FR2743298A1 - New cleansing or make-up removal composition - Google Patents

Abstract

New composition (I) to cleanse, or remove make-up from, skin and/or mucous membranes and/or eyes comprises a homogeneous poly-holoside (II) and/or a compound (III) containing (II). Also claimed is a method of cleansing or removing make-up from skin and/or mucous membranes and/or eyes comprising the application of (I).

Description

The present invention relates to the use of a polyholoside in a composition, in particular a cosmetic composition, intended for cleaning and / or removing makeup from the skin and / or mucous membranes and / or eyes.

 It is known to use makeup-removing oils in compositions for removing makeup from the skin and / or the eyes. Generally, these compositions also comprise surfactants which make it possible to improve the elimination of said oil and / or traces of makeup. However, it is known that the use of these compositions can leave an impression of discomfort, in particular on the eyelids and / or on the eyes.

 It is also known makeup removal compositions based solely on surfactants, which will allow the removal of traces of makeup while facilitating the emulsification of the composition, making compatible the fatty and aqueous phases of the composition when it present in the form of an emulsion. However, surfactants can have the disadvantage of being more or less irritating to the skin.

The object of the invention is to overcome the drawbacks of the prior art and to propose a composition which allows easy and adequate cleaning and / or make-up removal, which is not irritating to the skin and / or the eyes, and which does not contain a surfactant.

The first object of the invention is therefore a composition for cleaning and / or removing make-up from the skin and / or mucous membranes and / or eyes, comprising a homogeneous polyholoside.

Another subject of the invention is the use of homogeneous polyholoside in a composition for cleansing and / or removing make-up for the skin and / or the mucous membranes and / or the eyes, comprising a cosmetically or dermatologically acceptable support, in particular as cleaning agent and / or make-up remover, and / or in order to obtain a makeup-removing composition with little or no irritation, and / or in order to obtain a composition having a soft feel, and / or in order to obtain a gelled composition.

Another object of the invention is a method for cleaning and / or removing makeup from the skin and / or mucous membranes and / or eyes, characterized in that it is applied to the skin and / or to the mucous membranes and / or on the eyes a composition as defined above.

It has in fact been found that the use of a polyholoside according to the invention makes it possible to obtain an effective cleaning and / or make-up removing composition, non-irritating and slightly tacky, which moreover has a soft and pleasant feel.

In addition, the incorporation of a polyholoside into compositions, in particular cosmetic compositions, makes it possible to obtain a gelled composition without additional addition of gelling agent conventionally used. The gel obtained is smooth and creamy.

The present invention therefore relates to the use of a homogeneous polyholoside as a makeup-removing agent, and / or in a makeup-removing composition.

Saccharides, with the formula Cn (H2O) n, are generally divided into two categories: simple sugars or sugars, and osides or the association of several molecules.

Among the osides, a distinction can be made between holosides which are formed solely of sugars and heterosides which consist of one or more oses and a non-carbohydrate part.

Among the polyholosides, one can also distinguish homogeneous polyholosides which result from the association of the same ose, and heterogeneous polyholosides which result either from the association of different oses, or from the association of oses having the same raw chemical formula but of different geometric configuration (D and L isomers for example).

Thus, the polyholosides according to the invention are homogeneous, therefore consist only of sugars and result from the association of the same ose.

They can however be substituted, in particular by fatty chains or amino groups.

The polyholosides according to the invention can mainly comprise 2 to 10 times the same ose (oligoholosides), or more than 10 times the same ose.

The polyholosides according to the invention can mainly comprise a single daring motif, chosen from all possible daring motifs, of natural or synthetic origin, and in particular such as:
the aldoses like
pentoses: ribose, arabinose, xylose or apiose, for example,
hexoses: glucose, fucose, mannose or galactose, for example,
ketoses such as fructose,
. deoxyoses, such as rhamnose, digitoxose, cymarose or oleandrosis,
. oste derivatives such as uronic acids such as mannuronic, guluronic, galacturonic or glycuronic acids, or itols such as mannitol or sorbitol.

Among the polyholosides according to the invention, there may be mentioned:
chitin and its derivatives, such as chitosan derivatives, and in particular chitosan lactate, which an N-substituted polyholoside;
. derivatives of hyaluronic acid, such as metal salts, and in particular sodium hyaluronate which is an N-substituted polyholoside;
dextran and its derivatives, such as dextran sulfate,
. cellulose and its derivatives, such as cellulose gum, hydroxyethylcellulose, hydroxypropylcellulose, polyquaternium 10 and 24;
. Starch, amylose and amylopectin and their derivatives;
chondroid and its derivatives, such as chondroitin and chondroitin sulfate.

