FR2801206A1 - Cosmetic composition contains mono- and poly-carboxylic naphthalene acid derivative(s) and a photoprotective containing a hydroxyphenylbenzotriazole UV filter system - Google Patents

Abstract

Cosmetic composition comprises an oil-in-water cosmetic support containing mono- and poly-carboxylic naphthalene acid derivative(s) and a photoprotective containing a hydroxyphenylbenzotriazole UV filter system.

Description

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FILTERING COMPOSITIONS CONTAINING THE ASSOCIATION OF A DERIVATIVE
MONO- OR POLYCARBOXYLIC NAPHTHALENE ACID AND UV FILTER
The invention relates to cosmetic compositions for topical use, in particular for the photoprotection of the skin and / or the hair, characterized in that they comprise, in a cosmetically acceptable medium, particularly of the water-oil type, (a) at least one mono- or polycarboxylic naphthalene acid derivative and (b) at least one photoprotective system capable of filtering UV rays containing at least one organic UV filter of the hydroxyphenylbenzotriazole derivative type
The invention also relates to their application to the protection of the skin and hair against the effects of ultraviolet radiation.

It is known that light radiation of wavelengths between 280 nm and 400 nm allows the browning of the human epidermis and that the wavelength rays between 280 nm and 320 nm, known under the name of UV -
B, cause erythema and skin burns that can hinder the development of natural tanning; this UV-B radiation must therefore be filtered.

It is also known that UV-A rays of wavelengths between 320 nm and 400 nm, which cause browning of the skin, are capable of inducing an alteration thereof, particularly in the case of sensitive skin or skin continuously exposed to solar radiation UV-A rays cause in particular a loss of elasticity of the skin and the appearance of wrinkles leading to premature aging. They promote the triggering of the erythematous reaction or amplify this reaction in some subjects and may even be the cause of phototoxic or photoallergic reactions. It is therefore desirable to also filter the UV-A radiation.

Numerous cosmetic compositions intended for the photoprotection (UV-A and / or UV-B) of the skin have been proposed to date.

These antisolar compositions are quite often in the form of an oil-in-water emulsion (that is to say a cosmetically acceptable support consisting of an aqueous dispersant continuous phase and an oily disperse discontinuous phase) which contains at various concentrations, one or more conventional organic filters, lipophilic and / or hydrophilic, capable of selectively absorbing harmful UV radiation, these filters (and their amounts) being selected according to the desired sun protection factor (the solar protection (SPF) expressed mathematically by the ratio of the irradiation time required to reach the erythematogenic threshold with the UV filter at the time necessary to reach the erythematogenic threshold without UV filter) The Applicant has discovered, unexpectedly and surprisingly, that the use of a naphthalene mono- or polycarboxylic acid derivative in an antisolar composition comprising at least one UV filter of the type derived from hydroxyphenylbenzotriazole, allowed to substantially increase its level of protection vis-à-vis the effects induced by UV-A radiation This discovery is the basis of the present invention.

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By photoprotective system capable of filtering UV radiation, any system consisting of one or more organic compounds and / or mineral compounds filtering UV radiation (UVA and / or UV-B) is understood.

Thus, according to one of the objects of the present invention, it is now proposed new cosmetic or dermatological compositions, in particular antisolar, which are essentially characterized in that they comprise, in a cosmetically acceptable carrier: at least one mono- or polycarboxylic naphthalene acid derivative and (b) at least one photoprotective system capable of filtering UV rays containing at least one organic UV filter of the hydroxyphenylbenzotriazole derivative type. The subject of the present invention is also the use of Such compositions for the manufacture of cosmetic compositions intended for the protection of the skin and / or the hair against ultraviolet radiation, in particular solar radiation The subject of the present invention is also the use of a mono-naphthalene acid derivative. - or polycarboxylic in the preparation of a cosmetic or dermatological photopro composition comprising at least one organic UV filter of the hydroxyphenylbenzotriazole derivative type, in order to increase its level of protection against the effects induced by the UV-A radiation. Other features, aspects and advantages of the present invention will appear. upon reading the detailed description that follows.

dans laquelle : A, identiques ou différents, désignent un groupe OR1, un groupe NR2R3 ou un cation M x est un nombre de 1 à 8 ; y est un nombre de 0 à 7 avec x+y# 8 ; B, identiques ou différents, désignent hydrogène, OR, ; un groupe NR2R3 ou un groupe - (C=O)R1; R1, R2, R3, identiques ou différents, désignent hydrogène ; un alkyle en C1-C30, linéaire ou ramifié acyclique ou cyclique, éventuellement interrompu par un ou plusieurs hétéroatomes et éventuellement substitué par un ou plusieurs groupements B différents d'hydrogène ; un alcényle en C2-C30, linéaire ou ramifié acyclique ou cyclique, éventuellement interrompu par un ou plusieurs hétéroatomes (tels que 0, S, N) et éventuellement substitué par un ou plusieurs groupements B différents d'hydrogène ; un groupement aryle, aralkyle ou alkylaryle en C6-C30 , éventuellement substitué par un ou plusieurs groupements B différents d'hydrogène ; un hétérocycle en C3-C12, The naphthalene mono- or poly-carboxylic acid derivatives according to the invention may be chosen from compounds comprising at least one unit corresponding to the following structure:

wherein: A, the same or different, denotes a group OR1, a group NR2R3 or a cation M x is a number from 1 to 8; y is a number from 0 to 7 with x + y # 8; B, identical or different, denote hydrogen, OR,; an NR2R3 group or a - (C = O) R1 group; R1, R2, R3, which may be identical or different, denote hydrogen; an acyclic or cyclic linear or branched C1-C30 alkyl, optionally interrupted by one or more heteroatoms and optionally substituted with one or more different B groups of hydrogen; C 2 -C 30 alkenyl, linear or branched acyclic or cyclic, optionally interrupted by one or more heteroatoms (such as O, S, N) and optionally substituted with one or more different groups B of hydrogen; a C 6 -C 30 aryl, aralkyl or alkylaryl group, optionally substituted with one or more different B groups of hydrogen; a C3-C12 heterocycle,

