FR2814475A1 - Reduction of yellowing of textile articles treated with finishing agents based on amino silicone oil, involves adding acid or salt type derivative of phosphonic acid to finishing composition - Google Patents
Reduction of yellowing of textile articles treated with finishing agents based on amino silicone oil, involves adding acid or salt type derivative of phosphonic acid to finishing composition Download PDFInfo
- Publication number
- FR2814475A1 FR2814475A1 FR0012296A FR0012296A FR2814475A1 FR 2814475 A1 FR2814475 A1 FR 2814475A1 FR 0012296 A FR0012296 A FR 0012296A FR 0012296 A FR0012296 A FR 0012296A FR 2814475 A1 FR2814475 A1 FR 2814475A1
- Authority
- FR
- France
- Prior art keywords
- sep
- yellowing
- treated
- composition
- phosphonic acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 23
- 238000004383 yellowing Methods 0.000 title claims abstract description 19
- 239000004753 textile Substances 0.000 title claims abstract description 17
- 150000003839 salts Chemical class 0.000 title claims abstract description 14
- 239000002253 acid Substances 0.000 title claims abstract description 11
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 11
- 150000003009 phosphonic acids Chemical class 0.000 title abstract description 4
- 229920013822 aminosilicone Polymers 0.000 title description 16
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000004205 dimethyl polysiloxane Substances 0.000 claims abstract description 16
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims abstract description 16
- 238000000034 method Methods 0.000 claims abstract description 10
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 10
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims abstract 7
- -1 polydimethylsiloxane Polymers 0.000 claims description 14
- 239000000839 emulsion Substances 0.000 claims description 8
- 150000003007 phosphonic acid derivatives Chemical class 0.000 claims description 8
- 238000010438 heat treatment Methods 0.000 claims description 6
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 claims description 5
- 239000003638 chemical reducing agent Substances 0.000 claims description 4
- 230000002378 acidificating effect Effects 0.000 abstract description 2
- 125000003277 amino group Chemical group 0.000 abstract 2
- 239000003921 oil Substances 0.000 description 18
- 229920000742 Cotton Polymers 0.000 description 5
- 229940120146 EDTMP Drugs 0.000 description 5
- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 description 5
- NFDRPXJGHKJRLJ-UHFFFAOYSA-N edtmp Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CCN(CP(O)(O)=O)CP(O)(O)=O NFDRPXJGHKJRLJ-UHFFFAOYSA-N 0.000 description 5
- 239000004744 fabric Substances 0.000 description 5
- 239000004094 surface-active agent Substances 0.000 description 5
- 238000011282 treatment Methods 0.000 description 5
- 229940042400 direct acting antivirals phosphonic acid derivative Drugs 0.000 description 4
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 150000002191 fatty alcohols Chemical class 0.000 description 3
- 239000012634 fragment Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- YDONNITUKPKTIG-UHFFFAOYSA-N [Nitrilotris(methylene)]trisphosphonic acid Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CP(O)(O)=O YDONNITUKPKTIG-UHFFFAOYSA-N 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 239000004673 amino silicone softener Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000005303 weighing Methods 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 239000004907 Macro-emulsion Substances 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 239000008199 coating composition Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 description 1
- 238000010981 drying operation Methods 0.000 description 1
- DUYCTCQXNHFCSJ-UHFFFAOYSA-N dtpmp Chemical compound OP(=O)(O)CN(CP(O)(O)=O)CCN(CP(O)(=O)O)CCN(CP(O)(O)=O)CP(O)(O)=O DUYCTCQXNHFCSJ-UHFFFAOYSA-N 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000004530 micro-emulsion Substances 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
- D06M13/288—Phosphonic or phosphonous acids or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/44—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen containing nitrogen and phosphorus
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/44—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen containing nitrogen and phosphorus
- D06M13/447—Phosphonates or phosphinates containing nitrogen atoms
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
- D06M15/6436—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing amino groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/50—Modified hand or grip properties; Softening compositions
Abstract
Description
<Desc/Clms Page number 1> <Desc / Clms Page number 1>
L'invention concerne notamment un procédé pour réduire le jaunissement d'articles textiles traités avec des agents de finissage à base d'huile amino silicone. In particular, the invention relates to a method for reducing the yellowing of textile articles treated with finishing agents based on amino silicone oil.
L'utilisation d'agents de finissage adoucissants à base d'amino silicone permet d'obtenir un toucher particulièrement agréable en donnant du gonflant et de la souplesse à l'article textile traité. The use of softening finishing agents based on amino silicone makes it possible to obtain a particularly pleasant feel by giving the textile article treated a swelling and flexibility.
Mais l'utilisation de ces agents à base d'amino silicone a tendance à jaunir les articles lors des traitements thermiques. But the use of these agents based on amino silicone tends to yellow the articles during heat treatments.
Certes le jaunissement peut être diminué en utilisant des huiles amino silicone contenant un pourcentage relativement faible d'azote mais ceci présente l'inconvénient majeur de diminuer le pouvoir adoucissant du produit. While yellowing can be decreased by using amino silicone oils containing a relatively low percentage of nitrogen, this has the major disadvantage of reducing the softening power of the product.
