FR2908642A1 - Cosmetic composition, useful for make-up of keratinous matter, comprises multilayer interference pigment, coloring agent, reflective pigment and diffractive pigment - Google Patents

Abstract

Cosmetic composition comprising a multilayer interference pigment, a coloring agent sensitive to an external stimulus, a reflective pigment and a diffractive pigment, where the coverage of the composition is >= 25, preferably 30, and the multilayer interference pigment being in a content conferring to the composition a color deviation (delta E) of >= 5 between the color in the mass and color after application, in a medium. Independent claims are included for: (1) a non-powder cosmetic composition comprising 7-20 wt.% of multi-layer interference pigments, 0.1-10 wt.% of coloring agent sensitive to at least one exterior stimulus, reflective pigment or diffractive pigment, in a medium; (2) a powder cosmetic composition comprising 40-95 wt.% of the multilayer pigment, 0.1-60 wt.% of coloring agent sensitive to at least one exterior stimulus, reflective pigment or diffractive pigment, in a medium; and (3) a set of packaging comprising the composition and a user manual on the color composition after application on the keratin materials.

Description

The present invention relates to cosmetic compositions, and more

  especially those intended for the makeup of keratin materials. BACKGROUND It is known to incorporate diffractive pigments into make-up compositions in order to provide an iridescent appearance or a light-decomposing effect which induces a change of color as a function of the angle of incidence of the light. or observation. It is known to introduce in the makeup compositions diffusing pigments to produce colors by a phenomenon of absorption of light by specific chromophores. However, the intensity of the color produced by these compositions may be insufficient to lead to a completely satisfactory result. The multilayer interference pigments, comprising a stack of 15 layers whose refractive indexes and thicknesses are suitably chosen in order to generate a color by an interference phenomenon, make it possible to produce a greater intensity of color than the diffusing pigments above. . To the knowledge of the inventor, in commercially available compositions, with the exception of powders, these multilayer interference pigments are employed at a mass concentration of not more than 5%. It is also known by CHRYSALIDE eyeshadow brand LANCAME to confer both coverage and color intensity using a makeup involving a first act of depositing on the keratin materials a base layer of color a composition containing a diffusing pigment providing coverage and subsequently depositing a composition by means of a multilayer interference pigment with a second gesture on said base layer. Without the base layer, the covering layer is almost invisible because it is not covering and without color. The use of two successive applications complicates makeup and makes packaging more expensive. 2908642 2 Abstract There is a need to benefit from a composition capable of providing coverage and producing a saturated color, in order to be able to obtain in a single gesture a makeup that is both covering and colored. Furthermore, it is desirable to benefit from cosmetic compositions intended for the makeup of keratin materials which present new effects that are likely to attract consumers, without these new effects occurring to the detriment of the quality of the makeup obtained. The invention aims in particular to meet all or part of the needs identified above. According to one of its aspects, the subject of the invention is a cosmetic composition comprising, in a cosmetically acceptable medium, at least one multilayer interference pigment and at least one diffractive pigment, the coverage of the composition being greater than or equal to 25, best 30, the multilayer interference pigment content 15 conferring on the composition in the mass a color which differs from that of the composition after applying a difference AE greater than or equal to 5. The color after application is determined for the purposes of calculation of AE after spreading the composition on a contrast map, as for measuring the coverage. The composition may be anhydrous or aqueous. According to the compositions, the difference zE may be between 5 and 30 for example, especially greater than any integer value in this range. The coverage can be between 30 and 70, especially greater than any integer value in this range, for example greater than or equal to 40. In multilayer interference pigments, the production of color by the interference phenomenon is in competition. with the production of color by the phenomenon of absorption by the surface layer of the pigment. Thus, when the pigment concentration increases sufficiently, the color produced by the interference phenomenon decreases in favor of that produced by absorption. The invention, by exploiting this property, makes it possible to observe a color variation from the composition to the application, which confers a playful aspect to the use. The invention also offers new possibilities for the marketing of cosmetic compositions, allowing to play at the packaging level on this color variation before and after application. The ratio ml / m 2 between the mass content ml of multilayer interference pigment and the content m2 of diffractive pigment ranges, for example, from 0.1 to 1.5. The mass content of multilayer interference pigment may range from 7 to 20%, more preferably 8 to 15%, especially in the case of a non-pulverulent composition, for example liquid or stick. For a powdery composition, free or compacted, the content of multilayer interference pigment is, for example, from 40 to 95%, more preferably 40 to 80%. The color of the composition in the mass may be white, that is to say achromatic in the sense of the CIE. The composition, by weight, may have a whiteness index greater than or equal to 40. The composition may not comprise any other coloring agent other than the multilayer interference pigment (s) and the diffractive pigment (s). The multilayer interference pigment may comprise at least four layers, for example. The multilayer interference pigment may comprise a substrate of a transparent material. The multilayer interference pigment may comprise a substrate made of a more or less rough material, which may make it possible to impart more or less gloss to the composition. The substrate is for example chosen from natural mica, relatively rough, synthetic mica, alumina, silica or glass or metal for a smoother surface. In examples, the composition comprises more than 30% by weight in total. In examples, the composition comprises more than 10% by weight in total. (s). 30 wax (s). filler (s). The composition may comprise two multilayer interference pigments having layers consisting of the same materials, at least one layer of a pigment having a thickness different from a corresponding layer of the other pigment, so as to produce different colors. The subject of the invention is, according to another of its aspects, a non-pulverulent cosmetic composition, for example liquid (at 25 ° C.) or in the form of a stick comprising, in a cosmetically acceptable medium: between 7 and 20%, better 8 to 15% by weight, in total, of one or more multilayer interference pigments, - between 0.1 and 10% by weight, in total, of one or more diffractive pigments. The total content of diffractive pigment (s) may range from 1 to 7%. The subject of the invention is, according to another of its aspects, a powdery cosmetic composition (at 25 C) comprising, in a cosmetically acceptable medium: between 40 and 95%, better 50 and 80%, for example between 55 and 65% by weight, in total, of one or more multilayer interference pigments, - between 0.1 and 60% by mass, in total, of one or more diffracting pigments. The composition may comprise between 1 and 50% by weight of diffractive pigment (s).