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 optionally substituted with one or more different B groups of hydrogen; a halogen (such as fluorine, bromine or chlorine); a nitrile group; an amino group; a nitro group; a cyano group; a group S03H or SO3M; a group comprising at least one silicon atom; M represents an alkali metal or alkaline earth metal cation, an ammonium group or a quaternized amine or alkanolamine residue. Among the compounds of formula (I) known in the prior art and usable according to the invention, mention may be made of: (1) mono- or polycarboxylic naphthalene acids and their salts, such as: 1-naphthalene carboxylic acid (available from ALDRICH-catologue 1999-2000); 2-naphthalene carboxylic acid (available from ALDRICH); 1-hydroxy-2-naphthalene carboxylic acid (available from ALDRICH); 2-hydroxy-1-naphthalene carboxylic acid (available from ALDRICH); 3-hydroxy-2-naphthalene carboxylic acid (available from ALDRICH); 6-hydroxy-2-naphthalene carboxylic acid (available from ALDRICH); 1,4-naphthalene dicarboxylic acid (available from ALDRICH); 2,3-naphthalene dicarboxylic acid (available from ALDRICH); 2,6-naphthalene dicarboxylic acid (available from ALDRICH) 2,6-naphthalene dicarboxylic acid 1,3-naphthalene dicarboxylic acid 1,2-naphthalene dicarboxylic acid 1-acid 5-Naphthalene dicarboxylic acid - 1,6-naphthalene dicarboxylic acid - 1,7-naphthalene dicarboxylic acid - 2,7-naphthalene dicarboxylic acid - Potassium salt of 4-sulpho-1,8 -naphthalene dicarboxylic acid - 1,2,3-naphthalene tricarboxylic acid - 1,2,3-naphthalene tricarboxylic acid - 1,2,4-naphthalene tricarboxylic acid - 1,2,5-naphthalene acid tricarboxylic acid - 1,2,6-naphthalene tricarboxylic acid - 1,2,7-naphthalene tricarboxylic acid - 1,2,8-naphthalene tricarboxylic acid - 1,3,5-naphthalene tricarboxylic acid - 1,3,7-naphthalene tricarboxylic acid - 1,3,8-naphthalene tricarboxylic acid - 1,4,5-naphthalene tricarboxylic acid - 1,4,6-2-naphthalene tricarboxylic acid - 2,3,5-naphthalene tricarboxylic acid ue - 2,3,6-naphthalene tricarboxylic acid - 1,4,5,8-naphthalene tetracarboxylic acid (available from ALDRICH) - 1,2,3,4-naphthalene tetracarboxylic acid - acid 1,2,5,8-naphthalene tetracarboxylic acid - 1,3,6,8-naphthalene tetracarboxylic acid - 1,4,5,8-naphthalene tetracarboxylic acid - 2,3,6,7- naphthalene tetracarboxylic acid (2) mono- or polyesters of mono- or polycarboxylic naphthalene acid, such as: - 2,3-naphthalene dicarboxylic acid dimethyl ester - 2,3-naphthalene dicarboxylic acid dimethyl ester - methyl ester 2-naphthalene carboxylic acid (available from ALDRICH).

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. (3) mono- or polyamides of mono- or polycarboxylic naphthalene acid such as 2,3-naphthalene dicarboxylic acid diamide
More particularly, the naphthalene dicarboxylic acid derivatives containing glycols and alcohols sold under the trade name HALLBRITE will be used more particularly.
TQ by CP HALL.

 The naphthalene mono- or polycarboxylic acid derivatives according to the invention are generally present in the compositions according to the invention at a total concentration of between 0.1 and 20% by weight, and preferably between 0.5 and 10%. by weight, relative to the total weight of the composition.

 The UV filters of the hydroxyphenylbenzotriazole derivative type according to the present invention may be siliconized, that is to say comprise in their structure one or more silicon or hydrocarbon atoms.

dans laquelle : - D désigne un radical divalent -L-W- - Y, identiques ou différents, sont choisis parmi les radicaux alkyles en C1-C10, les halogènes, les radicaux alkoxy en C1-C10, des groupes sulfoniques, étant entendu que, dans ce dernier cas, deux Y adjacents d'un même noyau aromatique peuvent former ensemble un groupement alkylidène dioxy dans lequel le groupe alkylidène contient de 1 à 2 atomes de carbone ; sous réserve que les radicaux Y soient différents d'un groupe sulfonique quand D est différent d'hydrogène ; - n vaut 1,2 ou 3 ; - L est un radical divalent de formule (III) suivante

dans laquelle : - X représente 0 ou NH, - Z représente l'hydrogène ou un radical alkyle en C1-C4, - n est un nombre entier compris entre 0 et 3 inclusivement, - m est 0 ou 1, - p représente un nombre entier compris entre 1 et 10, inclusivement - West un radical de formule (1), (2) ou (3) suivante - Among the silicon derivatives of hydroxyphenylbenzotriazole, mention will in particular be made of those corresponding to the following formula (II):

in which: D denotes a divalent radical -LW- - Y, which may be identical or different, are chosen from C1-C10 alkyl radicals, halogens, C1-C10 alkoxy radicals and sulphonic groups, it being understood that, in in the latter case, two adjacent Y's of the same aromatic ring may together form an alkylidene dioxy group in which the alkylidene group contains from 1 to 2 carbon atoms; with the proviso that the radicals Y are different from a sulfonic group when D is different from hydrogen; n is 1, 2 or 3; L is a divalent radical of formula (III) below

in which: - X represents 0 or NH, - Z represents hydrogen or a C1-C4 alkyl radical, - n is an integer between 0 and 3 inclusive, - m is 0 or 1, - p represents a number integer between 1 and 10, inclusive - West a radical of formula (1), (2) or (3) following -

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ou -Si(R)3 (3) dans lesquelles : - R, identiques ou différents, sont choisis parmi les radicaux alkyles en C1-C10, phényle et trifluoro-3,3,3 propyle, au moins 80% en nombre des radicaux R étant méthyle, - E , identiques ou différents, sont choisis parmi les radicaux R et le radical V de formule suivante :

dans laquelle Y, n et L ont les mêmes significations indiquées ci-dessus ; - r est un nombre entier compris entre 0 et 50 inclusivement, et s est un nombre entier compris entre 1 et 20 inclusivement, et si s=0 au moins l'un des deux radicaux B désigne V; - u est un nombre entier compris entre 1 et 6 inclusivement, et t est un nombre entier compris entre 0 et 10 inclusivement, étant entendu que t + u est égal ou supérieur à 3.

or -Si (R) 3 (3) in which: R, which are identical or different, are chosen from C 1 -C 10 alkyl, phenyl and 3,3,3-trifluoropropyl radicals, at least 80% by number of the radicals; R being methyl, - E, which are identical or different, are chosen from the radicals R and the radical V of the following formula:

wherein Y, n and L have the same meanings given above; - r is an integer between 0 and 50 inclusive, and s is an integer between 1 and 20 inclusive, and if s = 0 at least one of the two radicals B is V; u is an integer from 1 to 6 inclusive, and t is an integer from 0 to 10 inclusive, with the proviso that t + u is equal to or greater than 3.

