FR2818990B1 - PROCESS AND DEVICE FOR DESULFURIZING HYDROCARBONS FILLED WITH THIOPHENIC DERIVATIVES - Google Patents

PROCESS AND DEVICE FOR DESULFURIZING HYDROCARBONS FILLED WITH THIOPHENIC DERIVATIVES

Info

Publication number
FR2818990B1
FR2818990B1 FR0017196A FR0017196A FR2818990B1 FR 2818990 B1 FR2818990 B1 FR 2818990B1 FR 0017196 A FR0017196 A FR 0017196A FR 0017196 A FR0017196 A FR 0017196A FR 2818990 B1 FR2818990 B1 FR 2818990B1
Authority
FR
France
Prior art keywords
hydrocarbons
organic
stage
oxidising
catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR0017196A
Other languages
French (fr)
Other versions
FR2818990A1 (en
Inventor
Silva Pedro Da
Edmond Payen
Jean Yves Carriat
Marc Bisson
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Total Marketing Services SA
Original Assignee
Total Raffinage Distribution SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to FR0017196A priority Critical patent/FR2818990B1/en
Application filed by Total Raffinage Distribution SA filed Critical Total Raffinage Distribution SA
Priority to US10/250,431 priority patent/US20060180501A1/en
Priority to DE60107602T priority patent/DE60107602T2/en
Priority to AT01994923T priority patent/ATE283905T1/en
Priority to JP2002555194A priority patent/JP2004517193A/en
Priority to KR1020037008824A priority patent/KR100824422B1/en
Priority to ES01994923T priority patent/ES2234930T3/en
Priority to PCT/FR2001/004090 priority patent/WO2002053683A1/en
Priority to EP01994923A priority patent/EP1346009B1/en
Publication of FR2818990A1 publication Critical patent/FR2818990A1/en
Application granted granted Critical
Publication of FR2818990B1 publication Critical patent/FR2818990B1/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G53/00—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more refining processes
    • C10G53/02—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more refining processes plural serial stages only
    • C10G53/14—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more refining processes plural serial stages only including at least one oxidation step
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G27/00—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
    • C10G27/04—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen
    • C10G27/12—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen with oxygen-generating compounds, e.g. per-compounds, chromic acid, chromates

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)
  • Saccharide Compounds (AREA)

Abstract

The invention relates to a selective desulphurisation method for thiophene derivatives contained in the hydrocarbons emitted from the distillation of crude oil, refined or not, consisting in oxidising the atoms of thiophene sulphur in sulphone in the presence of an oxidising agent and separating the sulphonated compounds from said hydrocarbons. This inventive method comprises at least one first stage involving the oxidation/absorption by heterogeneous catalysis of the sulphurous compounds in an organic environment, at a temperature of at least 40?C, at atmospheric pressure in the presence of an organic oxidiser from the family of peroxides and peracids, in the presence of a catalyst having a specific surface area greater than 100 m2/g and a porosity varying from 0.2 to 4 ml/g, and a second stage wherein the used catalyst is regenerated.
FR0017196A 2000-12-28 2000-12-28 PROCESS AND DEVICE FOR DESULFURIZING HYDROCARBONS FILLED WITH THIOPHENIC DERIVATIVES Expired - Fee Related FR2818990B1 (en)

Priority Applications (9)

Application Number Priority Date Filing Date Title
FR0017196A FR2818990B1 (en) 2000-12-28 2000-12-28 PROCESS AND DEVICE FOR DESULFURIZING HYDROCARBONS FILLED WITH THIOPHENIC DERIVATIVES
DE60107602T DE60107602T2 (en) 2000-12-28 2001-12-20 METHOD OF DISSOLVING HYDROCARBONS CONTAINING THIOPHEN DERIVATIVES
AT01994923T ATE283905T1 (en) 2000-12-28 2001-12-20 METHOD FOR DESULFURIZING HYDROCARBONS CONTAINING THIOPHENE DERIVATIVES
JP2002555194A JP2004517193A (en) 2000-12-28 2001-12-20 Method and apparatus for desulfurizing hydrocarbons containing thiophene derivatives
US10/250,431 US20060180501A1 (en) 2000-12-28 2001-12-20 Process and device for desulphurizing hydrocarbons containing thiophene derivatives
KR1020037008824A KR100824422B1 (en) 2000-12-28 2001-12-20 Method for desulphurising hydrocarbons containing thiophene derivatives
ES01994923T ES2234930T3 (en) 2000-12-28 2001-12-20 PROCEDURE FOR DESULFURING HYDROCARBONS CONTAINING THIOPHENIC DERIVATIVES.
PCT/FR2001/004090 WO2002053683A1 (en) 2000-12-28 2001-12-20 Method and device for desulphurising hydrocarbons containing thiophene derivatives
EP01994923A EP1346009B1 (en) 2000-12-28 2001-12-20 Method for desulphurising hydrocarbons containing thiophene derivatives

