FR2630353A1 - Antigraffiti coating system - Google Patents

Antigraffiti coating system Download PDF

Info

Publication number
FR2630353A1
FR2630353A1 FR8805836A FR8805836A FR2630353A1 FR 2630353 A1 FR2630353 A1 FR 2630353A1 FR 8805836 A FR8805836 A FR 8805836A FR 8805836 A FR8805836 A FR 8805836A FR 2630353 A1 FR2630353 A1 FR 2630353A1
Authority
FR
France
Prior art keywords
parts
acrylic
agent
coating
additive
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR8805836A
Other languages
French (fr)
Other versions
FR2630353B1 (en
Inventor
Georges Turzan
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jival SA Peintures
Original Assignee
Jival SA Peintures
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jival SA Peintures filed Critical Jival SA Peintures
Priority to FR8805836A priority Critical patent/FR2630353B1/en
Publication of FR2630353A1 publication Critical patent/FR2630353A1/en
Application granted granted Critical
Publication of FR2630353B1 publication Critical patent/FR2630353B1/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00—Processes for applying liquids or other fluent materials
    • B05D1/32—Processes for applying liquids or other fluent materials using means for protecting parts of a surface not to be coated, e.g. using stencils, resists
    • B05D1/322—Removable films used as masks
    • B05D1/327—Masking layer made of washable film
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/50—Multilayers
    • B05D7/52—Two layers
    • B05D7/53—Base coat plus clear coat type

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

A pair, called system, of coating agents, the nature of these two agents being such that the two coatings adhere sufficiently to each other to stand up to inclement weather, but also such that the second agent acts as diluent for the surface layer previously formed by it itself, with the result that it finally forms a regenerating cleaning agent for the coating. It is characterised in that the said system comprises two agents: the actual coating agent and the regenerating cleaning agent, the former consisting of two compounds, one called a base, the other called an antigraffiti additive, the base being either hydroxylated acrylic resins and their isocyanate hardener, or acrylic copolymer resins in solution in aromatic and ketonic solvents, while the antigraffiti additive is a composition incorporating at least one of the following components: polyethylene wax, silicone oil, a mixture of polyurethane, an acrylic solution, and finally the cleaning agent is a mixture of polyethylene wax and of a polar synthetic oil of high molecular weight. Application: painting of walls, with antigraffiti protection, protection of stone monuments and buildings.

Description

La présente invention est du domaine de la chimie appliquée et elle a plus précisément pour objet un système de peinture, ou revêtement, antigraffiti. The present invention is in the field of applied chemistry and more specifically relates to an anti-graffiti paint or coating system.

On connatt des revêtementsanti- graffiti qui sont en substance des peintures contenant de la cire polyéthyle'ne, cette dernière conférant au revêtement un caractère hydrophobe élevé ; le caractère hydrophobe interdit la pénétration profonde des encres aqueuses ou en solution dans des solvants polaires. Anti-graffiti coatings are known which are, in essence, paints containing polyethylene wax, the latter giving the coating a high hydrophobic character; the hydrophobic character prohibits the deep penetration of aqueous inks or in solution in polar solvents.

Cependant, on a pu observer qu'avec la plupart des revêtements antigraffiti disponibles actuellement dans le commerce, et bien que ceux-ci rendent délébiles les inscriptions ou salissures portées sur leur surface, il subsiste de ces inscriptions certaines traces indélébiles, celles-ci étant dues à la présence dans les encres de corps chimiques colorés de nature lyophile (hydrophobe) qui, en petite quantité,, arrivent à se dissoudre dans le revêtement et en particulier dans son constituant polyéthylène. However, it has been observed that with most of the anti-graffiti coatings currently available on the market, and although these make the markings or soiling on their surface debilitated, there remain certain indelible marks from these inscriptions, these being due to the presence in inks of colored chemical bodies of a lyophilic (hydrophobic) nature which, in small quantities, manage to dissolve in the coating and in particular in its polyethylene component.

L'idée mère de la présente invention consiste à proposer non plus un revêtement unique mais un couple d'agents de revêtements, dit pour cette raison système, dont l'un est un revêtement proprement dit et dont l'autre est une couche ou pellicule superficielle recouvrant le premier, la nature de ces deux agents étant telle que ces deux revêtements adhèrent suffisamment l'un à l'autre pour résister aux intempéries, mais telle aussi que le second agent serve de diluant de la couche superficielle constituée antérieurement par lui-même, de telle sorte que finalement il constitue pour le revêtement un agent de nettoyage regél,Srant.  The main idea of the present invention consists in no longer proposing a single coating but a couple of coating agents, called for this reason a system, one of which is a coating proper and the other of which is a layer or film. surface covering the first, the nature of these two agents being such that these two coatings adhere sufficiently to each other to resist weathering, but also such that the second agent serves as a diluent for the surface layer previously formed by it- even, so that ultimately it constitutes for the coating a frozen cleaning agent, Srant.