For the compounds of formula (II), the alkyl radicals can be linear or branched and chosen especially from the methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, ter-butyl, n-amyl, isoamyl and neopentyl radicals. n-hexyl, n-heptyl, n-octyl, 2-ethylhexyl and tert.-octyl. The preferred alkyl radicals R according to the invention are the methyl, ethyl, propyl, n-butyl, n-octyl and 2-ethylhexyl radicals. Even more preferably, the radicals R are all methyl radicals. For the compounds of formula (II), it is preferred to use those in which W corresponds to formula (1), that is to say linear chain polyorganosiloxanes. .

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Of the linear polyorganosiloxanes falling within the scope of the present invention, more particularly preferred are random or well-defined block derivatives having at least one, and even more preferably all, of the following characteristics: R is alkyl and more preferably is methyl, - E is alkyl and even more preferably is methyl, - r is between 0 and 15 inclusively; s is between 1 and 5 inclusive, - n is non-zero, and preferably equal to 1, and Y is then chosen from methyl, ter butyl or C 1 -C 4 alkoxy, - Z is hydrogen or methyl, -m = 0 where [m = 1 and X = O] - p is equal to 1.

De préférence, cet accrochage se fait en position 3,4, 5 (noyau aromatique portant la fonction hydroxy) ou 4' (noyau benzénique adjacent le cycle triazolé), et encore plus préférentiellement en position 3,4 ou 5. Dans une forme préférée de réalisation de l'invention, l'accrochage se fait en position 3. As is apparent from the formula (II) given above, the attachment of - (X) m- (CH 2) p -CH (Z) -CH 2 - to the benzotriazole unit, which thus ensures the connection of said benzotriazole unit. to the silicon atom of the silicone chain, may, according to the present invention, be carried out in all the available positions offered by the two aromatic rings of hydroxyphenylbenzyltriazole:

Preferably, this attachment is at the 3,4-position (aromatic ring carrying the hydroxy function) or 4 '(benzene ring adjacent the triazole ring), and even more preferably at the 3,4 or 5-position. In a preferred form embodiment of the invention, the attachment is in position 3.

Similarly, the attachment of the substituent unit Y can be done in all other positions available in benzotriazole. However, preferably, this attachment is in position 3,4, 4 ', 5 and / or 6. In a preferred embodiment of the invention, the attachment is in position 5.

A family of compounds particularly suitable for the invention is that defined by the following general formula -

avec 0 5 r ~< 15 , de préférence 0 :<- ruz 10 1 # s # 5 , de préférence 1 # s # 3 et où G représente le radical divalent :

with 0 5 r ~ <15, preferably 0: <- ruz 10 1 # s # 5, preferably 1 # s # 3 and where G represents the divalent radical:

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Dans une forme particulièrement préférée de réalisation de l'invention, on utilisera la silicone benzotriazole répondant à la formule générale (Il') dans laquelle :

plus connue sous le nom CTFA Drometrizole Trisiloxane et vendue par RHODIA CHIMIE sous le nom SILATRIZOLE.

In a particularly preferred embodiment of the invention, use will be made of benzotriazole silicone corresponding to the general formula (II ') in which:

more known under the name CTFA Drometrizole Trisiloxane and sold by RHODIA CHIMIE under the name SILATRIZOLE.

dans laquelle a vaut 1,2 ou 3 et les radicaux T1, identiques ou différents, sont choisis parmi les parmi les radicaux alkyles en C1-C18, les halogènes, des groupes sulfoniques, les radicaux alkoxy en C1-C18,, étant entendu que, dans ce dernier cas, deux T1 adjacents d'un même noyau aromatique peuvent former ensemble un groupement alkylidène dioxy dans lequel le groupe alkylidène contient de 1 à 2 atomes de carbone. These silicon derivatives of hydroxybenzotriazole of formula (II) are known per se and are described in particular in patents EP-B-0392 883 and EP-B-660 701. Among the hydrocarbon derivatives of hydroxyphenylbenzotriazole according to the invention, it is possible to give the compounds corresponding to the following formula (4):

wherein a is 1,2 or 3 and the radicals T1, which may be identical or different, are chosen from among the C1-C18 alkyl radicals, halogens, sulphonic groups, and C1-C18 alkoxy radicals, it being understood that in the latter case, two adjacent T1's of the same aromatic ring may together form an alkylidene dioxy group in which the alkylidene group contains from 1 to 2 carbon atoms.

Among the compounds of formula (4) that can be used according to the invention, mention may be made, for example.

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 2- (2'-hydroxy-5'-methylphenyl) benzotriazole (a = 1 and T1 = CH3) such as the product sold under the name UVAZOL P by the company Enichem Synth, the product sold under the name TINUVIN P by CIBA GEIGY; 2- (2'-hydroxy-3'-butyl-5'-methylphenyl) benzotriazole (a = 2 and the two T1 groups are -CH3 and -C (CH3) 3) such as the product sold under the name UVAZOL 236 by Enichem Synth; 2- (2'-hydroxy-5'-t-octylphenyl) benzotriazole (a = 1 and T = -C (CH 3) 2 -CH 2 -C (CH) 3) such as the product sold under the name UVAZOL 311 by the company Enichem Synth; 2- (2'-hydroxy-3'-sec-butyl-5'-benzenesulphonate) benzotriazole (a = 2 and the two T1 groups are SO 3 and -C (CH 3) -CH 2 -CH 3), such as the product sold under the name CIBAFAST by CIBA GEIGY.

dans laquelle T5 désigne un atome d'hydrogène ou un radical alkyle en C1-C18 ; T6 et T7, identiques ou différents, désignent un radical alkyle en C1-C18 éventuellement substitué par un phényle. Among the hydrocarbon UV filters of the hydroxybenzotriazole derivative type in accordance with the invention, mention may be made in particular of those of the following formula (5) as described in the application WO95 / 22959 (forming an integral part of the content of the description):

wherein T5 denotes a hydrogen atom or a C1-C18 alkyl radical; T6 and T7, identical or different, denote a C1-C18 alkyl radical optionally substituted with a phenyl.