  According to another of its aspects, the subject of the invention is also a packaging unit comprising: a composition as defined above; means for informing the user of the color of the composition after application to keratin materials (lips, skin, eyelashes, eyebrows, nails, hair). It may be for example an ink or varnish printing, a thin layer of composition or a molding or overmolding of a material incorporating the multilayer interference or pigments. Measurement of Coverage Liquid Compositions (at 25 ° C) Liquid composition is understood to mean a composition whose viscosity can be measured. A liquid composition can flow under the effect of its own weight. The coverage of the compositions is measured at a finite thickness of 50 m, the liquid compositions being, for example, compositions for application to the lips, in particular liquid lipsticks, liquid lip glosses and liquid lip balms, and nail polishes. , eye shadows, liquid foundations, mascaras and other liquid make-up products not intended to be applied to the lips. The composition is spread on matt black and matt white contrast cards, for example LENETA Form WP1 for the matte black card and LENETA 1A for the matte white card. The application can be performed with an automatic spreader. The measurements are carried out on the compositions thus spread. Solid compositions (at 25 C). Solid compositions are those whose viscosity can not be measured. They may be cast or powdered compositions in the form of free or compact powders. a) For powdery solid compositions, free or compacted, the composition is applied using the same contrast cards as above, covered with a transparent tape, slightly rough, for example brand BLENDERM 3M company and reference 15025, glued by the adhesive side on the contrast cards. The composition is deposited on the adhesive tape so as to obtain a homogeneous deposition of 0.5 mg / cm 2 0.02 mg / em 2. It is possible to use for the deposit a sponge loaded with the composition and mounted on a disintegrating device that makes predefined movements to the sponge. The sponge is for example a disposable sponge type LANCAME Photogenic, used on the pink side. b) The stick compositions are melted, for example at 90 ° C., then spread with a thickness of 50 m in the liquid state on matt black and matt white contrast cards, for example with the same references as above, no covered with BLENDERM. The spreading bar is maintained at the same temperature as the composition, so as to avoid thermal shock. 2908642 6 Measurements and calculations Reflectance spectra are acquired using a MINOLTA 3700-d spectrocolorimeter (diffuse measurement geometry / 8 and observation D65 / 10, specular component excluded mode, small aperture (CREISS)) on the backgrounds black and white, the 5 contrast cards being optionally covered with BLENDERM as indicated above. The spectra are expressed in colorimetric coordinates in the CIELab76 space within the meaning of the International Commission on Illumination according to Recommendation 15: 2004. The contrast ratio, or coverage, is calculated by averaging Y on a black background, divided by the average value of Y on a white background, multiplied by 100. Measurement of the composition in the mass The color in the mass is measured after filling a container 15 having a depth sufficiently large to be able to consider an infinite product thickness in view of the measurement, for example a depth of 3 mm or more. The coordinates L *, a * and b * are measured with a spectrocolorimeter, for example a MINOLTA CM-2002 mark (D65 / 10, specular component mode excluded). Color measurement after application The color is measured on the dark background of the contrast card, the composition being spread as for the coverage measurement as detailed above but with a thickness of 150 m instead of 50 gm for liquid compositions and non-pulverulent solid compositions, in particular as a stick. The difference AE is calculated as follows: L \ E ((* l2 + * * 2 * Z l / 2 ù \ a in the mass ~ k afterapplicatin) `u in the mass ùb afterapplicatin) + r \ I $ cdansla mass ù ~ afterapplicatin) Whiteness Index Measurement The whiteness index is calculated from the infinite-thickness color measurements and ASTM E313-05. Multilayer interference pigment 2908642 7 The term "multilayer interference pigment" denotes a pigment capable of producing a color by a phenomenon of interference between the light rays reflected by a plurality of superimposed layers of different refractive indices, in particular a succession of high layers. and low refractive indices. All multilayer interference pigments can be envisaged. The color produced by the multilayer interference pigment may be arbitrary, for example being of dominant wavelength between 580 and 650 nm or not. The composition may comprise a single multilayer interference pigment or a plurality of multilayer interference pigments having different dominant wavelengths. The multi-layer interference pigment may comprise a substrate (also called a core or core) covered on at least one face with one or more layers of materials and thicknesses chosen so that a color is produced by interference. Interferential pigment layers may or may not surround the substrate, which may or may not be flattened. The substrate may comprise natural mica, synthetic mica, glass, alumina, silica, or any metal, alloy or metal oxide. The nature of the substrate may be chosen according to the desired gloss. For example, for a very bright rendering, a glass or metal substrate may be preferred. The color produced by the multilayer interference pigment may not be of dominant wavelength between 580 and 650 nm. The interference pigment may comprise more than four layers of different refractive indices. The particle size of the multilayer interference pigment, given by the average particle size at half of the population, also called D50, ranges, for example, from 1 μm to 2000 μm, better still from 5 μm to 2000 μm. The proportion of multilayer interference pigment is, for example, greater than 7% and ranges, for example, from 7 to 20% for a non-pulverulent, liquid or cast composition, for example as a stick and from 40 to 95% for a powdery composition, free or compacted. The coverage of the composition may be due mainly to the multilayer interference pigment content. Alternatively, at least one diffusing pigment and / or fillers can provide coverage. Nacres are examples of multilayer interference pigments which may be suitable. Nacres By mother-of-pearl, it is necessary to understand colored particles of any shape, whether iridescent or not, in particular produced by certain molluscs in their shell or else synthesized and which exhibit a color effect by optical interference. Examples of pearlescent agents include pearlescent pigments such as iron oxide coated titanium mica, bismuth oxychloride coated mica, titanium mica coated with chromium oxide, titanium mica covered with an organic dye in particular as well as pearlescent pigments based on bismuth oxychloride. It may also be mica particles on the surface of which are superimposed at least two successive layers of metal oxides and / or organic dyestuffs. The nacres may have a yellow, pink, red, bronze, orange, brown, gold and / or copper color or reflection. By way of illustration of pearlescent agents which may be introduced as multilayer interference pigment, mention may be made of gold-colored pearlescent agents marketed by ENGELHARD under the name of Brillant gold 20 212G (Timica), Gold 222C (Cloisonne), Sparkle gold (Timica), Gold 4504 (Chromalite) and Monarch gold 233X (Cloisonne); bronze nacres sold especially by the company Merck under the names Bronze Fine (17384) (Colorona) and Bronze (17353) 20 (Colorona) and by Engelhard under the name Super Bronze (Cloisonne); orange nacres sold especially by the company Engelhard under the name Orange 363C (Cloisonne) and Orange MCR 101 (Cosmica) and by the company Merck under the name Passion Orange (Colorona) and Matte Orange (17449) (Microna); brown-colored pearlescent agents marketed by the company Engelhard under the name Nu-antique copper 340XB (Cloisonne) and Brown CL4509 (Chromalite); nacres with a copper sheen sold especially by Engelhard under the name Copper 340A (Timica); the nacres with a red glint sold especially by MERCK under the name Sienna fine (17386) (Colorona); nacres with a yellow glint sold especially by ENGELHARD under the name Yellow (4502) (Chromalite); the red-colored pearlescent agents with a gold glint sold especially by ENGELHARD under the name Sunstone G012 (Gemtone); pink nacres sold especially by the company Engelhard under the name Tan opal G005 (Gemtone); black nacres with gold glints sold by the company Engelhard under the name Nu antique bronze 240 AB (Timica), the blue nacres sold especially by Merck under the name Matte Blue (17433) 5 (Microna), the white nacres to silvery reflection sold especially by the company Merck under the name Xirona Silver and the golden-green