The polyholoside according to the invention can be optionally branched or linear. It can also be substituted, for example by fatty chains, in particular comprising 8 to 30 carbon atoms, and / or by amino groups.

In the context of the present invention, it is possible to use a homogeneous polyholoside alone, or a mixture of homogeneous polyholosides.

The polyholosides according to the invention are preferably introduced into the composition in the form of an aqueous solution which can comprise 0.01 to 5% by weight of polyholoside.

The polyholoside can be present in the final composition in an amount of 0.01 to 5% by weight, preferably 0.01 to 1% by weight.

The polyholosides according to the invention can therefore be used as a makeup-removing agent, in particular in a composition for cleansing and / or removing makeup from the skin of the body or face, mucous membranes such as the lips, and / or the eyes. .

Said composition can be in the form of an emulsion, in particular oil-in-water or water-in-oil, or even in the form of a multiple emulsion.

It can also be in the form of an aqueous solution, optionally gelled, or in the form of a lotion, for example two-phase, of a cream, of a milk, or even of a foam.

The composition according to the invention may comprise an oily phase based on animal, vegetable, mineral, silicone, fluorinated and / or synthetic oil.

The oily phase can also include fatty alcohols or fatty acids, as well as surfactants and emulsifiers.

Mention may in particular be made of hydrocarbon oils such as paraffin or petrolatum oil; perhydrosqualene; Arara oil; Sweet almond, calophyllum, palm, castor, avocado, jojoba, olive or germ of cereal oil; alcohols such as oleic alcohol, linoleic or linolenic alcohol,
Isostearic alcohol or octyl dodecanol. Mention may also be made of silicone oils such as PDMS, optionally phenylated such as phenyltrimethicones.

The oily phase may also comprise a cleansing oil such as a fatty acid ester, in particular the esters obtained from a straight or branched chain alcohol having from 1 to 17 carbon atoms and from a fatty acid to straight or branched chain having 3 to 18 carbon atoms.

 Such an ester can in particular be chosen from the group consisting of dioctyl adipate, 2-ethylhexyl palmitate, diisopropyl adipate, 2-ethylhexyl hexanoate, ethyl spleen , methyl myristate, octyldodecyl octanoate, isodecyl neopentanoate, ethyl myristate, myristyl propionate, 2-ethyl 2-ethylhexyl hexanoate, ethyl octanoate 2 hexyl, ca pratelcaprylate-2-hexyl, methyl palmitate, butyl myristate, isobutyl myristate, ethyl palmitate, isohexyl laurate, hexyl las spleen, I ' isopropyl isostearate.

The oily phase may be present in an amount of 5-95% by weight in the case of an emulsion.

The composition according to the invention can also comprise
. an agent allowing the suspension of the fatty phase, for example a copolymer of C1-C30 alkyl acrylates and acrylic or methacrylic acid or their ester (Pemulen TR1, Pemulen TR2, Carbopol 1342 from GOODRICH) ; or an acrylamidelethylpropane sulfonic acid copolymer (Sepigel from
SEPPIC), and / or
. an agent for dispersing the fatty phase, such as an emulsifying or vesicular system based on vesicles, optionally of nanometric size, consisting of ionic lipids (liposomes) or nonionic, and in particular the emulsifying systems well known in the art. skilled in the art consist of glyceryl stearate / PEG 100 stearate (CTFA), cetyl alcohol and stearyl alcohol.

The composition of the invention may also comprise an agent for modifying its viscosity, and obtaining more or less gelled textures, such as:
. cellulose derivatives (carboxymethylcellulose, hydroxyethylcellulose, hydroxypropylmethylcellulose),
. natural gums such as xanthan, guar, carob gums, scleroglucans, chitin or chitosan derivatives, carrageenans,
. polycarboxyvinyl derivatives of the Carbomer type (sold by GOODRICH under the names Carbopol, 940, 951, 980, or by 3V-SIGMA under the name Synthalen K or Synthalen L).

The composition according to the invention can also comprise, in a known manner, adjuvants commonly used in the field under consideration, such as preservatives, antioxidants, perfumes, fillers such as kaolin or starch, or even hollow microspheres, pigments, UV filters, sequestrants, essential oils, coloring matters, hydrophilic or lipophilic active agents such as moisturizers, in particular glycerin, butylene glycol, anti-inflammatory agents such as allantoin, bisabolol, anti -free radicals such as vitamin E or its derivatives, soothing agents such as blueberry water, iris extract, depigmentants, biological active agents such as urea, amino acids, vitamins and their derivatives, proteins, Salicylic acid and its derivatives, α-hydroxy acids, Pyrrolidone carboxylic acid and its salts, ceramides.