By way of example of compounds of formula (5), mention may be made of the commercial products TINUVIN 328, 320, 234 and 350 of the company CIBA-GEIGY of following structure

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Parmi les filtres UV hydrocarbonés du type dérivé d'hydroxyphénylbenzotriazole conformes à l'invention, on peut citer les composés tels que décrits dans les brevets US 5 687 521, US 5 687 521, US 5 373 037, US 5 362 881 et en particulier le [2 ,4'-dihydroxy- 3-(2H-benzotriazol-2-yl)-5-(1,1,3,3-tétraméthylbutyl)-2'-n-octoxy-5'-benzoyl] diphénylméthane vendu sous le nom MIXXIM PB30 par la société FAIRMOUNT CHEMICAL de structure :

Parmi les filtres UV organiques hydrocarbonés dérivés d'hydroxybenzotriazole conformes à l'invention, on peut citer les dérivés de méthylène bis-(hydroxyphényl benzotriazole) de structure suivante :

Among the hydrocarbon-based UV-filters of the hydroxyphenylbenzotriazole derivative type in accordance with the invention, mention may be made of the compounds as described in US Pat. Nos. 5,687,521, 5,687,521, 5,373,037 and 5,362,881, and in particular US Pat. [2,4'-dihydroxy-3- (2H-benzotriazol-2-yl) -5- (1,1,3,3-tetramethylbutyl) -2'-n-octoxy-5'-benzoyl] diphenylmethane sold under the name MIXXIM PB30 by the company FAIRMOUNT CHEMICAL of structure:

Among the hydrocarbon-based organic UV filters derived from hydroxybenzotriazole according to the invention, mention may be made of methylene bis (hydroxyphenyl benzotriazole) derivatives having the following structure:

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dans laquelle les radicaux T8 et Tg, identiques ou différents, désignent un radical alkyle en C1-C18 pouvant être substitué par un ou plusieurs radicaux choisis parmi alkyle en C1-C4. cycloalkyle en C5-C12 ou un reste aryle. Ces composés sont connus en soi et décrits dans les demandes US 5237 071, US 5 166 355, GB-A-2 303 549, DE 197 26 184 et EP-A-893 119 (faisant partie intégrante de la description).

in which the radicals T8 and Tg, which are identical or different, denote a C1-C18 alkyl radical which may be substituted by one or more radicals chosen from C1-C4 alkyl. C 5 -C 12 cycloalkyl or aryl residue. These compounds are known per se and described in the applications US Pat. No. 5,237,071, US Pat. No. 5,166,355, GB-A-2,303,549, DE 197,264 and EP-A-893,119 (forming an integral part of the description).

In the formula (6) defined above: the alkyl groups C 1 -C 18 may be linear or branched and are for example methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, tert-butyl, tert-octyl , n-amyl, n-hexyl, n-heptyl, n-octyl, isooctyl, n-nonyl, necyl, n-undecyl, n-dodecyl, tetradecyl, hexydecyl, or octadecyl; C 5 -C 12 cycloalkyl groups are, for example, cyclopentyl, cyclohexyl, cyclooctyl; aryl groups are for example phenyl, benzyl.

Among the compounds of formula (6), those of the following structure are more particularly preferred:

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Le composé (a) de nomenclature 2,2'-méthylène-bis-[6-(2H-benzotriazol-2-yl)-4-(1,1,3,3tetraméthylbutyl)phénol] est vendu sous le nom MIXXIM BB/100 par le société FAIRMOUNT CHEMICAL .

Compound (a) of the nomenclature 2,2'-methylene-bis- [6- (2H-benzotriazol-2-yl) -4- (1,1,3,3tetramethylbutyl) phenol] is sold under the name MIXXIM BB / 100 by FAIRMOUNT CHEMICAL.

The compound (c) of 2,2'-methylene-bis- [6- (2H-benzotriazol-2-yl) -4- (methyl) phenol] is sold under the name MIXXIM BB / 200 by the company FAIRMOUNT CHEMICAL .

According to one particular form of the invention, the hydroxyphenylbenzotriazole derivatives may be in particulate form and be insoluble or substantially insoluble in the usual cosmetic solvents (water, alcohols, fatty substances, etc.).

For the purposes of the present invention, insoluble or substantially insoluble compounds are understood to mean compounds which are insoluble in cosmetic media generally used in solar formulations and more particularly whose solubility in water at 25 C is less than 0.1%. by weight and whose solubility in paraffin oil at 25 C is less than 1% by weight.

The hydroxyphenylbenzotriazole derivatives may be brought into a suitable particulate form by any ad-hoc means such as in particular dry milling or in a solvent medium, sieving, atomization, micronisation, spraying.

According to a particular embodiment of the invention, the hydroxyphenylbenzotriazole derivatives may be in micronized insoluble form. The average size of such particles will generally vary from 0.01 to 2 m and more preferably from 0.02 to 1.5 m and more preferably from 0.05 to 1.0 m.

Hydroxyphenylbenzotriazole derivatives in micronized form. can be obtained by a grinding process of a hydroxyphenylbenzotriazole derivative in the form of coarse particles in the presence of a suitable surfactant to improve the dispersion of the particles thus obtained in cosmetic formulations.

The grinding apparatus used may be a jet mill, ball mill, vibration mill or hammer mill and preferably a high speed grinding mill or an impact mill and more particularly a rotary ball mill, a vibrating mill, tube mill or rod mill.

structure CH2+, O(C6H,005),H dans laquelle n est un entier de 8 à 16 et z est le degré moyen de polymérisation de l'unité (C6H10O5) et varie de 1,4 à 1,6. As surfactants that can be used for grinding said hydroxyphenylbenzotriazole derivatives, mention may in particular be made of the alkylpolyglucosides of

structure CH2 +, O (C6H, 005), wherein n is an integer of 8 to 16 and z is the average degree of polymerization of the unit (C6H10O5) and ranges from 1.4 to 1.6.

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They may be chosen from C1-C12 esters of a compound of structure CnH2n + 1O (C6H10O5) zH and more specifically an ester obtained by reaction of a C1-C12 carboxylic acid such as formic acid, acetic acid, propionic, butyric, sulfosuccinic, citric or tartaric with one or more free OH functions on the glucoside unit (C6H10O5). Said surfactants are generally used at a concentration ranging from 1 to 50% by weight and more preferably from 5 to 40% by weight relative to the filter derived from hydroxyphenylbenzotriazole in its micronized form. hydroxyphenylbenzotriazole according to the invention are generally present in the compositions according to the invention at a total concentration of between 0.1 and 20% by weight, and preferably between 0.5 and 10% by weight, relative to the total weight. of the composition.

The antisolar cosmetic compositions according to the invention may of course contain one or more complementary organic screening agents that are active in the UVA and / or UVB.

