliness and a certain clarity) which is non-uniform and changeable as a function of the observation conditions (light, temperature, viewing angles,. . . ).  They are therefore opposed to white or colored pigments that provide a uniform opaque, semi-transparent or conventional transparent tint.  There are two types of special effect pigments, those with a low refractive index such as fluorescent, photochromic or thermochromic pigments, and those with a higher refractive index such as nacres or flakes.  Special-effect pigments include pearlescent pigments such as white pearlescent pigments such as titanium coated mica, or bismuth oxychloride, colored pearlescent pigments such as titanium mica with iron oxides. , titanium mica with in particular ferric blue or chromium oxide, titanium mica with an organic pigment of the aforementioned type as well as pearlescent pigments based on bismuth oxychloride.  Non-substrate-bound interference pigments such as liquid crystals (Wacker Helicones HC), holographic interference flakes (Spectratek Geometric Pigments or Spectra f / x) can also be mentioned.  Special effect pigments also include fluorescent pigments, whether they are fluorescent substances in the light of day or that produce an ultraviolet fluorescence, phosphorescent pigments, photochromic pigments, thermochromic pigments and quantum dots, marketed for example by Quantum Dots Corporation.  Quantum dots are luminescent semiconductor nanoparticles capable of emitting, under light excitation, radiation having a wavelength of between 400 nm and 700 nm.  These nanoparticles are known from the literature.  In particular, they can be manufactured according to the processes described for example in US Pat. No. 6,225,198 or US 5,990,479, in the publications cited therein, as well as in the following publications: Dabboussi B. O.  et al (CdSe) ZnS core-shell quantum dots: Synthesis and characterization of a large series of highly luminescent nanocrystallites. Journal of Physical Chemistry B, Vol 101, 1997, pp 9463-9475.  and Peng, Xiaogang et al., "Epitaxial Growth of Highly Luminescent CdSe / CdS core / shell nanocrystals with photostability and electronic accessibility" Journal of the American Chemical Society, vol 119, No. 030, pp 7019-7029.  Special effect pigments also include fluorescent pigments, be they fluorescent substances in daylight or produce ultraviolet fluorescence, phosphorescent pigments, photochromic pigments, thermochromic pigments.  The pigment may be a mineral pigment.  By inorganic pigment is meant any pigment which meets the definition of the Ullmann encyclopedia in the inorganic pigment chapter.  Among the mineral pigments useful in the present invention, mention may be made of zirconium or cerium oxides, as well as iron or chromium oxides, manganese violet, ultramarine blue, chromium hydrate and ferric blue. , titanium dioxide.  The following inorganic pigments can also be used: Ta 2 O 5, Ti 3 O 5, Ti 2 O 3, TiO 2, ZrO 2 mixed with TiO 2, ZrO 2, Nb 2 O 5, CeO 2, ZnS.  The pigment may also be a pearlescent pigment such as white pearlescent pigments, for example mica coated with titanium, or bismuth oxychloride, colored pearlescent pigments such as mica coated with titanium and iron oxides, coated mica titanium and in particular ferric blue or chromium oxide, mica coated with titanium and an organic pigment as defined above, as well as pearlescent pigments based on bismuth oxychloride.  By way of example, mention may be made of Cellini pigments marketed by Engelhard (Mica-TiO2-lacquer), Prestige marketed by Eckart (Mica-TiO2) and Colorona marketed by Merck (Mica-TiO2-Fe203).  In addition to nacres on a mica support, it is possible to envisage multilayer pigments based on synthetic substrates such as alumina, silica, calcium and sodium borosilicate or calcium and aluminum borosilicate, and aluminum. .  The size of the pigment useful in the context of the present invention is generally between 10 nm and 200 μm, preferably between 20 nm and 80 μm, and more preferably between 30 nm and 50 μm.  According to a preferred embodiment, the composition according to the invention may comprise fillers.  By fillers, it is necessary to include particles of any form, colorless or white, mineral or synthetic, insoluble in the medium of the composition regardless of the temperature at which the composition is manufactured.  The fillers can be mineral or organic of any shape, platelet, spherical or oblong, irrespective of the crystallographic form (for example sheet, cubic, hexagonal, orthorhombic, etc.).  Mention may be made of talc, mica, silica, kaolin, polyamide (nylon) powders, poly-13-alanine powders, polyethylene powders, polymethyl methacrylates, polyurethane powders such as copolymer powder of hexamethylene diisocyanate and of trimethylol hexyl lactone sold under the names PLASTIC POWDER D-400 by TOSHIKI, tetrafluoroethylene polymer powders (Teflon), micronized wax particles, in particular Carnauba micro-waxes such as those marketed under the name MicroCare 350 by the company MICRO POWDERS, synthetic wax microwaxes such as those marketed under the name MicroEase 1145 by the company MICRO POWDERS, microwaxes consisting of a mixture of Carnauba wax and wax of polyethylene such as those sold under the names MicroCare 300 and 310 by the company MIC RO POWDERS, the microwaxes consisting of a mixture of Carnauba wax and synthetic wax such as those marketed under the name MicroCare 325 by the company Micro POWDERS, polyethylene microwaxes such as those marketed under the names MicroPoly 200, 220 , 220L, and 2505, by the company MICRO POWDERS, and those marketed under the name of CERAPURE H5-C by the company SHAMROCK, or polypropylene microwaxes such as those sold under the name MATTEWAX by the company MICRO POWDERS; lauroyl-lysine, starch, boron nitride, polymeric hollow microspheres such as those of polyvinylidene / acrylonitrile chloride such as Expancel (Nobel Industrie), acrylic acid copolymers, silicone resin powders , in particular silsesquioxane powders (powders of silicone resin 2910288 56 in particular described in patent EP 293795; Toshiba's Tospearls, for example), elastomeric polyorganosiloxane particles, precipitated calcium carbonate, carbonate and hydrochloride. magnesium carbonate, hydroxyapatite, hollow silica microspheres, microcapsules of glass or ceramics, soaps

