FR2684272A1 - COMPOSITIONS CONTAINING ASSOCIATIONS OF FUNGICIDE SUBSTANCES. - Google Patents

Abstract

The invention relates to novel combinations of active substances. The combinations of active substances of the invention comprise 1- (2-chlorophenyl) -2- (1-chlorocycloprop-1-yl) -3- (1,2,4-triazol-1-yl) -propane-2 -ol of formula (CF DRAWING IN BOPI) on the one hand and certain other known fungicidal active substances on the other hand. The new combinations of active substances of the invention are suitable for combating fungi.

Description

The present invention relates to novel combinations of substances

  active substances which consist on the one hand of 1- (2-chlorophenyl) -2- (1-chloro-cycloprop-1-yl) -3- (1,2,4-triazol-1-yl) propane-2 and known other fungicidal active substances, which are very suitable for combating phytopathogenic fungi. It is already known that 1- (2-chlorophenyl) -2- (1chloro-cyclopropyl-1-yl) -3- (1,3,4-triazol-1-yl) -propan-2-ol has properties fungicides (see EP-OS O 297 345) The activity of this substance is good; however, it is unsatisfactory in a number of cases when used in small amounts. It is furthermore already known that many

  azole derivatives derived from aromatic carboxylic acids

  Morpholine compounds and other heterocyclic compounds can be used to control fungi (see KH Bchel "Pflanzenschutz und Schddlingingsmpfung", pages 87, 136, 140, 141 and 146-153, Georg Thieme Verlag, Stuttgart 1977). action of the substances in question is not always satisfactory when using these substances

in small quantities.

  The Claimant has just found that the

  new companies of active substances including

  1- (2-chlorophenyl) -2- (1-chlorocycloprop-1-yl) -

  3- (1,3,4-Triazol-1-yl) -propan-2-ol of the Formula C 1 OH CH 2 C V Ci

CH 2 (1

N and

  (A) 1- (4-chlorophenyl) -4,4-dimethyl-3 (1,2,4-

  triazoleyl-2-yl) pentan-3-ol of the formula triazol-1-yl-triethylpentan-3-ol of the formula OH C II CH 2 CH 2 C C (CH 3) 3 CH 2 I (II)

(Tebuconazole)

an azole derivative of formula

X O CH Y -C (CH 3) 3

N (Ii) ((H Ia) X = Cl; Y = -CH (OH) -

(TRIADIMENOL)

  (H Ib) X =; Y = = -CH (OH) (BITERTANOL) Y II (II Ic) X = C 1; Y = -C (TRIADIMEFON) and / or (C) tetrachlorisophthalodinitrile of formula CN C 1 "CN C 1 (IV)

(CHLOROTHALONIL)

and / or (D)

  benzimidazole-2-methyl acid ester

carbamic acid of formula and / or (B)

  \ NH COOCH 3

H V)

(Carbendazim)

  tetramethylthiuram disulfide of the formula

S S

He he

(CH 3) 2 N-C-S S-C-N (CH 3) 2

(THIRAM)

and / or (F)

  6-methyl-2-oxo-1,3-dithiolol 4,5 bl-quinoline

  xaline of formula (VII) (Q Ui NOMETHIONATE) and / or (G) the triazine derivative of formula CI N-AN C1 C 1 YN Zk NIH It and / or (H) (VII (ANLAZ It) 3-cyano -4- (2-fluoro-3-chlorophenyl) -pyrrole of formula and / or (E) (VI) H 3 CS S S Cl F (IX) Piperidine derivative of formula

C N -CH 2CH CH 2} C (CH 3) 3

CH 3 a and / or (K) (x)

ENPROPIDINE)

  a morpholine derivative of formula CH 3

Y N C 13 H 27

CH 3 (X Ia)

RIDEMORPHE)

CH 3

O N CH 2 CH CH 2 E, C (CH 3) 3

CH 3 CH 3 (FENP

  CH 3 O N-Cm 2 H 25 n y-J CH 3 (X Ib)

ROPEMORPRE)

CH 3 + O N-C 12H 25-n CH 3 (X Ic)

(ALDIMORPHF,)

  and / or (I) or and / or (L) triphenyltin acetate of formula (EO) Sn-OCO CH 3 (XII)

(Fentin acetate)

  have very good fungicidal properties.

