FR2801207A1 - Cosmetic composition contains mono- and poly-carboxylic naphthalene acid derivative(s) and 1,4-di(3-methylidene-10-camphosulfonic acid)benzene as part of a UV filter system - Google Patents

Abstract

Cosmetic composition comprises an oil-in-water cosmetic support containing mono- and poly-carboxylic naphthalene acid derivative(s) and a UV filter system containing 1,4-di(3-methylidene-10-camphosulfonic acid)benzene.

Description

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FILTERING COMPOSITIONS CONTAINING THE ASSOCIATION OF A DERIVATIVE
OF MONO- OR POLYCARBOXYLIC NAPHTHALENE ACID AND ACID
The invention relates to cosmetic compositions for topical use, in particular for the photoprotection of the skin and / or the hair, characterized in that they comprise, in a cosmetically acceptable support, particularly of the water-oil type, (a) at least one mono- or polycarboxylic naphthalene acid derivative and (b) at least one photoprotective system capable of filtering UV rays containing at least benzene acid 1 , 4-di (3-methylidene-10-camphosulphonic), optionally in partially or completely neutralized form.

 The invention also relates to their application to the protection of the skin and hair against the effects of ultraviolet radiation.

It is known that light radiation of wavelengths between 280 nm and 400 nm allows the browning of the human epidermis and that the wavelength rays between 280 nm and 320 nm, known under the name of UV -
B, cause erythema and skin burns that can hinder the development of natural tanning; this UV-B radiation must therefore be filtered.

 It is also known that UV-A rays of wavelengths between 320 nm and 400 nm, which cause browning of the skin, are capable of inducing an alteration thereof, particularly in the case of sensitive skin or skin continuously exposed to solar radiation. UV-A rays cause in particular a loss of elasticity of the skin and the appearance of wrinkles leading to premature aging. They promote the triggering of the erythematous reaction or amplify this reaction in some subjects and may even be the cause of phototoxic or photoallergic reactions. It is therefore desirable to also filter the UV-A radiation.

Numerous cosmetic compositions intended for the photoprotection (UV-A and / or UV-B) of the skin have been proposed to date. These antisolar compositions are quite often in the form of an oil-in-water type emulsion ( that is to say a cosmetically acceptable support consisting of an aqueous dispersant continuous phase and an oily dispersed discontinuous phase) which contains, at various concentrations, one or more conventional organic lipophilic and / or hydrophilic filters capable of selectively absorb harmful UV radiation, these filters (and their quantities) being selected according to the desired sun protection factor (the sun protection factor (SPF) expressed mathematically by the ratio of the irradiation time required to reach the threshold erythematogen with the UV filter at the time necessary to reach the erythematogenic threshold without UV filter).

The Applicant has discovered, unexpectedly and surprisingly, that the use of a naphthalene mono- or polycarboxylic acid derivative in an antisolar composition comprising at least, as a UV filter, benzene 1,4-di (3) acid. -Methylidene-10camphosuffonic), optionally in partially or totally neutralized form, allowed to substantially increase its level of protection vis-à-vis the effects induced by UV-A radiation This discovery is the basis of the present invention.

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By photoprotective system capable of filtering UV radiation, any system consisting of one or more organic compounds and / or mineral compounds filtering UV radiation (UVA and / or UV-B) is understood.

Thus, according to one of the objects of the present invention, it is now proposed new cosmetic or dermatological compositions, in particular antisolar, which are essentially characterized in that they comprise, in a cosmetically acceptable carrier: at least one mono- or polycarboxylic naphthalene acid derivative and (b) at least one photoprotective system capable of filtering UV rays containing at least benzene 1,4-di (3-methylidene-10-camphosulfonic acid), optionally in partially or totally neutralized form.

The present invention also relates to the use of such compositions for the manufacture of cosmetic compositions for the protection of the skin and / or hair against ultraviolet radiation, in particular solar radiation.

