FR2902828A1 - EXHAUST LINE OF A DIESEL ENGINE AND METHOD OF DESULFATATION - Google Patents

Abstract

A process for desulfating a NOxTrap (6) from an exhaust line of a diesel engine, said method being for extracting during operation of said engine at least a portion of the sulfur compounds fixed in said NOxTrap, comprising the following steps: - production of a reformate by a reformer device from the engine fuel, - preheating of the NOxTrap by injecting the reformate into the flow (1) of the exhaust gas, at an injection point (5) downstream of the engine is upstream of the NOxTrap, until a predetermined desulfation temperature is reached in said NOxTrap, then- deriving the flow of the exhaust gas from a bypass point (2) of the exhaust line located upstream of the injection point and continuation of reformate injection into the NOxTrap to carry out said desulfation, the richness of the mixture feeding the diesel engine is not affected in this process by the Executing The implementation of the method therefore requires an exhaust line comprising a bypass from the diversion point upstream of the NOxTrap (6) and means, such as a valve (3). to 3-way, to derive (2, 7, 10) the exhaust gas via the bypass, and a reformer (4) that is to say a device that can transform hydrocarbons, such as the diesel engine fuel, into a mixture of reducing gases called reformate, composed mainly of CO, H2 and N2.

Description

.R442. 12GB. 1 2 JS dpt 1 The present invention relates to a line

  exhaust system of a diesel engine and a method of desulphating a NOxTrap of this line, the method being for extracting during operation of the engine at least a portion of the sulfur compounds fixed in said NOxTrap.

  Many motor vehicle diesel engine exhausts can use catalytic devices, commonly known as NOxTrap, capable of trapping nitrogen oxides NOx in the presence of excess oxygen in the exhaust gas, i.e. say in conditions of richness lower than 1, in order to reduce the rate of nitrogen oxide in the exhaust gases from the vehicles. However, sulfur compounds, in particular SOx, originating from the fuel and the lubricating oil, are present in the exhaust gases, and are preferentially adsorbed on the catalytic sites of NOxTrap, blocking them, so that a periodic regeneration of the NOxTrap catalyst, that is to say a SOx purge, generally described as desulfation, is necessary for the NOxTrap to regain its Nox storage activity.

  This regeneration consists in raising the temperature of the NOxTrap above a minimum desulfation temperature of between 400 and 900 degrees, often greater than 550, and in creating wealth conditions above 1, by injecting reducing gases into the atmosphere. the NOxTrap.

  WO 99/00588 discloses a regeneration of raising the temperature of the NOxTrap by operating the engine with a richer mixture than in normal operation. This method has the disadvantage of increasing fuel consumption, of having a negative impact on the operation of the engine and the driving pleasure of the vehicle and can lead to a dilution of the engine. engine oil. Documents EP 1 055 806 and EP 1 106 798 also describe regeneration systems based on the post-injection of fuel, with the same disadvantages. Document US 2005/0000 210 describes a system based on the injection of diesel fuel or reformate after having raised the temperature of the NOxTrap by modifying the richness of the mixture feeding the engine. The documents FR 2 838 770 and DE 199 39 807 describe systems based on the injection of hydrogen upstream of the NOxTrap, which therefore require a specific reservoir of hydrogen.

  The object of the present invention is to provide a method of non-intrusive desulfation vis-à-vis the engine, while minimizing overconsumption of fuel.

  This object is achieved by a process for desulfating a NOxTrap from an exhaust line of a diesel engine, this method being intended for extracting during operation of said engine at least a portion of the sulfur compounds fixed in said NOxTrap, comprising the following steps: - production of a reformate by a reformer device from the engine fuel, - preheating the NOxTrap by injecting the reformate into the flow of the exhaust gas, at an injection point located downstream of the engine and upstream of the NOxTrap, until a predetermined desulfation temperature is reached in said NOxTrap, and then -derivating the flow of the exhaust gas from a bypass point of the exhaust line located in upstream of the injection point and continuation of the injection of reformate in the NOxTrap to achieve the said .R442.12FR.I2 JS dpt 3 desulfation, the richness of the mixture feeding the diesel engine not being affected e in this method by performing the above steps.