orange-colored mother-of-pearl sold by Merck under the name Indian Summer (Xirona) and their mixtures. Multilayer interference pigments having magnetic properties are, for example, those marketed under the trade names COLORONA BLACKSTAR BLUE, COLORONA BLACKSTAR GREEN, COLORONA BLACKSTAR GOLD, COLORONA BLACKSTAR RED, CLOISONNE NU ANTIQUE SUPER GREEN, MICRONA MATTE BLACK (17437), MICA BLACK ( 17260), COLORONA PATINA SILVER (17289) and COLORONA PATINA GOLD (117288) from the company MERCK, or FLAMENCO TWILIGHT RED, FLAMENCO TWILIGHT GREEN, FLAMENCO TWILIGHT GOLD, FLAMENCO TWILIGHT BLUE, TIMICA NU ANTIQUE SILVER 110 AB, TIMICA NU ANTIQUE GOLD 212 GB, TIMICA NU-ANTIQUE COPPER 340 AB, TIMICA NU ANTIQUE BRONZE 240 AB, ANTIQUE CLOISONNE GREEN NU 828 CB, CLOISONNE NU ANTIQUE BLUE 20 626 CB, GEMTONE MOONSTONE G 004, ANTIQUE CLOISONNE NU RED 424 CB, CHROMA-LITE BLACK (4498), NARROW RED ANTIQUE CLOISONNE FLAMBE (code 440 XB), NARROW ANTIQUE BRONZE CLOISONNE (240 XB), NARROW ANTIQUE GOLD CLOISONNE (222 CB) and NARROW ANTIQUE CLOISONNE COPPER (340 XB) a company ENGELHARD. The multilayer interference pigment may be further selected from interferential reflective particles. Interferential Reflective Particles These particles may be chosen from particles with a synthetic substrate 30 at least partially coated with at least one layer of at least one metal oxide, selected for example from titanium oxides, in particular TiO 2, iron oxides in particular Fe 2 O 3, of tin, chromium, barium sulfate and the following materials: MgF 2, CrF 3, ZnS, ZnSe, SiO 2, Al 2 O 3, MgO, Y 2 O 3, SeO 3, SiO, HfO 2, ZrO 2, CeO 2, Nb 2 O 5, Ta 2 O 5, MoS 2 and their mixtures or alloys. By way of example of such particles, mention may be made, for example, of particles comprising a synthetic mica substrate coated with titanium dioxide, or coated glass particles of either brown iron oxide, titanium oxide, titanium dioxide or tin oxide or a mixture thereof such as those sold under the trade name REFLECKS by ENGELHARD. The multilayer interference pigment may be a goniochromatic pigment. Goniochromatic Pigment For the purposes of the present invention, the term "goniochromatic pigment" denotes a pigment which makes it possible, when the composition is spread on a support, to obtain a color path in the plane a * b * of the CIE 1976 color space. corresponds to a variation Dh of the hue angle h of at least 20 when the angle of observation is varied from normal between 0 and 80, for an angle of incidence of the light of 45. The color path can be measured, for example, by means of an INSTRUMENT SYSTEMS brand spectrogoniorflectometer and reference GON 360 GONIOMETER, after the composition has been spread in the fluid state with a thickness of 300 m by means of a automatic spreader on an ERICHSEN brand contrast card and Typ 24/5, the measurement being made on the black background of the card. The goniochromatic pigment may be selected from, for example, interfering multilayer structures and liquid crystal coloring agents. In the case of a multilayer structure, this may comprise for example at least two layers, each layer being made for example from at least one material selected from the group consisting of the following materials: MgF2, CeF3, ZnS , ZnSe, Si, SiO2, Ge, Te, Fe2O3, Pt, Va, Al2O3, MgO, Y2O3, 5203, SiO, HfO2, ZrO2, CeO2, Nb2O5, Ta2O5, TiO2, Ag, Al, Au, Cu, Rb, Ti, Ta, W, Zn, MoS2, cryolite, alloys, polymers and their combinations. The multilayer structure may or may not have, with respect to a central layer, a symmetry at the chemical nature of the stacked layers. Depending on the thickness and nature of the different layers, different effects are obtained. Examples of symmetrical interferential multilayer structures are for example the following structures: Fe 2 O 3 / SiO 2 / Fe 2 O 3 / SiO 2 / Fe 2 O 3, a pigment having this structure being marketed under the name SICOPEARL by the company BASF; MoS2 / SiO2 / mica-oxide / SiO2 / MoS2; Fe 2 O 3 / SiO 2 / mica-oxide / SiO 2 / Fe 2 O 3; TiO 2 / SiO 2 / TiO 2 and TiO 2 / Al 2 O 3 / TiO 2, pigments having these structures being sold under the name XIRONA by the company Merck (Darmstadt). The liquid crystal coloring agents comprise, for example, silicones or cellulose ethers onto which mesomorphic groups are grafted. As liquid crystal goniochromatic particles, it is possible, for example, to use those sold by CHENIX as well as those marketed under the name HELICONE HC by WACKER. As goniochromatic pigment, it is also possible to use certain nacres, pigments with effects on synthetic substrate, in particular substrate type alumina, silica, borosilicate, iron oxide, aluminum, or interference flakes from a polyterephthalate film. The material may further comprise dispersed goniochromatic fibers. Such fibers may have a length of less than 80 m for example. Diffractive Pigment For the purposes of the present invention, the term "diffractive pigment" denotes a pigment capable of producing a color variation according to the angle of observation when illuminated by white light, because of the presence of a structure which diffracts the light. Such a pigment is still sometimes called a holographic or rainbow pigment. A diffractive pigment may comprise a diffraction grating, capable for example of diffracting in a defined direction an incident monochromatic light ray. The diffraction grating may comprise a periodic pattern, in particular a line, the distance between two adjacent patterns being of the same order of magnitude as the wavelength of the incident light. When the incident light is polychromatic, the diffraction grating will separate the different spectral components of the light and produce a rainbow effect. Reference may be made to the structure of the diffracting pigments in the article Pigments Exhibiting Diffractive Effects by Alberto Argoitia and Mati Witzman, 2002, Society of Vacuum Coaters, 45th Annual Technical Conference, Proceedings 2002, the contents of which are incorporated by reference. The diffractive pigment may be made with patterns having different profiles, in particular triangular, symmetrical or not, in crenellations, of constant width or not, sinusoidal, stepwise. The spatial frequency of the network and the depth of the patterns will be chosen according to the degree of separation of the different orders desired. The frequency may vary for example between 500 and 3000 lines per mm. Preferably, the particles of the diffractive pigment each have a flattened shape, and in particular are platelet-shaped. The same pigment particle may comprise two crossed diffraction gratings, perpendicular or not, of the same linearization or not. The diffractive pigment may have a multilayer structure having a layer of a reflective material, covered at least on one side with a layer of a dielectric material. The latter can impart better rigidity and durability to the diffractive pigment. The dielectric material may then be selected from, for example, the following materials: MgF 2, SiO 2, Al 2 O 3, AlF 3, CeF 3, LaF 3, NdF 3, SmF 2, BaF 2, CaF 2, LiF and their combinations. The multilayer interference pigment and the diffractive pigment may have a substrate in the same material. The reflective material may be chosen for example from metals and their alloys and also from non-metallic reflective materials. Among the metals that can be used are Al, Ag, Cu, Au, Pt, Sn, Ti, Pd, Ni, Co, Rd, Nb, Cr and their materials, combinations or alloys. Such a reflective material may alone constitute the diffractive pigment which will then be monolayer. Alternatively, the diffractive pigment may comprise a multilayer structure comprising a substrate (also called core or core) of a dielectric material covered with a reflective layer at least on one side, or even completely encapsulating the substrate. A layer of a dielectric material may also cover the reflective layer (s). The dielectric material used is then preferably inorganic, and may be chosen for example from metal fluorides, metal oxides, metal sulfides, metal nitrides, metal carbides and their combinations. The dielectric material may be in the crystalline, semicrystalline or amorphous state. The dielectric material, in this configuration, may for example be selected from the following materials: MgF 2, SiO 2, SiO 2, Al 2 O 3, TiO 2, WO, AlN, BN, B 4 C, WC, TiC, TiN, N 4 Si 3, ZnS, glass particles , diamond-like carbons and their combinations. As a variant, the diffractive pigment may be composed of a preformed dielectric or ceramic material such as a natural lamella mineral, for example peroskovite mica or talc, or synthetic lamellae formed from glass, alumina, SiO2, carbon, iron oxide / mica, mica coated with BN, BC, graphite, bismuth oxychloride, and combinations thereof. In place of a layer of dielectric material, other materials improving the mechanical properties may be suitable. Such materials may include silicone, metal silicides, semiconductor materials formed from Group III, IV and V elements, metals having a centered