The subject of the present invention is also the use of a naphthalene mono- or polycarboxylic acid derivative in the preparation of a photoprotective cosmetic or dermatological composition comprising at least, as an organic UV filter, 1,4-benzene acid. di (3-methylidene-10-camphosulphonic acid), optionally in partially or totally neutralized form, in order to increase its level of protection against the effects induced by UV-A radiation Other characteristics, aspects and advantages of the present invention will appear on reading the detailed description which follows.

dans laquelle : A, identiques ou différents, désignent un groupe OR, ; un groupe NR2R3 ou un cation M x est un nombre de 1 à 8 ; y est un nombre de 0 à 7 avec x+y# 8 ; B, identiques ou différents, désignent hydrogène, OR, ; un groupe NR2R3 ou un groupe - (C=O)R1; Ri, R2, R3, identiques ou différents, désignent hydrogène ; un alkyle en C1-C30, linéaire ou ramifié acyclique ou cyclique, éventuellement interrompu par un ou plusieurs hétéroatomes et éventuellement substitué par un ou plusieurs groupements B différents d'hydrogène ; un alcényle en C2-C30, linéaire ou ramifié acyclique ou cyclique, éventuellement interrompu par un ou plusieurs hétéroatomes (tels que 0, S, N) et éventuellement substitué par un ou plusieurs groupements B différents d'hydrogène ; un The naphthalene mono- or poly-carboxylic acid derivatives according to the invention may be chosen from compounds comprising at least one unit corresponding to the following structure:

wherein: A, the same or different, denote a group OR,; an NR 2 R 3 group or a cation M x is a number from 1 to 8; y is a number from 0 to 7 with x + y # 8; B, identical or different, denote hydrogen, OR,; an NR2R3 group or a - (C = O) R1 group; R 1, R 2, R 3, which may be identical or different, denote hydrogen; an acyclic or cyclic linear or branched C1-C30 alkyl, optionally interrupted by one or more heteroatoms and optionally substituted with one or more different B groups of hydrogen; C 2 -C 30 alkenyl, linear or branched acyclic or cyclic, optionally interrupted by one or more heteroatoms (such as O, S, N) and optionally substituted with one or more different groups B of hydrogen; a

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 a C 6 -C 30 aryl, aralkyl or alkylaryl group, optionally substituted with one or more different B groups of hydrogen; a C3-C12 heterocycle, optionally substituted with one or more different B groups of hydrogen; a halogen (such as fluorine, bromine or chlorine); a nitrile group; an amino group; a nitro group; a cyano group; a group S03H or SO3M; a group comprising at least one silicon atom; M represents an alkali metal, alkaline earth metal cation, an ammonium group or a quaternized amine or alkanolamine residue.

Among the compounds of formula (I) known in the prior art and usable in accordance with the invention, mention may be made of: (1) mono- or polycarboxylic naphthalene acids and their salts, such as: 1-naphthalene carboxylic acid (available from ALDRICH-catologue 1999-2000); 2-naphthalene carboxylic acid (available from ALDRICH); 1-hydroxy-2-naphthalene carboxylic acid (available from ALDRICH); 2-hydroxy-1-naphthalene carboxylic acid (available from ALDRICH); 3-hydroxy-2-naphthalene carboxylic acid (available from ALDRICH); 6-hydroxy-2-naphthalene carboxylic acid (available from ALDRICH); 1,4-naphthalene dicarboxylic acid (available from ALDRICH); 2,3-naphthalene dicarboxylic acid (available from ALDRICH); 2,6-naphthalene dicarboxylic acid (available from ALDRICH) 2,6-naphthalene dicarboxylic acid 1,3-naphthalene dicarboxylic acid 1,2-naphthalene dicarboxylic acid 1-acid 5-Naphthalene dicarboxylic acid - 1,6-naphthalene dicarboxylic acid - 1,7-naphthalene dicarboxylic acid - 2,7-naphthalene dicarboxylic acid - Potassium salt of 4-sulpho-1,8 -naphthalene dicarboxylic acid - 1,2,3-naphthalene tricarboxylic acid - 1,2,3-naphthalene tricarboxylic acid - 1,2,4-naphthalene tricarboxylic acid - 1,2,5-naphthalene acid tricarboxylic acid - 1,2,6-naphthalene tricarboxylic acid - 1,2,7-naphthalene tricarboxylic acid - 1,2,8-naphthalene tricarboxylic acid - 1,3,5-naphthalene tricarboxylic acid - 1,3,7-naphthalene tricarboxylic acid - 1,3,8-naphthalene tricarboxylic acid - 1,4,5-naphthalene tricarboxylic acid - 1,4,6-2-naphthalene tricarboxylic acid - 2,3,5-naphthalene tricarboxylic acid ue - 2,3,6-naphthalene tricarboxylic acid - 1,4,5,8-naphthalene tetracarboxylic acid (available from ALDRICH) - 1,2,3,4-naphthalene tetracarboxylic acid - acid 1,2,5,8-naphthalene tetracarboxylic acid - 1,3,6,8-naphthalene tetracarboxylic acid - 1,4,5,8-naphthalene tetracarboxylic acid - 2,3,6,7-naphthalene tetracarboxylic acid

