FR2870245A1 - Synthese de copolymeres en forme d'etoile mikto par polymerisation radicalaire controlee - Google Patents

Synthese de copolymeres en forme d'etoile mikto par polymerisation radicalaire controlee

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Publication number
FR2870245A1
FR2870245A1 FR0405303A FR0405303A FR2870245A1 FR 2870245 A1 FR2870245 A1 FR 2870245A1 FR 0405303 A FR0405303 A FR 0405303A FR 0405303 A FR0405303 A FR 0405303A FR 2870245 A1 FR2870245 A1 FR 2870245A1
Authority
FR
France
Prior art keywords
radical polymerization
synthesis
shaped copolymers
star
controlled radical
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR0405303A
Other languages
English (en)
Other versions
FR2870245B1 (fr
Inventor
Claire Pitois
Mathias Destarac
Daniel Taton
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rhodia Chimie SAS
Original Assignee
Rhodia Chimie SAS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rhodia Chimie SAS filed Critical Rhodia Chimie SAS
Priority to FR0405303A priority Critical patent/FR2870245B1/fr
Priority to JP2007512295A priority patent/JP2007537323A/ja
Priority to EP05771223A priority patent/EP1765895A1/fr
Priority to AU2005248117A priority patent/AU2005248117B2/en
Priority to US11/596,169 priority patent/US20080114128A1/en
Priority to PCT/FR2005/001215 priority patent/WO2005116097A1/fr
Publication of FR2870245A1 publication Critical patent/FR2870245A1/fr
Application granted granted Critical
Publication of FR2870245B1 publication Critical patent/FR2870245B1/fr
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F299/00—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00—Living radical polymerisation
    • C08F2438/03—Use of a di- or tri-thiocarbonylthio compound, e.g. di- or tri-thioester, di- or tri-thiocarbamate, or a xanthate as chain transfer agent, e.g . Reversible Addition Fragmentation chain Transfer [RAFT] or Macromolecular Design via Interchange of Xanthates [MADIX]

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Graft Or Block Polymers (AREA)
  • Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

La présente invention concerne un procédé de préparation de copolymères en forme d'étoile comprenant au moins deux types de bras polymères de nature chimique différente, ledit procédé comprenant une étape de polymérisation radicalaire d'une composition comprenant :- au moins un monomère réticulant,- une source de radicaux libres, et- au moins deux (co)polymères de première génération de nature chimique différente et éventuellement de masse moléculaire différente.Elle concerne également les copolymères en étoile susceptibles d'être préparés par ce procédé et leurs utilisations.
FR0405303A 2004-05-14 2004-05-14 Synthese de copolymeres en forme d'etoile mikto par polymerisation radicalaire controlee Expired - Fee Related FR2870245B1 (fr)

Priority Applications (6)

Application Number Priority Date Filing Date Title
FR0405303A FR2870245B1 (fr) 2004-05-14 2004-05-14 Synthese de copolymeres en forme d'etoile mikto par polymerisation radicalaire controlee
JP2007512295A JP2007537323A (ja) 2004-05-14 2005-05-13 制御ラジカル重合によるミクト星形共重合体の合成
EP05771223A EP1765895A1 (fr) 2004-05-14 2005-05-13 Synthese de copolymeres en forme d'etoile mikto par polymerisation radicalaire contrôlee
AU2005248117A AU2005248117B2 (en) 2004-05-14 2005-05-13 Synthesis of copolymers in the form of a mikto star by controlled radical polymerization
US11/596,169 US20080114128A1 (en) 2004-05-14 2005-05-13 Synthesis of Copolymers in the Form of a Mikto Star by Controlled Radical Polymerization
PCT/FR2005/001215 WO2005116097A1 (fr) 2004-05-14 2005-05-13 Synthese de copolymeres en forme d'etoile mikto par polymerisation radicalaire contrôlee

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR0405303A FR2870245B1 (fr) 2004-05-14 2004-05-14 Synthese de copolymeres en forme d'etoile mikto par polymerisation radicalaire controlee

Publications (2)

Publication Number Publication Date
FR2870245A1 true FR2870245A1 (fr) 2005-11-18
FR2870245B1 FR2870245B1 (fr) 2008-08-22

Family

ID=34944994

Family Applications (1)

Application Number Title Priority Date Filing Date
FR0405303A Expired - Fee Related FR2870245B1 (fr) 2004-05-14 2004-05-14 Synthese de copolymeres en forme d'etoile mikto par polymerisation radicalaire controlee

Country Status (6)