X est également possible de diminuer le jaunissement des articles en réduisant les températures de séchage ou de traitement thermique. Cette dernière solution est industriellement peu satisfaisante car généralement, les adoucissants à base d'amino silicone sont utilisés conjointement à des
résines qui nécessitent une température supérieure à 140 C pour réagir correctement avec le support traité. It is also possible to reduce the yellowing of articles by reducing the drying or heat treatment temperatures. This latter solution is industrially unsatisfactory since, generally, the amino-silicone softeners are used together with
resins that require a temperature above 140 C to react properly with the treated substrate.
H existe donc un besoin pour des moyens qui permettraient de diminuer le jaunissement des articles textiles traités avec des agents de finissage adoucissants à base d'huile amino silicone et n'ayant pas d'influence défavorable sur le toucher. There is therefore a need for means which would make it possible to reduce the yellowing of textile articles treated with softening finishing agents based on amino silicone oil and having no adverse influence on the touch.
L'invention vise à satisfaire ce besoin. The invention aims to satisfy this need.
Plus particulièrement, l'invention concerne un procédé pour réduire le jaunissement, provoqué par un traitement thermique ultérieur, d'un article textile préalablement traité avec une composition aqueuse d'huile de polydiméthylsiloxane à fonctionnalité amino ayant une teneur massique d'azote comprise entre 0,05 % et 7, 5 % servant d'agent de finissage adoucissant, caractérisé en ce qu'on ajoute à ladite composition aqueuse d'huile de polydiméthylsiloxane à fonctionnalité amino un dérivé de l'acide phosphonique sous forme d'acide ou sous forme de sel hydrosoluble, à titre d'agent réducteur du jaunissement. More particularly, the invention relates to a method for reducing the yellowing, caused by a subsequent heat treatment, of a textile article previously treated with an aqueous amino-functional polydimethylsiloxane oil composition having a nitrogen mass content of between 0.degree. , 05% and 7.5% being used as a softening finishing agent, characterized in that a phosphonic acid derivative in the form of acid or in the form of phosphonic acid is added to said aqueous composition of amino-functional polydimethylsiloxane oil. of water-soluble salt, as reducing agent for yellowing.
<Desc/Clms Page number 2> <Desc / Clms Page number 2>
L'invention concerne aussi une composition aqueuse de finissage adoucissant pour articles textiles comprenant une huile de polydiméthylsiloxane à fonctionnalité amino ayant une teneur massique d'azote comprise entre 0,05 % et 7,5 %, caractérisée en ce qu'elle comprend, en outre, un dérivé de l'acide phosphonique sous forme acide ou sous forme de sel hydrosoluble. The invention also relates to an aqueous softening finishing composition for textile articles comprising an amino-functional polydimethylsiloxane oil having a mass content of nitrogen of between 0.05% and 7.5%, characterized in that it comprises, in in addition, a phosphonic acid derivative in acid form or in the form of water-soluble salt.
De préférence, la composition aqueuse est une émulsion. Preferably, the aqueous composition is an emulsion.
Selon l'invention, il a été observé de manière surprenante que l'utilisation de dérivés d'acide phosphonique permettait de réduire grandement le jaunissement des articles textiles traités avec des adoucissants à base d'huile amino silicone au cours des opérations de séchage et de traitement thermique. According to the invention, it has surprisingly been observed that the use of phosphonic acid derivatives makes it possible to greatly reduce the yellowing of textile articles treated with softeners based on amino silicone oil during the drying and drying operations. heat treatment.
Les principaux adoucissants à base d'huile amino silicone appartiennent généralement à au moins l'un des trois types suivants : - huile de polydiméthylsiloxane à fonction diamino contenant le fragment
- huile de polydiméthylsiloxane à fonction amino contenant le fragment
- huile de polydiméthylsiloxane à fonction amine stériquement encombrée contenant le fragment
The main softeners based on amino silicone oil generally belong to at least one of the following three types: diamino-functional polydimethylsiloxane oil containing the fragment
amino-functional polydimethylsiloxane oil containing the fragment
sterically hindered amine-containing polydimethylsiloxane oil containing the fragment
Cette liste n'est pas limitative et l'on pourrait utiliser d'autres types d'huiles aminosilicones. This list is not limiting and other types of amino silicone oils could be used.
<Desc/Clms Page number 3> <Desc / Clms Page number 3>
Les huiles de polydiméthylsiloxanes aminés sont caractérisées par leur teneur massique d'azote, qui varient généralement de 0, 05 à 7, 5 % mais plus couramment de 0,2 à 2%. Les émulsions aqueuses d'huile de polydiméthylsiloxanes aminés que l'on utilise préférentiellement sont sous forme de micro ou macroémulsions et contiennent généralement une teneur massique de polydiméthylsiloxane aminé comprise entre 5 et 50 % plus généralement entre 10 et 25 %, et un agent tensio-actif dont la teneur massique dans la composition est comprise entre 2,5 et 40 %. De nombreux agents tensio-actifs sont connus et utilisables. Un agent tensio-actif préféré est un alcool gras oxyéthyléné. Amino polydimethylsiloxane oils are characterized by their mass content of nitrogen, which generally ranges from 0.05 to 7.5% but more usually from 0.2 to 2%. The aqueous emulsions of aminated polydimethylsiloxane oil which are preferably used are in the form of micro or macroemulsions and generally contain a mass content of polydimethylsiloxane amine of between 5 and 50%, more generally between 10 and 25%, and a surfactant. active whose mass content in the composition is between 2.5 and 40%. Many surfactants are known and usable. A preferred surfactant is an oxyethylenated fatty alcohol.
