KR20050080169A - Paint for easy washing contaminant - Google Patents

Paint for easy washing contaminant Download PDF

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KR20050080169A
KR20050080169A KR1020050065883A KR20050065883A KR20050080169A KR 20050080169 A KR20050080169 A KR 20050080169A KR 1020050065883 A KR1020050065883 A KR 1020050065883A KR 20050065883 A KR20050065883 A KR 20050065883A KR 20050080169 A KR20050080169 A KR 20050080169A
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weight
solvent
resin
paint
additive
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KR1020050065883A
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Korean (ko)
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김선곤
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주식회사 신성사
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L1/00—Compositions of cellulose, modified cellulose or cellulose derivatives
    • C08L1/08—Cellulose derivatives
    • C08L1/16—Esters of inorganic acids
    • C08L1/18—Cellulose nitrate, i.e. nitrocellulose
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/04—Polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/062—Copolymers with monomers not covered by C09D133/06
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16—Antifouling paints; Underwater paints
    • C09D5/1687—Use of special additives

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

본 발명은 부착오염방지 및 수세척이 용이한 도료에 관한 것으로, 보다 상세하게는 전주, 가로등, 건물벽, 변압기 등의 각종 시설물에 도색되어 홍보물 등의 접착성 부착물이 부착되지 않도록 하고, 이에 묻은 매연이나 먼지 등을 물로써도 용이하게 세척랗 수 있도록 하기 위하여, 아크릴 수지와 이소시아네이트와 실리콘 수지가 공중합된 도료에 관한 것인다.The present invention relates to a paint that is easy to prevent adhesion contamination and washing with water, and more specifically, to various facilities such as electric poles, street lights, building walls, transformers, and the like, to prevent adhesive attachments such as promotional materials, The present invention relates to a coating material in which an acrylic resin, an isocyanate and a silicone resin are copolymerized so that soot or dust can be easily washed with water.

본 발명에 따르면, 안료와 용재 및 첨가제가 포함된 주제 배합제와; 용재와 첨가제가 포함되어, 사용시 상기의 주제 배합제와 혼합되어 사용되는 경화제 배합제로 구성된 도료에 있어서, 상기 주제 배합제는 안료 20~25중량％, 용재 29~50중량％, 첨가제 1~5중량％에 아크릴 수지 20~30중량％와 실리콘 수지 5~10중량％ 및 니트로셀룰로오스 1~5중량％가 포함되고, 경화제 배합제는 용재 35~55중량％, 첨가제 0~2중량％에 이소시아네이트 수지 50~60중량％가 포함되고, 상기 주제 배합제 80~90중량％와, 경화제 배합제 10~20중량％의 혼합비율로 사용되는 부착오염방지 및 수세척이 용이한 도료가 제공된다.According to the present invention, there is provided a main formulation comprising a pigment, a solvent and an additive; In the paint composed of a curing agent compounding agent, which contains a solvent and an additive and is mixed with the main compounding agent when used, the main compounding agent is 20 to 25% by weight of the pigment, 29 to 50% by weight of the solvent, and 1 to 5% by weight of the additive. 20-30 weight% of acrylic resin, 5-10 weight% of silicone resin, and 1-5 weight% of nitrocellulose are contained in%, 35-55 weight% of solvent materials, 0-2 weight% of additives, and isocyanate resin 50 The coating material which contains -60 weight% and is easy to prevent adhesion fouling and water washing used by the mixing ratio of 80-90 weight% of said main compounding agents and 10-20 weight% of hardening agent compounding agents is provided.

Description

부착오염방지 및 수세척이 용이한 도료{Paint for easy washing contaminant}Paint for easy stain prevention and water washing {Paint for easy washing contaminant}

본 발명은 부착오염방지 및 수세척이 용이한 도료에 관한 것으로, 보다 상세하게는 전주, 가로등, 건물벽, 변압기 등의 각종 시설물에 도색되어 홍보물 등의 접착성 부착물이 부착되지 않도록 하고, 이에 묻은 매연이나 먼지 등을 물로써도 용이하게 세척랗 수 있도록 하기 위하여, 아크릴 수지와 이소시아네이트와 실리콘 수지가 공중합된 도료에 관한 것인다.The present invention relates to a paint that is easy to prevent adhesion contamination and washing with water, and more specifically, to various facilities such as electric poles, street lights, building walls, transformers, and the like, to prevent adhesive attachments such as promotional materials, The present invention relates to a coating material in which an acrylic resin, an isocyanate and a silicone resin are copolymerized so that soot or dust can be easily washed with water.