These complementary filters may be chosen in particular from cinnamic derivatives; dibenzoylmethane derivatives; salicylic derivatives, camphor derivatives; triazine derivatives such as those described in patent applications US 4367390, EP863145, EP517104, EP570838, EP796851, EP775698, EP878469 and EP 933376; benzophenone derivatives; P, P'-diphenylacrylate derivatives, benzimidazole derivatives; bis-benzoazolyl derivatives as described in patents EP-A-0669323 and US 2,463,264, derivatives of p-aminobenzoic acid; filter polymers and silicone filters such as those described in particular in the application WO-93/04665.

l'éthyl-2-cyano-3, 3'-diphénylacrylate, l'acide 2-phényl benzimidazole 5-sulfonique et ses sels, le 3-(4'-triméthylammonium)-benzylidèn-bornan-2-on-méthylsulfate, le 2-hydroxy-4-méthoxybenzophénone, le 2-hydroxy-4-méthoxybenzophénone-5-sulfonate, le 2,4-dihydroxybenzophénone, le 2,2',4,4'-tétrahydroxybenzophénone, le 2,2'-dihydroxy-4,4'diméthoxybenzophénone, le 2-hydroxy-4-n-octoxybenzophénone, le 2-hydroxy-4-méthoxy-4'-méthylbenzophénone, Examples of UV-A and / or UV-B active sunscreens that may be mentioned include: p-aminobenzoic acid, oxyethylenated p-aminobenzoate (25mol), 2-ethylhexyl p-dimethylaminobenzoate ethyl p-aminobenzoate N-oxypropylenated glycerol p-aminobenzoate, homomenthyl salicylate, 2-ethylhexyl salicylate, triethanolamine salicylate, 4-isopropylbenzyl salicylate, 4-tert-butyl- 4'-methoxy-dibenzoylmethane, 4-isopropyl-dibenzoylmethane, 2-ethylhexyl 4-methoxy cinnamate, methyl diisopropyl cinnamate, isoamyl 4-methoxy cinnamate, diethanolamine 4-methoxy cinnamate, anthranilate menthyl, 2-ethylhexyl-2-cyano-3,3'-diphenylacrylate,

ethyl-2-cyano-3,3'-diphenylacrylate, 2-phenylbenzimidazole 5-sulfonic acid and its salts, 3- (4'-trimethylammonium) -benzyliden-bornan-2-on-methylsulfate, 2-hydroxy-4-methoxybenzophenone, 2-hydroxy-4-methoxybenzophenone-5-sulfonate, 2,4-dihydroxybenzophenone, 2,2 ', 4,4'-tetrahydroxybenzophenone, 2,2'-dihydroxy-4 4'-dimethoxybenzophenone, 2-hydroxy-4-n-octoxybenzophenone, 2-hydroxy-4-methoxy-4'-methylbenzophenone,

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le 3-(4'méthylbenzylidène)-d,i-camphre, le 3-benzylidène-d,l-camphre, l'acide benzène 1,4-di(3-méthylidène-10-camphosulfonique) et ses sels solubles, l'acide urocanique, la 2,4,6-tris-[ p-(2'-éthylhexyl-1 '-oxycarbonyl)anilino]-1 ,3,5-triazine, la 2-[p-(tertiobutylamido)anilino]-4,6-bis-[(p-(2'-éthylhexyl-1'-oxycarbonyl)anilino]-1,3,5triazine, la 2,4-bis {[4-2-éthyl-hexyloxy)]-2-hydroxy]-phenyl}-6-(4-méthoxy-phenyl)-1 ,3,5-triazine ; le polymère de N-(2 et 4)-[(2-oxobom-3-ylidèn)méthyl] benzyl]-acrylamide, l'acide 1,4-bis-benzimidazolyl-phénylen-3,3',5,5'-tétrasulfonique et ses sels solubles les polyorganosiloxanes à fonction benzalmalonate
Les compositions selon l'invention peuvent également contenir des agents de bronzage et/ou de brunissage artificiels de la peau (agents autobronzants), tels que par exemple de la dihydroxyacétone (DHA). α- (2-oxobom-3-ylidene) -tolyl-4-sulfonic acid and its soluble salts 3- (4'-sulfo) benzyliden-boman-2-one and its soluble salts,

3- (4'-methylbenzylidene) -d, i-camphor, 3-benzylidene-d, 1-camphor, benzene 1,4-di (3-methylidene-10-camphosulfonic acid) and its soluble salts, urocanic acid, 2,4,6-tris- [p- (2'-ethylhexyl-1'-oxycarbonyl) anilino] -1,3,5-triazine, 2- [p- (tert-butylamido) anilino] - 4,6-bis - [(p- (2'-ethylhexyl-1'-oxycarbonyl) anilino] -1,3,5triazine, 2,4-bis {[4-2-ethylhexyloxy]] -2- hydroxy] -phenyl} -6- (4-methoxy-phenyl) -1,3,5-triazine; N- (2 and 4) - [(2-oxobom-3-ylidene) methyl] benzyl] -acrylamide polymer, 1,4-bis-benzimidazolyl-phenyl-3,3 ', 5,5' Tetrasulfonic acid and its soluble salts the polyorganosiloxanes with benzalmalonate function
The compositions according to the invention may also contain agents for tanning and / or artificial browning of the skin (self-tanning agents), such as, for example, dihydroxyacetone (DHA).

 The cosmetic compositions according to the invention may also contain pigments or even nanopigments (average size of the primary particles: between 5 nm and 100 nm, preferably between 10 nm and 50 nm) of coated or uncoated metal oxides, for example nanopigments of titanium oxide (amorphous or crystallized in rutile and / or anatase form), iron, zinc, zirconium or cerium which are all UV photoprotective agents well known per se. Conventional coating agents are, moreover, alumina and / or aluminum stearate. Such nanopigments of metal oxides, coated or uncoated, are in particular described in patent applications EP-A-0518772 and EP-A-0518773.

 The compositions of the invention may furthermore comprise conventional cosmetic adjuvants, chosen especially from fatty substances, organic solvents, thickeners, softeners, opacifiers, stabilizers, emollients, antifoaming agents, moisturizing agents, perfumes, preservatives, polymers, fillers, sequestering agents, propellants, alkalizing or acidifying agents or any other ingredient usually used in cosmetics, in particular for the manufacture of sunscreen compositions in the form of emulsions.

 The fatty substances may consist of an oil or a wax or mixtures thereof, and they also include fatty acids, fatty alcohols and fatty acid esters. The oils may be chosen from animal, vegetable, mineral or synthetic oils. and especially from liquid petroleum jelly, paraffin oil, silicone oils, volatile or not, isoparaffins, polyolefins, fluorinated and perfluorinated oils. Likewise, the waxes may be chosen from animal, fossil, vegetable, mineral or synthesis waxes known per se. Among the organic solvents, mention may be made of lower alcohols and polyols.

Of course, those skilled in the art will take care to choose this or these optional additional compounds and / or their amounts in such a way that the advantageous properties, in particular the persistence with water, stability, intrinsically attached to the emulsions according to the invention are not, or not substantially, altered by the addition or additions envisaged.