  organic carboxylic acid-derived compounds having 8 to 22 carbon atoms, preferably 12 to 18 carbon atoms, for example zinc, magnesium or lithium stearate, zinc laurate, magnesium myristate; barium sulphate and their mixtures.

According to a preferred embodiment, the composition according to the invention may comprise a polytetrafluoroethylene (PTFE) powder. The fillers may be present in the composition according to the invention in a total content ranging from 0.1% to 30% by weight, relative to the total weight of the composition, preferably ranging from 0.5% to 20% by weight. weight, and preferably ranging from 0.8% to 10% by weight. Other Ingredients The compositions may also contain ingredients commonly used in cosmetics, such as vitamins, thickeners, trace elements, softeners, sequestering agents, perfumes, alkalizing or acidifying agents, preservatives, sunscreens, antioxidants, fibers, care agents or mixtures thereof.

The compositions according to the invention may comprise any cosmetic active agent such as the active ingredients chosen from antioxidants, preservatives, perfumes, bactericidal or antiperspirant active agents, neutralizers, emollients, moisturizers, vitamins and filters. particular solar.

According to one embodiment, the first, second and, if appropriate, third compositions are lipstick compositions. According to another embodiment, the first, second and, if appropriate, third compositions are eyelash or eyebrow coating compositions and more particularly mascaras.