도심의 가로에 설치되는 변압기, 교통신호변환기, 가로등, 건물의 벽, 울타리, 육교, 전신주, 터널, 신호등과 같은 다양한 시설물들의 표면에는 각종 홍보용 전단지와 자동차에 의한 매연 및 비산 먼지들에 의해 오염된다.The surface of various facilities such as transformers, traffic signal converters, street lamps, building walls, fences, viaducts, telephone poles, tunnels, traffic lights, etc., are contaminated by various promotional leaflets and smoke and scattering dust from automobiles. .

따라서 도시경관과 깨끗한 가로미관을 위하여 일정 주기로 상기의 시설물들에 부착된 홍보물이나 매연 및 먼지들을 세척하여야 하는데, 이와 같이 매연과 비산 먼지를 제거하기 위한 수세척 작업을 보다 용이하게 하는 기술과 방법이 요구되고 있으며, 보다 용이하면서도 흔적없이 제거되어 깨끗한 외관을 유지함으로써 이를 통해 쾌적한 주변환경을 제공할 필요성이 있다.Therefore, the publicity or soot and dust attached to the above facilities should be cleaned at regular intervals for the urban landscape and the clean railing. The technique and method for facilitating water washing to remove soot and fugitive dust are There is a need, and there is a need to provide a comfortable surroundings by maintaining a clean appearance that is easily removed without a trace.

본 발명의 목적은 각종 홍보용 부착물들이 용이하게 부착되지 않도록 하고, 매연이나 비산 먼지 및 각종 홍보물의 부착으로 인한 각종 오염을 물로써 간단하게 세척할 수 있도록, 내후성과 광택유지성이 좋은 아크릴 수지와, 기계적 물성과 부착력 및 화학적 물성이 좋은 이소시아네이트와, 막을 형성하여 부착성 홍보물의 부착을 방지하고 매연이나 비산 먼지 등의 수세척을 용이하게 하는 실리콘 수지가 공중합된 부착오염방지 및 수세척이 용이한 도료를 제공함에 있다.An object of the present invention is to prevent easy attachment of various promotional attachments, and to easily clean various contaminants due to the attachment of fumes, scattering dust and various promotional materials with water, acrylic resin having good weatherability and glossiness, and mechanical It is a paint that is easy to prevent adhesion contamination and wash with water that is copolymerized with isocyanate with good physical properties, adhesion and chemical properties, and silicone resin that forms a film to prevent adhesion of adhesive promotional materials and facilitates water washing such as smoke and scattering dust. In providing.

나아가 홍보물이나 매연 및 먼지가 시설물의 도색표면에 근본적으로 부착되지 않도록 하는 도료를 제공함에 있다.Furthermore, it is to provide paint that prevents promotional materials, soot and dust from attaching to the painted surface of the facility.

본 발명은 아크릴 수지와 실리콘 수지 및 니트로셀룰로오스를 포함한 주제 배합제와, 상기 주제 배합제와 사용시에 혼합되는 것으로 이소시아네이트 수지가 포함된 경화제 배합제로 구성됨에 특징이 있다.The present invention is characterized by being composed of a main compounding agent containing an acrylic resin, a silicone resin, and nitrocellulose, and a curing agent compounding agent containing an isocyanate resin that is mixed with the main compounding agent when used.

이와 같이 본 발명은 아크릴 수지와 실리콘 수지와 니트로셀룰로오스 및 이소시아네이트 수지의 공중합도료이고, 주제 배합제와 경화제 배합제가 사용시에 혼합되어 각종 시설물에 도색됨으로써 사용된다.Thus, this invention is a copolymer coating material of an acrylic resin, a silicone resin, nitrocellulose, and an isocyanate resin, It is used by mixing a main compounding agent and a hardening | curing agent compounding agent at the time of use, and painting them in various facilities.