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 (2) mono- or polyesters of mono- or polycarboxylic naphthalene acid such as: - 2,3-naphthalene dicarboxylic acid dimethyl ester - 2,3-naphthalene dicarboxylic acid dimethyl ester - Methyl ester 2-naphthalene carboxylic acid (available from ALDRICH).

(3) mono- or polyamides of mono- or polycarboxylic naphthalene acid such as the diamide of 2,3-naphthalene dicarboxylic acid.

More particularly, the naphthalene dicarboxylic acid derivatives containing glycols and alcohols sold under the trade name HALLBRITE TQ by the company C. P. HALL will be used more particularly.

The naphthalene mono- or polycarboxylic acid derivatives according to the invention are generally present in the compositions according to the invention at a total concentration of between approximately 0.1 and 20% by weight, and preferably between 0.5 and 10. % by weight, relative to the total weight of the composition.

Benzene 1,4-di (3-methylidene-10-camphosulphonic acid) and its various salts, described in particular in patent applications FR-A-2528420 and FR-A-2639347, are already known filters ( so-called broadband filters) capable indeed of absorbing ultraviolet rays of wavelength between 280 and 400 nm, with absorption maxima of between 320 and 400 nm, in particular around 345 nm.

dans laquelle D désigne un atome d'hydrogène, un métal alcalin ou encore un radical NH(R4)3+ dans lequel les radicaux R4, qui peuvent être identiques ou différents, désignent un atome d'hydrogène, un radical alkyle ou hydroxyalkyle en Ci-C4 ou encore un groupement M n+/n, M n+ désignant un cation métallique polyvalent dans lequel n est égal à 2 ou 3 ou 4, M n+ désignant de préférence un cation métallique choisi parmi Ca 2+, Zn2+, Mg2+, Ba2+, Al3+ et Zr4+. These filters correspond to the following general formula (II)

in which D denotes a hydrogen atom, an alkali metal or an NH (R4) 3+ radical in which the radicals R4, which may be identical or different, denote a hydrogen atom, a C1-alkyl or hydroxyalkyl radical; -C4 or a group M n + / n, M n + denoting a polyvalent metal cation in which n is equal to 2 or 3 or 4, M n + preferably denoting a metal cation chosen from Ca 2+, Zn 2+, Mg 2+, Ba 2+, Al3 + and Zr4 +.

Benzene 1,4-di (3-methylidene-10-camphosulphonic acid) and / or one of its various salts is generally present in the filter compositions according to the invention at a total concentration ranging from 0.1 to 20%. by weight approximately, and preferably from 0.5 to 10% by weight approximately, relative to the total weight of the composition.