Of course, a person skilled in the art will take care to choose this or these optional additional compounds, and / or their quantity, in such a way that the advantageous properties of the composition according to the invention are not, or not substantially, altered by the addition considered.

The composition preferably has a pH which respects the skin, generally between 5 and 8, preferably a pH of 5.5 to 7.5.

The invention is illustrated in more detail in the following examples.

EXAMPLE 1 Makeup Removing Eye Lotion
. chitosan lactate 0.5g
. allantoin 0.1 g
. blueberry water 3g .eauderose rosewater 0.5g
. conservative qs
. water qs 100 g
This lotion, which contains no surfactant, allows effective makeup removal of the eyes; moreover, it is particularly suitable for sensitive eyes.

EXAMPLE 2 Makeup Removing Eye Lotion
. sodium hyaluronate 0.05g
. allantoin 0.1 g
. blueberry water 3g
. rose water 0.5g
. conservative qs
. water qs 100 g
This lotion, which contains no surfactant, allows effective make-up removal and is particularly suitable for sensitive eyes.

Example 3: Two-phase cleansing lotion aqueous phase (55% by weight). chitosan lactate 0.5 g. copper salt 0.04 g. conservative qs. water qs 100 g fatty phase (45% by weight). petroleum jelly oil 15 g. volatile silicone oil 55g. 2-hexyl ethyl palmitate 30 g
A two-phase lotion is obtained which allows easy and effective makeup removal even for waterproof makeup.

EXAMPLE 4 Cleansing Milk for the Face and the Eyes
. dextran 0.5 g
. 2-hexyl ethyl palmitate 25 g
. glycerin 39
. 0.5 g carboxyvinyl polymer
. NaOH 0.3 g
. conservative qs
.water qs 100 g
This composition is in the form of a cleansing milk having good cosmetic properties, and being soft and comfortable to use.

EXAMPLE 5 Cleansing Milk for the Face and the Eyes
. sodium hyaluronate 0.05 g
. 2-hexyl ethyl palmitate 25 g
. glycerin 3g
. 0.5 g carboxyvinyl polymer
. NaOH 0.3 g
. conservative qs
. water qs 100g
This composition is in the form of a cleansing milk having good cosmetic properties, and being soft and comfortable to use.

EXAMPLE 6 Cleansing Gel for the Face
. sodium hyaluronate 0.05 g
. glycerin 39
. Carbomer 0.8 g
. shea butter 1 g
. alcohol 59
. conservative qs
. water qs 100 g
This composition is in the form of a make-up removing gel having good cosmetic properties.

EXAMPLE 7 Makeup Removal Cream
. sodium hyaluronate 0.01 g
. 2-hexyl ethyl palmitate 10g
. volatile silicone oil 10 g
. apricot almond oil 7g
stearyl alcohol 59
. potassium stearate 0.5 g
. sorbitan stearate + sucrose cocoate 4g
. xanthan gum 0.3 g
. conservative qs
. water qs 100 g
This composition is in the form of a cleansing cream having good cosmetic properties.

Example 8
Two aqueous solutions are prepared comprising, one 0.5% by weight of chitosan lactate, the other 0.05% by weight of sodium hyaluronate.

 Test1: we compare the make-up removing power of these two solutions, with that of water and that of a commercial make-up remover.

The make-up removing power is determined using the so-called "make-up removing robot" technique:
. The apparatus consists of a plate and an arm provided with a weight exerting on the plate a pressure of 100 g / cm 2 and equipped at one of its ends with a cotton which slides on the plate.

 a thin layer of a waterproof black mascara sold under the brand Keracils by Lancôme is placed on the plate.

 . this plate is left to dry for 4 h.

 . 8 simple passages are then carried out without return, of cotton soaked in 1 ml of composition to be tested, the cotton being changed after each passage.

 . the quantity of mascara remaining on the plate is visually evaluated after the 8 passes.

The 8 passages correspond to a perfect make-up removal with the commercial make-up remover, taken as a reference.

It is found that the make-up removing power of the two solutions comprising a polyholoside according to the invention is greater than that of water, and equal or even greater than that of the commercial make-up remover.

 Test2: these results were confirmed by an in vivo test, carried out on 10 people.