아래의 <표 1>은 주제 배합제의 일실시예의 구성이고, <표 2>는 경화제 배합제의 일실시예의 구성을 나타낸다.Table 1 below shows the configuration of one embodiment of the main formulation, and Table 2 shows the configuration of one embodiment of the curing agent formulation.

<표 1> 주제 배합제Table 1 Subject Formulations

화학물질명Chemical name 함유량(wt％)Content (wt%) 폴리에스테르 변성아크릴수지Polyester modified acrylic resin 20~3020-30 변성실리콘수지Modified silicone resin 5~105-10 안료(이산화티탄늄외)Pigment (titanium dioxide and others) 20~2520-25 니트로셀룰로오스Nitrocellulose 1~51-5 크실렌xylene 25~3025-30 톨루엔toluene 1~51-5 에틸 아세테이트Ethyl acetate 1~51-5 메탈 에틸 케톤Metal ethyl ketone 1~51-5 PM 아세테이트PM acetate 1~51-5 첨가제additive 1~51-5

<표 2> 경화제 배합제TABLE 2 Curing Agent Compound

화학물질명Chemical name 함유량(wt％)Content (wt%) 지방족 폴리이소시아네이트Aliphatic polyisocyanate 50~6050-60 PMA 글리콜 에테르 아세테이트PMA Glycol Ether Acetate 5~105-10 에틸 아세테이트Ethyl acetate 5~105-10 톨루엔toluene 10~1510-15 크실렌xylene 15~2015-20 첨가제additive 0~20 ~ 2

상기의 조성을 가진 본 발명을 사용할 경우에는 주제 배합제 80~90중량％와, 경화제 배합제 10~20중량％의 혼합비율로 사용된다.When using this invention which has the said composition, it is used by the mixing ratio of 80-90 weight% of the main compounding agents, and 10-20 weight% of a hardening | curing agent compounding agent.

본 발명은 아크릴 수지와 실리콘 수지 및 니트로셀룰로오스를 포함한 주제 배합제와, 이소시아네이트 수지가 포함된 경화제 배합제가 혼합되어 도색되는데, 상기의 실시예로서 <표 1>과 <표 2>에 각각 주제 배합제와 경화제 배합제가 예시되어 있다.In the present invention, the main compounding agent including acrylic resin, silicone resin and nitrocellulose and the curing agent compounding agent including isocyanate resin are mixed and painted. As the above examples, the main compounding agents are shown in Tables 1 and 2, respectively. And a hardener compounding agent are illustrated.

즉, 주제 배합제는 아크릴 수지로서 폴리에스테르 변성아크릴 수지 20~30중량％, 실리콘 수지로서 변성실리콘 수지 5~10중량％, 니트로셀룰로오스 1~5중량％를 가지고, 안료(이산화티탄늄외) 20~25중량％, 크실렌 25~30중량％, 톨루엔 1~5중량％, 에틸 아세테이트 1~5중량％, 메탈 에틸 케톤 1~5중량％, PM 아세테이트 1~5중량％, 첨가제 1~5중량％가 더 포함된다.That is, the main compounding agent has 20 to 30% by weight of polyester-modified acrylic resin as acrylic resin, 5 to 10% by weight of modified silicone resin and 1 to 5% by weight of nitrocellulose as silicone resin, and pigments (titanium dioxide and others) 20 to 25 wt%, xylene 25-30 wt%, toluene 1-5 wt%, ethyl acetate 1-5 wt%, metal ethyl ketone 1-5 wt%, PM acetate 1-5 wt%, additive 1-5 wt% More included.

상기의 아크릴 수지로서 폴리에스테르 변성아크릴 수지는 광택유지성과 내후성을 좋게 하고, 실리콘 수지로서 변성실리콘 수지는 접착성의 홍보물의 부착을 방지하고 매연이나 비산 먼지가 부착되지 않게 하는 막을 형성시키는 역할을 하며, 니트로셀룰로오스는 도색 후 수지의 건조를 촉진시키는 역할을 한다.As the acrylic resin, the polyester modified acrylic resin serves to maintain gloss retention and weather resistance, and the modified silicone resin as the silicone resin prevents adhesion of adhesive promotional materials and forms a film to prevent soot or scattering dust from adhering. Nitrocellulose serves to promote drying of the resin after painting.

