FR2728180B1 - Nouvelle composition catalytique a base de complexe de fer nitrosyle et procede pour la dimerisation du butadiene en vinyl-4 cyclohexene - Google Patents

Nouvelle composition catalytique a base de complexe de fer nitrosyle et procede pour la dimerisation du butadiene en vinyl-4 cyclohexene

Info

Publication number
FR2728180B1
FR2728180B1 FR9415294A FR9415294A FR2728180B1 FR 2728180 B1 FR2728180 B1 FR 2728180B1 FR 9415294 A FR9415294 A FR 9415294A FR 9415294 A FR9415294 A FR 9415294A FR 2728180 B1 FR2728180 B1 FR 2728180B1
Authority
FR
France
Prior art keywords
cyclohexene
vinyl
composition based
iron complex
catalytic composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR9415294A
Other languages
English (en)
Other versions
FR2728180A1 (fr
Inventor
Yves Chauvin
Souza Roberto De
Helene Olivier
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Original Assignee
IFP Energies Nouvelles IFPEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Priority to FR9415294A priority Critical patent/FR2728180B1/fr
Publication of FR2728180A1 publication Critical patent/FR2728180A1/fr
Application granted granted Critical
Publication of FR2728180B1 publication Critical patent/FR2728180B1/fr
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0277—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature
    • B01J31/0287—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature containing atoms other than nitrogen as cationic centre
    • B01J31/0288—Phosphorus
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0277—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature
    • B01J31/0278—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature containing nitrogen as cationic centre
    • B01J31/0281—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature containing nitrogen as cationic centre the nitrogen being a ring member
    • B01J31/0284—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature containing nitrogen as cationic centre the nitrogen being a ring member of an aromatic ring, e.g. pyridinium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/50—Diels-Alder conversion
    • C07C2/52—Catalytic processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/324—Cyclisations via conversion of C-C multiple to single or less multiple bonds, e.g. cycloadditions
    • B01J2231/326—Diels-Alder or other [4+2] cycloadditions, e.g. hetero-analogues
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/842—Iron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/16—Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
FR9415294A 1994-12-16 1994-12-16 Nouvelle composition catalytique a base de complexe de fer nitrosyle et procede pour la dimerisation du butadiene en vinyl-4 cyclohexene Expired - Fee Related FR2728180B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
FR9415294A FR2728180B1 (fr) 1994-12-16 1994-12-16 Nouvelle composition catalytique a base de complexe de fer nitrosyle et procede pour la dimerisation du butadiene en vinyl-4 cyclohexene

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR9415294A FR2728180B1 (fr) 1994-12-16 1994-12-16 Nouvelle composition catalytique a base de complexe de fer nitrosyle et procede pour la dimerisation du butadiene en vinyl-4 cyclohexene

Publications (2)

Publication Number Publication Date
FR2728180A1 FR2728180A1 (fr) 1996-06-21
FR2728180B1 true FR2728180B1 (fr) 1997-01-24

Family

ID=9469969

Family Applications (1)

Application Number Title Priority Date Filing Date
FR9415294A Expired - Fee Related FR2728180B1 (fr) 1994-12-16 1994-12-16 Nouvelle composition catalytique a base de complexe de fer nitrosyle et procede pour la dimerisation du butadiene en vinyl-4 cyclohexene

Country Status (1)

Country Link
FR (1) FR2728180B1 (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2757850B1 (fr) * 1996-12-27 1999-04-16 Inst Francais Du Petrole Procede ameliore pour la condensation dienique dite reaction de diels-alder
FR2806644B1 (fr) 2000-03-23 2002-05-10 Inst Francais Du Petrole Composition catalytique et procede pour la catalyse de dimerisation, de codimerisation et d'oligomerisation des olefines

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3446861A (en) * 1968-06-20 1969-05-27 Goodyear Tire & Rubber Cyclodimerization process
US3655793A (en) * 1970-12-10 1972-04-11 Phillips Petroleum Co Dimerization of conjugated dienes
US4144278A (en) * 1977-07-20 1979-03-13 Phillips Petroleum Company Diolefin dimerization using nitrosyl halides of iron triad metals
FR2425418A1 (fr) * 1978-05-09 1979-12-07 Charbonnages Ste Chimique Procede de dimerisation selective des diolefines conjuguees
US4973568A (en) * 1989-05-08 1990-11-27 The Dow Chemical Company Preparation of a catalyst useful in the dimerization of butadiene
NL9201931A (nl) * 1992-11-05 1994-06-01 Dsm Nv Werkwijze voor de dimerisatie van een geconjungeerd diëen.

Also Published As

Publication number Publication date
FR2728180A1 (fr) 1996-06-21

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Effective date: 20130830