Country Link
US (1) US20080114128A1 (fr)
EP (1) EP1765895A1 (fr)
JP (1) JP2007537323A (fr)
AU (1) AU2005248117B2 (fr)
FR (1) FR2870245B1 (fr)
WO (1) WO2005116097A1 (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2894971A1 (fr) * 2005-12-20 2007-06-22 Rhodia Recherches & Tech Composition pour le traitement et/ou la modification de surfaces dures, comprenant un polymere synthetique
DE102006037352A1 (de) * 2006-08-09 2008-02-14 Evonik Röhm Gmbh Verfahren zur Herstellung von säureterminierten ATRP-Produkten

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FR2917415B1 (fr) * 2007-06-14 2012-10-12 Rhodia Recherches Et Tech Microgel polymerique comprenant des unites cationiques
WO2009114596A1 (fr) 2008-03-13 2009-09-17 Kraton Polymers Us Llc Nouvelles compositions miktopolymériques
TW201009062A (en) * 2008-05-07 2010-03-01 Nissan Chemical Ind Ltd Electrochromic material
US8822610B2 (en) * 2008-12-22 2014-09-02 ATRP Solutions, Inc. Control over controlled radical polymerization processes
US8815971B2 (en) 2008-12-22 2014-08-26 ATRP Solutions, Inc. Control over controlled radical polymerization processes
WO2010109928A1 (fr) * 2009-03-24 2010-09-30 丸善石油化学株式会社 Polymère en étoile à base de vinyl éther et son procédé de production
WO2010111708A1 (fr) * 2009-03-27 2010-09-30 Carnegie Mellon University Préparation de macromolécules en étoile fonctionnelles
US8173750B2 (en) * 2009-04-23 2012-05-08 ATRP Solutions, Inc. Star macromolecules for personal and home care
WO2010123574A1 (fr) 2009-04-23 2010-10-28 Atrp Solutions Inc Macromolécules en étoile pour soins d'hygiène personnelle et soins domestiques
US9783628B2 (en) * 2009-04-23 2017-10-10 ATRP Solutions, Inc. Dual-mechanism thickening agents for hydraulic fracturing fluids
US8013065B2 (en) * 2009-06-09 2011-09-06 International Business Machines Corporation Methods for making multi-branched polymers
US9587064B2 (en) * 2010-12-08 2017-03-07 ATRP Solutions, Inc. Salt-tolerant star macromolecules
WO2012091965A1 (fr) 2010-12-17 2012-07-05 Carnegie Mellon University Polymérisation radicalaire par transfert d'atomes à médiation électrochimique
TWI520990B (zh) 2011-01-26 2016-02-11 Maruzen Petrochem Co Ltd Metal nano particle composite and its manufacturing method
EP2747753B1 (fr) 2011-08-22 2023-03-29 Carnegie Mellon University Polymérisation radicalaire par transfert d'atomes dans des conditions compatibles du point de vue biologique
JP5940274B2 (ja) * 2011-10-11 2016-06-29 東京インキ株式会社 重合体、重合体組成物、重合体の製造方法およびブロック共重合体の製造方法
US9533297B2 (en) 2012-02-23 2017-01-03 Carnegie Mellon University Ligands designed to provide highly active catalyst complexes
WO2014031154A1 (fr) * 2012-08-20 2014-02-27 The Lubrizol Corporation Polymères en étoile à noyau libre et composition lubrifiante à base de ceux-ci
JP6294885B2 (ja) * 2012-08-30 2018-03-14 エーティーアールピー ソリューションズ インコーポレイテッドＡＴＲＰ Ｓｏｌｕｔｉｏｎｓ，Ｉｎｃ． 星形高分子、星形高分子組成物および星形高分子の製造方法
CN105263978B (zh) 2013-02-04 2018-04-17 Atrp解决方案公司 耐盐星形大分子
JP6513335B2 (ja) * 2013-03-18 2019-05-15 第一工業製薬株式会社 分散剤及び固体粒子分散体
CN103721627A (zh) * 2013-12-16 2014-04-16 上海大学 热敏性杂臂星型高分子乳化剂及其制备方法
MX2017000076A (es) 2014-07-03 2017-05-01 Atrp Solutions Inc Macromoleculas estrellas compatibles con tensoactivos.
US9982070B2 (en) 2015-01-12 2018-05-29 Carnegie Mellon University Aqueous ATRP in the presence of an activator regenerator
FR3034421B1 (fr) * 2015-03-30 2017-04-28 Total Marketing Services Copolymere etoile et son utilisation comme ameliorant de viscosite
JP6557522B2 (ja) * 2015-06-17 2019-08-07 株式会社ダイセル ハードコート層形成用硬化性組成物、ハードコートフィルム、ハードコートフィルムの製造方法、接着剤組成物、硬化物、接着シート、積層物、及び装置
US11174325B2 (en) 2017-01-12 2021-11-16 Carnegie Mellon University Surfactant assisted formation of a catalyst complex for emulsion atom transfer radical polymerization processes
WO2018213704A2 (fr) * 2017-05-19 2018-11-22 Ecolab Usa Inc. Utilisation de polymères fonctionnalisés par un acide boronique à titre d'adhésifs pour revêtement yankee
CN111511817A (zh) * 2017-12-20 2020-08-07 3M创新有限公司 具有连接的含硫代羰基硫基的基团的聚合物基底
WO2020159972A1 (fr) 2019-01-28 2020-08-06 Dow Global Technologies Llc Inhibition de tartre à l'aide de polymères en étoile
JP7415485B2 (ja) * 2019-11-27 2024-01-17 東亞合成株式会社 ブロック共重合体の製造方法
WO2022170020A1 (fr) 2021-02-04 2022-08-11 Saudi Arabian Oil Company Copolymère séquencé ramifié pour récupération assistée des hydrocarbures dans des formations de grès
US11827732B2 (en) * 2021-02-04 2023-11-28 Saudi Arabian Oil Company Amphiphilic branched copolymer drilling additive
CN113480695A (zh) * 2021-07-29 2021-10-08 浙江杰特维新材料有限公司 一种核壳粘结剂材料及其制备方法