Comme dérivés de l'acide phosphonique utilisable, on peut utiliser notamment des dérivés commercialement disponibles tels que : l'acide nitrilotri (méthylène phosphonique) (en abrégé NTMP), l'acide éthylènediamine tétraméthylène phosphonique (en abrégé EDTMP), l'acide (1-hydroxyéthylidène) diphosphonique (en abrégé HEDP), et l'acide diéthylène triamine penta- (méthylène phosphonique) (en abrégé DTMP) et leurs sels. As derivatives of the phosphonic acid that may be used, it is possible to use especially commercially available derivatives such as: nitrilotri (methylenephosphonic acid) (abbreviated as NTMP), ethylenediamine tetramethylenephosphonic acid (abbreviated to EDTMP), and acid ( 1-hydroxyethylidene) diphosphonic acid (abbreviated to HEDP), and diethylene triamine penta- (methylene phosphonic acid) (abbreviated as DTMP) and their salts.
Pour des motifs de disponibilité commerciale, l'utilisation du sel de sodium des dérivés d'acide phosphonique sera la plus courante mais il va de soi que l'on pourrait leur substituer d'autres sels, par exemple d'ammonium, de potassium ou de magnésium et que l'utilisation de ces autres sels doit être considérée comme incluse dans le cadre de l'invention. For reasons of commercial availability, the use of the sodium salt of phosphonic acid derivatives will be the most common but it is obvious that they could be substituted for other salts, for example ammonium, potassium or magnesium and that the use of these other salts should be considered as included within the scope of the invention.
Ces dérivés de l'acide phosphorique et leurs sels sont disponibles en solution dans l'eau ou sous forme de poudre. These phosphoric acid derivatives and their salts are available in solution in water or in powder form.
Les propriétés séquestrantes de ces produits sont connues de l'homme de l'art, ce qui explique leur usage courant dans les bains de blanchiment mais aussi dans les formulations détergentes. The sequestering properties of these products are known to those skilled in the art, which explains their common use in bleaching baths but also in detergent formulations.
D'autre dérivés de l'acide phosphonique, comme par exemple les sels
d'acides alkylaminométhylènephosphoniques, décrits dans le brevet français 2 707 308 à titre d'agents ignifuges, permettent également de diminuer de Other derivatives of phosphonic acid, for example salts
of alkylaminomethylenephosphonic acids, described in French Pat. No. 2,707,308 as flameproofing agents, also make it possible to reduce
<Desc/Clms Page number 4><Desc / Clms Page number 4>
manière surprenante le jaunissement des articles textiles lors du traitement avec des adoucissants à base d'amino silicone. surprisingly the yellowing of textile articles during the treatment with softeners based on amino silicone.
Les dérivés de l'acide phosphonique ou leurs sels peuvent être ajoutés à raison de 2 à 200 % en poids par rapport à la quantité d'huile amino silicone. The phosphonic acid derivatives or their salts may be added in a proportion of 2 to 200% by weight relative to the amount of amino silicone oil.
Les compositions de l'invention sont de préférence, appliquées sur l'article textile par imprégnation à partir de bains de foulardage, puis les articles ainsi traités sont exprimés au foulard et séchés à une température de l'ordre de 100 à 2200 C. Le pH des bains de foulardage est réglé entre 1 et 9, de préférence entre 2,5 et 7. The compositions of the invention are preferably applied to the textile article by impregnation from padding baths, then the articles thus treated are expressed in a head scarf and dried at a temperature of the order of 100 to 2200 C. pH of the padding baths is set between 1 and 9, preferably between 2.5 and 7.
L'utilisation de dérivés de l'acide phosphonique dans des formulations d'enduction ou dans des pâtes d'impression est également réalisable. The use of phosphonic acid derivatives in coating formulations or in printing pastes is also feasible.
Les articles textiles susceptibles de bénéficier de la présente invention sont notamment un tissu, un tricot, un non-tissé en coton, laine, polyester, polyamide, acrylique, viscose ou mélange de ces différentes matières fibreuses. The textile articles that may benefit from the present invention are in particular a fabric, a knit, a nonwoven of cotton, wool, polyester, polyamide, acrylic, viscose or a mixture of these different fibrous materials.
Les exemples donnés ci-après à titre indicatif et non limitatif permettront de mieux comprendre l'invention. The examples given below by way of indication and not limitation will allow a better understanding of the invention.
Les méthodes d'évaluation suivantes ont été utilisées :
Evaluation du jaunissement :
On mesure à l'aide d'un spectrocolorimètre Minolta CM-3600d le degré de blanc d'un échantillon de tissu traité avec l'agent de l'invention. La mesure du degré de blanc est faite sur des échantillons séchés à 1200C, puis traités à 1800C pendant 1 minute. La mesure du degré de blanc est exprimé en Wl CIE. The following evaluation methods were used:
Evaluation of yellowing:
The degree of whiteness of a tissue sample treated with the agent of the invention is measured using a Minolta CM-3600d spectrocolorimeter. The measurement of the degree of whiteness is made on samples dried at 1200C, then treated at 1800C for 1 minute. The measure of the degree of whiteness is expressed in Wl CIE.
