FR2824268A1 - COLORFUL FILM-FORMING COSMETIC COMPOSITION - Google Patents

Abstract

The invention relates to a cosmetic composition comprising, in an aqueous medium, a film-forming polymer in the form of an aqueous dispersion of solid particles dispersed in said aqueous medium, an organic lacquer, said composition having a pH varying between 3 and 8. The inventive composition is particularly suitable as a nail varnish. The invention also relates to the use of an organic lacquer in a cosmetic composition comprising, in an aqueous medium, a film-forming polymer in the form of an aqueous dispersion of solid particles dispersed in said aqueous medium. The aforementioned composition has a pH varying between 3 and 8 and is used to apply make-up to keratinous matter, particularly the skin or nails, without leaving stains and/or preventing and/or reducing the bleeding of the organic lacquer on said keratinous matter.

Description

contains no detergent.

  The subject of the present invention is a film-forming cosmetic composition comprising

  taking an aqueous dispersion of polymer and an organic lacquer, usable in particular as a makeup or care composition for keratinous materials such as the skin, including the lips, nails, eyelashes, eyebrows,

  hair, especially of human beings. The invention also relates to a use

  tion of this composition for makeup or cosmetic care of materials

  keratin. It is intended more specifically for making up the nails.

  The composition may be in the form of nail polish, mascara, eyeliner, lip product, blush or eyeshadow,

  complexion, body makeup product, concealer product. More special-

  ment, the invention relates to a nail polish.

  The varnish or nail care composition can be used as a base

  for varnish, as a nail makeup product, as a composition of

  nition, also called "top coat" in English terminology, to be applied to the

  nail makeup product or even as a cosmetic care product

  only nails. These compositions can be applied to the nails of human beings

hands or false nails.

  EP-A-143480 and EP-A-648485 disclose nail varnish compositions comprising an aqueous dispersion of film-forming polymer particles. These compositions can be colored by adding color materials

  rants such as water-soluble dyes, mineral pigments or pigments

  organic elements. These include organic lacquers

  which contain insoluble salts of generally superior organic dyes

  worn on a particulate support.

  However, organic lacquers have the disadvantage of bleeding, that is to say that a part

  tie of the lacquer dye dissolves and settles on, or even migrates in,

  masked keratin materials. After removing make-up, the latter remain colo-

  This residual coloring is completely unsightly and cannot be removed.

removed with a makeup remover.

  The aim of the present invention is to provide a cosmetic cosmetic composition

  colored mogene which does not have the drawbacks mentioned above, in particular which does not stain keratin materials such as the nails or the skin. The inventors have found that the pH of the composition has an influence on the disgorgement of organic lakes. In particular, when the pH of the composition is between 3 and 8, it has been found that one totally decreases or even eliminates

  ment, the disgorgement of organic lacquers therefore the staining of kera-

tiniques.

  More specifically, the invention relates to a cosmetic composition comprising

  nant, in an aqueous medium, a film-forming polymer in the form of a dispersion

  aqueous solid particles dispersed in said aqueous medium, a lacquer or-

  ganic, the composition having a pH ranging from 3 to 8. This composition is in part

especially a nail polish.

  The invention also has a process for making up keratin materials comprising the application to the keratin materials of the composition defined above.

  Another subject of the invention is the use of an organic lacquer, in a composition

  cosmetic sition comprising, in an aqueous medium, a film-forming polymer

  in the form of an aqueous dispersion of solid particles dispersed in said medium

  aqueous place, the composition having a pH ranging from 3 to 8 for making up keratin materials without staining them eVou preventing eVou reducing the bleeding of the

  organic lacquer on keratin materials.

  The cosmetic composition according to the invention being colored, it is entirely suitable for

  cleans for making up keratin materials.

  The organic lacquer present in the composition according to the invention can be chosen

  sie, in known manner, among the insoluble salts of sodium, potassium, cal-

  cium, barium, aluminum, zirconium, strontium, titanium, dyes

  acids such as azo, anthraquinone, indigode, xantheni-

  ques, pyrenic, quinolinic, triphenylmethane, fluorane. These dyes

  generally contain at least one carboxylic or sulfonic acid group.

  The organic lacquer can also be supported by any compatible support such as

  a mineral support such as alumina, clay, zirconia or oxy-

  metals, in particular of zinc oxide or of titanium oxide, of talc, of calium car bonate, of barium sulfete. Preferably, the mineral support is chosen

  among alumina, titanium oxide and barium sulfate.