cubic crystal structure, cermet compositions or materials, glasses. semiconductors, and their varied associations. The diffractive pigment used may in particular be chosen from those described in US patent application US 2003/0031870 published on February 13, 2003. A diffractive pigment may comprise, for example, the following structure: MgF 2 / Al / MgF 2, a diffractive pigment having this structure being marketed under the name SPECTRAFLAIR 1400Pigment Silver by the company FLEX PRODUCTS, 25 or SPECTRAFLAIR 1400 Pigment Silver FG. The proportion by weight of the MgF 2 can be between 80 and 95% of the total weight of the pigment. Other diffractive pigments are marketed under the names Metal Prismatic by the company ECKART. Other possible structures are Fe / Al / Fe or Al / Fe / Al. The size of the diffractive pigment may be, for example, between 5 and 200 μm, more preferably between 5 and 100 μm, for example between 5 and 30 μm. The thickness of the diffractive pigment particles may be less than or equal to 3 m, more preferably 2 m, for example of the order of 1 m. Cosmetically acceptable medium A cosmetically acceptable medium designates a non-toxic medium that can be applied to keratin materials of human beings. The cosmetically acceptable medium will be adapted to the nature of the support to which the composition is to be applied and to the form in which the composition is to be packaged. The composition according to the invention may comprise an aqueous medium and / or a fatty phase, be anhydrous or not. Aqueous or Fatty Phase The composition may comprise water or a mixture of water and hydrophilic organic solvents such as alcohols and in particular lower linear or branched monoalcohols having from 2 to 5 carbon atoms, such as ethanol, isopropanol or n-propanol, polyols such as glycerine, diglycerine, propylene glycol, sorbitol, penthylene glycol, polyethylene glycols. The hydrophilic phase may further contain C 2 ethers and C 2 -C 4 hydrophilic aldehydes. The water or the mixture of water and hydrophilic organic solvents may be present in the composition according to the invention in a content ranging from 0% to 90%, especially 0.1% to 90% by weight, relative to the weight total of the composition, and preferably from 0% to 60% by weight, especially 0.1% to 60% by weight. The composition may also comprise a fatty phase, in particular constituted by liquid fats at 25 ° C. and optionally solid fatty substances at ambient temperature, such as waxes, pasty fatty substances, gums and mixtures thereof. As liquid fats which are liquid at room temperature and are often referred to as oils which may be used in the invention, mention may be made, inter alia, of vegetable hydrocarbon-based oils such as liquid triglycerides of fatty acids of 4 to 10 carbon atoms, such as the triglycerides of heptanoic or octanoic acids, or sunflower, corn, soya, grape seed, sesame, apricot, macadamia, castor oil, avocado, caprylic / capric acid triglycerides, jojoba oil, shea butter; linear or branched hydrocarbons of mineral or synthetic origin, such as paraffin oils and, in particular, C 8 -C 16 isoparaffins such as isododecane, isodecane, isohexadecane, petroleum jelly, polydecenes, polyisobutene, hydrogenated such as Parleam, squalane; esters and synthetic ethers, in particular of fatty acids, for example purcellin oil, isopropyl myristate, 2-ethylhexyl palmitate, octyl-2-dodecyl stearate, erucate octyl-2-dodecyl, isostearyl isostearate; hydroxylated esters such as isostearyl lactate, octyl hydroxystearate, octyldodecyl hydroxystearate, diisostearyl malate, triisocetyl citrate, heptanoates, octanoates, decanoates of fatty alcohols; polyol esters such as propylene glycol dioctanoate, neopentyl glycol diheptanoate, diethylene glycol diisononanoate; and pentaerythritol esters; fatty alcohols having 12 to 26 carbon atoms such as octyldodecanol, 2-butyloctanol, 2-hexyldecanol, 2-undecylpentadecanol, oleyl alcohol; partially hydrocarbon and / or silicone fluorinated oils; silicone oils, such as volatile or nonvolatile polymethylsiloxanes (PDMS), linear or cyclic, liquid or pasty at room temperature, such as cyclomethicones, dimethicones, optionally containing a phenyl group, such as phenyl trimethicones, phenyltrimethylsiloxydiphenylsiloxanes or diphenylmethyldimethyltrisiloxanes; diphenyl dimethicones, phenyl dimethicones, polymethylphenyl siloxanes; their mixtures. These oils can be present in a content ranging from 0.01 to 90% with respect to the total weight of the composition. The composition according to the invention may also comprise one or more physiologically acceptable organic solvents. This or these solvents, which may be lipophilic, may be present in a content ranging from 0 to 90%, better still from 0 to 60% by weight, relative to the total weight of the composition, and still more preferably from 0.1 to 30%. . The medium may comprise a liquid organic phase in which water is dispersed or emulsified. The composition may also have a continuous fat phase, which may contain less than 5% water, especially less than 1% water relative to its total weight and in particular be in anhydrous form. Film-forming agent The medium may comprise a film-forming agent, in particular a film-forming polymer. A film-forming agent is understood to mean an agent capable of forming, by itself or in the presence of an auxiliary film-forming agent, a film which is macroscopically continuous and adheres to the keratin materials, and preferably a cohesive film, and better still a film whose cohesion and the mechanical properties are such that said film can be isolatable and manipulable in isolation, for example when said film is made by casting on a non-stick surface such as a Teflon or silicone surface. The composition may comprise an aqueous phase and the film-forming polymer may be present in this aqueous phase. This may be a polymer in dispersion or in solution. The composition may comprise an oily phase and the film-forming polymer may be present in this oily phase. The polymer may then be in dispersion or in solution. Among the film-forming polymers that may be used, mention may be made of synthetic polymers, of radical type or of polycondensate type, polymers of natural origin, and their mixtures. The radical-type film-forming polymers may in particular be polymers, or copolymers, vinylic polymers, in particular acrylic polymers. Among the film-forming polycondensates, mention may be made of polyurethanes, polyesters, polyester amides, polyamides, and epoxy ester resins, polyureas. The polyesters can be obtained, in known manner, by polycondensation of dicarboxylic acids with polyols, especially diols. The polyester amides can be obtained in a similar manner to the polyesters by polycondensation of diacids with diamines or amino alcohols. Examples of liposoluble film-forming polymers that may be mentioned are vinyl ester copolymers (the vinyl group being directly connected to the oxygen atom of the ester group and the vinyl ester having a linear saturated hydrocarbon radical). 18 or branched, from 1 to 19 carbon atoms, linked to the carbonyl ester group) and at least one other monomer which may be a vinyl ester (different from the vinyl ester already present), an α-olefin (having from 8 to 28 carbon atoms), an alkyl vinyl ether (the alkyl group of which contains from 2 to 18 carbon atoms), or an allyl or methallyl ester (having a linear or branched, saturated hydrocarbon radical of from 1 to 19 carbon atoms). carbon, bonded to the carbonyl ester group). These copolymers may be cross-linked with crosslinking agents which may be of the vinyl type, or of the allyl or methallyl type, such as tetraallyloxyethane, divinylbenzene, divinyl octanedioate, divinyl dodecanedioate, and octadecanedioate. of divinyl. Examples of such copolymers include copolymers: vinyl acetate / allyl stearate, vinyl acetate / vinyl laurate, vinyl acetate / vinyl stearate, vinyl acetate / octadecene, vinyl acetate / octadecylvinylether vinyl propionate / allyl laurate, vinyl propionate / vinyl laurate, vinyl stearate / octadecene-1, vinyl acetate / dodecene-1, vinyl stearate / ethyl vinyl ether, vinyl propionate / cetyl vinyl ether, stearate vinyl acetate / allyl acetate, 2,2-dimethyl-2-vinyl octanoate / vinyl laurate, 2,2-dimethyl-2,2-allyl pentanoate / vinyl laurate, dimethyl vinyl propionate / vinyl stearate, allyl dimethyl propionate / vinyl stearate, vinyl propionate / vinyl stearate, crosslinked with 0.2% divinyl benzene, vinyl dimethyl propionate / vinyl laurate, crosslinked with 0.2% divinyl benzene, vinyl acetate / octadecyl vinyl ether, cross-linked with 0.2% of head Raallyloxyethane, vinyl acetate / allyl stearate, crosslinked with 0.2% divinyl benzene, vinyl acetate / octadecene-1 cross-linked with 0.2% divinyl benzene and allyl propionate / allyl stearate crosslinked with 0 2% divinyl benzene. The film-forming polymer may be further selected from silicone resins, generally soluble or swellable in silicone oils, which