FR2826904A1 - METHOD FOR MANUFACTURING FLOOR COVERING PLATES - Google Patents
METHOD FOR MANUFACTURING FLOOR COVERING PLATES Download PDFInfo
- Publication number
- FR2826904A1 FR2826904A1 FR0109004A FR0109004A FR2826904A1 FR 2826904 A1 FR2826904 A1 FR 2826904A1 FR 0109004 A FR0109004 A FR 0109004A FR 0109004 A FR0109004 A FR 0109004A FR 2826904 A1 FR2826904 A1 FR 2826904A1
- Authority
- FR
- France
- Prior art keywords
- polyol
- isocyanate
- casting
- molding
- additives
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F15/00—Flooring
- E04F15/02—Flooring or floor layers composed of a number of similar elements
- E04F15/10—Flooring or floor layers composed of a number of similar elements of other materials, e.g. fibrous or chipped materials, organic plastics, magnesite tiles, hardboard, or with a top layer of other materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C37/00—Component parts, details, accessories or auxiliary operations, not covered by group B29C33/00 or B29C35/00
- B29C37/0025—Applying surface layers, e.g. coatings, decorative layers, printed layers, to articles during shaping, e.g. in-mould printing
- B29C37/0028—In-mould coating, e.g. by introducing the coating material into the mould after forming the article
- B29C37/0032—In-mould coating, e.g. by introducing the coating material into the mould after forming the article the coating being applied upon the mould surface before introducing the moulding compound, e.g. applying a gelcoat
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C39/00—Shaping by casting, i.e. introducing the moulding material into a mould or between confining surfaces without significant moulding pressure; Apparatus therefor
- B29C39/003—Shaping by casting, i.e. introducing the moulding material into a mould or between confining surfaces without significant moulding pressure; Apparatus therefor characterised by the choice of material
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/10—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C04B26/16—Polyurethanes
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F15/00—Flooring
- E04F15/02—Flooring or floor layers composed of a number of similar elements
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C33/00—Moulds or cores; Details thereof or accessories therefor
- B29C33/38—Moulds or cores; Details thereof or accessories therefor characterised by the material or the manufacturing process
- B29C33/3842—Manufacturing moulds, e.g. shaping the mould surface by machining
- B29C33/3857—Manufacturing moulds, e.g. shaping the mould surface by machining by making impressions of one or more parts of models, e.g. shaped articles and including possible subsequent assembly of the parts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C33/00—Moulds or cores; Details thereof or accessories therefor
- B29C33/38—Moulds or cores; Details thereof or accessories therefor characterised by the material or the manufacturing process
- B29C33/40—Plastics, e.g. foam or rubber
- B29C33/405—Elastomers, e.g. rubber
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2075/00—Use of PU, i.e. polyureas or polyurethanes or derivatives thereof, as moulding material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2995/00—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
- B29K2995/0037—Other properties
- B29K2995/0055—Resistive to light
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/732—Floor coverings
Landscapes
- Engineering & Computer Science (AREA)
- Architecture (AREA)
- Chemical & Material Sciences (AREA)
- Structural Engineering (AREA)
- Ceramic Engineering (AREA)
- Civil Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Finishing Walls (AREA)
- Floor Finish (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
Description
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L'invention concerne un procédé pour fabriquer des plaques en matériau synthétique pour revêtement de sols. The invention relates to a method for manufacturing plates of synthetic material for floor covering.
On utilise depuis plusieurs années des plaques minces en matériau synthétique pour recouvrir des sols plans préalablement ragréés. Ces plaques ont en général une forme carrée ou rectangulaire et sont tirées de bandes minces en matériau synthétique. Thin sheets of synthetic material have been used for several years to cover previously leveled flat floors. These plates generally have a square or rectangular shape and are drawn from thin strips of synthetic material.
On ne connaît pas actuellement de plaques en matériau synthétique qui puissent être utilisées pour la répartition de sols revêtus de revêtements anciens en céramique, tels que les tomettes anciennes de couleur brique et de forme hexagonale. La forme de ces tomettes, leur épaisseur, et leur usure et patine nécessitent de remplacer les tomettes abîmées par d'autres tomettes du même type et de préférence de même âge et de même provenance, ce qui pose des problèmes difficiles à résoudre. Currently, there are no known sheets of synthetic material that can be used for the distribution of floors coated with old ceramic coverings, such as old brick-colored tiles and hexagonal in shape. The shape of these tiles, their thickness, and their wear and patina require replacing the damaged tiles with other tiles of the same type and preferably of the same age and from the same origin, which poses problems which are difficult to solve.