  The organic lacquer can also be supported by a support such as colo-

phane or aluminum benzoate.

  Among the organic lacquers which can be used according to the invention, there may in particular be those known under the following names: D & C Red n 2 Aluminum iake D & C Red n 3 Aluminum lake D & C Red n 4 Aluminum lake D & C Red n 6 Aluminum lake D & C Red n 6 Barium lake D & C Red n 6 Barium / Strontium lake D & C Red n 6 Strontium lake D & C Red n 6 Potassium lake D & C Red n 7 Aluminum lake D & C Red n 7 Barium lake D & C Red n 7 Calclum lake

  D & C Red n 7 Calcium / strontium lake -.

  D & C Red n 7 Zirconium lake D&C Red n 8 Sodiumlake D & C Red n 9 Aluminum lake D&C Redn 9 Bariumlake D & C Red n 9 Barium / Strontium lake D & C Red n 9 Zirconium lake D & C Red n 10 Sodium lake D & C Red n 19 Aluminum lake D & CRedn 19 Bariumlake D & C Red n 19 Zirconium lake D & C Red n 21 Aluminum lake D & C Red n 21 Zirconium lake D & C Red n 22 Aluminum lake D & C Red n 27 Aluminum lake D & C Red n 27 Aluminum / Titanium / Zirconium lake D & C Red n 27 Barium lake D & C Red n 27 Calcium lake D & C Red n 27 Zirconium lake D & C Red n 28 Aluminum lake D & C Red n 30 lake & C Red n 31 Calclum lake D & C Red n 33 Aluminum lake D & C Red n 34 Calclum lake D & C Red n 36 lake D & C Red n 40 Aluminum lake D & C Blue n 1 Aluminum lake D & C Green n 3 Aluminum lake D & C Orange n 4 Aluminum lake D & C Orange n 5 Aluminum lake D & C Orange n 5 Zirconium lake D & C Orange n 10 Aluminum lake D & C Orange n 17 Barium lake D & C Yellow n 5 Aluminum lake D & C Yellow n 5 Zirconium lake D & C Yellow n 6 Aluminum lake D & C Yellow n 7 Zirconium lake D & C Yellow n 10 Aluminum Lake FD & C Blue n 1 Aluminum lake FD & C Red n 4 Aluminum lake FD & C Red n 40 Aluminum lake FD & C Yellow n 5 Aluminum lake FD & C Yellow n 6 Aluminum lake The chemical compounds corresponding to each of the organic pigments mentioned above are mentioned in the book "International Cosmetic Ingredient Dictionnary and Handbock", Edition 1997, pages 371 at 386 and 524 at 528, published

  by "The Cosmetic, Toiletry, and Fragrance Association", whose content is

  incorporated in this application for reference.

  The organic lacquer can be present in the composition according to the invention in

  a content ranging from 0.01% to 20% by weight, relative to the total weight of the compound

  position, and preferably ranging from 0.1% to 10% by weight.

  Preferably, the pH of the composition according to the invention can range from 4 to 7.5 and

better from 5 to 7.

  The pH of the composition can be adjusted using a pH adjuster which can be

  a base or a mineral or organic acid.

  As a base, mineral bases can be used such as soda, potash,

  Ammonia, organic bases such as triethanolamine, triisopropyla-

  mine, monoethanolamine, diethanolamine, tri [(2-hydroxy) 1-propyl)] amine, N, N-dimethyl ethanolamine, 2-amino 2-methyl 1-propanol, 2-amino 2

  methyl 1,3-propanediol, triethylamine, dimethylaminopropylamine.

  As the acid, it is possible to use a mineral acid such as hydrochloric acid, or an organic acid such as acetic acid, iactic acid, glycolic acid,

  Mandelic acid, citric acid.

  The composition according to the invention also contains a film-forming polymer

  in the form of solid particles in aqueous dispersion, known ge

  usually under the name of latex or pseudolatex. By polymer in the form of solid particles in aqueous dispersion, is meant a phase containing water

  and optionally a water-soluble compound, in which is dispersed di-

  the polymer in the form of solid particles.

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  In the present application, the term "film-forming polymer" means a polymer capable of forming on its own or in the presence of an auxiliary film-forming agent, a film

  continuous and adherent on a support, especially on keratin materials.