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR0017196A FR2818990B1 (en) 2000-12-28 2000-12-28 PROCESS AND DEVICE FOR DESULFURIZING HYDROCARBONS FILLED WITH THIOPHENIC DERIVATIVES

Publications (2)

Publication Number Publication Date
FR2818990A1 FR2818990A1 (en) 2002-07-05
FR2818990B1 true FR2818990B1 (en) 2004-09-24

Family

ID=8858319

Family Applications (1)

Application Number Title Priority Date Filing Date
FR0017196A Expired - Fee Related FR2818990B1 (en) 2000-12-28 2000-12-28 PROCESS AND DEVICE FOR DESULFURIZING HYDROCARBONS FILLED WITH THIOPHENIC DERIVATIVES

Country Status (9)

Country Link
US (1) US20060180501A1 (en)
EP (1) EP1346009B1 (en)
JP (1) JP2004517193A (en)
KR (1) KR100824422B1 (en)
AT (1) ATE283905T1 (en)
DE (1) DE60107602T2 (en)
ES (1) ES2234930T3 (en)
FR (1) FR2818990B1 (en)
WO (1) WO2002053683A1 (en)

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JP2006518327A (en) * 2002-07-04 2006-08-10 シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ Reactor system with several parallel reactor units
FR2844518B1 (en) * 2002-09-16 2006-05-12 Inst Francais Du Petrole HYDROGEN-FREE DESULFURIZATION PROCESS
EP1403358A1 (en) * 2002-09-27 2004-03-31 ENI S.p.A. Process and catalysts for deep desulphurization of fuels
FR2850041B1 (en) * 2003-01-16 2006-07-07 Totalfinaelf France HYDROTREATING CATALYST, PROCESS FOR PREPARING THE SAME AND USE THEREOF IN A PROCESS FOR PURIFYING HYDROCARBONS
FR2864101B1 (en) * 2003-12-19 2006-03-17 Total France CATALYTIC METHOD FOR PURIFYING LIGHT HYDROCARBONS
ITRM20030598A1 (en) 2003-12-23 2005-06-24 Univ Roma PROCESS AND RELATIVE PLANT FOR DESOLFORATION
US7186328B1 (en) * 2004-09-29 2007-03-06 Uop Llc Process for the regeneration of an adsorbent bed containing sulfur oxidated compounds
KR20070091297A (en) * 2004-12-29 2007-09-10 비피 코포레이션 노쓰 아메리카 인코포레이티드 Oxidative desulfurization process
FR2882761B1 (en) * 2005-03-04 2007-08-31 Inst Francais Du Petrole PROCESS FOR THE DESULFURATION AND / OR DEAZOTATION OF A HYDROCARBONATED LOAD BY OXYDESULFURATION
CA2662627C (en) * 2006-03-03 2013-04-30 Saudi Arabian Oil Company Catalytic process for deep oxidative desulfurization of liquid transportation fuels
WO2008033230A2 (en) * 2006-09-15 2008-03-20 Exxonmobil Research And Engineering Company A method of making porous crystalline materials
KR100882259B1 (en) * 2006-10-12 2009-02-09 주식회사 코캣 A process for reducing sulfur, nitrogen and producing useful oxygenates via selective oxidation in a single step from hydrogen carbon materials
JP2008110298A (en) * 2006-10-30 2008-05-15 Nippon Shokubai Co Ltd Method for regenerating catalyst for dehydrating glycerin
JP5269321B2 (en) * 2007-01-11 2013-08-21 株式会社Ａｄｅｋａ Desulfurization agent for ultra-deep oxidative desulfurization and oxidative desulfurization method using the same
KR101642695B1 (en) 2007-05-03 2016-07-27 오테라, 인코포레이티드 Product containing monomer and polymers of titanyls and methods for making same
US8894843B2 (en) 2008-03-26 2014-11-25 Auterra, Inc. Methods for upgrading of contaminated hydrocarbon streams
MX2010010523A (en) * 2008-03-26 2011-11-02 Auterra Inc Sulfoxidation catalysts and methods and systems of using same.
US8241490B2 (en) * 2008-03-26 2012-08-14 Auterra, Inc. Methods for upgrading of contaminated hydrocarbon streams
US8197671B2 (en) * 2008-03-26 2012-06-12 Auterra, Inc. Methods for upgrading of contaminated hydrocarbon streams
US9061273B2 (en) 2008-03-26 2015-06-23 Auterra, Inc. Sulfoxidation catalysts and methods and systems of using same
US9206359B2 (en) 2008-03-26 2015-12-08 Auterra, Inc. Methods for upgrading of contaminated hydrocarbon streams
US8298404B2 (en) 2010-09-22 2012-10-30 Auterra, Inc. Reaction system and products therefrom
US8764973B2 (en) 2008-03-26 2014-07-01 Auterra, Inc. Methods for upgrading of contaminated hydrocarbon streams
CN102245563B (en) * 2008-12-15 2015-04-15 巴斯夫欧洲公司 Method for producing N-vinylcarboxamides
US8562821B2 (en) * 2008-12-15 2013-10-22 Council of Scientific & Industrial Research Center for High Technology Process for the removal of sulfones from oxidized hydrocarbon fuels
US9296960B2 (en) 2010-03-15 2016-03-29 Saudi Arabian Oil Company Targeted desulfurization process and apparatus integrating oxidative desulfurization and hydrodesulfurization to produce diesel fuel having an ultra-low level of organosulfur compounds
US20110220550A1 (en) * 2010-03-15 2011-09-15 Abdennour Bourane Mild hydrodesulfurization integrating targeted oxidative desulfurization to produce diesel fuel having an ultra-low level of organosulfur compounds
US8658027B2 (en) 2010-03-29 2014-02-25 Saudi Arabian Oil Company Integrated hydrotreating and oxidative desulfurization process
US8888994B2 (en) * 2010-04-22 2014-11-18 The United States Of America As Represented By The Administrator Of The U.S. Environmental Protection Agency Method for deep desulphurization of hydrocarbon fuels
US10081770B2 (en) 2010-09-07 2018-09-25 Saudi Arabian Oil Company Process for oxidative desulfurization and sulfone disposal using solvent deasphalting
US9598647B2 (en) 2010-09-07 2017-03-21 Saudi Arabian Oil Company Process for oxidative desulfurization and sulfone disposal using solvent deasphalting
US9828557B2 (en) 2010-09-22 2017-11-28 Auterra, Inc. Reaction system, methods and products therefrom
US9005433B2 (en) 2011-07-27 2015-04-14 Saudi Arabian Oil Company Integrated process for in-situ organic peroxide production and oxidative heteroatom conversion
CN103827268B (en) 2011-07-29 2016-05-18 沙特阿拉伯石油公司 Selective midbarrel hydrotreating method
US8906227B2 (en) 2012-02-02 2014-12-09 Suadi Arabian Oil Company Mild hydrodesulfurization integrating gas phase catalytic oxidation to produce fuels having an ultra-low level of organosulfur compounds
KR101918775B1 (en) * 2012-08-23 2018-11-15 에스케이이노베이션 주식회사 Oxidative desulfurization process for hydrocarbon
US8920635B2 (en) 2013-01-14 2014-12-30 Saudi Arabian Oil Company Targeted desulfurization process and apparatus integrating gas phase oxidative desulfurization and hydrodesulfurization to produce diesel fuel having an ultra-low level of organosulfur compounds
US10246647B2 (en) 2015-03-26 2019-04-02 Auterra, Inc. Adsorbents and methods of use
US10450516B2 (en) 2016-03-08 2019-10-22 Auterra, Inc. Catalytic caustic desulfonylation
CN114130384B (en) * 2020-09-03 2023-12-12 中国石油化工股份有限公司 Water-soluble catalyst, preparation method and application thereof, and method for processing residual oil