Le produit M1 est une émulsion aqueuse d'amino silicone dont l'extrait sec est de 25%
Le produit M1, présenté à un pH de 4 contient : - 15 % d'huile amino silicone dont la teneur en masse de N est de 0,5% - 10 % de tensio-actif (alcool gras oxyéthyléné) The product M1 is an aqueous emulsion of amino silicone whose solids content is 25%
The product M1, presented at a pH of 4 contains: - 15% of amino silicone oil whose mass content of N is 0.5% - 10% of surfactant (oxyethylenated fatty alcohol)
<Desc/Clms Page number 5> <Desc / Clms Page number 5>
Le produit M2 est une émulsion aqueuse d'amino silicone dont l'extrait sec est de 25 %. The product M2 is an aqueous emulsion of amino silicone whose solids content is 25%.
Le produit M2, présenté à un pH de 4 contient : - 13 % d'huile amino silicone dont la teneur en masse de N est de 1% - 12 % de tensio-actif (alcool gras oxyéthyléné). The M2 product, presented at a pH of 4 contains: 13% of amino silicone oil whose content in mass of N is from 1% to 12% of surfactant (oxyethylenated fatty alcohol).
Le produit P-ign correspond au produit décrit dans l'exemple n'1 du brevet français 2 707 308 concernant des ignifuges pour textiles à base d'acides alkylaminométhylènephosphoniques. The product P-ign corresponds to the product described in Example No. 1 of French Patent 2,707,308 relating to flame retardants for textiles based on alkylaminomethylenephosphonic acids.
Le produit P-ign est une solution à 50 % d'acide méthylaminobis (méthylènephosphonique) neutralisé avec un équivalent de dicyandiamide et un équivalent d'ammoniaque. P-ign is a 50% solution of methylaminobis (methylenephosphonic acid) neutralized with one equivalent of dicyandiamide and one ammonia equivalent.
Exemples 1 à 17
On imprègne un tissu 100% coton, azuré optiquement, d'un grammage de 125g/m2, dans différents bains de foulardage, les tissus sont ensuite exprimés et séchés à 120 C, puis traités 1 minute à 180 C. Puis on mesure le degré de blanc des différents échantillons. Examples 1 to 17
An impregnated fabric 100% cotton, optically azure, of a weight of 125 g / m2, in different padding baths, the tissues are then expressed and dried at 120 C, then treated for 1 minute at 180 C. Then the degree is measured of white different samples.
La composition des bains de foulardage et les résultats obtenus sont donnés dans les tableaux suivants :
The composition of the padding baths and the results obtained are given in the following tables:
<tb>
<tb> exemple <SEP> 1 <SEP> 2 <SEP> 3 <SEP> 4
<tb> M1 <SEP> en <SEP> gel <SEP> 40 <SEP> 40 <SEP> 40 <SEP> 40
<tb> NTMP <SEP> en <SEP> g/t0, <SEP> 5 <SEP> 1 <SEP> 2
<tb> degré <SEP> de <SEP> blanc <SEP> WI-CIE <SEP> 116, <SEP> 3 <SEP> 117, <SEP> 5 <SEP> 118, <SEP> 5 <SEP> 120
<tb> après <SEP> l'à <SEP> 180 <SEP> C
<tb> <Tb>
<tb> example <SEP> 1 <SEP> 2 <SEP> 3 <SEP> 4
<tb> M1 <SEP> in <SEP> freeze <SEP> 40 <SEP> 40 <SEP> 40 <SEP> 40
<tb> NTMP <SEP> in <SEP> g / t0, <SEP> 5 <SEP> 1 <SEP> 2
<tb> degree <SEP> of <SEP> white <SEP> WI-CIE <SEP> 116, <SEP> 3 <SEP> 117, <SEP> 5 <SEP> 118, <SEP> 5 <SEP> 120
<tb> after <SEP> at <SEP> 180 <SEP> C
<Tb>
<tb>
<tb> exemple <SEP> 1 <SEP> 5 <SEP> 6 <SEP> 7
<tb> M1 <SEP> en <SEP> gll <SEP> 40 <SEP> 40 <SEP> 40 <SEP> 40
<tb> DTMPA <SEP> en <SEP> gll <SEP> 0, <SEP> 5 <SEP> 1 <SEP> 2
<tb> degré <SEP> de <SEP> blanc <SEP> WI-CIE <SEP> 116, <SEP> 3 <SEP> 117, <SEP> 9 <SEP> 119, <SEP> 7 <SEP> 120, <SEP> 3