Grâce à un tel système de revêtement, dont la règle technique qui va être donnée dans la suite de la description constitue la présente invention, les marquages, inscriptions ou autres graffiti ou autres salissures n'affectent que la couche superficielle regénérable et sont entraînées avec elle lors d'une opération de net toyage-regé né ration.  Thanks to such a coating system, the technical rule of which will be given in the following description constitutes the present invention, the markings, inscriptions or other graffiti or other soiling affect only the regenerable surface layer and are carried along with it during a clean-up-regeneration operation.

Selon la présente invention, un système de revêtement antigraffiti comprend deux agents : un agent de revêtement proprement dit et un agent de nettoyage regénérant. According to the present invention, an anti-graffiti coating system comprises two agents: an actual coating agent and a regenerating cleaning agent.

L'agent de revêtement proprement dit est constitué de deux compositions, l'une dite base, l'autre dite additif antigraffiti ; la base est une composition du groupe comprenant les résines acryliques hydroxylées et leur durcisseur isocyanate d'une part, et les résines copolymères acryliques en solution dans des solvants aromatiques et cétoniques d'autre part ; l'additif antigraffiti est une composition incorporant au moins l'un des composants du groupe de composants comprenant la cire polyéthylène, l'huile de silicone, un mélange de polyuréthane, une solution acrylique. The actual coating agent consists of two compositions, one called base, the other called anti-graffiti additive; the base is a composition of the group comprising hydroxylated acrylic resins and their isocyanate hardener on the one hand, and acrylic copolymer resins in solution in aromatic and ketone solvents on the other hand; the anti-graffiti additive is a composition incorporating at least one of the components from the group of components comprising polyethylene wax, silicone oil, a mixture of polyurethane, an acrylic solution.

L'agent de nettoyage est un mélange de cire polyéthylène et d'une huile synthétique polaire à haut poids moléculaire. The cleaning agent is a mixture of polyethylene wax and a high molecular weight polar synthetic oil.

La règle technique générale ci-dessus formulée peut être appliquée selon deux types généraux de revêtements, à savoir les revêtements bi-composants et les revêtements mono-composant, types qui sont d'une manière générale connus en eux-mêmes ; on rappelle queles premiers sont utilisés après mélange extemporané d'un premier composant (résine) et d'un durcisseur, et que les seconds durcissent soit par évaporation d'un solvant, soit par action de l'oxygène de l'air soit par les deux phénomènes à la foisx
On donnera plus loin deux exempleSde systèmes de revêtement conformes à l'invention du type bi-composant ; ainsi'et suivant que l'on souhaite disposer d'une peinture (coloration opaque) ou d'un vernis (transparence), la résine sera pigmentée de manière à constituer une peinture pour le premier exemple, ou elle sera non pigmentée de manière à constituer un vernis pour le second exemple. The general technical rule formulated above can be applied according to two general types of coatings, namely two-component coatings and one-component coatings, types which are generally known in themselves; it is recalled that the former are used after extemporaneous mixing of a first component (resin) and a hardener, and that the latter harden either by evaporation of a solvent, or by the action of oxygen in the air or by two phenomena at once x
Two examples of coating systems according to the invention of the two-component type will be given below; Thus, depending on whether one wishes to have a paint (opaque coloring) or a varnish (transparency), the resin will be pigmented so as to constitute a paint for the first example, or it will be non-pigmented so as to constitute a varnish for the second example.

L'invention. sera mieux comprise à la description de trois exemples qui va être faite en relation avec les figures de la planche annexée, dans laquelle
- la fig.1 illustre schématiquement un premier exemple de système de revêtement antigraffiti relevant de l'invention,
- la fig.2 en illustre un deuxième exemple, et
- la fig.3 un troisième.The invention. will be better understood from the description of three examples which will be made in relation to the figures in the appended plate, in which
FIG. 1 schematically illustrates a first example of an anti-graffiti coating system relating to the invention,
- fig.2 illustrates a second example, and
- fig.3 a third.