Le but de l'invention est de proposer un procédé pour réaliser des plaques de revêtement qui puissent répondre notamment à ces besoins. Il est évident que les plaques obtenues par le procédé selon l'invention peuvent également être utilisées pour revêtir en totalité un sol nu préalablement ragréé. The object of the invention is to propose a method for producing covering plates which can meet these needs in particular. It is obvious that the plates obtained by the process according to the invention can also be used to completely cover a bare, previously leveled floor.
Le procédé selon l'invention est caractérisé par le fait que l'on coule dans un bac de moulage une résine de polyuréthanne ayant une dureté comprise entre 70 et 85 shore A, cette résine étant constituée de deux composants de base, à savoir du polyol et de l'isocyanate dans la proportion pondérale de 100 parts de polyol pour 25 parts d'isocyanate, et de six additifs exprimés ci-après dans une proportion pondérale par rapport au poids total des deux composants de base : - 30 à 50 % d'une charge de silice assurant la structure antiusure, - 15 à 25 % de brique pyrogénée assurant la pigmentation, - 5 à 10 % d'agent plastifiant, - 1 à 3 % d'agent anti ultra-violet, - 1 à 3 % d'agent anti oxydant, et - 0, 2 à 0,5 % d'un catalyseur accélérant. The method according to the invention is characterized by the fact that a polyurethane resin having a hardness of between 70 and 85 shore A is poured into a molding tank, this resin consisting of two basic components, namely polyol and isocyanate in the proportion by weight of 100 parts of polyol per 25 parts of isocyanate, and of six additives expressed below in a proportion by weight relative to the total weight of the two basic components: - 30 to 50% d '' a silica filler ensuring the anti-wear structure, - 15 to 25% of pyrogenic brick ensuring pigmentation, - 5 to 10% of plasticizing agent, - 1 to 3% of anti-ultraviolet agent, - 1 to 3% antioxidant, and - 0.2 to 0.5% of an accelerating catalyst.
Avantageusement on prémélange les six additifs dans le polyol, et on mélange l'isocyanate et le polyol enrichi des additifs lors de la coulée. Advantageously, the six additives are premixed in the polyol, and the isocyanate and the polyol enriched with the additives are mixed during casting.
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De préférence l'épaisseur de la plaque coulée est de 5mm environ. Preferably the thickness of the casting plate is approximately 5mm.
Cette épaisseur associée à la présence de silice assure une rigidité suffisante à la plaque réalisée par le procédé, ce qui permet au carreleur de travailler comme s'il s'agissait d'un élément unitaire de revêtement de sol en céramique. This thickness associated with the presence of silica ensures sufficient rigidity to the plate produced by the process, which allows the tiler to work as if it were a unitary element of ceramic flooring.
Afin d'obtenir la patine de surface souhaitée, on vaporise au fond du bac de moulage, avant la coulée, un vernis de gel coat de polyuréthanne nuancé. In order to obtain the desired surface patina, a spray of nuanced polyurethane gel coat is sprayed onto the bottom of the molding tank before casting.
Pour favoriser le durcissement de la plaque, on effectue après la coulée une post-cuisson à une température comprise entre 60 et 80 C. To promote hardening of the plate, post-baking is carried out after casting at a temperature between 60 and 80 C.
Pour éviter d'appliquer un agent de démoulage, on utilise des bacs de moulage en élastomère de silicone. To avoid applying a release agent, silicone elastomer molding tanks are used.
De préférence, les bacs de moulage sont obtenus à partir d'une empreinte d'un sol carrelé. Preferably, the molding trays are obtained from an imprint of a tiled floor.
Très avantageusement l'empreinte recouvre une pluralité d'éléments unitaires juxtaposés du sol carrelé. Ces éléments unitaires sont par exemple des tomettes. Very advantageously the imprint covers a plurality of unitary elements juxtaposed on the tiled floor. These unitary elements are for example tomettes.