According to another embodiment, the first, second and, if appropriate, third compositions are compositions for coating the skin of the body or of the face, more particularly makeup compositions for the skin of the body or of the face, such as by example of foundations or makeup compositions of the body. Those skilled in the art may choose the appropriate dosage form, as well as its method of preparation, on the basis of its general knowledge, taking into account, on the one hand, the nature of the constituents used, in particular their solubility in the support, and on the other hand, the intended application for each composition. The invention is further illustrated by the examples described hereinafter. Unless otherwise indicated, the quantities indicated are expressed as a percentage by mass. In the composition examples described below, use is made of the following two mixtures X 'and Y' prepared by the company Dow Corning: MIXTURE X ': Ingredient (INCI name) N CAS Content (%) Dimethyl Siloxane function at 68083- 19-2 55-95 Polymer endings Dimethylvinylsiloxy Silica Silylate 68909-20-6 10-40 Charge 1,3-Diethylen-1,1,3,3- 68478-92-2 Trace Catalyst tetramethyldisiloxane complex Tetramethyldivinyldisiloxane 2627-95-4 0.1 -1 Polymer MIXTURE Y ': 5 10 20 10 2910288 58 Ingredient (INCI name) N CAS Content (%) Dimethyl Siloxane Function, at 68083-19-2 55-95 Polymer endings Dimethylvinylsiloxy Silica Silylate 68909-20-6 10-40 Charge Dimethyl, 68037-59-2 1-10 Polymer Methylhydrogen siloxane, trimethylsiloxy-terminated Example 1: Lipsticks 5 Composition 1% by weight Phenyltrimethicone 1000 cSt 15.9 Phenyltrimethicone 20 cSt 19.8 Polybutene Indopol H 100 7, 8 Mixture X 'qs 100 Pigments 6.3 Composition 2 0/0 by weight Ph enyltrimethicone 1000 cSt 24.1 Phenyltrimethicone 20 cSt 13.8 Polybutene Indopol H 100 12.0 Mixture Y 'qsp 100 The extant first and second compositions are extemporaneously mixed in a proportion of 50/50 and then this mixture is applied to the lips . After a few minutes of drying, we get on the lips a comfortable film that does not transfer.

The transfer of the obtained film with the mixture of the two compositions is evaluated as previously described. The film from the mixture of compositions 1 and 2 has a transfer value of 0%.

Claims (32)