<tb> après <SEP> l'à <SEP> 180 <SEP> C
<tb> <Tb>
<tb> example <SEP> 1 <SEP> 5 <SEP> 6 <SEP> 7
<tb> M1 <SEP> in <SEP> gll <SEP> 40 <SEP> 40 <SEP> 40 <SEP> 40
<tb> DTMPA <SEP> in <SEP> gll <SEP> 0, <SEP> 5 <SEP> 1 <SEP> 2
<tb> degree <SEP> of <SEP> white <SEP> WI-CIE <SEP> 116, <SEP> 3 <SEP> 117, <SEP> 9 <SEP> 119, <SEP> 7 <SEP> 120, <SEP> 3
<tb> after <SEP> at <SEP> 180 <SEP> C
<Tb>
<Desc/Clms Page number 6> <Desc / Clms Page number 6>
<tb>
<tb> exemple <SEP> 1 <SEP> 8 <SEP> 9 <SEP> 10
<tb> M1 <SEP> en <SEP> gel <SEP> 40 <SEP> 40 <SEP> 40 <SEP> 40
<tb> HEDP <SEP> en <SEP> g/l <SEP> 0,5 <SEP> 1 <SEP> 2
<tb> degré <SEP> de <SEP> blanc <SEP> WI-CIE <SEP> 116, <SEP> 3 <SEP> 122, <SEP> 4 <SEP> 124, <SEP> 0 <SEP> 126, <SEP> 7
<tb> après <SEP> l'à <SEP> 180 <SEP> C
<tb> <Tb>
<tb> example <SEP> 1 <SEP> 8 <SEP> 9 <SEP> 10
<tb> M1 <SEP> in <SEP> freeze <SEP> 40 <SEP> 40 <SEP> 40 <SEP> 40
<tb> HEDP <SEP> in <SEP> g / l <SEP> 0.5 <SEP> 1 <SEP> 2
<tb> degree <SEP> of <SEP> white <SEP> WI-CIE <SEP> 116, <SEP> 3 <SEP> 122, <SEP> 4 <SEP> 124, <SEP> 0 <SEP> 126, <SEP> 7
<tb> after <SEP> at <SEP> 180 <SEP> C
<Tb>
<tb>
<tb> exemple <SEP> 1 <SEP> 11 <SEP> 12 <SEP> 13
<tb> M1 <SEP> en <SEP> gel <SEP> 40 <SEP> 40 <SEP> 40 <SEP> 40
<tb> EDTMP <SEP> en <SEP> gel <SEP> 0, <SEP> 5 <SEP> 1 <SEP> 2
<tb> degré <SEP> de <SEP> blanc <SEP> WO-WIE <SEP> 116, <SEP> 3 <SEP> 116, <SEP> 0 <SEP> 122, <SEP> 3 <SEP> 124, <SEP> 1
<tb> après <SEP> l'à <SEP> 180 <SEP> C
<tb> <Tb>
<tb> example <SEP> 1 <SEP> 11 <SEP> 12 <SEP> 13
<tb> M1 <SEP> in <SEP> freeze <SEP> 40 <SEP> 40 <SEP> 40 <SEP> 40
<tb> EDTMP <SEP> in <SEP> freeze <SEP> 0, <SEP> 5 <SEP> 1 <SEP> 2
<tb> degree <SEP> of <SEP> white <SEP> WO-WIE <SEP> 116, <SEP> 3 <SEP> 116, <SEP> 0 <SEP> 122, <SEP> 3 <SEP> 124, <SEP> 1
<tb> after <SEP> at <SEP> 180 <SEP> C
<Tb>
<tb>
<tb> exemple <SEP> 1 <SEP> 14 <SEP> 15 <SEP> 16
<tb> M1 <SEP> en <SEP> gel <SEP> 40 <SEP> 40 <SEP> 40 <SEP> 40
<tb> P-igneng/t05'12
<tb> degré <SEP> de <SEP> blanc <SEP> WI-CIE <SEP> 116, <SEP> 3 <SEP> 122, <SEP> 4 <SEP> 123, <SEP> 1 <SEP> 123, <SEP> 4
<tb> après <SEP> l'à <SEP> 180 <SEP> C
<tb> <Tb>
<tb> example <SEP> 1 <SEP> 14 <SEP> 15 <SEP> 16
<tb> M1 <SEP> in <SEP> freeze <SEP> 40 <SEP> 40 <SEP> 40 <SEP> 40
<tb> P-igneng / t05'12
<tb> degree <SEP> of <SEP> white <SEP> WI-CIE <SEP> 116, <SEP> 3 <SEP> 122, <SEP> 4 <SEP> 123, <SEP> 1 <SEP> 123, <SEP> 4
<tb> after <SEP> at <SEP> 180 <SEP> C
<Tb>
L'exemple 1 est le témoin c'est-à-dire I le bain de foulardage dans lequel il n'y a pas de phophonate. Example 1 is the control, i.e., the padding bath in which there is no phophonate.
Les exemples 2-17 montrent que les différents phosphonates utilisés permettent de réduire ou éviter le jaunissement du support traité. Examples 2-17 show that the various phosphonates used make it possible to reduce or avoid the yellowing of the treated support.
Exemples 18 à 21
On imprègne un tissu 100 % coton, azuré optiquement d'un grammage de 125g/m2, dans différents bains de foulardage, les tissus sont ensuite exprimés et séchés à 1200C puis traités 1 minute à 180 C. Puis on mesure le degré de blanc des différents échantillons. Examples 18 to 21
An impregnated fabric 100% cotton, optically azure of a weight of 125 g / m2, in different padding baths, the tissues are then expressed and dried at 1200C and then treated for 1 minute at 180 C. Then the degree of white of the different samples.