are crosslinked polyorganosiloxane polymers. The film-forming polymer may also be present in the composition in the form of particles dispersed in an aqueous phase or in a non-aqueous solvent phase, generally known as a latex or pseudolatex. The techniques for preparing these dispersions are well known to those skilled in the art. The composition according to the invention may comprise a plasticizer promoting the formation of a film with the film-forming polymer. Such a plasticizer may be chosen from all compounds known to those skilled in the art as being capable of performing the desired function. Of course, this list of polymers is not exhaustive. Other coloring agents The composition may comprise one or more diffusing pigments, generating a color by an absorption phenomenon, in a proportion that makes it possible to preserve the interference phenomenon responsible for the color of the composition when applied to the keratin materials . Various diffusing pigments may be envisaged, for example chosen from among the organic lakes or pigments selected in particular from the materials below and their mixtures: cochineal carmine, organic pigments of azo, anthraquinone, indigo, xanthene dyes, pyrene, quinoline, triphenylmethane, fluoran, organic lakes or insoluble salts of sodium, potassium, calcium, barium, aluminum, zirconium, strontium, titanium, acid dyes such as azo dyes , anthraquinone, indigo, xanthene, pyrene, quinoline, triphenylmethane, fluorane, these dyes may include at least one carboxylic or sulfonic acid group. Among the organic pigments, there may be mentioned those known under the following denominations: D & C Blue No. 4, D & C Brown No. 1, D & C Green No. 5, D & C Green No. 6, D & C Orange No. 4, D & C Orange No. 5, D & C Orange No. 10 , D & C Orange # 25 11, D & C Red # 6, D & C Red # 7, D & C Red # 17, D & C Red # 21, D & C Red # 22, D & C Red # 27, D & C Red # 28, D & C Red # 30, D & C Red n 31, D & C Red No. 33, D & C Red No. 34, D & C Red No. 36, D & C Violet No. 2, D & C Yellow No. 7, D & C Yellow No. 8, D & C Yellow No. 10, D & C Yellow No. 11, FD & C Blue No. 1, FD & C Green No. 3, FD & C Red No. 40, FD & C Yellow No. 5, FD & C Yellow No. 6. The lacquer may be supported by an organic carrier such as rosin or aluminum benzoate, for example. Among the organic lakes, mention may be made especially of those known under the following denominations: D & C Red N Aluminum Lake, D & C Red N Aluminum Lake, D & C Red N Aluminum Lake, D & C Red Aluminum Lake, D & C Red N 6 Barium lake, D & C Red # 6 Barium / Strontium lake, D & C Red # 6 Strontium lake, D & C 5 Red # 6 Potassium lake, D & C Red # 7 Aluminum lake, D & C Red # 7 Barium lake, D & C Red # 7 Calcium lake, D & C Red n 7 Calcium / Strontium lake, D & C Red n 7 Zirconium lake, D & C Red n 8 Sodium lake, D & C Red n 9 Aluminum lake, D & C Red n 9 Barium lake, D & C Red n 9 Barium / Strontium lake, D & C Red n 9 Zirconium Lake, D & C Red n 10 Sodium lake, D & C Red n 19 Aluminum lake, D & C Red n 19 Barium 10 lake, D & C Red n 19 Zirconium lake, D & C Red n 21 Aluminum lake, D & C Red n 21 Zirconium lake, D & C Red n 22 Aluminum lake, D & C Red n 27 Aluminum lake, D & C Red n 27 Aluminum / Titanium / Zirconium lake, D & C Red n 27 Barium lake, D & C Red n 27 Calcium lake, D & C Red # 27 Zirconium lake, D & C Red # 28 Aluminum lake, D & C Red # 30 lake, D & C Red # 31 Calcium lake, D & C Red # 33 Aluminum lake, 15 D & C Red # 34 Calcium lake, D & C Red # 36 lake, D & C Red # 40 Aluminum lake, D & C Blue n 1 Aluminum lake, D & C Green n 3 Aluminum lake, D & C Orange n 4 Aluminum lake, D & C Orange n 5 Aluminum lake, D & C Orange n 5 Zirconium lake, D & C Orange n 10 Aluminum lake, D & C Orange n 17 Barium Lake, D & C Yellow # 5 Aluminum Lake, D & C Yellow # 5 Zirconium Lake, D & C Yellow # 6 Aluminum Lake, 20 D & C Yellow # 7 Zirconium Lake, D & C Yellow # 10 Aluminum Lake, FD & C Blue # 1 Aluminum Lake, FD & C Red # 4 Aluminum Lake, FD & C Red No. 40 Aluminum Lake, FD & C Yellow No. 5 Aluminum Lake, FD & C Yellow No. 6 Aluminum Lake. The chemical materials corresponding to each of the organic dyestuffs mentioned above are mentioned in International Cosmetic Ingredient Dictionary and Handbook, Edition 1997, pages 371 to 386 and 524 to 528, published by The Cosmetic, Toiletry, and Fragrance Association, of which the content is incorporated in this application by reference. The diffusing pigment may be a composite pigment having a core at least partially coated with a bark. Such a composite pigment may be composed in particular of particles having an inorganic core and at least one at least partial coating of at least one organic dyestuff. At least one binder may advantageously contribute to the attachment of the organic dyestuff to the inorganic core. The composite pigment particles may have various shapes. These particles may in particular be platelet-shaped or globular, in particular spherical, and may be hollow or solid. Platelet-shaped means particles whose ratio of the largest dimension to the thickness is greater than or equal to 5. A composite pigment may have, for example, a specific surface area of between 1 and 1000 m 2 / g, especially between 10 and 600 m2 / g, and in particular between 20 and 400 m2 / g. The specific surface is the value measured by the BET method. The mass proportion of the core may exceed 50% based on the total weight of the composite pigment, for example from 50% to 70%, for example from 60% to 70%. The coloring agent may still be a dye. It may be a dye of plant, animal or mineral origin, in particular of vegetable or mineral origin, in particular of plant origin. This dye may be of a non-synthetic nature. The dye may be a water-soluble or fat-soluble natural dye. As an illustration of the natural water-soluble coloring agents that can be used according to the invention, mention may be made of caramel, beetroot juice and carmine, betanin (beet), copper chlorophyllin, blue of 20%. methylene, anthocyanins (enocianin, black carrot, hibiscus, elderberry) and riboflavin. By way of illustration of the fat-soluble natural coloring agents which can be used according to the invention, mention may be made in particular of Sudan red, β-carotene, carotenoids, lycopene, palm oil, Sudan brown, quinolinic yellow xanthophylls (capsanthin, capsorubin, lutein), and curcumin. As other natural dyes, there may be mentioned more particularly anthocyanins of flowers or fruits or their derivatives, flavonoids and tannins extracted from native or fermented plants, juglone, lawsone, fermented soy extracts, seaweed extracts, fungi, microorganisms, unsubstituted Flavylium salts in position 3 as described in patent EP 1 172 091, extracts of Gesneria Fulgens, Blechum Procerum, Saxifraga and pigments obtainable by extraction by a organic or hydro-organic solvent of a micromycete culture medium of the Monascus Monascus type. Examples of synthetic dyes that may be mentioned are synthetic liposoluble dyes such as, for example, DC Red 17, DC Red 21, DC Red 27, DC Green 6, DC Yellow II, DC Violet 2. and Orange DC 5. Examples of synthetic water-soluble dyes include FDC 5 Red 4, DC Red 6, DC Red 22, DC Red 28, DC Red 30, DC Red 33, DC Orange 4, DC Yellow 5, DC Yellow 6, DC Yellow 8, FDC Green 3, DC Green 5 and FDC Blue 1. Charges The cosmetic composition may comprise fillers. By fillers are meant any particles of any form insoluble in the medium of the composition, regardless of the temperature at which the composition is made. These fillers can serve in particular to modify the rheology or the texture of the composition. As an example of fillers, mention may be made, inter alia, of talc, mica, silica, kaolin, and polyamide powders (Nylon or Orgasol from Atochem). The content of charges will be chosen so as not to unduly hamper the desired result. Active ingredients and other compounds The cosmetic composition may also contain one or more cosmetic, dermatological, hygienic or pharmaceutical active ingredients. As cosmetic, dermatological, hygienic or pharmaceutical active agents that can be used in the compositions of the invention, mention may be made of moisturizers (polyol as glycerol), vitamins (C, A, E, F, B, or PP), essential fatty acids, essential oils, ceramides, sphingolipids, liposoluble sunscreens or in the form of nanoparticles, specific skin treatment active agents (protective agents, anti-bacterial agents, anti-wrinkle agents, etc.). These active agents can be used for example at concentrations of 0.001 to 15% relative to the total weight of the composition. The cosmetic composition may also contain ingredients commonly used in cosmetics, such as, for example, thickeners, surfactants, trace elements, moisturizers, softeners, sequestering agents, perfumes, alkalizing or acidifying agents, preservatives, antioxidants, UV filters, or mixtures thereof. The cosmetic composition may furthermore comprise, depending on the type of application envisaged, the constituents conventionally used in the fields