  It is surprising to note that the fungicidal action of the combinations of active substances according to the invention is considerably greater than the sum of the actions of the individual active substances. This is therefore a truly unpredictable synergistic effect and

  These are not actions that complement each other.

  It follows from the structural formula of the active substance of formula (I) that the compound has an asymmetrically substituted carbon atom. The product can therefore exist in the form of a mixture of various isomers or also in the form of an individual component. substance

  active ingredient of formula (I) is known (see EP

OS O 297,345).

  The fungicidal active substances additionally present in the combinations according to the invention are also known. The active substances are described in particular in the following publications:

(A): EP-OS 0 040 345;

  (B): DE-OS 2,324,010 and DE-OS-2,201,063;

  (C): K H B chel "Pflanzenschutz und Schâd-

  lingsbekâmpfung ", p. 146, Georg Thieme Verlag, Stuttgart 1977; (D): U.S. Patent No. 3,010,968; (E): KHB chel, loc. cit., p. 136; (F): KHB chel, loc cit, page 87; (G): KHB chel, loc cit, page 153;

(H): DE-OS 3,737,984;

(I): DE-OS 2,752,135;

  (K): KH B chel, loc cit, page 149 and patent of the Democratic Republic of Germany No. 140 412, and

(L): Angew Chem 70, 135 (1958).

  The combinations of active substances according to the invention contain, in addition to the active substance of formula (I), at least one active substance chosen from the compounds of groups (A) to (L).

  in addition to other components endowed with fungicidal activity.

  When the active substances are present in the combinations of active substances according to the invention in specific weight ratios, the synergistic effect is particularly distinct. However, in a relatively large range, the

  ratios by weight of the active substances in the

  Societies of these substances In general, it is used per part by weight of active substance of formula (I)

0.02 to

0.1 to

0.02 to

0.1 to

0.02 to

0.02 to

0.02 to

0.1 to

0.02 to

  0.1 to parts by weight, preferably parts by weight of substance group (A), parts by weight, preferably parts by weight of substance group (B) parts by weight, preferably parts by weight of substance group (C) parts by weight, preferably parts by weight of substance group (D) parts by weight, preferably parts by weight of substance active group (E) of the active of the active of the active of the active

0.02 to

0.1 to

0.02 to

1 to

0.02 to

0.1 to

0.02 to

0.1 to

0.02 to

0.1 to

0.02 to

  0.1 to parts by weight, preferably parts by weight of active substance of group (F) parts by weight, preferably parts by weight of active substance of group (G) parts by weight, preferably parts by weight of active substance group (H) parts by weight, preferably parts by weight of active substance of group (I) parts by weight, preferably parts by weight of active substance of group (K) parts by weight, preferably parts by weight of substance active

group (L).

  Associations of active substances compliant

  to the invention are endowed with very good properties

  gicides and can be used for combating

  plant pathogenic fungi such as plasmodiophoromycetes, oomycetes, chytridiomycetes, zygomycetes, ascomycetes, basidiomycetes, deuteromycetes, etc .; Associations of active substances compliant

  the invention are particularly suitable for combating

  cereal diseases, such as those caused by Erysiphe, Cochliobolus, Pyrenophora, Leptosphaeria,

Fusarium and Pseudocercosporella.

  The good compatibility of combinations of active substances with plants at the concentrations necessary to combat plant diseases allows the treatment of aerial parts of plants, plants and plants.

seed and soil.

  The combinations of active substances according to the invention can be incorporated into conventional formulations such as solutions, emulsions, suspensions,

  powders, foams, pastes, granules, aerosols, very fine encapsulations in polymers and in seed coating materials, as well as very low volume formulations.