The antisolar cosmetic compositions according to the invention may of course contain one or more complementary organic screening agents that are active in the UVA and / or UVB. These complementary filters may be chosen in particular from cinnamic derivatives; dibenzoylmethane derivatives; salicylic derivatives, camphor derivatives; triazine derivatives such as those described in patent applications US 4367390, EP863145, EP517104, EP570838, EP796851, EP775698, EP878469 and EP 933376; benzophenone derivatives; ss, ss'-diphenylacrylate derivatives, benzimidazole derivatives; bis-benzoazolyl derivatives as described in patents EP-A-0669323 and US 2,463,264; derivatives of p-aminobenzoic acid, filter polymers and silicone filters such as those described in particular in the application WO-93/04665.

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le 4-ter-butyl-4'-méthoxy-dibenzoylméthane, le 4-isopropyl-dibenzoylméthane, le 4-méthoxy cinnamate de 2-éthylhexyle, le diisopropyl cinnamate de méthyle, le 4-méthoxy cinnamate d'isoamyle, le 4-méthoxy cinnamate de diéthanolamine, l'anthranilate de menthyle, le 2-éthylhexyl-2-cyano-3,3'-diphénylacrylate, l'éthyl-2-cyano-3,3'-diphénylacrylate, l'acide 2-phényl benzimidazole 5-sulfonique et ses sels, le 3-(4'-triméthylammonium)-benzylidèn-bornan-2-on-méthylsulfate, le 2-hydroxy-4-méthoxybenzophénone, le 2-hydroxy-4-méthoxybenzophénone-5-sulfonate, le 2,4-dihydroxybenzophénone, le 2,2',4,4'-tétrahydroxybenzophénone, le 2,2'-dihydroxy-4,4'diméthoxybenzophénone, le 2-hydroxy-4-n-octoxybenzophénone, le 2-hydroxy-4-méthoxy-4'-méthylbenzophénone, l'acide a-(2-oxobom-3-ylidène)-tolyl-4-sulfonique et ses sels solubles le 3-(4'-sulfo)benzylidèn-boman-2-one et ses sels solubles, le 3-(4'méthylbenzylidène)-d,l-camphre, le 3-benzylidène-d,l-camphre, l'acide urocanique, la 2,4,6-tris-[ p-(2'-éthylhexyl-1'-oxycarbonyl)anilino]-1,3,5-triazine,

la 2-[p-(tertiobutylamido)anilino]-4,6-bis-[(p-(2'-éthylhexyl-1'-oxycarbonyl)anilino]-1,3,5triazine, la 2,4-bis {[4-2-éthyl-hexyloxy)]-2-hydroxy]-phenyl}-6-(4-méthoxy-phenyl)-1 ,3,5-triazine ; le polymère de N-(2 et 4)-[(2-oxobom-3-ylidèn)méthyl] benzyl]-acrylamide, l'acide 1,4-bis-benzimidazolyl-phénylen-3,3',5,5'-tétrasulfonique et ses sels solubles les polyorganosiloxanes à fonction benzalmalonate les polyorganosiloxanes à fonction benzotriazole tels que le Drométrizole Trisiloxane Les compositions selon l'invention peuvent également contenir des agents de bronzage et/ou de brunissage artificiels de la peau (agents autobronzants), tels que par exemple de la dihydroxyacétone (DHA). Examples of UV-A and / or UV-B active sunscreens that may be mentioned include: p-aminobenzoic acid, oxyethylenated p-aminobenzoate (25mol), 2-ethylhexyl p-dimethylaminobenzoate ethyl p-aminobenzoate N-oxypropylenated glycerol p-aminobenzoate, homomenthyl salicylate, 2-ethylhexyl salicylate, triethanolamine salicylate, 4-isopropylbenzyl salicylate,