The compositions of the invention may be prepared according to the techniques well known to those skilled in the art, in particular those intended for the preparation of oil-in-water or water-in-oil type emulsions.

<Desc / Clms Page number 14>

These compositions may be in particular in the form of an emulsion, simple or complex (O / W, W / O, O / W / H or W / O / W) such as cream, milk, gel or gel cream, powder, solid stick and optionally be packaged in aerosol and be in the form of foam or spray.

In the case of an emulsion, the aqueous phase thereof may comprise a nonionic vesicular dispersion prepared according to known methods (Bangham, Standish and Watkins J. Mol Biol 13, 238 (1965), FR2315991 and FR2416008) The cosmetic composition of the invention can be used as a composition for protecting the human epidermis or the hair against ultraviolet rays, as an antisolar composition or as a makeup product.

When the cosmetic composition according to the invention is used for the protection of the human epidermis against UV rays, or as an antisolar composition, it may be in the form of a nonionic vesicular dispersion, an emulsion, in particular an oil-in-water emulsion, cream, milk, gel, cream gel, suspension, dispersion, powder, solid stick, foam or spray.

When the cosmetic composition according to the invention is used for protecting the hair against UV rays, it may be in the form of a shampoo, a lotion, a gel, an emulsion or a nonionic vesicle dispersion and may constitute, for example, a composition. rinsing, applying before or after shampooing, before or after coloring or bleaching, before, during or after permanent or straightening, a styling or treatment lotion or gel, a lotion or a gel for blow-drying or setting, a composition of permanent or straightening, coloring or discoloration of hair.

When the composition is used as a makeup product for eyelashes, eyebrows or skin, such as epidermis cream, foundation, lipstick stick, eyeshadow, blush, mascara or liner also called "eyeliner", it can be in solid or pasty, anhydrous or aqueous form, such as oil-in-water or water-in-oil emulsions, nonionic vesicular dispersions or suspensions As an indication, for antisolar formulations that comply According to the invention, which have an oil-in-water emulsion type support, the aqueous phase (comprising in particular the hydrophilic filters) generally represents from 50 to 95% by weight, preferably from 70 to 90% by weight, relative to the entire formulation, the oily phase (including in particular the lipophilic filters) of 5 to 50% by weight, preferably 10 to 30% by weight, relative to the entire formulation, and the or the co) em ulsionnant (s) from 0.5 to 20% by weight, preferably from 2 to 10% by weight, relative to the entire formulation.

A concrete example, but in no way limiting, illustrating the invention, will now be given.

<Desc / Clms Page number 15>

<Tb>
<Tb>

COMPOSITION <SEP>%
<tb> in
<tb> oids
<tb> Mixture <SEP> mono / distearate <SEP> of <SEP> glycerol <SEP> / <SEP> stearate <SEP> of <SEP> polyethylene <SEP> 2
<tb> Glycol <SEP> (100 <SEP> OE) <SEP> ARLACEL <SEP> 165 <SEP> FL <SEP> - <SEP> HERE
<tb> Stearyl alcohol <SEP><SEP> 1
<tb> LANTERN <SEP> 18 <SEP> - <SEP> HENKEL <SEP>
<tb><SEP> Stearic acid <SEP> oil <SEP> of <SEP> palm <SEP> 2.5
<tb> STEARINE <SEP> TP <SEP> - <SEP> STEARINERY <SEP> DUBOIS
<tb> poly <SEP> dimethylsiloxane <SEP> 0 <SEP> 5 <SEP>
<tb> DOW <SEP> CORNING <SEP> 200 <SEP> FLUID <SEP> - <SEP> DOW <SEP> CORNING
<tb> Benzoate <SEP> of alcohols <SEP> in <SEP> C12 / C15 <SEP> 20
<tb> ITCONOL <SEP> TN <SEP> -WITCO
<tb> Tnethanolamine <SEP> 0. <SEP> 5
<tb> Methylene <SEP> bis- (tetramethylbutyl <SEP> hydroxyphenyl <SEP> benzotriazole) <SEP> 5
<tb> Glycerine <SEP> 5
<tb> Phosphate <SEP> of alcohol <SEP> hexadecyl, salt <SEP> of <SEP> potassium
<tb> AMPHISOL <SEP> K <SEP> - <SEP> HOFFMAN <SEP> LAROCHE <SEP> ~~ <SEP> ~ <SEP> 1
<tb> Polyacrylic acid <SEP><SEP> 0 <SEP> 3 <SEP>
<tb> SYNTHALEN <SEP> K <SEP> - <SEP> 3V)
<tb> Hydroxypropyl <SEP> methyl <SEP> cellulose <SEP> 0.1
<tb> METHOCEL <SEP> F4M <SEP> -DOW <SEP> CHEMICAL
<tb> Butyl <SEP> methoxydibenzoyl <SEP> methane <SEP> 2
<tb> (Parsol <SEP> 1789 <SEP>;<SEP> GIVAUDAN)
<tb> Derivative <SEP> of acid <SEP> naphthalene <SEP> dicarboxylic acid <SEP> to <SEP> termination <SEP> glycol <SEP> and <SEP> 4
<tb> proposed <SEP> alcohol <SEP> under <SEP><SEP> denomination <SEP> HALLBRITE <SEP> TQ <SEP> by <SEP><SEP> company
<tb> CP <SEP> HALL
<tb> Drometzole <SEP> Trisiloxane <SEP> (SILATRIZOLE <SEP> -RHODIA <SEP> CHEMISTRY
<tb> Triethanolamine <SEP> qs <SEP> pH
<tb> Conservatives <SEP> qs
<tb> Demineralized <SEP> water <SEP> qsp <SEP> 100 <SEP> g
<Tb>

Claims (45)