<Desc/Clms Page number 7> <Desc / Clms Page number 7>
La composition des bains de foulardage et les résultats obtenus sont donnés dans les tableaux suivants.
The composition of the padding baths and the results obtained are given in the following tables.
<tb>
<tb> exemple <SEP> 17 <SEP> 18 <SEP> 19 <SEP> 20
<tb> M2 <SEP> en <SEP> g/l <SEP> 40 <SEP> 40 <SEP> 40 <SEP> 40
<tb> HEDP <SEP> en <SEP> gel <SEP> 2 <SEP> 4 <SEP> 8
<tb> degré <SEP> de <SEP> blanc <SEP> WI-CIE <SEP> 113, <SEP> 5 <SEP> 117, <SEP> 5 <SEP> 118, <SEP> 8 <SEP> 122
<tb> après <SEP> l'à <SEP> 180 <SEP> C
<tb> <Tb>
<tb> example <SEP> 17 <SEP> 18 <SEP> 19 <SEP> 20
<tb> M2 <SEP> in <SEP> g / l <SEP> 40 <SEP> 40 <SEP> 40 <SEP> 40
<tb> HEDP <SEP> in <SEP> freeze <SEP> 2 <SEP> 4 <SEP> 8
<tb> degree <SEP> of <SEP> white <SEP> WI-CIE <SEP> 113, <SEP> 5 <SEP> 117, <SEP> 5 <SEP> 118, <SEP> 8 <SEP> 122
<tb> after <SEP> at <SEP> 180 <SEP> C
<Tb>
<tb>
<tb> exemple <SEP> 17 <SEP> 21 <SEP> 22 <SEP> 23
<tb> M2 <SEP> en <SEP> gel <SEP> 40 <SEP> 40 <SEP> 40 <SEP> 40
<tb> EDTMP <SEP> en <SEP> g/l <SEP> 2 <SEP> 4 <SEP> 8
<tb> degré <SEP> de <SEP> blanc <SEP> WI-CIE <SEP> 113, <SEP> 5 <SEP> 116, <SEP> 0 <SEP> 117, <SEP> 8 <SEP> 121, <SEP> 3
<tb> après <SEP> 1'à <SEP> 180 <SEP> C
<tb> <Tb>
<tb> example <SEP> 17 <SEP> 21 <SEP> 22 <SEP> 23
<tb> M2 <SEP> in <SEP> freeze <SEP> 40 <SEP> 40 <SEP> 40 <SEP> 40
<tb> EDTMP <SEP> in <SEP> g / l <SEP> 2 <SEP> 4 <SEP> 8
<tb> degree <SEP> of <SEP> white <SEP> WI-CIE <SEP> 113, <SEP> 5 <SEP> 116, <SEP> 0 <SEP> 117, <SEP> 8 <SEP> 121, <SEP> 3
<tb> after <SEP>1'to<SEP> 180 <SEP> C
<Tb>
L'exemple n 17 est le témoin c'est-à-dire le bain de foulardage dans lequel il n'y a pas de phosphonate.
Example 17 is the control ie the padding bath in which there is no phosphonate.
On constate que l'exemple n 17 jaunit plus que l'exemple nol En effet, le pourcentage d'azote dans l'huile amino silicone contenue dans
l'émulsion M2 est supérieure au pourcentage d'azote contenu dans l'émulsion M1 Les exemples 18-21 montrent que l'addition d'un phosphonate dans le bain de foulardage permet de réduire le jaunissement du support traité avec l'émulsion M2. It can be seen that Example 17 yellows more than the example. In fact, the percentage of nitrogen in the amino silicone oil contained in
the emulsion M2 is greater than the percentage of nitrogen contained in the emulsion M1. Examples 18-21 show that the addition of a phosphonate in the padding bath makes it possible to reduce the yellowing of the support treated with the emulsion M2.
Exemples 24 à 27
On imprègne un tissu 100% coton d'un grammage 125g/m2, dans
différent bains de foulardage, les tissus sont ensuite exprimés et séchés à 120 C puis traités 1 minute à 170 C. Puis on mesure le degré de blanc des différents échantillons. Examples 24 to 27
A 100% cotton fabric weighing 125 g / m2 is impregnated into
different padding baths, the tissues are then expressed and dried at 120 C and then treated for 1 minute at 170 C. Then the degree of whiteness of the different samples is measured.
<Desc/Clms Page number 8> <Desc / Clms Page number 8>
La composition des bains de foulardage et les résultats obtenus sont donnés dans les tableaux suivants : Le pH des bains 24 et 26 est ajusté avec de l'acide acétique. The composition of the padding baths and the results obtained are given in the following tables: The pH of the baths 24 and 26 is adjusted with acetic acid.
Le pH des bains 25 et 27 est ajusté avec de la soude.
The pH of the baths 25 and 27 is adjusted with sodium hydroxide.