4-tert-butyl-4'-methoxy-dibenzoylmethane, 4-isopropyl-dibenzoylmethane, 2-ethylhexyl 4-methoxy cinnamate, methyl diisopropyl cinnamate, isoamyl 4-methoxy cinnamate, 4-methoxy diethanolamine cinnamate, menthyl anthranilate, 2-ethylhexyl-2-cyano-3,3'-diphenylacrylate, ethyl-2-cyano-3,3'-diphenylacrylate, 2-phenylbenzimidazole acid 5- sulphonic acid and its salts, 3- (4'-trimethylammonium) -benzyliden-bornan-2-on-methylsulfate, 2-hydroxy-4-methoxybenzophenone, 2-hydroxy-4-methoxybenzophenone-5-sulphonate, 2, 4-dihydroxybenzophenone, 2,2 ', 4,4'-tetrahydroxybenzophenone, 2,2'-dihydroxy-4,4'-dimethoxybenzophenone, 2-hydroxy-4-n-octoxybenzophenone, 2-hydroxy-4-methoxy 4'-methylbenzophenone, α- (2-oxobom-3-ylidene) -tolyl-4-sulfonic acid and its soluble salts 3- (4'-sulfo) benzyliden-boman-2-one and its soluble salts 3- (4'-methylbenzylidene) -d, 1-camphor, 3-benzylidene-d, 1-camphor, urocanic acid 2,4,6-tris- [p- (2'-ethylhexyl-1'-oxycarbonyl) anilino] -1,3,5-triazine,

2- [p- (tert-butylamido) anilino] -4,6-bis - [(p- (2'-ethylhexyl-1'-oxycarbonyl) anilino] -1,3,5triazine, 2,4-bis [[ 4-2-ethylhexyloxy)] - 2-hydroxy-phenyl-6- (4-methoxy-phenyl) -1,3,5-triazine; N- (2 and 4) - [(2-oxobom-3-ylidene) methyl] benzyl] -acrylamide polymer, 1,4-bis-benzimidazolyl-phenyl-3,3 ', 5,5' Tetrasulfonic acid and its soluble salts benzalmalonate-functional polyorganosiloxanes benzotriazole-functional polyorganosiloxanes such as drometrazole trisiloxane The compositions according to the invention may also contain artificial tanning and / or browning agents for the skin (self-tanning agents), such as for example dihydroxyacetone (DHA).

The cosmetic compositions according to the invention may also contain pigments or even nanopigments (average size of the primary particles generally between 5 nm and 100 nm, preferably between 10 nm and 50 nm) of coated or uncoated metal oxides, for example nanopigments of titanium oxide (amorphous or crystallized in rutile and / or anatase form), iron, zinc, zirconium or cerium which are all UV photoprotective agents well known per se. Conventional coating agents are, moreover, alumina and / or aluminum stearate. Such oxide nanopigments

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 coated or uncoated metal, are in particular described in patent applications EP-A-0518772 and EP-A-0518773.

The compositions of the invention may furthermore comprise conventional cosmetic adjuvants, chosen especially from fatty substances, organic solvents, thickeners, softeners, opacifiers, stabilizers, emollients, antifoaming agents, moisturizing agents, perfumes, preservatives, polymers, fillers, sequestering agents, propellants, alkalizing or acidifying agents or any other ingredient usually used in cosmetics, in particular for the manufacture of sunscreen compositions in the form of emulsions
The fatty substances may be an oil or a wax or mixtures thereof, and they also include fatty acids, fatty alcohols and fatty acid esters. The oils may be chosen from animal, vegetable, mineral or synthetic oils and in particular from petrolatum oil, paraffin oil, silicone oils, which may or may not be volatile, isoparaffins, polyolefins, fluorinated oils and the like. perfluorinated. Similarly, the waxes can be chosen from animal, fossil, vegetable, mineral or synthetic waxes known per se.

 Among the organic solvents, mention may be made of lower alcohols and polyols.

 Of course, one skilled in the art will take care to choose this or these optional additional compounds and / or their amounts in such a way that the advantageous properties, in particular, the level of protection vis-à-vis the effects induced by UV-radiation. A intrinsically attached to the compsitions according to the invention are not, or not substantially, impaired by the addition or additions envisaged.

The compositions of the invention may be prepared according to the techniques well known to those skilled in the art, in particular those intended for the preparation of oil-in-water or water-in-oil type emulsions.