  By polymer in the form of particles in aqueous dispersion, is meant a phase containing water and optionally a compound soluble in water, in

  which is directly dispersed the polymer in the form of particles.

  Among the film-forming polymers which can be used in the composition of the present in

  We can cite polymers of the radical type, polymers of the po type.

  lycondensate, polymers of natural origin, and mixtures thereof.

  By radical film-forming polymer is meant a polymer obtained by polymer-

  sation of unsaturated monomers, in particular ethylenic, each monomer

  being likely to homopolymerize (unlike polycondensates).

  The film-forming polymers of the radical type can in particular be poly-

  or vinyl copolymers, especially acrylic polymers with

  excluding styrene-acrylic polymers, i.e.

  providing at least one styrenic monomer (styrene and its derivatives) and at least one acrylic monomer ((meth) acrylic acid and its derivatives such as esters and

the amides).

  O nyl film-forming polymers can result from the polymerization of

  ethylenically unsaturated nomères having at least one acid group and / or

  esters of these acid monomers and / or amides of these acid monomers

  of. Anlonic film-forming polymers are preferably used, that is to say polymers having at least one monomer with an acid group such as a group

  carboxylic acid or sulfonic acid or phosphonic acid.

  As the monomer carrying an acid group, it is possible to use

  cc, -ethylenic unsaturated boxyls such as acrylic acid, methacry acid-

  lique, crotonic acid, malelic acid, itaconic acid. Preferably (meth) acrylic acid and crotonic acid are used, and more preferably

(meth) acrylic acid.

  The esters of acidic monomers are advantageously chosen from the esters of (meth) acrylic acid (also called (meth) acrylates), in particular alkyl (meth) acrylates, in particular C′-C20 alkyl, preferably CC, aryl (meth) acrylates, in particular C6-C0 aryl, (meth) acrylates

  of hydroxyalkyl, in particular of hydroxyalkyl in C2-C6.

  Among the alkyl (m eth) acrylates, mention may be made of methyl methacryl ate, ethyl methacrylate, butyl methacrylate, isobutyl methacrylate,

  2-ethylhexyl methacrylate, lauryl methacrylate.

  Among the hydroxyalkyl (meth) acrylates, mention may be made of hydroxyethyl acrylate, 2-hydroxypropyl acrylate, hydroxyethyl methacrylate, 2-hydroxypropyl methacrylate. Mention may be made, among aryl (meth) acrylates, of benzyl acrylate and phenyl acrylate. Particularly preferred (meth) acrylic acid esters are

(meth) alkyl acrylates.

  According to the present invention, the alkyl group of the esters can be either fluorinated or perfluorinated, that is to say that part or all of the hydrogen atoms of the

  alkyl groups are substituted by fluorine atoms.

  As amides of the acidic monomers, mention may be made, for example, of (meth) acrylamides, and in particular of N-alkyl (meth) acrylamides, in particular of C2-C 2 -alkyl. N-alkyl (m eth) acryla m ides, there may be mentioned N-ethyl

  acrylamide, N-t-butyl acrylamide and N-t-octyl acrylamide.

  Vinyl film-forming polymers can also result from homopoly-

  merization or copolymerization of monomers chosen from viny esters

  lics and styrene monomers. In particular, these monomers can be polymerized with acidic monomers and / or their esters and their amides,

  such as those mentioned above.

  As an example of vinyl esters, mention may be made of vinyl acetate, neodeca-

  vinyl noate, vinyl pivalate, vinyl benzoate and tbutyl benzoate

vinyl.

  As styrene monomers, mention may be made of styrene and alpha-methyl styrene.

  The list of monomers given is not exhaustive and it is possible to use any

  monomer known to those skilled in the art falling into the categories of monomer-

  acrylic and vinyl res (including the monomers modified by a silicone chain).

  As an aqueous dispersion of acrylic film-forming polymer which can be used according to the invention.

  We can cite those sold under the names NEOCRYL XK90,

  NEOCRYL A-1070 (), NEOCRYL A-1090 (3, NEOCRYL BT-62 (), NEOCRYL A-

  1079, NEOCRYL A-523, NEOCRYL BT-24 by the company AVECIA NEORESINS, DAITOSOL 5000 AD by the company DAITO KASEY KOGYO; Among the polycondensates which can be used as film-forming polymer, mention may be made of anlonic, cationic, nonionic or amphoteric polyurethanes, poly

  urethanes-acrylics, poly-urethanes-polyvinylpirrolidones, polyester-

  polyurethanes, polyether polyurethanes, polyureas, poly-

  ureelpolyurethanes, silicone polyurethanes, and mixtures thereof.