  The implementation of the method according to the invention therefore requires an exhaust line comprising a bypass from the diversion point upstream of the NOxTrap and means, such as a 3-way valve, for diverting the exhaust gases. exhaust via the bypass, and a reformer that is to say a device that transforms hydrocarbons, such as diesel fuel, into a mixture of reducing gases called reformate, mainly composed of CO , H2 and N2.

  The reformate can be produced by a technique chosen from partial oxidation reforming (PDX, partial oxidation), steam reforming, and auto thermal reforming (ATR), which are techniques known per se.

  The duration of the derivation step may be predetermined, in particular this duration may be between 10 seconds and 20 minutes.

  The duration of the preheating step can also be predetermined.

  The duration of at least one of the preheating and / or derivation steps can also be determined by a temperature measurement, representative of the temperature of the catalytic sites of NoxTrap. At the end of the bypass stage the exhaust gases can be redirected into the NOxTrap and the production of reformat can be stopped.25 .R442.I2EN.12 JS dpt 4 According to another embodiment, the production of reformat can be continuous while several preheating and bypass stages alternate in cycles.

  With the method according to the invention, it is possible to regenerate a particle filter, commonly called FàP, arranged in the exhaust line downstream of the NOxTrap, the reformate flow rate being adjusted in this embodiment to reach a temperature of predetermined regeneration downstream of said particulate filter, and the exhaust gases derived during the NOxTrap desulfation step being reintroduced into the exhaust line at a reinjection point located downstream of the NOxTrap and upstream of the particulate filter.

  This method can be applied to the regeneration of an exhaust line comprising 2 NOxTraps connected in parallel, a particle filter mounted downstream of said NOxTraps, a valve system for distributing the flow of exhaust gases between the two NOxTraps, using a valve system for distributing the reformer outgoing reformate between two injection points arranged in parallel upstream respectively of the first and second NOxTrap. Each of the two NOxTrap can alternatively be in preheating phase and desulfation phase during the regeneration of the particulate filter.

  In such an exhaust line, NOx purges of one of the NOxTrap can be performed while the other NOxTrap is in the desulfation phase, by momentary reversal of the valve systems. Other features and advantages of the invention will be apparent to those skilled in the art from the following description of three embodiments and accompanying figures, in which - FIG. a schematic representation of a first embodiment of an exhaust line

  - Figure 2 is a schematic representation of a second embodiment of an exhaust line - Figure 3 is a schematic representation of a third embodiment of an exhaust line.

  FIG. 1 shows an exhaust line comprising a NOxTrap 6 and a reformer 4, the reformate stream, symbolized by dotted arrows, being injected into the exhaust line at an injection point 5. The flow of gases exhaust 1 from the engine is symbolized by arrows in full lines on the left of Figure 1; these gases can be diverted to a bypass 2 by a valve system 3. During the preheating stage, the reformate is injected into the flow of the exhaust gas flowing through the NOxTrap 6. These exhaust gases containing Oxygen, the latter oxidizes the components H2 and CO of the reformate in contact with a catalyst (noble metal) contained in the NOxTrap. This reaction is highly exothermic and the heat thus released allows the NOxTrap to be heated up to the temperature necessary for desulfation. The flow of the reformate is controlled by means of a control loop to reach the desired temperature range. When the desulfation temperature, between 400 ° C. and 9000 ° C., for example of the order of 650, is reached, while continuing the injection of reformate into the NOxTrap 6, the valve 3 is activated to divert the exhaust gases 1 to the bypass 2. Under these conditions, the NOxTrap 6 is traversed by a flux of reformate of wealth equal to that of the air / fuel mixture which feeds the reformer 4. For example, in the case of a diesel POx, the optimal wealth can be 2.9. Under these conditions, the sulfur present in NOxTrap is released in the form of compounds such as H2S, COS and SO2. This desulfation step has a duration that can typically range from 10 seconds to several minutes, for example 20 minutes.

