FR2516944A1 - PROCESS FOR MANUFACTURING AN ABSORBER FOR SOLAR INSTALLATIONS - Google Patents
PROCESS FOR MANUFACTURING AN ABSORBER FOR SOLAR INSTALLATIONS Download PDFInfo
- Publication number
- FR2516944A1 FR2516944A1 FR8219304A FR8219304A FR2516944A1 FR 2516944 A1 FR2516944 A1 FR 2516944A1 FR 8219304 A FR8219304 A FR 8219304A FR 8219304 A FR8219304 A FR 8219304A FR 2516944 A1 FR2516944 A1 FR 2516944A1
- Authority
- FR
- France
- Prior art keywords
- substrate
- approximately
- gas
- absorber
- titanium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/06—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of metallic material
- C23C16/08—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of metallic material from metal halides
- C23C16/14—Deposition of only one other metal element
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/02—Pretreatment of the material to be coated
- C23C16/0254—Physical treatment to alter the texture of the surface, e.g. scratching or polishing
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24S—SOLAR HEAT COLLECTORS; SOLAR HEAT SYSTEMS
- F24S70/00—Details of absorbing elements
- F24S70/20—Details of absorbing elements characterised by absorbing coatings; characterised by surface treatment for increasing absorption
- F24S70/225—Details of absorbing elements characterised by absorbing coatings; characterised by surface treatment for increasing absorption for spectrally selective absorption
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24S—SOLAR HEAT COLLECTORS; SOLAR HEAT SYSTEMS
- F24S70/00—Details of absorbing elements
- F24S70/20—Details of absorbing elements characterised by absorbing coatings; characterised by surface treatment for increasing absorption
- F24S70/25—Coatings made of metallic material
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/40—Solar thermal energy, e.g. solar towers
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Physics & Mathematics (AREA)
- Sustainable Energy (AREA)
- Combustion & Propulsion (AREA)
- General Engineering & Computer Science (AREA)
- Thermal Sciences (AREA)
- Sustainable Development (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Chemical Vapour Deposition (AREA)
- Solid-Phase Diffusion Into Metallic Material Surfaces (AREA)
- Physical Vapour Deposition (AREA)
Abstract
Description
"ProcBdé pour fabriquer un absorbeur pour des installations
solaires."Process for manufacturing an absorber for installations
solar.
L'invention concerne un procédé pour labri quer un absorbeur pour des installations solaires, moyennant le recouvrement d'un substrat au moyen d' un procédé en phase gazeuse. The invention relates to a method for labeling an absorber for solar installations, by covering a substrate by means of a gas phase method.
Un procédé connu en phase gazeuse est le dé- pôt chimique en phase gazeuse (cep), a l'aide duquel on réalise des couches d'absorbeur constituées par des matériaux non métalliques par des métaux à haut point de fusion. Dans le cas de l'utilisation de ma tériaux déterminés de recouvrement, on a pu fabriquer, grâce a une forte structuration finement divisée du dépôt, des couches d'absorbeur realisant une absorption élevée de la lumière. Cependant il s'est avéré que ces couches ne présentent pas une adhérence suffisante et possèdent une mauvaise stabilité en température. A known process in the gas phase is the chemical deposit in the gas phase (cep), with the aid of which layers of absorber are made up of non-metallic materials by metals with a high melting point. In the case of the use of certain materials for covering, it was possible to manufacture, thanks to a strong finely divided structure of the deposit, layers of absorber achieving a high absorption of light. However, it has been found that these layers do not have sufficient adhesion and have poor temperature stability.
L'invention a pour but de trouver un procédé du type indiqué plus haut permettant de fabriquer un absorbeur avec des couches -qui, tout en conservant un pouvoir absorbant élevé, présentent également a des températures assez élevées, une bonne adhérence au substrat. The invention aims to find a method of the type indicated above for manufacturing an absorber with layers -which, while retaining a high absorbency, also have at fairly high temperatures, good adhesion to the substrate.
