FR2868965A1 - Catalyseur basique solide a base de csf supporte sur alumine alpha - Google Patents
Catalyseur basique solide a base de csf supporte sur alumine alphaInfo
- Publication number
- FR2868965A1 FR2868965A1 FR0404120A FR0404120A FR2868965A1 FR 2868965 A1 FR2868965 A1 FR 2868965A1 FR 0404120 A FR0404120 A FR 0404120A FR 0404120 A FR0404120 A FR 0404120A FR 2868965 A1 FR2868965 A1 FR 2868965A1
- Authority
- FR
- France
- Prior art keywords
- basic
- reactions
- csf
- catalyst based
- alpha alumina
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003054 catalyst Substances 0.000 title abstract 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 title abstract 2
- XJHCXCQVJFPJIK-UHFFFAOYSA-M caesium fluoride Chemical compound [F-].[Cs+] XJHCXCQVJFPJIK-UHFFFAOYSA-M 0.000 abstract 3
- 238000006243 chemical reaction Methods 0.000 abstract 2
- 238000003512 Claisen condensation reaction Methods 0.000 abstract 1
- 238000003476 Darzens condensation reaction Methods 0.000 abstract 1
- 238000006845 Michael addition reaction Methods 0.000 abstract 1
- 150000001298 alcohols Chemical class 0.000 abstract 1
- 125000005910 alkyl carbonate group Chemical group 0.000 abstract 1
- 238000006555 catalytic reaction Methods 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 238000005809 transesterification reaction Methods 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
- B01J23/04—Alkali metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/06—Halogens; Compounds thereof
- B01J27/08—Halides
- B01J27/12—Fluorides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C68/00—Preparation of esters of carbonic or haloformic acids
- C07C68/06—Preparation of esters of carbonic or haloformic acids from organic carbonates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
- B01J21/04—Alumina
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/613—10-100 m2/g
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
La présente invention concerne un catalyseur basique solide comprenant du fluorure de césium CsF supporté sur de l'alumine α.L'invention concerne également le procédé de préparation de ce catalyseur, ainsi que l'utilisation du catalyseur pour réaliser la catalyse basique hétérogènes de réactions chimiques utiles en particulier en chimie fine, telles que, notamment, des réactions de transestérification de carbonate d'alkyles par des alcools, des réactions d'addition de Michaël ou des réactions de Darzens ou de Claisen.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0404120A FR2868965A1 (fr) | 2004-04-19 | 2004-04-19 | Catalyseur basique solide a base de csf supporte sur alumine alpha |
PCT/FR2005/000929 WO2005107941A1 (fr) | 2004-04-19 | 2005-04-18 | CATALYSEUR BASIQUE SOLIDE A BASE DE CSF SUPPORTE SUR ALUMINE α |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0404120A FR2868965A1 (fr) | 2004-04-19 | 2004-04-19 | Catalyseur basique solide a base de csf supporte sur alumine alpha |
Publications (1)
Publication Number | Publication Date |
---|---|
FR2868965A1 true FR2868965A1 (fr) | 2005-10-21 |
Family
ID=34944811
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR0404120A Pending FR2868965A1 (fr) | 2004-04-19 | 2004-04-19 | Catalyseur basique solide a base de csf supporte sur alumine alpha |
Country Status (2)
Country | Link |
---|---|
FR (1) | FR2868965A1 (fr) |
WO (1) | WO2005107941A1 (fr) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN115819769B (zh) * | 2022-12-31 | 2023-11-03 | 杭州瑞思新材料有限公司 | 一种有机硅用催化剂及制备方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0059422A1 (fr) * | 1981-02-25 | 1982-09-08 | Mitsubishi Petrochemical Co., Ltd. | Catalyseur à base d'argent pour la production de l'oxyde d'éthylène |
EP0299569A1 (fr) * | 1987-07-15 | 1989-01-18 | Shell Internationale Researchmaatschappij B.V. | Procédé de préparation d'un catalysateur à base d'argent |
US5110991A (en) * | 1991-04-01 | 1992-05-05 | Texaco Chemical Company | Heterogeneous catalyst for alkoxylation of alcohols |
-
2004
- 2004-04-19 FR FR0404120A patent/FR2868965A1/fr active Pending
-
2005
- 2005-04-18 WO PCT/FR2005/000929 patent/WO2005107941A1/fr active Application Filing
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0059422A1 (fr) * | 1981-02-25 | 1982-09-08 | Mitsubishi Petrochemical Co., Ltd. | Catalyseur à base d'argent pour la production de l'oxyde d'éthylène |
EP0299569A1 (fr) * | 1987-07-15 | 1989-01-18 | Shell Internationale Researchmaatschappij B.V. | Procédé de préparation d'un catalysateur à base d'argent |
US5110991A (en) * | 1991-04-01 | 1992-05-05 | Texaco Chemical Company | Heterogeneous catalyst for alkoxylation of alcohols |
Non-Patent Citations (1)
Title |
---|
J. H. CLARK, D. G. CORK, M. S. ROBERTSON: "Fluoride ion catalysed Michael Reactions", CHEMISTRY LETTERS, 1983, pages 1145 - 1148, XP001203419 * |
Also Published As
Publication number | Publication date |
---|---|
WO2005107941A1 (fr) | 2005-11-17 |
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