  The film-forming polyurethanes as defined in the invention can also be obtained from polyesters, branched or not, or from alkyds comprising mobile hydrogens which are modified by reaction with a diisocyanate and a

  bifunctional organic compound (for example dihydro, diamino or hydroxyami-

  no), additionally comprising either a carboxylic acid or carboxylate group, or a sulphonic acid or sulphonate group, or even a group

  neutralizable tertiary amine or a quaternary ammonium group.

  As aqueous dispersion of film-forming polyurethane which can be used according to the invention, those marketed under the names NEOREZ R-981, NEOREZ R-974 by the company AVECIA-NEORESINS, the AVALURE UR-4053 can be used,

  AVALURE UR-410 (, AVALURE UR-425'8), AVALURE UR-450 (, SANCURE 875

  , SANCURE 861, SANCURE 878, SANCURE 2060 by the company GOODRICH, IMPRANIL 85 by the company BAYER, AQUAMERE H-1511 by the

HYDROMER company.

  Among the film-forming polycondensates, mention may also be made of polyesters, polyester amides, fatty chain polyesters, polyamides, and epoxy ester resins. The polyesters can be obtained, in known manner, by polycondensation

  dicarboxylic acids with polyols, especially diols.

  The dicarboxylic acid can be aliphatic, alicyclic or aromatic. Examples of such acids include: oxalic acid, malonic acid, dimethylmalonic acid, succinic acid, glutaric acid, adipic acid, pimelic acid, 2,2-dimethylglutaric acid , Azelaque acid, suberic acid, sebacic acid, fumaric acid, malelic acid, itaconic acid, phthalic acid, dodecanedioic acid, 1,3cyclohexanedicarboxylic acid, 1,4-cyclohexa-nedicarboxylic acid, isophthalic acid, terephthalic acid, 2,5-norborane dicarboxylic acid, ',' diplycolic acid, thiodiproplonic acid, 2,5-napUthalenedicarboxylic acid, I 2,6-naphtha-lenedicarboxylic acid. These dicarboxylic acid monomers can be used singly or in combination of at least two dicarboxylic acid monomers. Among these monomers, we choose

  preferably phthalic acid, isophthalic acid, terephthalic acid.

  The diol can be chosen from aliphatic, alicyclic, aromatic diols. Preferably, a diol chosen from: ethylene glycol, diethylene glycol,

  triethylene glycol, 1,3-propanediol, cyclobexane dimethanol, 4butanediol.

  Like other polyols, glycerol, pentaerythritol, sorbitol,

trimethylol propane.

8 2824268

  The polyester amides can be obtained in a similar manner to the polyesters,

  by polycondensation of diacids with diamines or amino alcohols.

  As diamine, ethylenediamine, hexamethylenediamine, meta- or para-phenylenediamine can be used. As amino alcohol, monethanolamine can be used. The polyester may also comprise at least one monomer carrying at least

  a group -SO3M, with M representing a hydrogen atom, an am ion

  monium NH4 + or a metal ion, such as for example a Na +, Li +, K +, Mg2 + ion,

  Ca2 +, Cu2 +, Fe2 +, Fe3 +. One can use in particular an aromatic monomer bi-

  functional comprising such a group-SO3M.

  The aromatic nucleus of the bifunctional aromatic monomer further bearing a group -SO3M as described above can be chosen, for example, from benzene, naphthalene, anthracene, diphenyl, oxydiphenyl, sulfonyldiphenyl,

  methylenediphenyl. As an example, a bi-

  functional additionally carrying a group -SO3M: sulfoisophthalic acid, sulfoterephthalic acid, sulfophthalic acid, 4-sulfonaphthalene-2,7 acid

dicarboxylic.

  In the compositions which are the subject of the invention, it is preferred to use copolymers with

  isophthalate / sulfoisophthalate base, and more particularly copolymers ob-

  held by condensation of di-ethylene glycol, cyclohexane di-methanol, isophthalic acid, sulfoisophthalic acid. Such polymers are sold for example

  under the brand name Eastman AQ by Eastman Chemical Products.