  According to a first variant, after a desulfation step, the reformer is deactivated, and the valve system 3 returns to its initial position so that the exhaust gases pass back into the NOxTrap.

  According to a second variant, the reformate is continuously injected into the NoxTrap during a succession of several steps.

  While injecting the reformate, the valve system is regularly actuated between the two positions so that the flow of gas passing through the NOxTrap alternates between poor phases and rich phases. During the poor phases, the exhaust gases pass into the NOxTrap and the reformate reacts with the oxygen of these gases at the catalytic surface of NOxTrap (platinum or palladium), the exothermic oxidation reaction making it possible to maintain the NOxTrap in temperature. During the rich phases, the exhaust gases are diverted via the bypass 2 and the reformate passes alone in the NOxTrap so that it is de-poison accumulated sulfur. Typically the duration of the lean phase can range from 20 seconds to several minutes and the duration of the rich phase from 10 seconds to several minutes. The durations of each of the phases are adjusted according to the catalytic formulation of NOxTrap and its thermal behavior. One of the main advantages of this rich / poor alternating cycling compared to a continuous exhaust bypass is a better control of the temperature within the NOxTrap during desulfation. This avoids premature aging of NOxTrap.

  The desulfation of a NOxTrap as described above can be advantageously coupled to the regeneration of a particulate filter. FIG. 2 shows an exhaust line comprising the same elements 1 6 as those of FIG. 1. Downstream of the NOxTrap 6 is mounted a catalyzed particulate filter 8. The exhaust gases passing through the bypass 2 are supplied via a bypass line 7 to a reinjection point 10 downstream of the NOxTrap 6 and upstream of the particulate filter 8. The temperature in the particulate filter 8 is measured by means of a temperature sensor 9 placed slightly downstream of the filter 8. The value of this temperature is sent to the calculator 11 of the reformer 4, which also drives the valve system 3.

  The regeneration of the particulate filter 8 requires a temperature of the order of 600 C. to initiate the combustion of soot trapped by the filter. In a first step, the valve system 3 for diverting the exhaust gases in the bypass 2 is not activated so that the exhaust gases pass into the NOxTrap 6. Reformat is injected at 5, which is oxidized by the oxygen present in the exhaust gases in contact with the catalytic deposition of NOxTrap 6. This exothermic oxidation of the reformate allows both the heating of the NOxTrap 6 with a view to its desulfation and the heating of the particulate filter 8 exhaust gases downstream of the NOxTrap. The flow rate of the reformate is adjusted so as to reach at the sensor 9 a regeneration temperature, typically of the order of 600 C, sufficient to allow the oxidation of the soot stored in the filter 8. When this regeneration temperature is reached, the NOxTrap has also reached a temperature sufficient for desulfation.

  In a second step, when the regeneration temperature of the particle filter 8 is reached, the valve system 3 is activated and the exhaust gases are deviated from the NOxTrap and pass into the bypass line 7. The reformate injection is maintained so that the NOxTrap 6 is subjected to a stream rich in reducing compounds and de-poisons the accumulated sulfur by dropping mainly H2S and COS. The duration of this step may be greater than 10 minutes.

  During desulphation, a large or even majority of the reformate does not react in the NOxTrap 6, exits, mixes with the exhaust gas from the bypass line 7, passes into the particulate filter 8, and reacts with the oxygen contained in the exhaust gas in contact with the catalytic deposition of the particulate filter 8.

  This exothermic reaction makes it possible to maintain the particulate filter at its regeneration temperature for the entire duration of the desulfation of NOxTrap 6.