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WO1986000626A1 (fr) * 1984-07-05 1986-01-30 E.I. Du Pont De Nemours And Company Polymeres acryliques en etoile
WO2000002939A1 (fr) * 1998-07-10 2000-01-20 E.I. Du Pont De Nemours And Company Micorgels et procedes de preparation associes
WO2000056795A1 (fr) * 1999-03-23 2000-09-28 Carnegie Mellon University Procedes catalytiques de polymerisation controlee de monomeres (co)polymerisables par des radicaux libres et systemes de polymeres fonctionnels prepares de la sorte
US6336966B1 (en) * 1999-12-16 2002-01-08 Ppg Industries Ohio, Inc. Pigment dispersions containing dispersants having core and arm star architecture prepared by controlled radical polymerization
US6545095B1 (en) * 1998-05-07 2003-04-08 University Of Melbourne Process for microgel preparation

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US6150468A (en) * 1998-11-12 2000-11-21 National Starch And Chemical Investment Holding Corporation Water soluble amphiphilic heteratom star polymers and their use as emulsion stabilizers in emulsion polymerization

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1986000626A1 (fr) * 1984-07-05 1986-01-30 E.I. Du Pont De Nemours And Company Polymeres acryliques en etoile
US6545095B1 (en) * 1998-05-07 2003-04-08 University Of Melbourne Process for microgel preparation
WO2000002939A1 (fr) * 1998-07-10 2000-01-20 E.I. Du Pont De Nemours And Company Micorgels et procedes de preparation associes
WO2000056795A1 (fr) * 1999-03-23 2000-09-28 Carnegie Mellon University Procedes catalytiques de polymerisation controlee de monomeres (co)polymerisables par des radicaux libres et systemes de polymeres fonctionnels prepares de la sorte
US6336966B1 (en) * 1999-12-16 2002-01-08 Ppg Industries Ohio, Inc. Pigment dispersions containing dispersants having core and arm star architecture prepared by controlled radical polymerization

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2894971A1 (fr) * 2005-12-20 2007-06-22 Rhodia Recherches & Tech Composition pour le traitement et/ou la modification de surfaces dures, comprenant un polymere synthetique
WO2007071591A1 (fr) * 2005-12-20 2007-06-28 Rhodia Operations Composition pour le traitement et/ou la modification de surfaces dures, comprenant un polymere synthetique
US8163100B2 (en) 2005-12-20 2012-04-24 Rhodia Operations Synthetic microgel polymer compositions for treating and/or modifying hard surfaces
DE102006037352A1 (de) * 2006-08-09 2008-02-14 Evonik Röhm Gmbh Verfahren zur Herstellung von säureterminierten ATRP-Produkten

Also Published As

Publication number Publication date
JP2007537323A (ja) 2007-12-20
US20080114128A1 (en) 2008-05-15
AU2005248117A1 (en) 2005-12-08
FR2870245B1 (fr) 2008-08-22
WO2005116097A1 (fr) 2005-12-08
AU2005248117B2 (en) 2008-07-31
EP1765895A1 (fr) 2007-03-28

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