D'autres avantages et caractéristiques de l'invention ressortiront à la lecture de la description suivante faite à titre d'exemple et en référence aux dessins annexés dans lesquels :
La figure 1 montre un carrelage traditionnel en tomettes anciennes sur lequel on prélève une empreinte, à partir de laquelle sont réalisés des bacs de moulage ;
La figure 2 est une vue de dessus d'un bac de moulage ;
La figure 3 est une coupe selon la ligne III III de la figure 2 du bac de moulage ;
La figure 4 montre le principe d'une installation pour mettre en oeuvre l'invention ; et
La figure 5 montre en perspective une plaque de revêtement de sol réalisée par le procédé selon l'invention. Other advantages and characteristics of the invention will emerge on reading the following description given by way of example and with reference to the appended drawings in which:
Figure 1 shows a traditional tiling in old tiles on which we take an imprint, from which are made molding trays;
Figure 2 is a top view of a molding pan;
Figure 3 is a section along line III III of Figure 2 of the molding pan;
FIG. 4 shows the principle of an installation for implementing the invention; and
Figure 5 shows in perspective a floor covering plate produced by the method according to the invention.
La figure 1 montre un carrelage 1 ancien traditionnel en tomettes, chaque tomette a une forme hexagonale régulière et la distance séparant deux angles opposés est par exemple de 24 cm. Figure 1 shows a traditional old tile 1 in tiles, each tile has a regular hexagonal shape and the distance between two opposite angles is for example 24 cm.
Sur ce carrelage 1 on prélève une empreinte 2 très précise de six tomettes juxtaposées réparties en deux rangées de trois tomettes On this tiling 1 take a very precise imprint 2 of six juxtaposed tomettes distributed in two rows of three tomettes
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par des méthodes connues. Le contour de cette empreinte est montré par la ligne fermée brisée référencée 3. by known methods. The outline of this imprint is shown by the broken closed line referenced 3.
A partir de cette empreinte on réalise un outil de moulage servant à fabriquer les bacs de moulage 4 des plaques selon l'invention. From this imprint, a molding tool is used which is used to manufacture the molding trays 4 for the plates according to the invention.
Les figures 2 et 3 montrent le bac de moulage 4 réalisé en élastomère de silicone dont le fond présente une empreinte identique à l'empreinte 1 réalisée et complémentaire de celle des plaques à réaliser. On voit notamment les nervures 5 qui correspondent aux joints des tomettes utilisées pour prélever l'empreinte initiale. Figures 2 and 3 show the molding tray 4 made of silicone elastomer, the bottom of which has an imprint identical to the imprint 1 produced and complementary to that of the plates to be produced. We see in particular the ribs 5 which correspond to the joints of the tiles used to take the initial imprint.
La figure 4 montre l'installation 10 utilisée pour mettre en oeuvre l'invention. Cette installation comporte un châssis 11 supportant un bac 12 contenant le polyol enrichi des six additifs et un bac 13 contenant de l'isocyanate. Des agitateurs permettent d'homogénéiser en permanence les produits contenus dans les bacs 12 et 13. FIG. 4 shows the installation 10 used to implement the invention. This installation comprises a frame 11 supporting a tank 12 containing the polyol enriched with the six additives and a tank 13 containing isocyanate. Agitators are used to permanently homogenize the products contained in tanks 12 and 13.
Des pompes amènent le polyol enrichi des six additifs et l'isocyanate vers une tête de coulée 14 par intermédiaire de conduits séparés 15 et 16. La tête de coulée 14 est disposée au-dessus d'un bac de moulage 4 et est équipée d'une poignée de manoeuvre 17 qui permet de faire couler et mélanger une dose de polyol enrichi des six additifs et une dose d'isocyanate dans un bac de moulage 4. Pumps bring the polyol enriched with the six additives and the isocyanate to a casting head 14 via separate conduits 15 and 16. The casting head 14 is arranged above a molding pan 4 and is equipped with an operating handle 17 which makes it possible to run and mix a dose of polyol enriched with the six additives and a dose of isocyanate in a molding tank 4.
L'installation comporte naturellement des moyens pour régler les doses dans les proportions définies dans l'introduction. The installation naturally includes means for adjusting the doses in the proportions defined in the introduction.