  For a total regeneration of the particulate filter 8, the duration of the injection is typically of the order of 20 minutes. If the time required for desulfation is much less than the time required for regeneration of the particulate filter, the bypass may be deactivated once the desulphatation is complete. The reformate injection is then maintained to allow the regeneration of the particulate filter 8 to continue, the reformate being oxidized by the exhaust gas, or on the catalytic surface of the NOxTrap if by-pass has been disabled, either directly on the catalytic surface of the particulate filter if the bypass is maintained, so that the particulate filter 8 is maintained at regeneration temperature. The advantage of the second option (by-pass maintained) is to minimize the over-consumption of fuel supplying the reformer. In fact, the fact of simultaneously oxidizing the reformate on the particulate filter and regenerating its soot makes it possible to immediately use the energy released by the exothermic oxidation reaction of the reformate and thus to minimize the thermal losses that occur between the NOxTrap and the particle filter when proceeding according to the first option. By doing so, it optimizes the fuel penalty due to fuel reformer fuel.

  The smell of H2S could be an odor nuisance in the environment close to the vehicle during desulfation. But as H2S and COS are oxidized in the particulate filter 8 by the exhaust gas, this problem is solved. Regeneration of the particulate filter can typically be performed every 500 km traveled by the vehicle and the desulfation of NOxTrap is performed simultaneously.

  The method according to the invention can be applied to an exhaust line having two NOx Traps connected in parallel. Such an exhaust line is illustrated schematically in FIG. 3. On this exhaust line, injection of the reformate can be carried out upstream of each of the two NOxTrap 6 and 6b by means of a valve system 12 capable of distribute the reformate outgoing reformer 4 between the two .R442.I2FR.12 JS dpt 10 injection points 5 and 5b. The valve system 3 can switch between the following positions: - position 1: the exhaust gases completely pass through the NOxTrap 6 - position 2: the exhaust gases completely pass through the NOxTrap 6b - position 3: the exhaust gases are divided by half between NOxTraps 6 and 6b.

  The regeneration is carried out as follows: In a first step the valve system 3 is in position 1 so that the exhaust gases completely pass into the NOxTrap 6. The reformate is injected at 5 and oxidized by the oxygen This exothermic reaction serves both to heat the NOxTrap 6 to its desulfation temperature and the particulate filter 8 to its regeneration temperature. The reformate flow rate is adjusted to reach at the sensor 9 downstream of the particulate filter 8 a sufficient temperature to allow oxidation of soot in the filter, typically 600 C. When this temperature is reached, the valve system 3 It is moved to position 2 to deflect the exhaust gases into the NOxTrap 6b and, through line 7b, into the particulate filter 8.

  After the switching of the valve system 3, the reformate injection into the NOxTrap 6 is maintained, and the latter, at the desulphatation temperature, de-poisons the accumulated sulfur by dropping mainly H2S and COS. To ensure complete desulfation of the NOxTrap 6, this position of the system is maintained for a duration of the order of or greater than 10 minutes. .R442.12EN.12 JS dpt 11 During this NOxTrap 6 desulphatation phase, the NOx present in the exhaust gas accumulates in the NOxTrap 6b. So that the NOxTrap 6b does not saturate with NOx, NOx purges of the NOxTrap 6b can be carried out: the valve system 3 passes momentarily into position 1 and reformate is injected into the NOxTrap 6b.

  During desulfation, most of the reformate exits the NOxTrap and is oxidized on the catalytic surface of the particulate filter 8, so that it is maintained at a temperature sufficient for the oxidation of the suites throughout the regeneration. Once the regeneration of the particulate filter, which can take about 20 minutes, is complete, the calculator 11 of the reformer 4 cuts the injection and the valve system goes to a position 3 so as to distribute the flow of the gases. exhaust in both NOxTrap and allow the treatment of NOx.

  During a regeneration operation of the particulate filter, which is typically every 500 km traveled by the vehicle, can be successively desulfate each of the two NOxTrap, by reversing the positions of the valve systems 12 and 3, or desulfate only the one of the NOxTrap and desulfate the other during the next particle filter regeneration operation.