Ce problème est résolu conformément a l'invention grâce au fait qu'on utilise un substrat formé d'un alliage contenant du nickel et du titane et qu'on le soumet à un traitement préalable et que le processus de dépôt est réalisé dans une phase gazeuse con lait du titane, la formation des couches s'eErec- tuant avec la participation du matériau du substrat. This problem is solved in accordance with the invention thanks to the fact that a substrate formed of an alloy containing nickel and titanium is used and that it is subjected to a preliminary treatment and that the deposition process is carried out in a phase carbonated with titanium, the formation of the layers taking place with the participation of the substrate material.
Dans le cas du procédé conforme à l'invention, il se produit une diffusion entre des éléments du substrat et la couche, de sorte que la couche déposée s'allie au substrat en y étant fixée solidement. In the case of the method according to the invention, there is a diffusion between elements of the substrate and the layer, so that the deposited layer is combined with the substrate by being firmly fixed therein.
Grâce a la forte structuration simultanée du dépôt, on a pumesurerune absorption très intense pour la plage spectrale du rayonnement solaire.Thanks to the strong simultaneous structuring of the deposit, we have a very intense absorption for the spectral range of solar radiation.
A l'raide de ce procédé on forme la phase intermétallique Ni3Ti qui possède non seulement un pou voir absorbant élevé, mais en outre une résistance élevée à l'oxydation .I1 s'est également avéré que l'on peut former cette couche dans le cas d'alliages possédant une teneur en Ni aussi faible qu'environ 5 % en atomes, une teneur en Ti égale environ à 0,5 %. With the aid of this process, the intermetallic phase Ni3Ti is formed which not only has a high absorbent power, but also a high resistance to oxidation. It has also been found that this layer can be formed in the case of alloys having a Ni content as low as about 5 atomic%, a Ti content equal to about 0.5%.
Un autre avantage du procédé conforme à l'invention réside dans le fait qutil n'y a pas, comme dans le cas du dépôt chimique usuel en phase gazeuse, à introduire au moins deux partenaires réactionnels gazeux en les dosant selon des quantités et des rapports entre quantités, difficiles à optimi ser,niàveiller à obtenir dans l'enceinte réactionnelle un mélange intime uniforme, mais qu'ici seul un partenaire réactionnel unique est nécessaire. Another advantage of the process according to the invention lies in the fact that there is not, as in the case of the usual chemical deposition in the gas phase, the introduction of at least two gaseous reaction partners by dosing them according to quantities and ratios between quantities, difficult to optimize, or to ensure that a uniform intimate mixture is obtained in the reaction vessel, but that only a single reaction partner is necessary here.
On peut obtenir des couches d'absorbeur présentant un pouvoir absorbant particulièrement élevé en utilisant du tétrachlorure de titane (TiC14) comme gaz réactionnel
On obtient une optimisation des résultats en utilisant environ 1 t en volume de TiCi4 dans le courant de gaz total du processus de dépôt.Absorber layers with particularly high absorbency can be obtained by using titanium tetrachloride (TiC14) as the reaction gas.
Optimization of the results is obtained by using approximately 1 t by volume of TiCi4 in the total gas stream of the deposition process.
Dans le cas d'une température de recouvrement d'environ 900 C, il se forme, au cours d'une durée de recouvrement déjà d'environ 1 heure, des couches stables présentant un pouvoir absorbant suffisant. La température de recouvrement est égale de préférence à 700-10000C, la durée de recouvrement diminuant entre 3 et 1 heure avec la tenpérature. In the case of a covering temperature of approximately 900 ° C., stable layers with sufficient absorbency are formed during a covering time already of approximately 1 hour. The coating temperature is preferably 700-10000C, the coating time decreasing between 3 and 1 hour with the temperature.