  1. Cosmetic kit comprising at least two compositions packaged separately, the kit comprising at least one compound X, at least one compound Y, and optionally at least one catalyst or a peroxide, at least one of the compounds X or Y being silicone, with the proviso that compounds X and Y - and the catalyst when present or peroxide when present - are not simultaneously in one of said compositions, - said compounds X and Y being capable of reacting together by a reaction hydrosilylation, or by a condensation reaction or by a crosslinking reaction in the presence of a peroxide, when they are brought into contact with each other, - at least one of the first and second compositions containing at least a sticky oil whose stickiness index is greater than or equal to 0.05 J / m2.   2. Kit according to claim 1, characterized in that the transfer index of a deposit comprising the two compositions is less than or equal to 40 out of 100.   3. Kit according to any one of the preceding claims, characterized in that the transfer index of a deposit comprising the two compositions is less than or equal to 30 out of 100, preferably less than 20 out of 100, more preferably less than 10 to 100, more preferably less than 5 to 100.   4. Kit according to any one of the preceding claims, characterized in that the adhesive index is greater than or equal to 0.10 J / m2.   5. Kit according to any one of the preceding claims, characterized in that the adhesive index greater than or equal to 0.15 J / m2.   6. Kit according to any one of the preceding claims, characterized in that the sticky oil is chosen from polybutenes.   7. Kit according to one of the preceding claims, characterized in that the adhesive oil is from 1 to 99%, preferably from 10 to 80%, by weight of the total weight of the first composition or the second composition. 10 2910288 61   8. Kit according to one of the preceding claims, characterized in that the adhesive oil is 5 to 70% and more preferably 5 to 15% of the total weight of the first and / or second composition. 5   9. Kit according to one of the preceding claims, characterized in that the compounds X and Y are silicone.   10. Kit according to one of the preceding claims, characterized in that the compounds X and Y are capable of reacting by hydrosilylation.   11. Kit according to claim 11, characterized in that the compound X is chosen from polyorganosiloxanes comprising siloxane units of formula: RSO In. In which: R represents a monovalent hydrocarbon group, linear or cyclic, comprising from 1 to 20 carbon atoms, m is 1 or 2 and R 'is an unsaturated aliphatic group such as a cyclohexenyl group or a group R "CH = CHR" "where R" is a divalent aliphatic chain bonded to 20 silicon atom and R "'is a hydrogen atom or an alkyl radical   12. Kit according to claim 12, characterized in that R represents an alkyl radical comprising from 1 to 10 carbon atoms or a phenyl group and R 'is chosen from vinyl, allyl and hexenyl groups, and mixtures thereof.   Kit according to claim 11 or 12, characterized in that compound X is chosen from polyorganosiloxanes additionally comprising units of formula nnk (II) in which R is a group as defined in claim 11, n is equal to 1.2ou3.   14. Kit according to claim 10, characterized in that the compound X is chosen from dimethylvinylsiloxy-terminated polydimethylsiloxanes. 25 2910288 62   15. Kit according to one of the preceding claims, characterized in that the compound Y is selected from polyorganosiloxanes comprising at least two free Si-H groups.   16. Kit according to one of the preceding claims, characterized in that the compound Y is chosen from polyorganosiloxanes comprising alkylhydrogenosiloxane units of the following formula: in which: R represents a monovalent hydrocarbon group, linear or cyclic, comprising from 1 to 20 carbon atoms, and p is 1 or 2.   17. Kit according to one of the preceding claims, wherein the compound Y is a trimethylsiloxy-terminated dimethyl-methylhydrogensiloxane.   18. Kit according to one of the preceding claims, characterized in that at least one of the first and second compositions comprises a platinum-based catalyst.   19. Kit according to one of the preceding claims, characterized in that the catalyst is a 1,3-diethenyl-1,1,3,3-tetramethyldisiloxane complex.   20. Kit according to one of the preceding claims, characterized in that the molar ratio XI (X + Y) x 100 may vary from 5% to 95%, preferably from 10% to 90%, more preferably from 20% to 100%. % to 80%.   21. Kit according to one of the preceding claims, characterized in that the first and second compositions are free of volatile oil or each have a volatile oil content of less than or equal to 50% by weight, preferably less than or equal to 30% by weight and better still less than or equal to 10% by weight relative to the total weight of each composition.   22. Kit according to any one of the preceding claims, characterized in that the first and second compositions are anhydrous. 5 20 2910288 63   23. Kit according to any one of the preceding claims, characterized in that at least one of the first and second compositions comprises at least one dyestuff.   24. Kit according to one of the preceding claims, characterized in that the compound X represents from 5 to 60% by weight of the weight of the composition containing it, and the compound Y represents from 0.5 to 5% by weight of the weight of the composition containing it. 10   25. Kit according to any one of the preceding claims, characterized in that the ratio of sticky oil / compound X is preferably between 1/20 and 1/1, preferably between 1/10 and 1/4. 15   26. Kit according to any one of the preceding claims, characterized in that the ratio of sticky oil / compound Y is preferably between 1/20 and 1/1, preferably between 1/10 and 1/4.   27. Cosmetic process comprising the application to said keratinous materials, via at least one composition, of compounds X and Y at least one of which is silicone, compounds X and Y being suitable, when they are contact one another, to react together by hydrosilylation, condensation, or crosslinking in the presence of a peroxide, and - at least one oil whose stickiness index is greater than or equal to 0.05 J / m2.   28. The cosmetic method according to claim 27, comprising the application to keratinous substances: a. at least one layer of a first composition comprising compound X and a catalyst; b. at least one layer of a second composition comprising the compound X and the compound Y. the sticky oil being present in at least one of the first and second compositions. 35   29. The cosmetic method according to claim 28, comprising the application on said keratinous materials of the mixture of a first composition comprising the compound X and a second composition comprising the compound Y, said mixture being obtained either extemporaneously 2910288 before application to the keratin materials, or simultaneously with its application to keratin materials, the sticky oil being present in at least one of the first and second compositions. 5   30. Method according to one of claims 28 to 29, characterized in that the sticky oil is in accordance with the oil described in one of claims 4 to 6.   31. The method according to claim 27 or 28, characterized in that the transfer index of a deposit comprising the two compositions is less than or equal to 30 out of 100, preferably less than 20 out of 100, more preferably less than 10 out of 100, more preferably less than 5 out of 100.   32. Process according to any one of claims 27 to 31, characterized in that compounds X and Y are in accordance with the compounds described in one of claims 9 to 16.