  The polymers of natural origin, optionally modified, can be chosen from shellac resin, sandara gum, dammars, elemis,

  copals, water-insoluble cellulosic polymers, and mixtures thereof.

  Mention may also be made of the polymers resulting from the radical polymerization of one or more radical monomers inside eVou partially at the surface, of pre-existing particles of at least one polymer chosen from the group consisting of polyurethanes, polyureas, polyesters , polyesteramides eVou

  alkyds. These polymers are generally called hybrid polymers.

  The aqueous dispersion comprising one or more film-forming polymers can

  be prepared by the skilled person on the basis of his general knowledge.

  The size of the solid particles of polymer in aqueous dispersion can range from 10

  nm to 500 nm, and preferably from 20 nm to 300 nm.

  The film-forming polymer in aqueous dispersion may be present in the composition.

  tion according to the invention in an amount sufficient to form a film on the materials

  keratin res, in particular in a content ranging from 1% to 60% by weight, preferably from 5% to 40% by weight, of dry matter of film-forming polymer relative to the total weight of the composition.

  The composition according to the invention may comprise an auxiliary film-forming agent.

  tion promoting the formation of a film with the particles of the film-forming polymer. Such a film-forming agent can be chosen from all the compounds known to a person skilled in the art as being capable of fulfilling the desired function, and

  in particular be chosen from plasticizing agents and coalescing agents.

  The medium of the composition of the invention is advantageously an aqueous medium.

  This aqueous medium may consist essentially of water or alternatively also include a mixture of water and of water-miscible solvent such as lower monohycohols having 1 to 5 carbon atoms, glycols having from 2 to 8 carbon atoms, C3-C4 ketones, C2-C4 aldehydes. The water content in the composition can range from 40% to 95% by weight, relative to the total weight of the composition, preferably from 50% to 90% by weight, and better still

60% to 85% by weight.

  The composition according to the invention may also comprise additional coloring materials, different from the organic lakes described above, such as water-soluble dyes, puiferulent dyes such as

  mineral pigments, mother-of-pearl, glitter well known to those skilled in the art

  tier. The dyestuffs may be present, in the composition, in a content ranging from 0.01% to 50% by weight, relative to the weight of the composition,

  preferably from 0.01% to 30% by weight.

  The composition according to the invention can also comprise any cosmetic ingredient.

  as known to a person skilled in the art as being capable of being incorporated into such a composition, such as thickening agents, fillers, spreading agents, wetting agents, dispersing agents, anti-foaming agents, preservatives , UV filters, waxes, oils, cosmetic active ingredients, surfactants, moisturizers, perfumes, stabilizers, antioxidants. Well

  understood, the skilled person will take care to choose this or these possible compounds

  additional, eVou their quantity, such that the advantageous properties

  of the composition co rrespon da nte lon the invention n not be, or su bstantiel-

  not altered by the proposed addition.

  The invention is illustrated in more detail in the following examples.

Example 1:

  Nail varnish was prepared having the following composition: - Polyurethane in aqueous dispersion at 35% in dry matter of polymer (AVALURE UR 405 from GOODRICH) 30 g MA - FD & C Blue n 1 Aluminum lake 0, 9 9 MA Soda qs to adjust the pH - water qs 1 0O g 5 compositions were prepared (respectively compositions A, B. C, D, E) having

  respectively a pH equal to 8; 8.5; 9; 9.5; 10.

  Each composition was prepared, left for 24 hours at temperature

  ambient (25 C), then applied to the horn. Each make-up horn has been dried

  kept in an oven for 24 hours at 30 C. Then, each corm was removed

  keel and staining of the horn was assessed.

  It can be seen that the horns priced with compositions B. C, D and E, then die

  make-up remains very colored, that is to say when the pH of the composition applied

  quée is greater than 8. Only the horn treated with composition A which has a pH

equal to 8 is not stained.