Premier exemple (fig.1)
L'agent de revêtement proprement dit est constitué d'une base et d'un additif ; la base est constituée - d'une peinture acrylique hydroxylée : 100 parties (A) - d'un durcisseur isocyanate : 25 parties (B)
Ces deux composants sont conditionnés dans des conditionnements distincts.First example (fig. 1)
The actual coating agent consists of a base and an additive; the base consists of - a hydroxylated acrylic paint: 100 parts (A) - an isocyanate hardener: 25 parts (B)
These two components are packaged in separate packages.

L'additif antigraffiti est constitué - d'un mélange de laque polyuréthane : 100 parties (C) - de cire polyéthylène : 0,2 à 20 parties (D) - d'huile de silicone : 0,2 à 20 parties (E)
L'additif antigraffiti, ainsi que cela apparat sur la figure est mélangé à la peinture acrylique.The anti-graffiti additive consists - of a mixture of polyurethane lacquer: 100 parts (C) - of polyethylene wax: 0.2 to 20 parts (D) - of silicone oil: 0.2 to 20 parts (E)
The anti-graffiti additive, as it appears in the figure, is mixed with acrylic paint.

Toujours sur la fiv.1, un troi sieme conditionnement livré avec les deux conditionnements précédents, mais qui peut être aussi bien livré séparément, contient l'agent de nettoyage comprenant un mélange de cire polyéthylène (0,2 à 20 parties) (F) et une huile synthétique polaire de haut poids moléculaire (0,2 à 20 parties) (G). Still on fiv. 1, a third packaging delivered with the two previous packaging, but which can also be delivered separately, contains the cleaning agent comprising a mixture of polyethylene wax (0.2 to 20 parts) (F) and a high molecular weight polar synthetic oil (0.2 to 20 parts) (G).

L'indication d'une peinture acrylique dans la composition de base signifie qu'au moins un pigment coloré est incorporé dans cette dernière
Deuxième exemple (fig.2)
L'agent de revêtement proprement dit est constitué d'une base et d'un additif ; la base est constituée - d'un vernis acrylique : 100 parties (H) - d'un durcisseur isocyanate : 25 parties (B)
Ces deux composants sont conditionnés dans des conditionnements distincts.The indication of an acrylic paint in the base composition means that at least one colored pigment is incorporated in the latter
Second example (fig. 2)
The actual coating agent consists of a base and an additive; the base consists of - an acrylic varnish: 100 parts (H) - an isocyanate hardener: 25 parts (B)
These two components are packaged in separate packages.

L'additif antigraffiti est constitué - d'un mélange de laque polyuréthane : 100 parties (C) - de cire polyéthylène : 0,2 à 20 parties (D) - d'huile de silicone : 0,2 à 20 parties (E)
L'additif antigraffiti, ainsi que cela apparat sur la figure est mélangé à la peinture acrylique.The anti-graffiti additive consists - of a mixture of polyurethane lacquer: 100 parts (C) - of polyethylene wax: 0.2 to 20 parts (D) - of silicone oil: 0.2 to 20 parts (E)
The anti-graffiti additive, as it appears in the figure, is mixed with acrylic paint.

Toujours sur la fig.2, un troisième conditionnement livré avec les deux conditionnements précédents, mais qui peut être aussi bien livré séparément, contient l'agent de nettoyage comprenant un mélange de cire polyéthylène (0,2 à 20 parties)(F) et une huile synthétique polaire de haut poids moléculaire (0,2 à 20 parties)(G). Still in fig. 2, a third package delivered with the two previous packages, but which can also be delivered separately, contains the cleaning agent comprising a mixture of polyethylene wax (0.2 to 20 parts) (F) and a high molecular weight polar synthetic oil (0.2 to 20 parts) (G).

Lt indication d'un vernis dans la composition de base signifie qu' aucun pigment coloré nest
incorporé dans cette dernière.The indication of a varnish in the basic composition means that no colored pigment is
incorporated into it.

Troisième exemple (fig.3.)
La base est une résine copolymè- re acrylique en solution dans des solvants aromatiques et cétoniques (iOO) parties (M).Third example (fig. 3)
The base is an acrylic copolymer resin in solution in aromatic and ketone solvents (100 parts).

L'additif antigraffiti comprend - une solution acrylique : 100 parties -, (J) - de la cire polyéthylène : 0,2 à 20 parties * (K) - de l'huile silicone : 0,2 à 20 parties (L)
L'additif antigraffiti, ainsi que cela apparaît sur la figure est mélangé à la peinture acrylique.The anti-graffiti additive includes - an acrylic solution: 100 parts -, (J) - polyethylene wax: 0.2 to 20 parts * (K) - silicone oil: 0.2 to 20 parts (L)
The anti-graffiti additive, as it appears in the figure, is mixed with acrylic paint.