Exemple
On a soumis un substrat d'acier spécial X5 CrNiTi 18q à un traitement de meulage et de polissage, avec lequel on a obtenu une rugosité maximale
Ra = 1 Vm. Example
A special X5 CrNiTi 18q steel substrate was subjected to a grinding and polishing treatment, with which a maximum roughness was obtained.
Ra = 1 Vm.
Le substrat prétraité fut ensuite placé dans une enceinte réactionnelle, protégée, vis-avis de l'accès de l'atmosphère, dans un courant d' hydrogène a une température d'environ 9O00C. The pretreated substrate was then placed in a reaction chamber, protected, vis-a-vis the access of the atmosphere, in a stream of hydrogen at a temperature of about 9O00C.
Après l'obtention de cette température, on a ajouté au courant d'hydrogène le composant réactif formé par du tétrachlorure de titane (TiC14),en faisant passer un courant partiel d'hydrogène ou un courant supplémentaire d'argon au-dessus d'une enceinte d'évaporateur thermostatée contenant du TiCl4 liquide. Le courant de gaz porteur et la température de l'évaporateur furent choisis de manière que la quantité TiC 14 gazeux entrainée atteigne 1 % en volume. La conduite de gaz entre l'évaporateur et l'enceinte réactionnelle fut chauffée afin d' éviter la condensation du TiC14. After this temperature was obtained, the reactive component formed by titanium tetrachloride (TiC14) was added to the hydrogen stream, passing a partial stream of hydrogen or an additional stream of argon over a thermostatically controlled evaporator enclosure containing liquid TiCl4. The stream of carrier gas and the temperature of the evaporator were chosen so that the amount of TiC 14 gas entrained reached 1% by volume. The gas line between the evaporator and the reaction vessel was heated to prevent condensation of the TiC14.
La phase gazeuse réactive agit pendant environ 1 heure à 9000C sur le substrat. Ensuite l'envoi de TiC14 fut interrompu et l'enceinte réactionnulle munie des corps échantillon recouvexts situés dans le courant d'hydrogène ou d'argon fut refroidie à la température ambiante. The reactive gas phase acts for approximately 1 hour at 9000C on the substrate. Then the sending of TiC14 was interrupted and the reaction vessel provided with the covered sample bodies located in the stream of hydrogen or argon was cooled to room temperature.
Avec ce procédé on a pu réaliser sur un substrat une couche adhérant fermement et possédant une épaisseur moyenne de l'ordre du dixieme de micron. With this process, it was possible to produce a firmly adhering layer on a substrate having an average thickness of the order of a tenth of a micron.
La taille maximale des particules- individuelles était égale à environ 1 ijm. Les couches présentaient des degrés d'absorption dans la plage du rayonnement visible allant jusqu'à 98 %. L'émission de rayonnement infrarouge est déterminée ici essentiellement par le support. The maximum size of the individual particles was approximately 1 µm. The layers exhibited absorption levels in the visible radiation range of up to 98%. The emission of infrared radiation is determined here essentially by the support.