Claims (22)

  1. Cosmetic composition comprising, in an aqueous medium, a filamentous polymer   mogeneous in the form of an aqueous dispersion of solid particles dispersed in said aqueous medium, an organic lacquer, the composition having a pH ranging from 3 to 8. 2. Composition according to Claim 1, characterized in that the pH ranges from 4 to 7.5, and better from 5 to 7.   3. Composition according to claim 1 or 2, characterized in that the lacquer   organic is chosen from the insoluble sodium, potassium and cal-   clum, barium, aluminum, zirconium, strontium, titanium, dyes organic acids.   4. Composition according to claim 3, characterized in that the acid organic dyes are chosen from azo, anthraquinone dyes,   indigodes, xanthenic, pyrenic, quinolinic, triphenylmethane, fluo- Rane.   5. Composition according to any one of the preceding claims, charac-   sée by the fact that the organic lacquer is supported by a mineral support.   6. Composition according to claim 5, characterized in that the support mi   mineral is chosen from particles of clay, alumina, zirconia, metallic oxides   metal, in particular zinc oxide or titanium oxide, talc, carbonate calcium, barium sulfete.   7. Composition according to any one of the preceding claims, charac   due to the fact that the organic lacquer is supported on a support chosen from   particles of alumina, titanium oxide and barium sulfete.   8. Composition according to any one of claims 1 to 4, characterized by   the fact that the organic lacquer is supported by a support chosen from colo phane, aluminum benzoate.   9. Composition according to any one of the preceding claims, charac-   sée by the fact that the organic lacquer is present in a content ranging from 0.01% to 20% by weight, relative to the total weight of the composition, and preferably al from 0.1% to 10% by weight.   10. Composition according to any one of the preceding claims, character-   laughed at by the fact that it comprises at least one pH-modifying agent. 1 2 2824268   11. Composition according to claim 9, characterized in that the modifying agent   pH enhancer is a base chosen from sodium hydroxide, potassium hydroxide, ammonia, triethanolamine, triisopropylamine, monoethanolamine, diethanolamine, tri [(2-hydroxy) 1-propyl)] amine, N, N- dimethyl ethanolamine, 2-amino 2-   methyl 1-propanol, 2-amino 2-methyl 1,3-propanediol, triethylamine, dimer thylaminopropylamine.   12. Composition according to any one of the preceding claims, character   laughed at by the fact that the pH-modifying agent is an acid chosen from acid   hydrochloric acid, acetic acid, lactic acid, glycolic acid, mandelic acid that, citric acid.   13. Composition according to any one of the preceding claims, character   laughed at by the fact that the film-forming polymer in aqueous dispersion is chosen from the group formed by radical polymers, polycondensates, polymers   of natural origin and their mixtures.   14. Composition according to claims 13, characterized in that the poly   radical mothers are chosen from the group formed by vinyl polymers   resulting from the polymerization of monomers chosen from carboxylic acids   as unsaturated oc "D, -ethylenic, esters of these said acids, amides of these-   said acids, vinyl esters, styrenic monomers.   15. Composition according to claim 13, characterized in that the poly-   condensates are chosen from the group formed by polyurethanes, polyes-   ters, rs amid polestes, polyamides, epoxy ester resins.   16. Composition according to claim 13, characterized in that the polymers of natural origin are chosen from the group formed by shellac resin,   sandaraque gum, dammars, elemis, copals, cell polymers   water insoluble losiques, and mixtures thereof.   17. Composition according to any one of the preceding claims, character   laughed at by the fact that the solid particles of polymer have a size ranging from 10 nm to 500 nm.   18. Composition according to any one of the preceding claims, character-   laughed at by the fact that the film-forming polymer in aqueous dispersion is present in   a content ranging from 1% to 60% by weight of dry matter of film-forming polymer   gene, relative to the total weight of the composition, and preferably from 5% to 40% in weight.   19. Composition according to any one of the preceding claims, character-   laughed at by the fact that it comprises a cosmetic ingredient chosen from the group formed by thickening agents, fillers, spreading agents, wetting agents, dispersing agents, defoamers, preservatives, UV filters, waxes , oils, cosmetic active ingredients, surfactants, hydrating agents, perfumes, stabilizers, antioxidants, additional coloring matters.   20. Composition according to any one of the preceding claims, character   laughed at by the fact that it comes in the form of nail polish, eyeliner, lip product, blush or eyeshadow, foundation,   body makeup product, concealer product.   21. Nail varnish comprising a composition according to any one of re vendications 1 to 19.   22. Use of an organic lacquer in a cosmetic composition comprising   nant, in an aqueous medium, a film-forming polymer in the form of an aqueous dispersion of solid particles dispersed in said aqueous medium, the composition having a pH ranging from 3 to 8 for making up keratin materials, in particular the   skin or nails, without staining and / or preventing and / or reducing the disgorges-