  These formulations are prepared in a known manner, for example by mixing the active substances or combinations of active substances with diluents, i.e. liquid solvents, pressurized liquefied gases and / or solid carriers. , optionally using surfactants, i.e. emulsifiers and / or dispersing agents and / or foam producing agents. In the case of the use of water as a diluent, it is possible, for example Organic solvents as auxiliary solvents are also used. Liquid solvents are mainly: aromatic hydrocarbons such as xylene, toluene or alkylnaphthalenes, chlorinated aromatic hydrocarbons or chlorinated aliphatic hydrocarbons such as chlorobenzenes, chloroethylenes or methylene, aliphatic hydrocarbons such as cyclohexane or paraffins, for example petroleum fractions, alcohols such as butanol or glycol and their ethers and esters, ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents such as dimethylformamide and dimethylsulfoxide, as well as water. or liquefied gaseous supports of liquids which are gaseous at normal temperature and under normal pressure, for example aerosol propellants such as butane, propane, nitrogen and carbon dioxide.

  solid supports: for example natural mineral powders

  such as kaolins, aluminas, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth, and synthetic mineral powders such as silicic acid, aluminum oxide and highly dispersed silicates Solid supports for granular materials include: crushed and fractionated natural rocks such as calcite, marble, pumice, sepiolite, dolomite, as well as synthetic granules of inorganic and organic powders, and granules of an organic material such as sawdust, coconut husks, maize cobs and tobacco stems. Emulsifiers and / or foam-producing agents include: for example non-ionogenic emulsifiers and anions such as polyoxyethylene esters of fatty acids, polyoxyethylene ethers of fatty alcohols, for example alkylarylpolyglycol ethers, alkylsulfonates, alkyls; sulfates, arylsulfonates and albumin hydrolysates. As dispersants,

  consider, for example, lignin-containing waste liquors

and methylcellulose.

  Adhesives such as carboxymethylcellulose, natural and synthetic polymers in the form of powders, granules or latices, such as gum arabic, a vinyl alcohol polymer, a vinyl acetate polymer, can be used in the formulations. as well as natural phospholipids such as cephalins and lecithins, and synthetic phospholipids.

  additives can be mineral and vegetable oils.

  Dyes such as inorganic pigments, for example iron oxide, titanium oxide, Prussian blue, and organic dyes such as alizarin dyes, azo dyes and the like can be used. metal derivatives of phthalocyanines, and trace nutrients such as salts

  iron, manganese, boron, copper, cobalt, molybdenum and zinc.

  Formulations usually contain between

  0.1 and 95 percent by weight of active substance, preferably

between 0.5 and 90%.

  The combinations of active substances according to the invention may be present in the formulations in admixture with other known active substances such as fungicides, insecticides, acaricides and herbicides, and in admixture with fertilizers or regulators. plant growth. Associations of active substances can

  to be used as such, in the form of their

  mixtures or in the forms of application prepared from them, such as solutions, emulsifiable concentrates, emulsions, suspensions, sprayable powders, soluble powders and ready-to-use granules. The application is carried out in a conventional manner, for example by watering,

  spraying, sprinkling, spreading, painting, disinfecting

  drying, wet disinfection, disinfection with

  immersion, disinfection in suspension or incrustation.

  For the treatment of parts of plants, one can

  vary within a fairly wide range of

  concentrations of active substances in the forms of application

  They are generally between 1 and 0.0001% in

  weight, preferably between 0.5 and 0.001%.

  For seed treatment, it is generally necessary

  use amounts of active substance of 0.001 to

  50 g per kilogram of seed, preferably 0.01 to 10 g.

  For the treatment of the soil, concentrations of active substances from 0.00001 to 0.1% by weight, preferably from 0.0001 to 0.02% by weight are required at the site of action. The good fungicidal activity of the combinations of active compounds according to the invention is apparent from the

  following examples While the active substances in-

  have weaknesses in their fungicidal action, the associations are deploying an action which

  goes beyond the simple sum of actions.

  A synergistic effect always exists, in the case of fungicides, when the fungicidal action of the active substance combinations is greater than the sum of the actions of the active substances applied individually.5 Example 1 Erysiphe test (barley) / protective action To obtain suitable preparation of active substances, commercially available active compound formulations are diluted to each desired concentration, with

the water.

  To test the protective activity, the young plants are treated by spraying with the preparation of active substances, until a dew is formed. After drying the sprayed layer, the seedlings are powdered.

  spores of Erysiphe graminis f sp hordei.

  Plants are placed in a greenhouse at a temperature of about 200 ° C and a relative atmospheric humidity of about 80% to promote development.

pustules of plants.

  7 days after inoculation, the evaluation

  ation. Active substances, their concentrations and

  the results of the tests are shown in the following tables.