 1. Cosmetic or dermatological composition, in particular antisolar, characterized in that it comprises, in a cosmetically acceptable support: (c) at least one mono- or polycarboxylic acid naphthalene derivative and (d) at least one system photoprotective agent capable of filtering UV rays containing at least one organic UV filter of the type derived from hydroxyphenylbenzotriazole. 2. Composition according to claim 1, wherein the naphthalene mono or poly-carboxylic acid derivative (s) are chosen from compounds comprising at least one unit corresponding to the following structure:

 wherein: A, the same or different, denote a group OR,; an NR 2 R 3 group or a cation M x is a number from 1 to 8; y is a number from 0 to 7 with x + y # 8; B, identical or different, denote hydrogen, OR,; an NR2R3 group or a - (C = O) R1 group; R1, R2, R3, which may be identical or different, denote hydrogen; an acyclic or cyclic linear or branched C1-C30 alkyl, optionally interrupted by one or more heteroatoms and optionally substituted with one or more different B groups of hydrogen; an acyclic or cyclic linear or branched C 2 -C 30 alkenyl, optionally interrupted by one or more heteroatoms (such as O, S, N) and optionally substituted with one or more different B groups of hydrogen; a C 6 -C 30 aryl, aralkyl or alkylaryl group, optionally substituted with one or more different B groups of hydrogen; a C3-C12 heterocycle, optionally substituted with one or more different B groups of hydrogen; a halogen (such as fluorine, bromine or chlorine); a nitrile group; an amino group; a nitro group; a cyano group; a group S03H or SO3M; a group comprising at least one silicon atom; M represents an alkali metal, alkaline earth metal, ammonium or quaternized amine or alkanolamine residue 3. Composition according to claim 1 or 2, wherein the naphthalene mono- or poly-carboxylic acid derivative (s) are chosen from the group consisting of: (1) mono- or polycarboxylic naphthalene acids and their salts; (2) mono- or polyesters of mono- or polycarboxylic naphthalene acids and their salts, (3) mono- or polycarboxylic naphthalene mono- or polyamides and their salts; 2,3-naphthalene acid diamide dicarboxylic acid and their salts <Desc / Clms Page number 17>  4. Composition according to any one of claims 1 to 3, wherein the mono- or poly-carboxylic naphthalene acid derivative (s) are derivatives of naphthalene dicarboxylic acid containing glycols and alcohols. 5. Composition according to any one of claims 1 to 3, wherein the naphthalene mono- or poly-carboxylic acid derivative (s) present in the compositions according to the invention at a total concentration of between 0.1 and 20% by weight. about weight, and preferably between 0.5 and 10% by weight, relative to the total weight of the composition. 5. Composition according to any one of claims 1 to 4, wherein the UV filter (s) of the hydroxyphenylbenzotriazole derivative type are siliconized or hydrocarbon-based. 6. The composition according to claim 5, wherein the one or more silicious UV filters of hydroxyphenylbenzotriazole are chosen from those corresponding to the following formula (II):

 in which: D denotes a divalent radical -LW- - Y, which may be identical or different, are chosen from C1-C10 alkyl radicals, halogens, C1-C10 alkoxy radicals and sulphonic groups, it being understood that, in in the latter case, two adjacent Y's of the same aromatic ring may together form an alkylidene dioxy group in which the alkylidene group contains from 1 to 2 carbon atoms; with the proviso that the radicals Y are different from a sulfonic group when D is different from hydrogen; n is 1, 2 or 3; L is a divalent radical of formula (III) below

 in which X represents 0 or NH, - Z represents hydrogen or a C1-C4 alkyl radical, - n is an integer between 0 and 3 inclusive, - m is 0 or 1, - p represents a number integer between 1 and 10, inclusive. - W is a radical of formula (1), (2) or (3) below: <Desc / Clms Page number 18>  Which ones?

 wherein Y, n and L have the same meanings given above; - r is an integer between 0 and 50 inclusive, and s is an integer between 1 and 20 inclusive, and if s = 0 at least one of the two radicals B is V; u is an integer from 1 to 6 inclusive, and t is an integer from 0 to 10 inclusive, with the proviso that t + u is equal to or greater than 3.

 R, which are identical or different, are chosen from C 1 -C 10 alkyl, phenyl and 3,3,3-trifluoropropyl radicals, at least 80% by number of the radicals R being methyl, E, which are identical or different, are chosen; among the radicals R and the radical V of the following formula - 7. Composition according to claim 6, wherein the UV filter (s) of formula (II) are linear polyorganosiloxanes and W corresponds to formula (1). 8. Composition according to claim 7, wherein the UV filter (s) of formula (II) are linear random or block polyorganosiloxanes having at least one of the following characteristics: R is alkyl-E is alkyl and even more preferably is methyl, r is from 0 to 15 inclusive; s is between 1 and 5 inclusive, <Desc / Clms Page number 19>  n is non-zero, and preferably 1, and Y is then selected from methyl, ter-butyl or C 1 -C 4 alkoxy, Z is hydrogen or methyl, -m = 0, or [m = 1 and X = O] - p is equal to 1 9. Composition according to claim 8, wherein the UV filter (s) of formula (II) are linear random or block polyorganosiloxanes having all of the features set forth in claim 8. 10. Composition according to claim 7 or 8, wherein the UV filter (s) of formula (II) are linear random or block polyorganosiloxanes having at least one of the following characteristics: R is methyl, E is methyl, r is from 0 to 15 inclusive; s is between 1 and 5 inclusive, - n is 1, and Y is then selected from methyl, tert-butyl or C 1 -C 4 alkoxy, - Z is hydrogen or methyl, - m = 0, or [m = 1 and X = O] - p is equal to 1. 11. Composition according to claim 10, wherein the UV filter (s) of formula (II) are linear random or block polyorganosiloxanes having all of the features set forth in claim 10. 12. Composition according to any one of claims 6 to 11, according to which for the compounds of formula (II), the attachment of the - (X) m- (CH 2) p -CH (Z) -CH 2 - linkage on the hydroxyphenylbenzotriazole unit is in position 3,4, 5 or 4 '. 13. Composition according to claim 12, wherein for the compounds of formula (II), the attachment of the - (X) m- (CH2) p-CH (Z) -CH2- linkage on the hydroxyphenylbenzotriazole unit is in position. 3,4 or 5. 14. A composition according to claim 13, wherein for the compounds of formula (II), the attachment of the - (X) m- (CH 2) p -CH (Z) -CH 2 - to the hydroxyphenylbenzotriazole unit is in position 3. 15. Composition according to any one of claims 6 to 14, according to which for the compounds of formula (II), the attachment of the substituent unit Y is in position 3, 4, 4 ', 5 and / or 6 and preferably in position 5. Composition according to any one of claims 6 to 15, the compound of formula (II) has the following structure: <Desc / Clms Page number 20>

 with 0 # r # 15, preferably 0 # r # 10 1 <s # 5, preferably 1 # s # 3 and G represents one of the following divalent radicals:

 17. Composition according to claim 16, wherein the compound of formula (II ') has as structure is the compound of structure:

 18. Composition according to any one of Claims 6 to 17, according to which the hydrocarbon derivative (s) of hydroxyphenylbenzotriazole are chosen from compounds corresponding to the following formula (4): <Desc / Clms Page number 21>  wherein a is 1,2 or 3 and the radicals T1, which may be identical or different, are chosen from among the C1-C18 alkyl radicals, halogens, sulphonic groups, and C1-C18 alkoxy radicals, it being understood that in the latter case, two adjacent Ti of the same aromatic ring may together form an alkylidene dioxy group in which the alkylidene group contains from 1 to 2 carbon atoms.