Toujours sur la fig.3 un deuxième conditionnement livré avec le conditionnement précédent, mais qui peut être aussi bien livré séparément, contient l'agent de nettoyage comprenant un mélange de cire polyéthylène (0,2 à 20 parties) (F) et une huile synthétique polaire de haut poids moléculaire (0,2 à 20 parties)(G). Still on fig. 3 a second package delivered with the previous package, but which can also be delivered separately, contains the cleaning agent comprising a mixture of polyethylene wax (0.2 to 20 parts) (F) and an oil high molecular weight synthetic polar (0.2 to 20 parts) (G).

Le système de ce troisième exemple est du type vernis et il est plus particulièrement destiné à constituer un enduit pour de la pierre nue de bâtiment ou de monument exemple, en raison du fait qu'il évite les reflets. The system of this third example is of the varnish type and it is more particularly intended to constitute a coating for bare stone of a building or of a monument example, due to the fact that it avoids reflections.

Un système de revêtement tel que celui du premier exemple est destiné à la mise en peinture de murs, avec protection antigraffiti ; un système de revêtement tel que celui du deuxième exemple est destiné à traiter les supports avec un aspect incolore et transparent, avec la même protection antigraffiti que le système précédent ; un système de revêtement tel que celui du troisième exemple, incolore et transparent, est destiné à protéger les pierres des monuments et bâtiments sans changer l'aspect des pierres.  A coating system such as that of the first example is intended for painting walls, with anti-graffiti protection; a coating system such as that of the second example is intended to treat the supports with a colorless and transparent appearance, with the same anti-graffiti protection as the previous system; a coating system such as that of the third example, colorless and transparent, is intended to protect the stones of monuments and buildings without changing the appearance of the stones.

Claims (1)

REVENDICATIONS 1.- Système de revêtement "antigraffiti", caractérisé1.- "anti-graffiti" coating system, characterized en ce que ledit système de revê in that said dream system tement comprend deux agents : l'agent de revêtement pro two agents: the pro coating agent prement dit et l'agent de nettoyage regénérant, prement said and the regenerating cleaning agent, - l'agent de revêtement proprement dit étant constitué - the coating agent proper being constituted de deux compositions, l'une dite base, l'autre dite of two compositions, one called base, the other called additif antigrafitti, antigrafitti additive, la base étant une composition the base being a composition du groupe comprenant les résines acryliques hydroxylées from the group comprising hydroxylated acrylic resins et leur durcisseur isocyanate d'une part, et les résines and their isocyanate hardener on the one hand, and the resins copolymères acryliques en solution dans des solvants acrylic copolymers in solution in solvents aromatiques et cétoniques, d'autre part, aromatic and ketone, on the other hand, l'additif antigraffiti étant the anti-graffiti additive being une composition incorporant au moins l'un des composants a composition incorporating at least one of the components du groupe de composants comprenant la cire polyéthylène, from the group of components comprising polyethylene wax, l'huile de silicone, un mélange de polyuréthane, une silicone oil, a mixture of polyurethane, a solution acrylique, acrylic solution, - l'agent de nettoyage est un mélange de cire polyéthy-  - the cleaning agent is a mixture of polyethylene wax- lène et d'une huile synthétique polaire à haut poids lene and a high-weight polar synthetic oil moléculaire 2.- Système de revêtement selon la revendication 1, caracté 2. Molecular coating system according to claim 1, character risé laughed en ce que, pour l'agent de revê in that for the dream agent tement proprement dit strictly speaking la base est constituée par the base consists of ,, une résine acrylique à raison ,, an acrylic resin rightly de 100 parties, un un durcisseur isocyanate à  100 parts, an isocyanate hardener to raison de 25 parties, due to 25 games, ces constituants étant condi these constituents being condi tionnés de façon séparée, tandis que separately treated, while l'additif est constitué par un un mélange de laque polyuré-  the additive consists of a mixture of polyurea lacquer thane à raison de 100 parties, thane at the rate of 100 parts, .. de la cire polyéthylène à .. from polyethylene wax to raison de 0,2 à 20 parties, from 0.2 to 20 parts, .. de l'huile de silicone à .. silicone oil to raison de 0,2 à 20 parties 3.- Système de revêtement selon la revendication 2, caracté from 0.2 to 20 parts 3.- coating system according to claim 2, character risé laughed en ce que ladite résine est in that said resin is pigmentée de manière à constituer une peinture 4.- Système de revêtement selon la revendication 2, caracté pigmented so as to constitute a paint 4. Coating system according to claim 2, character risé laughed en ce que ladite résine est non in that said resin is not pigmentée de manière à constituer un vernis 5.- Système de revêtement selon la revendication 1, caracté pigmented so as to constitute a varnish 5.- coating system according to claim 1, character risé laughed en ce que pour l'agent de revê in that for the dream agent tement proprement dit strictly speaking . la base est constituée par une . the base consists of a résine copolymère acrylique en solution dans des sol acrylic copolymer resin in solution in soil vants aromatiques et cétoniques, tandis que aromatic and ketonic, while l'additif est constitué par the additive consists of ,. une solution acrylique à rai ,. spoke acrylic solution son dé 100 parties, his 100 game die, .. de la cire polyéthylène à .. from polyethylene wax to raison de 0-,2 à 20 parties, due to 0-, 2 to 20 parts, .. de l'huile de silicone à .. silicone oil to raison de 0,2 à 20 parties.  from 0.2 to 20 parts.
FR8805836A 1988-04-25 1988-04-25 ANTI-GRAFFITI COATING SYSTEM Expired - Fee Related FR2630353B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
FR8805836A FR2630353B1 (en) 1988-04-25 1988-04-25 ANTI-GRAFFITI COATING SYSTEM