Table Ia

  Erysiphe test (barley) / protective action Active substance Concentration of active substance in spray liquor, ppm Known:

C 1 OH

CH 2C CI

I CH 2

(I) N

  N CH 3 O N-C 13 H 27 n CH 3 (X Ia) 0.5 0.5

Degree of activity

  as a% of the untreated control According to the invention:

(I) 1

+ J (1: 1)

(Xia) 0.25 0.2 g

Table lb

  Erysiphe test (barley) / protective action Active substance Concentration of active substance in spray liquor, ppm

Degree of activity

  as a% of the untreated control Known:

C 1 OH

  CH 2-C Ci CH 2 1 (I) CH 3 0 N-C 12 H 25 n CH 3 CH 3 O N C 12 H 25 n CH 3 (X Ic) According to the invention: () (X Ic)

(1: 1)

0.125} 0.125 0.0625 l + t 25100

0.0625 "

Example 2

  Erysiphe (wheat) test / curative action In order to obtain a suitable preparation of active substance, commercially active substance formulations are diluted with water at each desired concentration.

  To test the healing activity, seedlings are sprinkled with spores of Erysiphe graminis fsp tritici.

  48 hours after inoculation, the plants are treated by spraying with the preparation of active substances

until a dew is formed.

  Plants are placed in a greenhouse at a temperature of about 200 C and at atmospheric humidity

  about 80% to promote the development of white pustules.

  7 days after inoculation, the evaluation

  ation. Active substances, their concentrations and

  the results of the tests are shown in the following tables.

Table 2 a

  Erysiphe (wheat) test / curative action Active substance Concentration of active substance in spray liquor, ppm

Degree of activity

  %, as a% of the untreated control Known as: ## STR1 ## ## STR2 ## ## STR1 ## 27 n CH 3 (X Ma) Table 2 a (continued) Erysiphe (wheat) test / curative action Active substance Concentration of active substance in spray liquor, ppm

Degree of activity

  As a% of the untreated control According to the invention: (Ia)} (1 :) + Ia J (1: 1) (I)

}) (1: 1)

(X Ia) Z: S 0.5} 0.5

Table 2b

  Erysiphe (wheat) test / healing action

  Active substance Concentration in Activity Level

  active substance in%, in the non-sprayable control liquor, ppm treated: C H OH CH 2 C ci 0.5 88 CH 2

(I) N '

NNN N CH 3 O N-C 12 H 25 n y-J CH 3

+ 0.5 88

  CH 3 O N-C 12 H 25 n CH 3 (X 1 C) OH C 1 L o O CH CH (CH 3) 3 -> I

N, 1 N 0.5 79

  (I Ia) Table 2b (contd) Erysiphe (wheat) test / curative action Active substance Concentration of active substance in pulverulent liquor, ppm

Degree of activity

  %, as a% of the untreated control In accordance with the invention X (ic)} (1: 1) (IIa) (IIa)} (1 1) 0.25 + 0.2 Y 0.25 0.25

Example 3

  Test Cochliobolus sativus-Test (barley) / protective action To obtain a suitable preparation of active substance, formulations of active substance are diluted with water to each desired concentration. To test the protective activity, seedlings are sprayed with the active compound preparation until dew occurs. After drying the spray coat, the plants are sprayed with a conidia suspension of Cochliobolus sativus On the plants are kept for 48 hours at 200 ° C with humidity

  100% relative atmospheric in an incubator.

  Plants are placed in a greenhouse at a temperature of about 20 C and at atmospheric humidity

about 80%.

  7 days after inoculation, the evaluation

  ation. Active substances, their concentrations and

  the results of the tests are shown in the following table.

Table 3

  Test on Cochliobolus sativus (barley) / protective action

  Active substance Concentration in Activity Level

  active substance in% of in the non-sprayable reference liquor, ppm treated: CH 2 CH 2 C Ci

CH 2 6.25 88

  N, N CH 3 CH / e 6.25 25 0 N-C 13 H 27 n / CH 3 (X Ia) Cl Cl

NH / N 6.25 25

  (VI Ii) C1 According to the invention:

(J) 3.125

+ 100

ta) (1: 1) 3.125 (1) i 3.125

(VII) (11 1) 3

3, + 1 00

(VI, 3.125

Example 4

  Test on Pyrenophora teres (barley) / protective action To obtain a suitable preparation of active substance, commercial formulations of active substance are diluted with water to each desired concentration. To test the protective activity, young plants are sprayed with the preparation of

  active substance until formation of dew After drying of the sprayed layer, the plants are sprinkled with

  The conidia of Pyrenophora teres were maintained for 48 hours at 20 ° C and 100% relative humidity in an incubator. The plants were placed in a greenhouse at a temperature of about 200 ° C. C and atmospheric humidity

about 80%.