크실렌, 톨루엔, 에틸 아세테이트, 메탈 에틸 케톤, PM 아세테이트는 용재로서 알반적인 구성이고, 다른 용재와의 대체도 가능하다. 상기 중 첨가제는 기포발생을 억제하고 흘러내림을 방지하는 성분으로서 일반적인 것이다. Xylene, toluene, ethyl acetate, metal ethyl ketone, and PM acetate have a general composition as a solvent and can be replaced with other solvents. Among the additives, the additives are general as components for suppressing bubble generation and preventing flowing down.

그리고 경화제 배합제는 이소시아네이트로서 지방족 폴리이소시아네이트 50~60중량％, PMA 글리콜 에테르 아세테이트 5~10중량％, 에틸 아세테이트 5~10중량％, 톨루엔 10~15중량％, 크실렌 15~20중량％, 첨가제 0~2중량％의 혼합조성을 가진다.And the curing agent compounding agent is 50 to 60% by weight of aliphatic polyisocyanate, 5 to 10% by weight of PMA glycol ether acetate, 5 to 10% by weight of ethyl acetate, 10 to 15% by weight of toluene, 15 to 20% by weight of xylene, additive 0 It has a mixing composition of ˜2% by weight.

상기의 이소시아네이트는 도료의 경도를 향상시켜 스크래치 등의 발생을 방지하는 역할을 하고, PMA 글리콜 에테르 아세테이트, 에틸 아세테이트, 톨루엔, 크실렌은 용재이고, 첨가제는 주제 배합제의 경우에서와 같다.The isocyanate serves to improve the hardness of the paint to prevent the occurrence of scratches, PMA glycol ether acetate, ethyl acetate, toluene, xylene is a solvent, and the additive is the same as in the case of the main compounding agent.

도심의 변압기, 분전반, 교통신호변환기, 가로등, 건물벽, 울타리, 육교, 전신주, 터널 등 장소와 시설물의 종류에 구애됨이 없이 상기의 조성을 가진 도료를 도장 해 줌으로써, 무분별하게 부착되는 각종 홍보물의 부착이 실리콘 수지에 의해 형성된 막에 의해 용이하게 부착되지 않게 되고, 차량의 시꺼먼 매연이나 먼지 등의 부착도 어려우며, 부착되었더라도 수세척만으로도 깨끗하게 청소할 수 있어 도시미관 및 가로미관을 좋게 할 수가 있게 된다.By applying the paint with the above composition without regard to the types of places and facilities, such as transformers, distribution boards, traffic signal converters, street lights, building walls, fences, overpasses, telephone poles, tunnels, etc. The adhesion is not easily adhered by the film formed by the silicone resin, it is difficult to adhere to the fumes, dust, etc. of the vehicle, and even if attached, it can be cleaned cleanly only by washing with water, which makes it possible to improve the appearance of beauty and the appearance of beauty.

일반적으로 기존 도료로써는 에멀젼 수지로 만든 수성도료 또는 유성 타입인 알키드수지 에나멜, 아크릴 수지의 아크릴도료, 염화고무 수지로 된 라바도료, 우레탄도료, 에폭시도료로써는 오염을 제거할 수 없었다.In general, the existing paints could not be removed with an aqueous paint made of an emulsion resin or an alkyd resin enamel of an oil type, an acrylic paint of an acrylic resin, a lava paint made of a chlorinated rubber resin, a urethane paint, and an epoxy paint.

그러나 상기의 배합으로 된 본 발명의 도료는 아크릴 수지와, 이소시아네이트, 실리콘 수지 등이 공중합됨으로써, 아크릴 수지에 의해 외관의 광택과 그 지속성이 향상됨과 내후성이 좋아지고, 이소시아네이트에 의해 경도 등의 기계적 물성이 향상되어 스크래치 등의 발생이 억제됨과 부착력과 내약품성이 증대되며, 실리콘 수지에 의한 막의 생성으로 홍보물의 부착이 어렵고 매연이나 비산 먼지의 부착 또한 방지되는 다양한 특성을 가지게 된다.However, the coating material of the present invention in the above-mentioned formulation is copolymerized with an acrylic resin, an isocyanate, a silicone resin, and the like, thereby improving the gloss and durability of the appearance by the acrylic resin and improving weather resistance, and by using the isocyanate, mechanical properties such as hardness. As a result, the occurrence of scratches is suppressed, adhesion strength and chemical resistance are increased, and the production of a film by the silicone resin makes it difficult to attach the promotional material, and also has various characteristics in which adhesion of soot and scattering dust is also prevented.