<tb>
<tb> <Tb>
<Tb>
Exemple <SEP> 24 <SEP> 25 <SEP> 26 <SEP> 27
<tb> M1 <SEP> en <SEP> gll <SEP> 60 <SEP> 60 <SEP> 60 <SEP> 60
<tb> HEDP <SEP> en <SEP> gel <SEP> 6 <SEP> 6
<tb> pH <SEP> du <SEP> bain <SEP> 3,5 <SEP> 8 <SEP> 3,5 <SEP> 8
<tb> degré <SEP> de <SEP> blanc <SEP> WO-JE <SEP> 116, <SEP> 8 <SEP> 113, <SEP> 6 <SEP> 120, <SEP> 8 <SEP> 120, <SEP> 1
<tb> après <SEP> l'à <SEP> 180 <SEP> C
<tb>
Les bains 24 et 25 sont des bains témoins.
Example <SEP> 24 <SEP> 25 <SEP> 26 <SEP> 27
<tb> M1 <SEP> in <SEP> gll <SEP> 60 <SEP> 60 <SEP> 60 <SEP> 60
<tb> HEDP <SEP> in <SEP> freeze <SEP> 6 <SEP> 6
<tb> pH <SEP> of <SEP> bath <SEP> 3.5 <SEP> 8 <SEP> 3.5 <SEP> 8
<tb> degree <SEP> of <SEP> white <SEP> WO-JE <SEP> 116, <SEP> 8 <SEP> 113, <SEP> 6 <SEP> 120, <SEP> 8 <SEP> 120, <SEP> 1
<tb> after <SEP> at <SEP> 180 <SEP> C
<Tb>
Baths 24 and 25 are control baths.
On constate que l'addition de phosphonate dans le bain de traitement permet de réduire le jaunissement indépendamment du pH du bain de foulardage. It is found that the addition of phosphonate in the treatment bath makes it possible to reduce the yellowing independently of the pH of the padding bath.
Classiquement les pH des bains de traitement sont légèrement acides : pH entre 3,5 et 5,5. Conventionally, the pH of the treatment baths are slightly acidic: pH between 3.5 and 5.5.
Exemples 28 à 33
On imprègne un tissu 100% coton d'un grammage 125 g/m2, dans différents bains de foulardage, les tissus sont ensuite exprimés et séchés à
120 C puis traités 1 minute à 140 C pour les exemples n 28 et 29 ou traités 1 minute à 180 C pour les exemples nu 30 et 31 ou traités 1 minute à 200 C pour les exemples nu 32 et 33. Examples 28 to 33
A 100% cotton fabric weighing 125 g / m 2 is impregnated in different padding baths, the tissues are then expressed and dried.
120 C then treated for 1 minute at 140 ° C. for Examples Nos. 28 and 29 or treated for 1 minute at 180 ° C. for Examples 30 and 31 or treated for 1 minute at 200 ° C. for Examples 32 and 33.
Puis on mesure le degré de blanc des différents échantillons
La composition des bains de foulardage et les résultats obtenus sont donnés dans le tableau suivant : Then we measure the degree of whiteness of the different samples
The composition of the padding baths and the results obtained are given in the following table:
<Desc/Clms Page number 9> <Desc / Clms Page number 9>
<tb>
<tb> Exemple <SEP> 28 <SEP> 29 <SEP> 30 <SEP> 31 <SEP> 32 <SEP> 33
<tb> M1 <SEP> en <SEP> gll <SEP> 60 <SEP> 60 <SEP> 60 <SEP> 60 <SEP> 60 <SEP> 60
<tb> EDTMP <SEP> en <SEP> gel <SEP> 6 <SEP> 6 <SEP> 6
<tb> température <SEP> de <SEP> traitement <SEP> 140 <SEP> 140 <SEP> 180 <SEP> 180 <SEP> 200 <SEP> 200
<tb> thermique <SEP> en <SEP> C
<tb> degré <SEP> de <SEP> blanc <SEP> WI-CIE <SEP> 127, <SEP> 8 <SEP> 131, <SEP> 1 <SEP> 116, <SEP> 0 <SEP> 120,0 <SEP> 100, <SEP> 5 <SEP> 112
<tb> <Tb>
<tb> Example <SEP> 28 <SEP> 29 <SEP> 30 <SEP> 31 <SEP> 32 <SEP> 33
<tb> M1 <SEP> in <SEP> gll <SEP> 60 <SEP> 60 <SEP> 60 <SEP> 60 <SEP> 60 <SEP> 60
<tb> EDTMP <SEP> in <SEP> freeze <SEP> 6 <SEP> 6 <SEP> 6
<tb> temperature <SEP> of <SEP> treatment <SEP> 140 <SEP> 140 <SEP> 180 <SEP> 180 <SEP> 200 <SEP> 200
<tb> thermal <SEP> in <SEP> C
<tb> degree <SEP> of <SEP> white <SEP> WI-CIE <SEP> 127, <SEP> 8 <SEP> 131, <SEP> 1 <SEP> 116, <SEP> 0 <SEP> 120, 0 <SEP> 100, <SEP> 5 <SEP> 112
<Tb>
Les bains 28,30 et 32 sont les bains témoins. Baths 28, 30 and 32 are the control baths.
On constate que l'addition de phosphonate dans le bain de traitement permet de réduire le jaunissement lors du traitement thermique. It is found that the addition of phosphonate in the treatment bath makes it possible to reduce the yellowing during the heat treatment.
On voit aussi que les phosphonates sont efficaces en tant que réducteur de jaunissement, dans une large gamme de température, lors de l'application d'adoucissants à base d'amino-silicone It is also seen that phosphonates are effective as a yellowing reducer, in a wide temperature range, when applying amino-silicone softeners.