  7 days after inoculation, the evaluation

  ation. Active substances, their concentrations and

  the results of the tests are shown in the following table.

Table 4 a

  Test on Pyrenophora teres (barley) / protective action Active substance Concentration of active substance in spray liquor, ppm

Degree of activity

  as a% of the untreated control Known: ci OH

CH 2C C 1

I CH 2) N Ci F CN (IX)

CN S'C

(VII) According to the invention:

(IX) 1 (1: 1)

  (IX) (Iv) (1: 1) 12.5 12.5 12.5} I I 12.5 + 12.5

Table 4b

  Test on Pyrenophora teres (barley) / protective action Active substance Concentration of active substance in spray liquor, ppm

Degree of activity

  as a% of the untreated control Known:

OH

CH 2 C SZ CI

I CH 2 N 3.125 (I)

CH 3 3.125

O N CH 2CH CH 23 C (CH 3) 3

* CH 3 CH 3

(X Ib)

CH 3 CH 3

  O N-C 12 H 25 N O N-C 12 H 25 n CH 3 (X Ic) CH 3 CN CI (rv) 3,125 3,125 CN Cl OH

C_O C CH CH C (CH 3) 3 3.125

  N N (Ila) N U Table 4b (cont.) Test on Pyrenophora teres (barley) / protective action Active substance Concentration of active substance in spray liquor, ppm

Degree of activity

  %, as a% of the untreated control Known as: ## STR5 ## CH 2 C (CH 3) 3 CH 2 3,125 (II)

N, 3.125

C g NH COOCH 3 3.125

H V)

N-CH CH CH 2-5 C (CH 3) 3

CH 3 3.125-

(X)

S S

He He

(CH 3) 2 N-C-S S-C N (CH 3) 2 3.125

  (VI) o N N N 11 Table 4b (cont'd) Test on Pyrenophora teres (barley) / protective action Active substance Concentration of active substance in spray liquor, ppm

Degree of activity

  As a% of the untreated control According to the invention: (1 X 1b) (I) (X 1b) J (1: 1)

1.5625

+ 100

1,5625 -

1.5625

+}

1.5625}

1.5625}

1.5625

1.5625

1.5625

1.5625

+ 100

1.5625 J

1.5625

1.5625

1.5625}

+ 100

1.5625

1.5625

1.5625}

1.5625

I (1: 1)

} (1: 1)

I (1: 1)

  (I) + (X Ic) (I) + (IV) (I) + (I Ia) + (n) (i) + (W) (I) + () (X) (I) + VI) ( VI)

I (1: 1)

} (1: 1)

} (1: 1)

} (1: 1)

Example 5

  Test on Leptosphaeria nodorum (wheat) / protective action To obtain a suitable preparation of active substance, commercial formulations of active substance are diluted with water to each desired concentration. To test for protective activity, seedlings are sprayed with the active compound preparation until dew occurs. After drying the spray coat, the plants are sprayed with spore suspension of Leptosphaeria nodorum On keeps the plants for 48 hours at 20 C and humidity

  100% relative atmospheric in an incubator.

  Plants are placed in a greenhouse at a temperature of about 200 C and at atmospheric humidity

about 80%.

  days after inoculation, the evaluation is performed. Active substances, their concentrations and

  the results of the tests are shown in the following table.

Table 5

  Test on Leptosphaeria nodorum (wheat) / protective action Active substance Concentration of active substance in spray liquor, ppm

Degree of activity

  as a% of the untreated control Known:

C 1 OH

CH 2-C C CI

(I) 3.125 I CH 2 INEN $. CH 3

O N-CH 2 CH-CH 2 C (CH 3) 3

CH 3 CH 3 3.1

(X Ib)

CH 3 CH 3

  ## STR2 ##

C _ O C CH C (CH 3) 3 3.125

  N N o Y o o o Table 5 (continued) Test on Leptosphaeria nodorum (wheat) / protective action Active substance Concentration of active substance in spray liquor, ppm