이와 같이 본 발명은 각종 홍보용 부착물들이 부착되지 않아 근본적으로 각종 시설물을 깨끗하게 유지시킬 수가 있고, 매연이나 비산 먼지 및 각종 홍보물의 부착으로 인한 각종 오염이 있더라도, 물로써 간단하게 세척할 수 있는 효과가 있다.As described above, the present invention is not attached to various promotional attachments, so it is possible to keep various facilities clean, and even if there are various pollutions due to the attachment of fumes, scattering dust and various promotional materials, there is an effect that can be easily washed with water. .

Claims (2)

안료와 용재 및 첨가제가 포함된 주제 배합제와; 용재와 첨가제가 포함되어, 사용시 상기의 주제 배합제와 혼합되어 사용되는 경화제 배합제로 구성된 도료에 있어서, 상기 주제 배합제는 안료 20~25중량％, 용재 29~50중량％, 첨가제 1~5중량％에 아크릴 수지 20~30중량％와 실리콘 수지 5~10중량％ 및 니트로셀룰로오스 1~5중량％가 포함되고, 경화제 배합제는 용재 35~55중량％, 첨가제 0~2중량％에 이소시아네이트 수지 50~60중량％가 포함되고, 상기 주제 배합제 80~90중량％와, 경화제 배합제 10~20중량％의 혼합비율로 사용됨을 특징으로 하는 부착오염방지 및 수세척이 용이한 도료.A main formulation containing a pigment, a solvent, and an additive; In the paint composed of a curing agent compounding agent, which contains a solvent and an additive and is mixed with the main compounding agent when used, the main compounding agent is 20 to 25% by weight of the pigment, 29 to 50% by weight of the solvent, and 1 to 5% by weight of the additive. 20-30 weight% of acrylic resin, 5-10 weight% of silicone resin, and 1-5 weight% of nitrocellulose are contained in%, 35-55 weight% of solvent materials, 0-2 weight% of additives, and isocyanate resin 50 The coating material which is easy to prevent adhesion pollution and water washing is contained by -60 weight%, It is used in the mixing ratio of 80-90 weight% of the said main compounding agents, and 10-20 weight% of a hardening | curing agent compounding agent. 제 1항에 있어서, 아크릴 수지는 폴리에스테르 변성아크릴 수지이고, 실리콘 수지는 변성실리콘 수지이며, 이소시아네이트는 지방족 폴리이소시아네이트인 부착오염방지 및 수세척이 용이한 도료.The paint of claim 1, wherein the acrylic resin is a polyester-modified acrylic resin, the silicone resin is a modified silicone resin, and the isocyanate is an aliphatic polyisocyanate.
KR1020050065883A 2005-07-20 2005-07-20 Paint for easy washing contaminant KR20050080169A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100771856B1 (en) * 2007-06-21 2007-11-01 주식회사 신도디앤텍 Manufacturing method and color paint for preventing an adhering material
KR100858371B1 (en) * 2007-02-13 2008-09-11 (주)씨케이 Nitrocellulose lacquer and method preparing theirof
KR101053928B1 (en) * 2010-02-12 2011-08-04 김종희 Composite for preventing adhesion and method of coating anti-adhesive having the composite
KR101412870B1 (en) * 2012-10-10 2014-06-26 안재준 Paint composition for insulation and preventing adhesion of advertising material

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100858371B1 (en) * 2007-02-13 2008-09-11 (주)씨케이 Nitrocellulose lacquer and method preparing theirof
KR100771856B1 (en) * 2007-06-21 2007-11-01 주식회사 신도디앤텍 Manufacturing method and color paint for preventing an adhering material
KR101053928B1 (en) * 2010-02-12 2011-08-04 김종희 Composite for preventing adhesion and method of coating anti-adhesive having the composite
KR101412870B1 (en) * 2012-10-10 2014-06-26 안재준 Paint composition for insulation and preventing adhesion of advertising material

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