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR8805836A FR2630353B1 (en) 1988-04-25 1988-04-25 ANTI-GRAFFITI COATING SYSTEM

Publications (2)

Publication Number Publication Date
FR2630353A1 true FR2630353A1 (en) 1989-10-27
FR2630353B1 FR2630353B1 (en) 1990-08-24

Family

ID=9365877

Family Applications (1)

Application Number Title Priority Date Filing Date
FR8805836A Expired - Fee Related FR2630353B1 (en) 1988-04-25 1988-04-25 ANTI-GRAFFITI COATING SYSTEM

Country Status (1)

Country Link
FR (1) FR2630353B1 (en)

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2681072A1 (en) * 1991-09-10 1993-03-12 Meynier Claude Protective varnish with nonadhesive outer surface
FR2683540A1 (en) * 1991-11-08 1993-05-14 Casco Nobel France Antigraffiti paint, its preparation and process for removing the graffiti formed on a surface covered with such a paint
FR2686615A1 (en) * 1992-01-27 1993-07-30 Pomero Vincent Process for protecting buildings from graffiti
WO1998021282A1 (en) * 1996-11-08 1998-05-22 Martin Louis Marie Joseph Anti-graffiti paint composition
GB2330781A (en) * 1997-10-31 1999-05-05 Sho Bond Corp Graffiti removing method
EP0912260A1 (en) * 1996-07-11 1999-05-06 Brandeis University Improved anti-graffiti coatings and method of graffiti removal
US5910535A (en) * 1996-05-03 1999-06-08 Decora, Incorporated Water based coating composition having sacrificial layer for stain removal
US6084020A (en) * 1994-08-16 2000-07-04 Decora, Incorporated Non-stick polymer-coated articles of manufacture, and process and coatings for the production thereof
WO2009009273A1 (en) * 2007-07-12 2009-01-15 Exopack-Technology, Llc Low-gloss anti-graffiti surface for electronic white boards
US7985472B2 (en) 2007-06-22 2011-07-26 Exopack-Technology, Llc Low-gloss dry-erase coating formulation
WO2011135149A3 (en) * 2010-04-28 2011-12-29 Repsol Ypf Lubricantes Y Especialidades, S.A. Anti -graffiti coating emulsions based on wax and oil

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107236405A (en) * 2016-12-14 2017-10-10 邹小金 A kind of aqueous PU varnish

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1052146A (en) * 1952-03-06 1954-01-21 Product for cleaning and protecting surfaces and mainly surfaces coated with varnish, paints or lacquers
FR1318034A (en) * 1961-02-13 1963-02-15 Rohm & Haas Composition for the protection of wooden or metal surfaces

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1052146A (en) * 1952-03-06 1954-01-21 Product for cleaning and protecting surfaces and mainly surfaces coated with varnish, paints or lacquers
FR1318034A (en) * 1961-02-13 1963-02-15 Rohm & Haas Composition for the protection of wooden or metal surfaces

Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2681072A1 (en) * 1991-09-10 1993-03-12 Meynier Claude Protective varnish with nonadhesive outer surface
FR2683540A1 (en) * 1991-11-08 1993-05-14 Casco Nobel France Antigraffiti paint, its preparation and process for removing the graffiti formed on a surface covered with such a paint
FR2686615A1 (en) * 1992-01-27 1993-07-30 Pomero Vincent Process for protecting buildings from graffiti
US6084020A (en) * 1994-08-16 2000-07-04 Decora, Incorporated Non-stick polymer-coated articles of manufacture, and process and coatings for the production thereof
US6120849A (en) * 1994-08-16 2000-09-19 Decora, Incorporated Process for producing coated articles of manufacture
US6153304A (en) * 1994-08-16 2000-11-28 Decora Incorporated Hydrophobic coating system for application to an inorganic, organic or metallic substrate
US5910535A (en) * 1996-05-03 1999-06-08 Decora, Incorporated Water based coating composition having sacrificial layer for stain removal
EP0912260A1 (en) * 1996-07-11 1999-05-06 Brandeis University Improved anti-graffiti coatings and method of graffiti removal
EP0912260A4 (en) * 1996-07-11 1999-08-18 Univ Brandeis Improved anti-graffiti coatings and method of graffiti removal
US6288163B1 (en) * 1996-11-08 2001-09-11 Louis-Marie Joseph Martin Anti-graffiti paint composition
WO1998021282A1 (en) * 1996-11-08 1998-05-22 Martin Louis Marie Joseph Anti-graffiti paint composition
GB2330781A (en) * 1997-10-31 1999-05-05 Sho Bond Corp Graffiti removing method
GB2330781B (en) * 1997-10-31 2002-02-27 Sho Bond Corp Graffiti removing method
US7985472B2 (en) 2007-06-22 2011-07-26 Exopack-Technology, Llc Low-gloss dry-erase coating formulation
US8426485B2 (en) 2007-06-22 2013-04-23 Exopack-Technology, Llc Low-gloss dry-erase coating formulation
WO2009009273A1 (en) * 2007-07-12 2009-01-15 Exopack-Technology, Llc Low-gloss anti-graffiti surface for electronic white boards
US9139742B2 (en) 2007-07-12 2015-09-22 Coveris Technology Llc Low-gloss anti-graffiti surface for electronic white boards
WO2011135149A3 (en) * 2010-04-28 2011-12-29 Repsol Ypf Lubricantes Y Especialidades, S.A. Anti -graffiti coating emulsions based on wax and oil

Also Published As

Publication number Publication date
FR2630353B1 (en) 1990-08-24

Similar Documents

Publication Publication Date Title
FR2630353A1 (en) Antigraffiti coating system
CA1048887A (en) Cleaning composition
DE69002263D1 (en) PRECURRENT COATING COMPOSITIONS.
US5158609A (en) Water based aerosol marking paint
AU646337B2 (en) Faux finish methods and compositions
DE60128942D1 (en) METHOD FOR PARFING A SURFACE
Uzaki et al. Carbon isotope evidence for oil-pollution in long chain normal alkanes in Tokyo Bay sediments
KR940007138A (en) Antimicrobial Epoxy Resin Composition
US4781757A (en) Coating composition
EP0263959A1 (en) Floor polish
KR20050080169A (en) Paint for easy washing contaminant
JPS57165466A (en) Coating agent
DE2102091C3 (en) Process for the production of decorative surface layers
Blázquez et al. The volatile oil of Thymus leptophyllus growing in Spain
EP1347019A1 (en) Formulations and method for coloring natural and/or artificial stones and resulting colored stones
JP2007313686A (en) Mirror finish building material
KR970074876A (en) Release Composition Based on Water and Anisole
US6800332B2 (en) Method for improving the transfer efficiency of paint
ES2123943T3 (en) TWO COMPONENT LACQUER SYSTEM.
JPS5644080A (en) Finishing coating method of water paint
CN1836015A (en) High gloss inks and preparations thereof
Turner An investigation of polymer coatings used in hydrogen maser storage bulbs
DE1220067B (en) Preparations for polishing motor vehicles, for treating leather, skis and floors
Piqueras Solsona et al. Understanding the formation of highly durable heartwood in larch by use of Synchrotron infrared imaging and multivariate resolution techniques.
JPS63273677A (en) Oily ink

Legal Events

Date Code Title Description
ST Notification of lapse