These compositions may be in particular in the form of an emulsion, simple or complex (O / W, W / O, O / W / H or W / O / W) such as cream, milk, gel or gel cream, powder, solid stick and optionally be packaged in aerosol and be in the form of foam or spray When it is an emulsion, the aqueous phase thereof may comprise a nonionic vesicular dispersion prepared according to known methods (Bangham, Standish and Watkins, J. Mol Biol 13, 238 (1965), FR2315991 and FR2416008).

The cosmetic composition of the invention can be used as a composition for protecting the human epidermis or the hair against ultraviolet rays, as an antisolar composition or as a makeup product.

When the cosmetic composition according to the invention is used for the protection of the human epidermis against UV rays, or as an antisolar composition, it may be in the form of a nonionic vesicular dispersion, an emulsion, in particular an oil-in-water emulsion, cream, milk, gel, cream gel, suspension, dispersion, powder, solid stick, foam or spray.

When the cosmetic composition according to the invention is used for protecting the hair against UV rays, it may be in the form of a shampoo, a lotion, a gel, an emulsion or a nonionic vesicle dispersion and may constitute, for example, a composition. rinse, apply before or after shampoo, before or after

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 staining or discoloration, before, during or after permanent or straightening, a styling or treating lotion or gel, a lotion or a gel for blow-drying or setting, a composition of permanent or straightening, coloring or bleaching of the hair .

When the composition is used as a makeup product for eyelashes, eyebrows or skin, such as epidermis cream, foundation, lipstick stick, eyeshadow, blush, mascara or liner also called "eyeliner", it can be in solid or pasty, anhydrous or aqueous, such as oil in water or water in oil emulsions, nonionic vesicular dispersions or suspensions.

As an indication, for the antisolar formulations in accordance with the invention which have an oil-in-water emulsion type support, the aqueous phase (including in particular the hydrophilic filters) generally represents from 50 to 95% by weight, preferably from 70 to 70% by weight. at 90% by weight, relative to the overall formulation, the oily phase (including in particular the lipophilic filters) of 5 to 50% by weight, preferably 10 to 30% by weight, relative to the whole of the formulation, and the or (co) emulsifier (s) from 0.5 to 20% by weight, preferably from 2 to 10% by weight, with respect to the entire formulation A concrete example, but not at all limiting, illustrating the invention, will now be given.

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<Tb>

COMPOSITION <SEP>% <SEP> in <SEP> weight
<tb> Mixture <SEP> mono <SEP> / distearate <SEP> of <SEP> glycerol <SEP> / <SEP> stearate <SEP> of <SEP> polyethylene <SEP> 2
<tb> Glycol <SEP> (100 <SEP> OE) <SEP> ARLACEL <SEP> 165 <SEP> FL <SEP> - <SEP> HERE
<tb> Stearyl alcohol <SEP><SEP> LANET <SEP> 18 <SEP> - <SEP> HENKEL <SEP> 1
<tb><SEP> stearic acid <SEP> oil <SEP> of <SEP> palm <SEP> 2. <SEP> 5
<tb> STEARINE <SEP> TP <SEP> - <SEP> STEARINERY <SEP> DUBOIS
<tb> Poly <SEP> Dimethylsiloxane <SEP> (DOW <SEP> CORNING <SEP> 200 <SEP> FLUID <SEP> - <SEP> DOW <SEP> 0.5
<tb> CORNING
<tb> Benzoate <SEP> of alcohols <SEP> in <SEP> C12 / C15 <SEP> ITCONOL <SEP> TN <SEP> -WITCO) <SEP> 20
<tb> Triethanolamine <SEP> 0.5
2,4-Bis - {[4-tris (trimethylsiloxy-silylpropyloxy) -2-hydroxy] -phenyl} <SEP> 2. <SEP> 5
<tb> -6- (4-methoxyphenyl) -1,3,5-triazine
<tb> Glycerine <SEP> 5
<tb> Phosphate <SEP> of alcohol <SEP> hexadecyl, salt <SEP> of <SEP> potassium <SEP> (AMPHISOL <SEP> K <SEP> HOFFMAN <SEP> LAROCHE <SEP> 1
<tb> Polyacrylic acid <SEP><SEP> 0 <SEP> 3 <SEP>
<tb> SYNTHALEN <SEP> K <SEP> 3V)
<tb> Hydroxypropyl <SEP> methyl <SEP> cellulose <SEP> 0 <SEP> 1
<tb> METHOCEL <SEP> F4M-DOW <SEP> CHEMICAL
<tb> Butyl <SEP> methoxydibenzoyl <SEP> methane <SEP> 2
<tb> (Parsol <SEP> 1789 <SEP>;<SEP> GIVAUDAN
<tb> Derivative <SEP> of acid <SEP> naphthalene <SEP> dicarboxylic acid <SEP> to <SEP> termination <SEP> glycol <SEP> and <SEP> 4
<tb> alcohol <SEP> (proposed <SEP> under <SEP> the <SEP> denomination <SEP> HALLBRITE <SEP> TQ <SEP> by <SEP>
<tb> company <SEP> CP <SEP> HALL
<tb><SEP> Benzene <SEP> 1,4-di (3-methylidene-10-camphosulfonic acid) <SEP> 1 <SEP> 5 <SEP>
<tb>, Mexo <SEP> SX
<tb> Triethanolamine <SEP> qs <SEP> pH <SEP> 7
<tb> Conservatives <SEP> qs
<tb> Demineralized water <SEP><SEP> qsp <SEP> 100
<Tb>