  considered, which are present in an amount appropriate to the desired dosage form.

Galenic Forms The cosmetic composition may be in any galenical form normally used for topical application and in particular in anhydrous or non-anhydrous form, in solid form, free or compacted powdery form, cast, for example as a stick, liquid, an oily or aqueous solution, an oily or aqueous gel, an oil-in-water or water-in-oil emulsion, a multiple emulsion, an oil dispersion in water by means of vesicles located at the oil / water interface or spray. By anhydrous composition is meant a composition having less than 5% by weight of water, better less than 3%, or even less than 1%. An anhydrous composition may not have intentionally added water during the preparation of the composition. The composition may especially be in the form of a stick. The cosmetic composition may constitute, among other make-up products, a stick or liquid lipstick, a liquid lip gloss, a lipstick paste, a blush, a foundation, a product of outline of eyes, an eyeliner, a mascara, a nail polish, an eye shadow, a makeup base, and more generally any body makeup product or hair. The composition of the invention can be obtained according to the preparation methods conventionally used in cosmetics.

Packaging and Methods of Application The composition may be packaged in any receptacle or on any support provided for this purpose. The composition may be applied using an applicator, flocked or not, such as a foam, tip, brush, felt, spatula, sinter, brush, comb, woven or nonwoven. The application may also be carried out with the finger or by directly depositing the composition on the support to be made up, for example by friction in the case of a stick or by spraying or projection using a piezoelectric device or by transfer of a layer of composition previously deposited on an intermediate support. The composition may, if appropriate, be applied as a base coat coated with a layer of another composition (top coat), intended for example to impart gloss, or as a coating layer on a layer of another composition, or even between a base layer and a coating layer. The composition may be packaged in a conditioning device which reveals the color of the composition in the mass.

