FR2869617A1 - Procede de preparation d'une composition d'un polymere du styrene expansible sous forme de perles - Google Patents
Procede de preparation d'une composition d'un polymere du styrene expansible sous forme de perlesInfo
- Publication number
- FR2869617A1 FR2869617A1 FR0404511A FR0404511A FR2869617A1 FR 2869617 A1 FR2869617 A1 FR 2869617A1 FR 0404511 A FR0404511 A FR 0404511A FR 0404511 A FR0404511 A FR 0404511A FR 2869617 A1 FR2869617 A1 FR 2869617A1
- Authority
- FR
- France
- Prior art keywords
- composition
- styrene polymer
- pearls
- preparing
- expandable styrene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/16—Making expandable particles
- C08J9/20—Making expandable particles by suspension polymerisation in the presence of the blowing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0061—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof characterized by the use of several polymeric components
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/06—CO2, N2 or noble gases
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2325/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
- C08J2325/02—Homopolymers or copolymers of hydrocarbons
- C08J2325/04—Homopolymers or copolymers of styrene
- C08J2325/06—Polystyrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2491/00—Characterised by the use of oils, fats or waxes; Derivatives thereof
Abstract
La présente invention concerne un procédé de préparation d'une composition d'un polymère du styrène expansible sous forme de perles. Il comprend une polymérisation du styrène en suspension aqueuse, réalisée en présence (a) du peroxyde de dibenzoyle, (b) du peroxyde de dicumyle, (c) du dimère de l'alpha-méthylstyrène, (d) d'une cire de Fischer-Tropsch, (e) d'au moins un agent de suspension et (f) d'au moins un agent porogène. La composition ainsi obtenue permet d'améliorer substantiellement les propriétés d'isolation thermique des matériaux expansés résultant de ladite composition.
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0404511A FR2869617A1 (fr) | 2004-04-28 | 2004-04-28 | Procede de preparation d'une composition d'un polymere du styrene expansible sous forme de perles |
AT05732848T ATE553146T1 (de) | 2004-04-28 | 2005-04-12 | Verfahren zur herstellung einer zusammensetzung eines expandierbaren styrolpolymers in form von perlen |
EP05732848A EP1745091B1 (fr) | 2004-04-28 | 2005-04-12 | Procede de preparation d'une composition de polymere styrene expansible sous forme de perles |
PCT/GB2005/001390 WO2005105905A1 (fr) | 2004-04-28 | 2005-04-12 | Procede de preparation d'une composition de polymere styrene expansible sous forme de perles |
CN2005800218265A CN1976984B (zh) | 2004-04-28 | 2005-04-12 | 珠粒形式的可发苯乙烯聚合物组合物的制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0404511A FR2869617A1 (fr) | 2004-04-28 | 2004-04-28 | Procede de preparation d'une composition d'un polymere du styrene expansible sous forme de perles |
Publications (1)
Publication Number | Publication Date |
---|---|
FR2869617A1 true FR2869617A1 (fr) | 2005-11-04 |
Family
ID=34944563
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR0404511A Pending FR2869617A1 (fr) | 2004-04-28 | 2004-04-28 | Procede de preparation d'une composition d'un polymere du styrene expansible sous forme de perles |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP1745091B1 (fr) |
CN (1) | CN1976984B (fr) |
AT (1) | ATE553146T1 (fr) |
FR (1) | FR2869617A1 (fr) |
WO (1) | WO2005105905A1 (fr) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20080300328A1 (en) * | 2007-04-25 | 2008-12-04 | Dow Global Technologies Inc. | Process for the Preparation of Expandable Polystyrene Beads |
EP3055349A1 (fr) | 2013-10-11 | 2016-08-17 | Bewi Styrochem Oy | Billes de polystyrène de faible conductivité thermique |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0124656A1 (fr) * | 1983-05-04 | 1984-11-14 | The Dow Chemical Company | Procédé de préparer des mousses de polymères de styrène à caractéristiques de non-inflammabilité améliorées |
EP0612792A1 (fr) * | 1993-02-25 | 1994-08-31 | BASF Aktiengesellschaft | Perles expansibles de polystyrène à faible teneur en eau, et leur procédé de préparation |
EP0969037A1 (fr) * | 1998-06-29 | 2000-01-05 | BP Chemicals Limited | Composition de polystyrène expansible, perles expansées et pièces moulées |
-
2004
- 2004-04-28 FR FR0404511A patent/FR2869617A1/fr active Pending
-
2005
- 2005-04-12 CN CN2005800218265A patent/CN1976984B/zh not_active Expired - Fee Related
- 2005-04-12 AT AT05732848T patent/ATE553146T1/de active
- 2005-04-12 EP EP05732848A patent/EP1745091B1/fr active Active
- 2005-04-12 WO PCT/GB2005/001390 patent/WO2005105905A1/fr active Application Filing
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0124656A1 (fr) * | 1983-05-04 | 1984-11-14 | The Dow Chemical Company | Procédé de préparer des mousses de polymères de styrène à caractéristiques de non-inflammabilité améliorées |
EP0612792A1 (fr) * | 1993-02-25 | 1994-08-31 | BASF Aktiengesellschaft | Perles expansibles de polystyrène à faible teneur en eau, et leur procédé de préparation |
EP0969037A1 (fr) * | 1998-06-29 | 2000-01-05 | BP Chemicals Limited | Composition de polystyrène expansible, perles expansées et pièces moulées |
Also Published As
Publication number | Publication date |
---|---|
CN1976984A (zh) | 2007-06-06 |
EP1745091A1 (fr) | 2007-01-24 |
EP1745091B1 (fr) | 2012-04-11 |
WO2005105905A1 (fr) | 2005-11-10 |
CN1976984B (zh) | 2010-09-29 |
ATE553146T1 (de) | 2012-04-15 |
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