Typiquement, avec le bac de moulage 4 qui correspond à six tomettes de 24 cm de diamètre en deux angles opposés, le poids total des deux doses est de 1,5 kg environ et l'épaisseur du mélange déversé au fond du bac de moulage est de 0,5 cm. Typically, with the molding tray 4 which corresponds to six 24 cm diameter tiles at two opposite angles, the total weight of the two doses is approximately 1.5 kg and the thickness of the mixture poured into the bottom of the molding tray is 0.5 cm.
Pour accélérer le durcissement de la plaque réalisée, les bacs de moulage sont introduits, après la coulée, dans une chambre de cuisson, où ils sont soumis à une température comprise entre 60 et 80 C pendant une durée comprise entre 5 et 10 minutes. To accelerate the hardening of the plate produced, the molding tanks are introduced, after casting, in a baking chamber, where they are subjected to a temperature between 60 and 80 C for a period of between 5 and 10 minutes.
Il suffit ensuite de démouler les plaques, de les ébarber, de les conditionner et de les stocker. It then suffices to unmold the plates, deburr them, condition them and store them.
Pour obtenir la patine de surface souhaitée, on vaporise au fond des bacs de moulage 4 un vernis de gel coat avant de procéder à la To obtain the desired surface patina, a gel coat varnish is sprayed on the bottom of the molding tanks 4 before proceeding to the
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coulée. On attend 3 à 5 minutes avant de couler une nouvelle plaque, afin de permettre la prise du gel coat . casting. We wait 3 to 5 minutes before pouring a new plate, to allow the gel coat to set.
Il va de soi que l'empreinte 2 peut être réalisée sur tout type de carrelage traditionnel sans sortir du cadre de l'invention. It goes without saying that the imprint 2 can be made on any type of traditional tiling without departing from the scope of the invention.
La figure 5 montre une plaque 20 réalisée selon le procédé décrit ci-dessus. Ces plaques 20 ont des contours tels qu'ils s'emboîtent les uns dans les autres lors de la pose. Ces plaques 20 sont fixées sur un sol plan, propre et sec avec une colle acrylique. FIG. 5 shows a plate 20 produced according to the method described above. These plates 20 have contours such that they fit into each other during installation. These plates 20 are fixed on a flat, clean and dry floor with an acrylic adhesive.
Elles ont une dimension hors tout de 42 x 73 cm, ce qui leur donne une certaine souplesse permettant une pose sur un sol légèrement déformé. They have an overall dimension of 42 x 73 cm, which gives them a certain flexibility allowing a pose on a slightly deformed ground.
Les plaques 20 obtenues par le procédé ont une grande résistance au piétinement, aux taches diverses, et une bonne tenue aux brûlures de cigarettes. Elles peuvent être utilisées pour recouvrir les sols des passages, hall d'entrée, cuisine etc. Elles peuvent également être utilisées dans les salles de bains du fait de leur étanchéité. The plates 20 obtained by the method have a high resistance to trampling, various stains, and good resistance to cigarette burns. They can be used to cover the floors of passageways, entry halls, kitchens, etc. They can also be used in bathrooms because of their tightness.