It may be a container having an at least partially transparent body and / or a packaging device comprising an at least partially transparent closure member. The composition may be packaged in a device which makes it possible to see both the color of the composition in the mass and the color of the composition after application to keratin materials. The composition may also be packaged in a device which comprises means representative of the color revealed on application, for example a deposit of a layer of the composition or of an ink or varnish comprising the same coloring agents as the composition .

The subject of the invention is also a composition thus conditioned. If necessary, the composition may be conditioned with a magnet making it possible to modify the orientation of the multilayer interference pigment particles and / or the reflective particles of the metal-reflecting pigment, when at least one of these pigments has a non-magnetic susceptibility. nothing.

Another aspect of the invention according to another aspect of the invention is a method for presenting a cosmetic composition produced in accordance with the invention, comprising the steps of: lighting at least a first region of a composition sample with diffuse illumination so as to show the color in the mass, - illuminating at least a second region of a composition sample with directional illumination so as to reveal the interferential color. The first and second regions may be different regions of the same composition sample. Alternatively, the first and second regions belong to different samples.

Alternatively, the first and second regions correspond to the same region and the diffuse and directional lighting are applied alternately. The invention further relates, in another of its aspects, a display comprising: - a directional lighting source, - a diffuse lighting source, - a support for exposing at least one sample composition at the diffuse lighting source and at least one composition sample at the directional lighting source.

The invention also relates to a process for making up keratin materials using a composition according to the invention. It may be skin makeup, lips, nails, eyelashes, eyebrows or hair. The present invention also relates to a make-up kit comprising: a first composition according to the invention; a second composition comprising a cosmetically acceptable medium and to be applied under or on the first composition. This second composition is for example intended to improve the behavior of the first composition and / or to change the appearance.

Proposed Examples The proportions indicated are by weight. Example 1: Octyl-2 dodecanol lip gloss Ditertiobutyl 4-hydroxytoluene 0.07 Polybutene (95/5 monoolefins / isoparaffins) (MW: 37 2060) Mixture of isopropyl p-hydroxybenzoates, iso-butyl, 0.6 n -butyl (40/30/30) Pentaerythrityl tetraisisostea 11,33 2908642 27 Tridecyl tri-mellitate 11 2-decyltetradecanoic acid triglyceride (GUERBET 15 C24) Multilayered interferential pigment * 12 Diffractive pigment * * 3 * TIMIRON SILK RED from MERCK ** SPECTRAFLAIR Diffractive Pigment from FLEX PRODUCTS The effect of lip gloss results from the combination of several phenomena. The first is the color rendering to the application which is intense and covering. Added to this is the rainbow effect provided by the diffractive pigment. This eyeshadow has a mass color that is white. Example 2: Tri-decyl tri-mellitate lipstick 11 Liquid lanolin Iso-stearyl malate 12 Acetylated lanolin 10 Triglycerides of lauric / palmitic / cetyl / stearic acids 5 (50/20/10/10) Microcrystalline wax (C20-C60) 3 protected isopropyl lanolate 9 Octyl-2-decanol Phenyl trimethylsiloxy trisiloxane (VISCOSITY: 20 CST -4 MW: 372) Polyethylene wax (MW: 500) 8 Multilayer interference pigment * 10 Diffractive pigment ** 3 * TIMIRON SILK RED from MERCK 10 ** SPECTRAFLAIR Diffractive Pigment from FLEX PRODUCTS The effect produced by this lipstick results from the combination of several phenomena. The first is the color rendering to the application which is intense and covering. Added to this is the rainbow effect provided by the diffractive pigment. This lipstick has a mass color that is white.

Example 3 Blush Triethanolamine 1 Ethylene diamine tetracetic acid, disodium salt, 2H 2 O 0.2 Cross-linked carboxyvinyl homopolymer 0.5 Polyvinylpyrrolidone 0.6 Glycerol 5.75 Deionized water 77.45 1.3 Butylene glycol 2 Silica microsphere (3 m) 1.5 Multilayer interference pigment * 8 Diffractive pigment * * 3 * TIMIRON SILK RED from MERCK ** Diffractive pigment SPECTRAFLAIR from FLEX PRODUCTS 5 The effect produced by this blush results from the combination of several phenomena. The first is the color rendering to the application which is intense and covering. Added to this is the rainbow effect provided by the diffractive pigment. This blush has a mass color that is white.

EXAMPLE 4 Water-Based Nail Polish Tetrasodium Pyophosphate 0.2 Polydimethylsiloxane Methoxy Oxyethylene 0.5 Terminates Aliphatic Polyurethane Blend, N-Methylpyrrolidone, Triethylamine, Water (35 / 8.5 / 2 / 54.5) Glycerol 1 Deionized Water 15 Ethyl Alcohol (96) 2.8 Synthetic Laponite (Mixed Silicate 1.3 Magnesium / Lithium / Sodium) Multilayer Interferential Pigment * 11.2 Differentiating Pigment * * 3 * TIMIRON SILK BLUE from MERCK ** Diffractive Pigment SPECTRAFLAIR of the company FLEX PRODUCTS The effect produced by this nail polish results from the combination of several phenomena. The first is the color rendering to the application which is intense and covering. Added to this is the rainbow effect provided by the diffractive pigment. This nail polish has a mass color that is white.

Example 5: Organic Solvent Based Nail Polish Nitrocellulose 11 N-ethyl o, p-toluenesulfonamide Alkyd resin 10 Isopropanol 4 Multilayered interferential pigment * 10 Diffractive pigment * * 3 Butyl acetate / ethyl acetate 50/50 Qsp 100 * XIRONA SILVER from MERCK ** SPECTRAFLAIR Diffractive Pigment from FLEX PRODUCTS 5 The effect of this nail polish results from the combination of several phenomena. The first is the color rendering to the application which is intense and covering. Added to this is the rainbow effect provided by the diffractive pigment. This nail polish has a mass color that is white.