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Publication number Priority date Publication date Assignee Title
US3595778A (en) * 1968-12-16 1971-07-27 Texaco Inc Desulfurization process including an oxidation step with ozone and a vanadium catalyst
US3565793A (en) * 1968-12-27 1971-02-23 Texaco Inc Desulfurization with a catalytic oxidation step
US4051014A (en) * 1972-12-26 1977-09-27 Atlantic Richfield Company Process for treating sulfur-containing hydrocarbon feedstocks to produce high yield coke
GB9903164D0 (en) * 1999-02-15 1999-04-07 Ici Plc Sulpher removal
FR2802939B1 (en) * 1999-12-28 2005-01-21 Elf Antar France PROCESS FOR THE DESULFURATION OF THIOPHENE DERIVATIVES CONTAINED IN FUELS

Also Published As

Publication number Publication date
DE60107602T2 (en) 2005-11-24
WO2002053683A1 (en) 2002-07-11
EP1346009B1 (en) 2004-12-01
KR20030065585A (en) 2003-08-06
US20060180501A1 (en) 2006-08-17
ES2234930T3 (en) 2005-07-01
FR2818990A1 (en) 2002-07-05
DE60107602D1 (en) 2005-01-05
ATE283905T1 (en) 2004-12-15
JP2004517193A (en) 2004-06-10
KR100824422B1 (en) 2008-04-22
EP1346009A1 (en) 2003-09-24

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Effective date: 20081020