Degree of activity

  %, as a% of the untreated control Known: CN-C Hf CH CH 2 C (CH 3) 3 H CH 3 3, IV * CH 3 3 1 According to the invention:

1.5625

1.5625}

1.5625

1,5625 1

1.5625

1.5625 J

1.5625 I

1.5625

+ 100

1.5625

1.5625

+} 100

1.5625 J

  (I) + (X Ib) (I) + (X Ic) (I) + (IV) (I) + (II Ia) (I) + (X)

} (1: 1)

} (1 1)

} (1: 1)

} (1: 1)

(1: 1)

vki

Claims (4)

  1 Fungicidal compositions, characterized by a content of a combination of active substances consisting of   1- (2-chlorophenyl) -2- (1-chloro-cycloprop-1-yl) -3- (1,2,4-   triazol-1-yl) -propan-2-ol of formula C 1 OH CH 2-C CI C CH 2 N (I)   1- (4-chlorophenyl) -4,4-dimethyl-3- (1,2,4-   triazol-1-ylmethyl pentan-3-ol of the formula ## STR1 ## wherein (Tebuconazole)   and / or (B) an azole derivative of formula X-CH-Y-C (CH 3) 3   N, N 11 (II Ila) X = Cl; Y = -CH (OH) (TRIADIMENOL (IIb) X =; Y = - CH (OH) (BITERTANOL) (II Ic) X = C; Y = -C (RIADIMEFON (h I) X = C; Y = C (TRIADIMEFON and (A) (III)) w 5 i) tetrachlorisophthalodinitrile of formula (IV) (CHLOROTHALONIL) CN C 1 and / or (D)   benzimidazole-2-carboxylic acid methyl ester   bicarbonate of the formula (III) (III) (III) (III) (V) (CARBENDAZI Mr,) of tetramethylthiuram disulfide of formula S II (CH 3) 2 N C S - S He S C N (CH 3) 2 (VI) (THRAME) and or   (F) 6-methyl-2-oxo-1,3-dithiolol 4,5 bl-which-   noxalin of formula I NS (VII) (Qu INOMETHIONATE) and / or (C) CN and / or (E) and / or (G) of the triazine derivative of formula Ci NIIN ci C 1 Nk (VIII) (ANILAZINE) and or (H) 3-cyano-4- (2-fluoro-3-chlorophenyl) -pyrrole of the formula Cl F CN ii N (IX) NH and / or (I) of the piperidine derivative of the formula LO CN-CH 27 CH CH 2 C (CH 3) 3 CH 3 (FENPROPIDINE)   and / or (K) of a morpholine derivative of formula CH 3 O N-C 13 H 27 (X Ia) (TRIDEMORPI *)   CH 3 CH 3 O N CH 2 CH CH 2 C (CH 3) 3 (X Ib) CH 3 CH 3 (FENPROPEMORPH) or CH 3 CH 3   Y N C 12 H 2 N + O N C 12 H 2 N (X Ic) CH 3 CH 3   (ALDIMORPH) and / or (L) triphenyltin acetate of formula 3 to 50) Sn-O -COCH 3 (XII) (Fentin acetate)   Compositions according to Claim 1, characterized in that in the combinations of active substances the ratio by weight of the active substance of the formula (I) to the active substance of the group (A) is between 1: 0.02 and 1:50, to the active substance in group (B) is between 1: 0.02 and 1:50, the active substance in group (C) is between 1: 0.02 and 1:50, at the active substance in the group (D) is between 1: 0.02 and 1:50, the active substance in the group (E) is between 1: 0.02 and 1:50, and the active substance in the group (F ) is between 1: 0.02 and 1:50, the active substance in group (G) is between 1: 0.02 and 1:50, the active substance in group (H) is between 1: 0.02 and 1:50, the active substance in group (I) is between 1: 0.02 and 1:50, the active substance in group (K) is between 1: 0.02 and 1: 50, the active substance in group (L) is between 1: 0.02 and 1:50.   Process for combating fungi, characterized in that associations of   active substance according to claim 1 on the and / or on their environment.   Use of combinations of active substances according to claim 1 for combating fungi. Process for the preparation of fungicidal compositions, characterized in that the combinations of active compounds according to Claim 1 are mixed with   diluents and / or surfactants.