Claims (20)

 1. Cosmetic composition for topical use, in particular for the photoprotection of the skin and / or hair, characterized in that it comprises, in a cosmetically acceptable medium, particularly of the oil-in-water type, (a) minus one mono- or polycarboxylic naphthalene acid derivative and (b) at least one photoprotective system capable of filtering UV rays containing at least benzene 1,4di (3-methylidene-10-camphosulphonic acid), optionally in part form or totally neutralized. 2. Composition according to claim 1, wherein the naphthalene mono or poly-carboxylic acid derivative (s) are chosen from compounds comprising at least one unit corresponding to the following structure:

 in which A, identical or different, denote a group OR,; an NR 2 R 3 group or a cation M x is a number from 1 to 8; y is a number from 0 to 7 with x + y # 8, B, the same or different, denote hydrogen, OR,; an NR2R3 group or a - (C = O) R1 group; R1, R2, R3, which may be identical or different, denote hydrogen; an acyclic or cyclic linear or branched C1-C30 alkyl, optionally interrupted by one or more heteroatoms and optionally substituted with one or more different B groups of hydrogen; C 2 -C 30 alkenyl, linear or branched acyclic or cyclic, optionally interrupted by one or more heteroatoms (such as O, S, N) and optionally substituted with one or more different groups B of hydrogen; a C 6 -C 30 aryl, aralkyl or alkylaryl group, optionally substituted with one or more different B groups of hydrogen; a C3-C12 heterocycle, optionally substituted with one or more different B groups of hydrogen; a halogen (such as fluorine, bromine or chlorine); a nitrile group; an amino group; a nitro group; a cyano group; a group S03H or SO3M; a group comprising at least one silicon atom; M represents an alkali metal, alkaline earth metal cation, an ammonium group or a quaternized amine or alkanolamine residue. 3. Composition according to claim 1 or 2, wherein the naphthalene mono- or poly-carboxylic acid derivative (s) are chosen from the group consisting of: (1) naphthalene mono- or polycarboxylic acids and their salts, (2) mono- or polyesters of mono- or polycarboxylic naphthalene acid and their salts; (3) mono- or polyamides of mono- or polycarboxylic naphthalene acid and their salts, 2,3-naphthalene dicarboxylic acid diamide and their salts <Desc / Clms Page number 9>  4. Composition according to any one of claims 1 to 3, wherein the mono- or poly-carboxylic naphthalene acid derivative (s) are derivatives of naphthalene dicarboxylic acid containing glycols and alcohols. 5. Composition according to any one of claims 1 to 3, wherein the naphthalene mono- or poly-carboxylic acid derivative (s) present in the compositions according to the invention at a total concentration of between 0.1 and 20% by weight. about weight, and preferably between 0.5 and 10% by weight, relative to the total weight of the composition. 6. Composition according to any one of claims 1 to 5, characterized in that the benzene 1,4-di (3-methylidene-10-camphosulfonic acid) and its salts has the following formula (II):