Claims (14)

claims   1. A method of desulfating a NOxTrap (6) of an exhaust line of a diesel engine, said method being intended to extract during operation of said engine at least a portion of the sulfur compounds fixed in said NOxTrap , characterized by the following steps: -production of a reformate by a reformer device (4) from fuel of said engine, - preheating of said NOxTrap by injection of said reformate in the flow of the exhaust gas at a point d injection (5) located downstream of the engine and upstream of the NOxTrap, until a predetermined desulfation temperature is reached in said NOxTrap, and then - bypassing the flow of the exhaust gases from a point diverting the exhaust line located upstream of said injection point, and continuing reformate injection in said NOxTrap to achieve said desulfation, and by the fact that the richness of the mixture feeding the said diesel engineis not affected by the execution of the steps of said method.   2. Method according to claim 1, characterized in that the duration of the derivation step is predetermined, in particular that the duration of the derivation step is between 10 seconds and 20 minutes.   3. Method according to claim 1 or 2, characterized in that the duration of the preheating step is predetermined.   4. Method according to claim 1, characterized in that the duration of at least one of the preheating and / or derivation steps is determined by a temperature measurement.   5. Method according to one of the preceding claims, characterized in that at the end of a said bypass step, the exhaust gas is redirected into the NOxTrap (6) and the production of reformate is stopped.   6. Method according to one of claims 1- 4, characterized in that a plurality of preheating and bypass stages alternate in cycles, and the production of reformate is continuous during said cycles. 10   7. Method according to one of the preceding claims, characterized in that the reformate is produced by a technique selected from partial oxidation reforming, steam reforming and auto thermal reforming. 15   8. Method according to one of the preceding claims, for simultaneously regenerating a particulate filter (8) placed in said exhaust line downstream of said NOxTrap (6), characterized in that during the preheating step of said NOxTrap, the reformate flow rate is adjusted to reach a predetermined regeneration temperature downstream of said particulate filter and in that during said desulfation step of said NOxTrap the exhaust gases are re-introduced into the exhaust line at a reinjection point (10) located downstream of said NOxTrap and upstream of said particle filter. 25   9. Use of a method according to claim 8 for the regeneration of an exhaust line comprising two NOxTraps (6,6b) connected in parallel, a particulate filter (8) mounted downstream of the two NOxTraps and a control system. valves (3) for distributing the flow of exhaust gas between the two NOxTraps, characterized by the use of a valve system (12) for distributing the reformate leaving the reformer (4) between two injection points (5,5b) arranged in parallel respectively upstream of the first and second NOxTrap.   10. Use according to claim 9, characterized in that during the regeneration of the particulate filter (8) each of the two NOxTrap (6,6b) is alternately in preheating phase and desulfation phase. 10   11. Use according to claim 9 or 10, characterized in that NOx purges of each NOxTrap are performed while the other NOxTrap is in the desulfation phase, by momentary reversal of said valve systems (3,12). 15   12. Exhaust line of diesel engines comprising a NOxTrap (6) and a particulate filter (8) arranged downstream of said NOxTrap, characterized by the presence of a valve device (3) upstream of said NOxTrap and a bypass line (7) allowing the exhaust gas to bypass said NOxTrap and be reinjected upstream (10) of said particulate filter, by the presence of a reformer (4) and by the presence of a computer (11) capable of driving a method according to claim 8.   13. Exhaust line of diesel engines for implementing a method according to one of claims 9 - 11, comprising two NOxTraps (6.6b) connected in parallel, a particle filter (8) mounted downstream of the two NOxTraps and a valve system (3) for distributing the flow of exhaust gases between the two NOxTraps, characterized by the presence of a reformer (4), a valve system (12) for distributing the reformate exiting the reformer (4) between two injection points (5,5b) arranged in parallel respectively in the first and second NOxTrap and a calculator (11) implementing the said method.   14. A method of regenerating a particulate filter (8) of a diesel engine exhaust line according to claim 12, characterized by the following steps: production of a reformate by said reformer (4) from fuel said engine and injecting (5) said reformate into said exhaust line downstream of said valve device (3), -derencing the flow of exhaust gas into said bypass line (7) and reinjecting said gases into the filter with particles (8) - oxidation of the reformate by the exhaust gases at the active surface of the particulate filter.