Claims (10)
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0109004A FR2826904A1 (en) | 2001-07-06 | 2001-07-06 | METHOD FOR MANUFACTURING FLOOR COVERING PLATES |
PCT/FR2002/002359 WO2003004434A1 (en) | 2001-07-06 | 2002-07-05 | Method for making flooring tiles |
EP02764943A EP1404628A1 (en) | 2001-07-06 | 2002-07-05 | Method for making flooring tiles |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0109004A FR2826904A1 (en) | 2001-07-06 | 2001-07-06 | METHOD FOR MANUFACTURING FLOOR COVERING PLATES |
Publications (1)
Publication Number | Publication Date |
---|---|
FR2826904A1 true FR2826904A1 (en) | 2003-01-10 |
Family
ID=8865209
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR0109004A Withdrawn FR2826904A1 (en) | 2001-07-06 | 2001-07-06 | METHOD FOR MANUFACTURING FLOOR COVERING PLATES |
Country Status (3)
Country | Link |
---|---|
EP (1) | EP1404628A1 (en) |
FR (1) | FR2826904A1 (en) |
WO (1) | WO2003004434A1 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2887805A1 (en) * | 2005-07-04 | 2007-01-05 | Guillaume Elric Dussud | Architectural marquetry for e.g. dwelling, has parts made of polyurethane resin, silica and mineral powders such as clay, that are resistant to temperature until eighty degree Celsius, waterproof and moisture proof |
WO2012156550A1 (en) * | 2011-05-19 | 2012-11-22 | Matridos, S.L. | Paving slab for blind people |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10347663A1 (en) * | 2003-10-09 | 2005-05-04 | Basf Ag | Thermoplastic (especially a polyurethane) for use e.g. in instrument panel coverings or sports shoe components contains a phenolic group-containing compound at 5.5-50 wt.% |
WO2016162726A1 (en) * | 2015-04-07 | 2016-10-13 | Paola Ferrari | Automated system for the production of very slim resin tiles with the help of tray-shaped containers |
EP3078472A1 (en) * | 2015-04-07 | 2016-10-12 | Paola Ferrari | Automated system for the production of very slim resin tiles with the help of tray-shaped containers |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4105594A (en) * | 1975-05-31 | 1978-08-08 | Bayer Aktiengesellschaft | Highly filled polyurea foams |
US4740577A (en) * | 1987-08-28 | 1988-04-26 | Minnesota Mining And Manufacturing Company | Energy polymerizable polyurethane precursors |
US5053274A (en) * | 1990-02-08 | 1991-10-01 | Jonas Arthur E | Highly filled substantially solid polyurethane, urea and isocyannurate composites for indoor and outdoor applications, for load bearing, structural and decorative products |
FR2704551A1 (en) * | 1993-04-28 | 1994-11-04 | Roehm Gmbh | Polymeric molded articles made of casting resins and having a metallic and possibly colored surface. |
DE19642516A1 (en) * | 1996-10-15 | 1998-04-16 | Joerg Harnisch | Production of matrix comprising slabs, tiles or mosaic elements for e.g. cladding or flooring, indoors or out |
DE19726502C1 (en) * | 1997-06-23 | 1998-07-30 | Peter Silbernagel | Imitation stone slabs comprising polyurethane foam filled with natural or synthetic powdered stone |
-
2001
- 2001-07-06 FR FR0109004A patent/FR2826904A1/en not_active Withdrawn
-
2002
- 2002-07-05 EP EP02764943A patent/EP1404628A1/en not_active Withdrawn
- 2002-07-05 WO PCT/FR2002/002359 patent/WO2003004434A1/en not_active Application Discontinuation
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4105594A (en) * | 1975-05-31 | 1978-08-08 | Bayer Aktiengesellschaft | Highly filled polyurea foams |
US4740577A (en) * | 1987-08-28 | 1988-04-26 | Minnesota Mining And Manufacturing Company | Energy polymerizable polyurethane precursors |
US5053274A (en) * | 1990-02-08 | 1991-10-01 | Jonas Arthur E | Highly filled substantially solid polyurethane, urea and isocyannurate composites for indoor and outdoor applications, for load bearing, structural and decorative products |
FR2704551A1 (en) * | 1993-04-28 | 1994-11-04 | Roehm Gmbh | Polymeric molded articles made of casting resins and having a metallic and possibly colored surface. |
DE19642516A1 (en) * | 1996-10-15 | 1998-04-16 | Joerg Harnisch | Production of matrix comprising slabs, tiles or mosaic elements for e.g. cladding or flooring, indoors or out |
DE19726502C1 (en) * | 1997-06-23 | 1998-07-30 | Peter Silbernagel | Imitation stone slabs comprising polyurethane foam filled with natural or synthetic powdered stone |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2887805A1 (en) * | 2005-07-04 | 2007-01-05 | Guillaume Elric Dussud | Architectural marquetry for e.g. dwelling, has parts made of polyurethane resin, silica and mineral powders such as clay, that are resistant to temperature until eighty degree Celsius, waterproof and moisture proof |
WO2012156550A1 (en) * | 2011-05-19 | 2012-11-22 | Matridos, S.L. | Paving slab for blind people |
ES2393361A1 (en) * | 2011-05-19 | 2012-12-20 | Matridos, S.L. | Paving slab for blind people |
Also Published As
Publication number | Publication date |
---|---|
WO2003004434A1 (en) | 2003-01-16 |
EP1404628A1 (en) | 2004-04-07 |
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