FR2785610B1 - Procede de dedoublement d'un melange racemique d'aldehydes, procede de preparation dudit aldehyde et utilisation dudit aldehyde sous forme de l'un de ses enantiomeres ou sous forme racemique - Google Patents

Procede de dedoublement d'un melange racemique d'aldehydes, procede de preparation dudit aldehyde et utilisation dudit aldehyde sous forme de l'un de ses enantiomeres ou sous forme racemique

Info

Publication number
FR2785610B1
FR2785610B1 FR9814022A FR9814022A FR2785610B1 FR 2785610 B1 FR2785610 B1 FR 2785610B1 FR 9814022 A FR9814022 A FR 9814022A FR 9814022 A FR9814022 A FR 9814022A FR 2785610 B1 FR2785610 B1 FR 2785610B1
Authority
FR
France
Prior art keywords
aldehyde
racemic
enantiomers
aldehydes
splitting
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR9814022A
Other languages
English (en)
Other versions
FR2785610A1 (fr
Inventor
Francois Mercier
Stephane Lelievre
Francois Mathey
Michel Spagnol
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rhodia Chimie SAS
Original Assignee
Rhodia Chimie SAS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to FR9814022A priority Critical patent/FR2785610B1/fr
Application filed by Rhodia Chimie SAS filed Critical Rhodia Chimie SAS
Priority to US09/831,044 priority patent/US6613945B1/en
Priority to EP99954063A priority patent/EP1127037A1/fr
Priority to JP2000580960A priority patent/JP2002529431A/ja
Priority to CA002349918A priority patent/CA2349918A1/fr
Priority to PCT/FR1999/002700 priority patent/WO2000027778A1/fr
Priority to AU10519/00A priority patent/AU1051900A/en
Publication of FR2785610A1 publication Critical patent/FR2785610A1/fr
Application granted granted Critical
Publication of FR2785610B1 publication Critical patent/FR2785610B1/fr
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6568—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus atoms as the only ring hetero atoms
    • C07F9/65685—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus atoms as the only ring hetero atoms the ring phosphorus atom being part of a phosphine oxide or thioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/1875—Phosphinites (R2P(OR), their isomeric phosphine oxides (R3P=O) and RO-substitution derivatives thereof)
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6568—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus atoms as the only ring hetero atoms
    • C07F9/65683—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus atoms as the only ring hetero atoms the ring phosphorus atom being part of a phosphine
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
FR9814022A 1998-11-06 1998-11-06 Procede de dedoublement d'un melange racemique d'aldehydes, procede de preparation dudit aldehyde et utilisation dudit aldehyde sous forme de l'un de ses enantiomeres ou sous forme racemique Expired - Fee Related FR2785610B1 (fr)

Priority Applications (7)

Application Number Priority Date Filing Date Title
FR9814022A FR2785610B1 (fr) 1998-11-06 1998-11-06 Procede de dedoublement d'un melange racemique d'aldehydes, procede de preparation dudit aldehyde et utilisation dudit aldehyde sous forme de l'un de ses enantiomeres ou sous forme racemique
EP99954063A EP1127037A1 (fr) 1998-11-06 1999-11-04 Procede de deboublement d'un melange racemique d'aldehydes
JP2000580960A JP2002529431A (ja) 1998-11-06 1999-11-04 アルデヒドのラセミ混合物の分割方法
CA002349918A CA2349918A1 (fr) 1998-11-06 1999-11-04 Procede de deboublement d'un melange racemique d'aldehydes
US09/831,044 US6613945B1 (en) 1998-11-06 1999-11-04 Resolution method for a racemic mixture of aldehydes
PCT/FR1999/002700 WO2000027778A1 (fr) 1998-11-06 1999-11-04 Procede de deboublement d'un melange racemique d'aldehydes
AU10519/00A AU1051900A (en) 1998-11-06 1999-11-04 Resolution method for a racemic mixture of aldehydes

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR9814022A FR2785610B1 (fr) 1998-11-06 1998-11-06 Procede de dedoublement d'un melange racemique d'aldehydes, procede de preparation dudit aldehyde et utilisation dudit aldehyde sous forme de l'un de ses enantiomeres ou sous forme racemique

Publications (2)

Publication Number Publication Date
FR2785610A1 FR2785610A1 (fr) 2000-05-12
FR2785610B1 true FR2785610B1 (fr) 2001-02-09

Family

ID=9532480

Family Applications (1)

Application Number Title Priority Date Filing Date
FR9814022A Expired - Fee Related FR2785610B1 (fr) 1998-11-06 1998-11-06 Procede de dedoublement d'un melange racemique d'aldehydes, procede de preparation dudit aldehyde et utilisation dudit aldehyde sous forme de l'un de ses enantiomeres ou sous forme racemique

Country Status (7)

Country Link
US (1) US6613945B1 (fr)
EP (1) EP1127037A1 (fr)
JP (1) JP2002529431A (fr)
AU (1) AU1051900A (fr)
CA (1) CA2349918A1 (fr)
FR (1) FR2785610B1 (fr)
WO (1) WO2000027778A1 (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2815344B1 (fr) * 2000-10-13 2004-01-30 Rhodia Polyamide Intermediates Procede d'hydrocyanation de composes organiques a insaturation ethylenique

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2760457B1 (fr) * 1997-03-04 1999-04-23 Rhodia Chimie Sa Nouvelles diphosphines de 6,6'-bis-(1-phosphanorbornadiene), leur preparation et leurs applications

Also Published As

Publication number Publication date
US6613945B1 (en) 2003-09-02
AU1051900A (en) 2000-05-29
EP1127037A1 (fr) 2001-08-29
JP2002529431A (ja) 2002-09-10
CA2349918A1 (fr) 2000-05-18
FR2785610A1 (fr) 2000-05-12
WO2000027778A1 (fr) 2000-05-18

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Legal Events

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