Claims (10)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0012296A FR2814475A1 (en) | 2000-09-27 | 2000-09-27 | Reduction of yellowing of textile articles treated with finishing agents based on amino silicone oil, involves adding acid or salt type derivative of phosphonic acid to finishing composition |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0012296A FR2814475A1 (en) | 2000-09-27 | 2000-09-27 | Reduction of yellowing of textile articles treated with finishing agents based on amino silicone oil, involves adding acid or salt type derivative of phosphonic acid to finishing composition |
Publications (1)
Publication Number | Publication Date |
---|---|
FR2814475A1 true FR2814475A1 (en) | 2002-03-29 |
Family
ID=8854739
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR0012296A Pending FR2814475A1 (en) | 2000-09-27 | 2000-09-27 | Reduction of yellowing of textile articles treated with finishing agents based on amino silicone oil, involves adding acid or salt type derivative of phosphonic acid to finishing composition |
Country Status (1)
Country | Link |
---|---|
FR (1) | FR2814475A1 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2319485A3 (en) * | 2009-10-09 | 2015-11-04 | Beiersdorf AG | Non-yellowing hair treatment agent with amino silicones |
CN109293923A (en) * | 2018-09-26 | 2019-02-01 | 黄山市强力化工有限公司 | A kind of flame-retardant modified silicone oil and preparation method thereof, application |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6128075A (en) * | 1984-07-12 | 1986-02-07 | 大日本インキ化学工業株式会社 | Melt-proof processing of synthetic fiber product |
FR2707308A1 (en) * | 1993-07-09 | 1995-01-13 | Protex Manuf Prod Chimiq | Process for nonpermanent flame-retardant treatment of textiles with the aid of solutions of alkylaminomethylenephosphonic acid salts |
US5593611A (en) * | 1992-06-29 | 1997-01-14 | Osi Specialties, Inc. | Method for imparting softness with reduced yellowing to a textile using a low amine content, high molecular weight aminopolysiloxane |
-
2000
- 2000-09-27 FR FR0012296A patent/FR2814475A1/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6128075A (en) * | 1984-07-12 | 1986-02-07 | 大日本インキ化学工業株式会社 | Melt-proof processing of synthetic fiber product |
US5593611A (en) * | 1992-06-29 | 1997-01-14 | Osi Specialties, Inc. | Method for imparting softness with reduced yellowing to a textile using a low amine content, high molecular weight aminopolysiloxane |
FR2707308A1 (en) * | 1993-07-09 | 1995-01-13 | Protex Manuf Prod Chimiq | Process for nonpermanent flame-retardant treatment of textiles with the aid of solutions of alkylaminomethylenephosphonic acid salts |
Non-Patent Citations (1)
Title |
---|
DATABASE WPI Section Ch Week 198612, Derwent World Patents Index; Class A26, AN 1986-078891, XP002176284 * |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2319485A3 (en) * | 2009-10-09 | 2015-11-04 | Beiersdorf AG | Non-yellowing hair treatment agent with amino silicones |
CN109293923A (en) * | 2018-09-26 | 2019-02-01 | 黄山市强力化工有限公司 | A kind of flame-retardant modified silicone oil and preparation method thereof, application |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP2831409B2 (en) | Starch containing curable amine-functional silicone for fabric wrinkle reduction and shape retention | |
AU768906C (en) | Fabric softening compositions | |
JP2752449B2 (en) | Aqueous compositions and methods for treating textiles | |
KR101988072B1 (en) | Liquid fabric softener composition | |
JP6159988B2 (en) | Textile treatment composition | |
CZ20021239A3 (en) | Preparation for treating textile materials | |
WO2013176288A1 (en) | Treatment agent composition for fiber product | |
JPS62257463A (en) | Clothing treatment composition and method | |
JP2002212879A (en) | Method for reducing wrinkle in fabric and improving feeling | |
JP5906523B2 (en) | Textile treatment composition | |
FR2531447A1 (en) | N-ALKYLISOSTEARAMIDES AS ANTISTATIC AGENTS | |
FR2814475A1 (en) | Reduction of yellowing of textile articles treated with finishing agents based on amino silicone oil, involves adding acid or salt type derivative of phosphonic acid to finishing composition | |
AU737841B2 (en) | Use of selected polydiorganosiloxanes in fabric softener compositions | |
JP5863114B2 (en) | Liquid treatment composition for textile products | |
WO2014185454A1 (en) | Liquid treatment composition for textile product | |
JP6171202B2 (en) | Textile processing method | |
JP2548714B2 (en) | Textile processing agent | |
JP4832949B2 (en) | Textile treatment composition | |
ES2647234T3 (en) | Method for producing textile surfaces substantially free of wrinkles | |
JP6171200B2 (en) | Textile treatment composition | |
FR2707308A1 (en) | Process for nonpermanent flame-retardant treatment of textiles with the aid of solutions of alkylaminomethylenephosphonic acid salts | |
JP2013245422A (en) | Softener composition | |
JPS63219680A (en) | Softener for fiber | |
JP2001164464A (en) | Treating agent for textile product | |
JP2006257565A (en) | Treatment agent for textile product |