19. Composition according to claim 18, wherein the compounds of formula (4) are chosen from: 2- (2'-hydroxy-5'-methylphenyl) benzotriazole; 2- (2'-hydroxy-3'-butyl-5'-methylphenyl) benzotriazole; 2- (2'-hydroxy-5'-t-octylphenyl) benzotriazole; 2- (2'-hydroxy-3'-sec-butyl-5'-benzenesulfonate) benzotriazole. 20. Composition according to any one of Claims 6 to 17, according to which the hydrocarbon derivative (s) of hydroxyphenylbenzotriazole are chosen from those of the following formula (5):

 wherein T5 denotes a hydrogen atom or a C1-C18 alkyl radical; T6 and T7, identical or different, denote a C1-C18 alkyl radical optionally substituted with a phenyl. <Desc / Clms Page number 22>

 The composition of claim 20, wherein the compounds of formula (5) are selected from the following compounds - <Desc / Clms Page number 23>

 22. Composition according to any one of claims 6 to 17, according to which the hydrocarbon derivative of hydroxyphenylbenzotriazole is [2,4'-dihydroxy-3- (2H-benzotriazol-2-yl) -5- (1,1,3 3-tetramethylbutyl) -2'-n-octoxy-5'-benzoyl] diphenylmethane of structure:  23. Composition according to any one of claims 6 to 17, according to which the hydrocarbon derivative (s) of hydroxybenzotriazole are chosen from methylene bis (hydroxyphenyl benzotriazole) derivatives having the following structure:

 in which the radicals T8 and T9, which are identical or different, denote a C1-C18 alkyl radical which may be substituted with one or more radicals chosen from C1-C4 alkyl, C5-C12 cycloalkyl or an aryl radical. Composition according to claim 23, wherein the compound of formula (6) is selected from compounds of the following structure: <Desc / Clms Page number 24>

 25. Composition according to any one of claims 1 to 24, wherein the hydroxyphenylbenzotriazole derivatives are in particulate form and are insoluble or substantially insoluble in the usual cosmetic solvents. 26. The composition according to claim 25, wherein the hydroxyphenylbenzotriazole derivatives are in micronized insoluble form. 27. Composition according to claim 25 or 26, wherein the hydroxyphenylbenzotriazole derivatives are in the form of particles of average size ranging from 0.01 to 2 m. 28. The composition according to claim 27, wherein the hydroxyphenylbenzotriazole derivatives are in the form of particles of average size ranging from 0.02 to 1.5 m. <Desc / Clms Page number 25> 29. The composition of claim 28, wherein the hydroxyphenylbenzotriazole derivatives are in the form of particles of average size ranging from 0.05 to 1.0 m. 30. Composition according to any one of claims 25 to 29, wherein the hydroxyphenylbenzotriazole derivatives in micronized form can be obtained by a grinding process of a hydroxyphenylbenzotriazole derivative in the form of coarse particles in the presence a surfactant. 31. A composition according to claim 30, wherein the surfactant is chosen from alkylpolyglucosides having the structure CnH2n + O (C6H10O5) zH in which n is an integer of 8 to 16 and z is the average degree of polymerization of the unit. (C6H10O5) and ranges from 1.4 to 1.6. 32 Composition according to any one of claims 30 and 31, characterized in that the surfactant is used at a concentration ranging from 1 to 50% by weight relative to the derivative of hydroxyphenyl benzotriazole in its micronized form 33. Composition according to any one of claims 1 to 32, characterized in that the filter or filters of the hydroxyphenylbenzotriazole derivative type are present in a concentration ranging from 0.1 to 20% by weight, and preferably between 0.5 to 10% by weight approximately, relative to the total weight of the composition. Composition according to any one of Claims 1 to 33, characterized in that the said cosmetically acceptable support is in the form of an oil-in-water type emulsion. 35. Composition according to any one of claims 1 to 34, characterized in that it further comprises one or more complementary organic filters active in the UV-A and / or UV-B. 36. Composition according to claim 29, characterized in that said complementary organic screening agents are chosen from cinnamic derivatives; dibenzoylmethane derivatives; salicylic derivatives, camphor derivatives; triazine derivatives; benzophenone derivatives; ss, ss'-diphenylacrylate derivatives, benzimidazole derivatives; bis-benzoazolyl derivatives; derivatives of paminobenzoic acid; filter and silicone polymers. 37. Composition according to any one of claims 1 to 36, characterized in that it further comprises, as complementary UV photoprotective agents, pigments or nanopigments of metal oxides, coated or uncoated. 38. The composition as claimed in claim 37, characterized in that said pigments or nanopigments are chosen from titanium, zinc, iron, zirconium and cerium oxides and their mixtures, whether coated or not. 39. Composition according to any one of claims 1 to 38, characterized in that it further comprises at least one agent for tanning and / or artificial browning of the skin. 40. Composition according to any one of claims 1 to 39, characterized in that it further comprises at least one adjuvant selected from fatty substances, organic solvents, thickeners, softeners, opacifiers, stabilizers, emollients, anti-foam agents, moisturizers, perfumes, preservatives, polymers, fillers, sequestering agents, propellants, basifying or acidifying agents. <Desc / Clms Page number 26> 41. A composition according to any one of claims 1 to 40, characterized in that it is a protective composition of the human epidermis or an antisolar composition and it is in the form of a non-ionic vesicle dispersion, an emulsion, in particular an oil-in-water emulsion, a cream, a milk, a gel, a cream gel, a suspension , a dispersion, a powder, a solid stick, a foam or a spray. 42. Composition according to any one of claims 1 to 40, characterized in that it is a makeup composition of the eyelashes, eyebrows or skin and that it is in solid or pasty form. , anhydrous or aqueous, an emulsion, a suspension or a dispersion. 43. A composition according to any one of claims 1 to 40, characterized in that it is a composition for protecting the hair against ultraviolet rays and is in the form of a shampoo, lotion, gel, emulsion, non-ionic vesicular dispersion. 44. Use of the composition defined according to any one of claims 1 to 43 for the manufacture of cosmetic compositions for the protection of the skin and / or the hair against ultraviolet radiation, in particular solar radiation. Use of a naphthalene mono- or polycarboxylic acid derivative in the preparation of a photoprotective cosmetic or dermatological composition comprising at least one organic UV filter of the hydroxyphenylbenzotriazole derivative type as defined in the preceding claims, with the aim of increase its level of protection against effects induced by UV-A radiation