Example 6: Eyelid powder TERTIOBUTYL 4-HYDROXYANISOLE 0.012 DITERTIOBUTYL 4-HYDROXYTOLUENE 0.012 WHITE VASELINE 1.2 OLEIC ALCOHOL 1.2 LANOLIN LIQUID PROTECTED 0.66 VASELIN OIL 6.516 CASTOR OIL 1.296 ISOPROPYL MYRISTATE 0.864 P- PROPYL HYDROXYBENZOATE 0.24 MIXTURE P-HYDROXYBENZOATES OF 0.6 METHYL, ETHYL, PROPYL, BUTYL ISOBUTYL / PHENOXY-2 ETHANOL Multi-layered interferential pigment * 50.3 MAGNESIUM STEARATE 4 TALC 30.1 Diffractive pigment ** 3 * TIMIRON SILK RED from MERCK ** SPECTRAFLAIR Diffractive Pigment from FLEX PRODUCTS The effect produced by this eyeshadow results from the combination of several phenomena. The first is the color rendering to the application which is intense and covering. Added to this is the rainbow effect provided by the diffractive pigment. This nail polish has a mass color that is white.

EXAMPLE 7 Liquid Eyeshadow DITERTIOBUTYL 4-HYDROXYTOLUENE 0.09 MODIFIED HECTORITY DISTEARYL DIMETHYL 3.74 AMMONIUM ACIDIC TRIGLYCERIDES 6.46 LAURIC / PALMITIC / CETYLIC / STEARIC (50/20/10/10) CARBONATE OF PROPYLENE 1.22 BEAN WAX WHITE 7,77 SHOREA BUTTER PROTECTED 1,7 LIQUID FRACTION OF SHEA BUTTER 0,85 PROTECTED NYLON POWDER 12 10, 4 ISO-DODECANE 32,32 PROPYLENE P-HYDROXYBENZOATE 0, 17 PROTECTED REFINED PARAFFIN 3.88 TALC 10.4 Multilayered Interferential Pigment * 15 Diffractive Pigment * * 3 * TIMIRON SILK RED from MERCK ** SPECTRAFLAIR Diffractive Pigment from FLEX PRODUCTS The effect of this eye shadow results from the association of several phenomena. The first is the color rendering to the application which is intense and covering. Added to this is the rainbow effect provided by the diffractive pigment. This nail polish has a mass color that is white. Of course, the invention is not limited to the examples that have just been given. The expression containing one is synonymous with having at least one and understood between understood inclusive limits.

Claims (31)

  1. Cosmetic composition comprising, in a cosmetically acceptable medium, at least one multilayer interference pigment and at least one diffractive pigment, the coverage of the composition being greater than or equal to 25, better 30, and the content of multilayer interference pigment conferring on the composition in the mass a color which differs from that of the composition after application of a gap AE greater than or equal to 5.   2. Composition according to claim 1, the ratio ml / m2 between the mass content ml multilayer interference pigment and the content m2 diffractive pigment ranging from 0.1 to 1.5.   3. Composition according to claim 1 or 2, the mass content of diffractive pigment ranging from 0.1 to 60.   4. Composition according to any one of the preceding claims, the multilayer interference pigment comprising a substrate of silica, mica or glass, aluine or metal.   5. Composition according to any one of the preceding claims, the diffractive pigment having a multilayer structure.   6. Composition according to claim 1, the multilayer interference pigment and the diffractive pigment having a substrate in the same material. 20   7. Composition according to any one of claims 1 to 7, the composition being anhydrous.   8. Composition according to any one of claims 1 to 7, the composition being aqueous.   9. Composition according to any one of Claims 1 to 8, the composition being non-pulverulent, in particular liquid or in the form of a stick, and the total mass content of multilayer interference pigment ranging from 7 to 20%, better still 8 to 15%. .   10. Composition according to any one of claims 1 to 8, the composition being pulverulent and the total mass content of multilayer interference pigment ranging from 40 to 95%, more preferably 40 to 80%. 30   11. Composition according to any one of claims 1 to 10, the color of the composition in the mass being white. 2908642 32   The composition of claim 11 wherein the bulk composition has a Whiteness Index greater than or equal to 40.   13. Composition according to any one of claims 1 to 12, the composition having no other dyeing agent than the multilayer interference pigment (s) and the diffractive pigment (s).   14. Composition according to any one of claims 1 to 13, the multilayer interference pigment comprising at least four layers.   15. Composition according to any one of claims 1 to 14, the multilayer interference pigment comprising a substrate of a transparent material.   16. Composition according to any one of claims 1 to 15, the multilayer interference pigment comprising a substrate of silica, mica or glass.   17. Composition according to any one of the preceding claims, the color produced by the multilayer interference pigment not having a dominant wavelength between 580 and 650 nm.   18. Composition according to any one of claims 1 to 17, comprising only a single multilayer interference pigment.   19. Composition according to any one of claims 1 to 18, comprising at least two multilayer interference pigments.   20. Composition according to claim 19, the two multilayer interference pigments having layers consisting of the same materials but at least one layer of a pigment having a thickness different from a corresponding layer of the other pigment.   21. A non-pulverulent cosmetic composition comprising, in a cosmetically acceptable medium: between 7 and 20% by weight, in total, of one or more multilayer interference pigments, between 0.1 and 10% by weight, in total, of one or more diffracting pigments.   22. Composition according to claim 21, the composition being in the form of a stick.   23. The composition of claim 21, the composition being liquid. 2908642 33   24. Composition according to one of claims 21 to 23, the total content of multilayer diffractive pigment (s) ranging from 8 to 15%.   25. Composition according to one of claims 21 to 24, the total content of diffractive pigment (s) ranging from 1 to 7%. 5   26. A pulverulent cosmetic composition comprising, in a cosmetically acceptable medium: - between 40 and 95% by weight, in total, of one or more multilayer interference pigments, - between 0.1 and 60% by mass, in total, of one or more diffractive pigments.   27. Composition according to claim 26, the composition comprising between 50 and 80% by weight of pigment (s) diffractant (s).   28. Composition according to claim 26, the composition comprising between 55 and 65% by weight of pigment (s) diffractant (s). 15   29. Composition according to any one of claims 26 to 28, the composition comprising between 1 and 50% by weight of pigment (s) diffractant (s).   30. A process for making up keratin materials, comprising applying to the keratin materials a composition according to any one of claims 1 to 29.   31. Packaging assembly comprising: - a composition as defined in any one of claims 1 to 29, - means for informing the user on the color of the composition after application on keratin materials. 25