 in which D denotes a hydrogen atom, an alkali metal or an NH (R4) 3+ radical in which the radicals R4, which may be identical or different, denote a hydrogen atom, a C1-alkyl or hydroxyalkyl radical; -C4 or a group M n + / n, M n + denoting a polyvalent metal cation in which n is equal to 2 or 3 or 4, M n + preferably denoting a metal cation chosen from Ca 2+, Zn 2+, Mg 2+, Ba 2+, Al3 + and Zr4 +. 7. Composition according to any one of 1 to 6, characterized in that benzene 1,4-di (3-methylidene-10-camphosulfonic acid), or a salt thereof is generally present at a concentration. total of between 0.1 and 20% by weight approximately relative to the total weight of the composition 8. The composition of claim 7 wherein the concentration is between 0.5 and 10% by weight, relative to the total weight of the composition 9. Composition according to any one of claims 1 to 8, characterized in that said cosmetically acceptable carrier is in the form of an oil-in-water type emulsion. 10. Composition according to any one of claims 1 to 9, characterized in that it further comprises one or more complementary organic filters active in the UV-A and / or UV-B. 11 Composition according to claim 10, characterized in that said complementary organic filters are selected from cinnamic derivatives; dibenzoylmethane derivatives; salicylic derivatives, camphor derivatives; triazine derivatives; benzophenone derivatives; ss, ss'-diphenylacrylate derivatives, benzimidazole derivatives; bis-benzoazolyl derivatives; p-aminobenzoic acid derivatives; filter and silicone polymers. 12. Composition according to any one of claims 1 to 11, characterized in that it further comprises, as complementary UV photoprotective agents, pigments or nanopigments of metal oxides, coated or uncoated <Desc / Clms Page number 10>  13. Composition according to claim 12, characterized in that said pigments or nanopigments are selected from titanium oxides, zinc, iron, zirconium, cerium and mixtures thereof, coated or not. 14. Composition according to any one of claims 1 to 13, characterized in that it further comprises at least one agent for tanning and / or artificial browning of the skin. 15. Composition according to any one of claims 1 to 14, characterized in that it further comprises at least one adjuvant selected from fatty substances, organic solvents, thickeners, softeners, opacifiers, stabilizers, emollients, anti-foam agents, moisturizers, perfumes, preservatives, polymers, fillers, sequestering agents, propellants, basifying or acidifying agents. 16. Composition according to any one of claims 1 to 15, characterized in that it is a protective composition of the human epidermis or an antisolar composition and that it is in the form of a non-ionic vesicle dispersion, an emulsion, in particular an oil-in-water emulsion, a cream, a milk, a gel, a cream gel, a suspension , a dispersion, a powder, a solid stick, a foam or a spray. Composition according to any one of Claims 1 to 15, characterized in that it is a makeup composition for eyelashes, eyebrows or skin and that it is in solid or pasty form, anhydrous or aqueous, an emulsion, a suspension or a dispersion. 18. Composition according to any one of claims 1 to 15, characterized in that it is a composition for protecting the hair against ultraviolet rays and is in the form of a shampoo, lotion, gel, emulsion, non-ionic vesicular dispersion. 19. Use of the composition defined according to any one of claims 1 to 18 for the manufacture of cosmetic compositions for the protection of the skin and / or hair against ultraviolet radiation, in particular solar radiation. 20. Use of a naphthalene mono- or polycarboxylic acid derivative as defined in the preceding claims in the preparation of a photoprotective cosmetic or dermatological composition comprising at least, as organic UV filter, less benzene acid 1,4 -di (3-methylidene-10-camphosulfonic acid), optionally in partially or completely neutralized form, in order to increase its level of protection against effects induced by UV-A radiation