The solutions according to the invention are tested in comparison with the commercial make-up remover (control), for at least 3 days.

Three criteria are evaluated: cleansing power, cosmetic character (softness, slippery, ...) and comfort.

The following results are obtained
. solution comprising chitosan lactate:
. Makeup remover identical to that of the witness makeup remover
. cosmetic character identical to that of the control makeup remover
. superior comfort to that of the witness makeup remover. solution including sodium hyaluronate
. superior make-up removal power than that of the control makeup remover
. cosmetic character superior to that of the witness makeup remover
superior comfort to that of the witness makeup remover

Claims (21)

 CLAIMS 1. Composition for cleaning and / or removing make-up from the skin and / or mucous membranes and / or eyes, comprising a homogeneous polyholoside. 2. Composition according to claim 1, in which the homogeneous polyholoside mainly comprises an ose motif chosen from aldoses, ketoses, deoxyoses, ose derivatives, and mixtures thereof. 3. Composition according to one of the preceding claims, in which the homogeneous polyholoside is substituted by amino groups and / or fatty chains, preferably having 8-30 carbon atoms. 4. Composition according to one of the preceding claims, in which the homogeneous polyholoside is in linear or branched form. 5. Composition according to one of the preceding claims, in which the homogeneous polyholoside is chosen from chitin and its derivatives, such as chitosan derivatives, and in particular chitosan lactate; derivatives of hyaluronic acid, such as metal salts, and in particular sodium hyaluronate; dextran and its derivatives, such as dextran sulfate; cellulose and its derivatives, such as cellulose gum, hydroxyethylcellulose, hydroxypropylcellulose, polyquaternium 10 and 24; Starch, Amylose and lamylopectin and their derivatives; chondroid and its derivatives, such as chondroitin and chondroitin sulfate. 6. Composition according to one of the preceding claims, in which the polyholoside is present in the final composition in an amount of 0.01 to 5% by weight, preferably 0.02 to 1% by weight, relative to the composition . 7. Composition according to one of the preceding claims, not comprising a surfactant. 8. Composition according to one of the preceding claims, which is in the form of an emulsion, an optionally gelled aqueous solution, a lotion in particular two-phase, a cream, a milk, a foam. . 9. Use of at least one homogeneous polyholoside in a cleaning and / or makeup-removing composition for the skin and / or the mucous membranes and / or the eyes, comprising a cosmetically or dermatologically acceptable support. 10. Use according to claim 9, of homogeneous polyholoside, as a cleaning and / or makeup-removing agent. 11. Use according to one of claims 9 to 10, in order to obtain a makeup-removing composition with little or no irritation. 12. Use according to one of claims 9 to 11, in order to obtain a composition having a soft feel. 13. Use according to one of claims 9 to 12, in order to obtain a gelled composition. 14. Use according to one of claims 9 to 13, in which the homogeneous polyholoside mainly comprises a dare motif chosen from aldoses, ketoses, deoxyoses, derivatives of ose, and mixtures thereof. 15. Use according to one of claims 9 to 14, wherein the homogeneous polyholoside is substituted by amino groups and / or fatty chains, preferably having 8-30 carbon atoms. 16. Use according to one of claims 9 to 15, in which the homogeneous polyholoside is in linear or branched form. 17. Use according to one of claims 9 to 16, in which the homogeneous polyholoside is chosen from chitin and its derivatives, such as chitosan derivatives, and in particular chitosan lactate; derivatives of hyaluronic acid, such as metal salts, and in particular sodium hyaluronate; dextran and its derivatives, such as dextran sulfate; cellulose and its derivatives, such as cellulose gum, hydroxyethylcellulose, hydroxypropylcellulose, polyquaternium 10 and 24; Starch, Amylose and amylopectin and their derivatives; chondroid and its derivatives, such as chondroitin and chondroftin sulfate. 18. Use according to one of claims 9 to 17, in which the polyholoside is present in the final composition in an amount of 0.01 to 5% by weight, preferably 0.02 to 1% by weight, relative to the composition. 19. Use according to one of claims 9 to 18, in which the composition does not comprise a surfactant. 20. Use according to one of claims 9 to 19, in a composition in the form of an emulsion, an aqueous solution, optionally gelled, a lotion in particular two-phase, a cream, a milk, froth. 21. A method of cleaning and / or removing make-up from the skin and / or mucous membranes and / or the eyes, characterized in that a composition is applied to the skin and / or the mucous membranes and / or the eyes 'one of claims 1 to 8.