Claims (6)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19813146083 DE3146083A1 (en) | 1981-11-20 | 1981-11-20 | Method of producing an absorber for solar installations |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2516944A1 true FR2516944A1 (en) | 1983-05-27 |
FR2516944B1 FR2516944B1 (en) | 1986-08-14 |
Family
ID=6146838
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR8219304A Expired FR2516944B1 (en) | 1981-11-20 | 1982-11-18 | PROCESS FOR MANUFACTURING AN ABSORBER FOR SOLAR INSTALLATIONS |
Country Status (4)
Country | Link |
---|---|
DE (1) | DE3146083A1 (en) |
ES (1) | ES8307920A1 (en) |
FR (1) | FR2516944B1 (en) |
IT (1) | IT1148484B (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0614217A1 (en) * | 1993-03-01 | 1994-09-07 | Motorola, Inc. | A process for forming an intermetallic layer and a device formed by the process |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1952173A1 (en) * | 1968-10-12 | 1970-04-23 | Battelle Memorial Institute | Process for the production of a titanium coating on a solid body |
GB1314528A (en) * | 1969-06-06 | 1973-04-26 | Chrome Alloying Co | Pack diffusion coating with titanium |
FR2203892A1 (en) * | 1972-10-24 | 1974-05-17 | Gen Electric | |
JPS5535804A (en) * | 1978-09-04 | 1980-03-13 | Toyo Kohan Co Ltd | Heat collecting member for arresting and collecting solar heat |
JPS5653346A (en) * | 1980-09-08 | 1981-05-12 | Yazaki Corp | Selective absorption face of solar heat utilizing heat collector and preparation thereof |
JPS56142347A (en) * | 1979-11-30 | 1981-11-06 | Matsushita Electric Works Ltd | Production of solar heat absorbing body |
-
1981
- 1981-11-20 DE DE19813146083 patent/DE3146083A1/en not_active Withdrawn
-
1982
- 1982-11-12 ES ES517344A patent/ES8307920A1/en not_active Expired
- 1982-11-18 FR FR8219304A patent/FR2516944B1/en not_active Expired
- 1982-11-19 IT IT49538/82A patent/IT1148484B/en active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1952173A1 (en) * | 1968-10-12 | 1970-04-23 | Battelle Memorial Institute | Process for the production of a titanium coating on a solid body |
GB1314528A (en) * | 1969-06-06 | 1973-04-26 | Chrome Alloying Co | Pack diffusion coating with titanium |
FR2203892A1 (en) * | 1972-10-24 | 1974-05-17 | Gen Electric | |
JPS5535804A (en) * | 1978-09-04 | 1980-03-13 | Toyo Kohan Co Ltd | Heat collecting member for arresting and collecting solar heat |
JPS56142347A (en) * | 1979-11-30 | 1981-11-06 | Matsushita Electric Works Ltd | Production of solar heat absorbing body |
JPS5653346A (en) * | 1980-09-08 | 1981-05-12 | Yazaki Corp | Selective absorption face of solar heat utilizing heat collector and preparation thereof |
Non-Patent Citations (4)
Title |
---|
CHEMICAL ABSTRACTS, vol. 88, no. 18, 1 mai 1978, page 234, no. 124941u, Columbus, Ohio, US; S.OKAMOTO et al.: "Study on chemical vapor deposition. I. Properties of titanium, titanium nitride and titanium carbide layers on iron substrate plated by chemical vapor deposition" & KIKAI GIJUTSU KENKYUSHO SHOHO 1977, 31(5), 286-9 * |
PATENTS ABSTRACTS OF JAPAN, vol. 4, no. 72 (M-13)[554], 27 mai 1980, pages 95 M 13; & JP - A - 55 35 804 (TOYO KOUHAN K.K.) 13-03-1980 * |
PATENTS ABSTRACTS OF JAPAN, vol. 5, no. 112 (M-79)[784], 21 juillet 1981; & JP - A - 56 53 346 (YAZAKI SOUGIYOU K.K.) 12-05-1981 * |
PATENTS ABSTRACTS OF JAPAN, vol. 6, no. 23 (M-111)[901], 10 février 1982; & JP - A - 56 142 347 (MATSUSHITA DENKO K.K.) 06-11-1981 * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0614217A1 (en) * | 1993-03-01 | 1994-09-07 | Motorola, Inc. | A process for forming an intermetallic layer and a device formed by the process |
Also Published As
Publication number | Publication date |
---|---|
FR2516944B1 (en) | 1986-08-14 |
IT8249538A0 (en) | 1982-11-19 |
DE3146083A1 (en) | 1983-05-26 |
ES517344A0 (en) | 1983-08-16 |
ES8307920A1 (en) | 1983-08-16 |
IT1148484B (en) | 1986-12-03 |
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Legal Events
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ST | Notification of lapse |