FR2542630B1 - Procede de preparation d'un catalyseur d'oxydation des mercaptans en disulfures et application de ce catalyseur a l'adoucissement des distillats petroliers - Google Patents

Procede de preparation d'un catalyseur d'oxydation des mercaptans en disulfures et application de ce catalyseur a l'adoucissement des distillats petroliers

Info

Publication number
FR2542630B1
FR2542630B1 FR8304628A FR8304628A FR2542630B1 FR 2542630 B1 FR2542630 B1 FR 2542630B1 FR 8304628 A FR8304628 A FR 8304628A FR 8304628 A FR8304628 A FR 8304628A FR 2542630 B1 FR2542630 B1 FR 2542630B1
Authority
FR
France
Prior art keywords
catalyst
disulfides
mercaptans
softening
oxidation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
FR8304628A
Other languages
English (en)
French (fr)
Other versions
FR2542630A1 (fr
Inventor
Jean-Pierre Franck
Hubert Mimoun
Claude Marty
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Original Assignee
IFP Energies Nouvelles IFPEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Priority to FR8304628A priority Critical patent/FR2542630B1/fr
Priority to DE8484400300T priority patent/DE3462436D1/de
Priority to EP19840400300 priority patent/EP0119885B1/fr
Priority to CA000449747A priority patent/CA1212371A/fr
Priority to JP5206784A priority patent/JPS59177139A/ja
Publication of FR2542630A1 publication Critical patent/FR2542630A1/fr
Application granted granted Critical
Publication of FR2542630B1 publication Critical patent/FR2542630B1/fr
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/165—Polymer immobilised coordination complexes, e.g. organometallic complexes
    • B01J31/1658—Polymer immobilised coordination complexes, e.g. organometallic complexes immobilised by covalent linkages, i.e. pendant complexes with optional linking groups, e.g. on Wang or Merrifield resins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
    • B01J31/08—Ion-exchange resins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G27/00—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
    • C10G27/04—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen
    • C10G27/10—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen in the presence of metal-containing organic complexes, e.g. chelates, or cationic ion-exchange resins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/70—Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/10—Complexes comprising metals of Group I (IA or IB) as the central metal
    • B01J2531/16—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/20—Complexes comprising metals of Group II (IIA or IIB) as the central metal
    • B01J2531/26—Zinc
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/845—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/847—Nickel

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
FR8304628A 1983-03-18 1983-03-18 Procede de preparation d'un catalyseur d'oxydation des mercaptans en disulfures et application de ce catalyseur a l'adoucissement des distillats petroliers Expired FR2542630B1 (fr)

Priority Applications (5)

Application Number Priority Date Filing Date Title
FR8304628A FR2542630B1 (fr) 1983-03-18 1983-03-18 Procede de preparation d'un catalyseur d'oxydation des mercaptans en disulfures et application de ce catalyseur a l'adoucissement des distillats petroliers
DE8484400300T DE3462436D1 (en) 1983-03-18 1984-02-15 Process for the preparation of a catalyst for the oxidation of mercaptans to disulfides, and use of this catalyst in the sweetening of petroleum distillates
EP19840400300 EP0119885B1 (fr) 1983-03-18 1984-02-15 Procédé de préparation d'un catalyseur d'oxydation des mercaptans en disulfures et application de ce catalyseur à l'adoucissement des distillats pétroliers
CA000449747A CA1212371A (fr) 1983-03-18 1984-03-16 Procede de preparation d'un catalyseur d'oxydation des mercaptans en disulfures et application de ce catalyseur a l'adoucissement des distillats petroliers
JP5206784A JPS59177139A (ja) 1983-03-18 1984-03-16 メルカプタンから二硫化物への酸化用触媒の調製方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR8304628A FR2542630B1 (fr) 1983-03-18 1983-03-18 Procede de preparation d'un catalyseur d'oxydation des mercaptans en disulfures et application de ce catalyseur a l'adoucissement des distillats petroliers

Publications (2)

Publication Number Publication Date
FR2542630A1 FR2542630A1 (fr) 1984-09-21
FR2542630B1 true FR2542630B1 (fr) 1987-11-13

Family

ID=9287079

Family Applications (1)

Application Number Title Priority Date Filing Date
FR8304628A Expired FR2542630B1 (fr) 1983-03-18 1983-03-18 Procede de preparation d'un catalyseur d'oxydation des mercaptans en disulfures et application de ce catalyseur a l'adoucissement des distillats petroliers

Country Status (5)

Country Link
EP (1) EP0119885B1 (enExample)
JP (1) JPS59177139A (enExample)
CA (1) CA1212371A (enExample)
DE (1) DE3462436D1 (enExample)
FR (1) FR2542630B1 (enExample)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPWO2006028146A1 (ja) * 2004-09-07 2008-05-08 和光純薬工業株式会社 パラジウム固定化イオン交換樹脂及びそれを用いた還元方法
EA018297B1 (ru) * 2012-02-07 2013-06-28 Фролкин, Владимир Владимирович Катализатор окисления сероводорода, низкомолекулярных и высокомолекулярных меркаптанов в углеводородных средах, в том числе в нефти, в газовом конденсате и в продуктах переработки

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2723222A (en) * 1954-12-06 1955-11-08 Phillips Petroleum Co Use of chelating agents to improve color and color stability of petroleum distillate
US2792334A (en) * 1955-05-26 1957-05-14 Mercaptan
NL270089A (enExample) * 1960-10-12
FR1391934A (fr) * 1964-01-29 1965-03-12 Dev De La Catalyse Ind Soc D E Procédé d'oxydation de mercaptans
FR2202726A1 (en) * 1972-10-16 1974-05-10 Raffinage Cie Francaise Catalysts for oxidising mercaptans to disulphides - esp. for sweetening petroleum distillates, with the oxidn-active component fixed to a support
FR2320769A1 (fr) * 1975-08-12 1977-03-11 Rhone Poulenc Ind Procede d'elimination du sulfure d'hydrogene de gaz par oxydation catalytique en soufre sans formation d'oxydes de soufre
US4298502A (en) * 1978-11-06 1981-11-03 Uop Inc. Catalytic composite particularly useful for the oxidation of mercaptans and the removal of gums contained in a sour petroleum distillate
FR2524818A1 (fr) * 1982-04-09 1983-10-14 Raffinage Cie Francaise Nouveau catalyseur d'oxydation de mercaptans en disulfures, son procede de preparation et son application a l'adoucissement des distillats petroliers

Also Published As

Publication number Publication date
DE3462436D1 (en) 1987-04-09
JPH0512025B2 (enExample) 1993-02-17
EP0119885B1 (fr) 1987-03-04
JPS59177139A (ja) 1984-10-06
EP0119885A1 (fr) 1984-09-26
FR2542630A1 (fr) 1984-09-21
CA1212371A (fr) 1986-10-07

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