FR2514756B1 - Procede de conversion catalytique de l'acide butyrique ou d'un de ses equivalents fonctionnels en le derive a insaturation a,b-ethylenique correspondant par oxydeshydrogenation - Google Patents

Procede de conversion catalytique de l'acide butyrique ou d'un de ses equivalents fonctionnels en le derive a insaturation a,b-ethylenique correspondant par oxydeshydrogenation

Info

Publication number
FR2514756B1
FR2514756B1 FR8119520A FR8119520A FR2514756B1 FR 2514756 B1 FR2514756 B1 FR 2514756B1 FR 8119520 A FR8119520 A FR 8119520A FR 8119520 A FR8119520 A FR 8119520A FR 2514756 B1 FR2514756 B1 FR 2514756B1
Authority
FR
France
Prior art keywords
oxydeshydrogenation
unsaturated
butyric acid
functional equivalent
catalytic conversion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
FR8119520A
Other languages
English (en)
French (fr)
Other versions
FR2514756A1 (fr
Inventor
Daniel Chelliah
Phyllis L Brusky
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ashland LLC
Original Assignee
Ashland Oil Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to US06/124,030 priority Critical patent/US4298755A/en
Priority to SE8105937A priority patent/SE435925B/sv
Priority to GB08130549A priority patent/GB2107305A/en
Priority to CA000387725A priority patent/CA1162936A/en
Priority to ZA817089A priority patent/ZA817089B/xx
Priority to FR8119520A priority patent/FR2514756B1/fr
Application filed by Ashland Oil Inc filed Critical Ashland Oil Inc
Priority to CH6706/81A priority patent/CH653005A5/de
Priority to JP56166520A priority patent/JPS5872537A/ja
Priority to NL8104803A priority patent/NL8104803A/nl
Priority to DD81234498A priority patent/DD201999A5/de
Priority to BR8107073A priority patent/BR8107073A/pt
Priority to DE3143152A priority patent/DE3143152C2/de
Publication of FR2514756A1 publication Critical patent/FR2514756A1/fr
Application granted granted Critical
Publication of FR2514756B1 publication Critical patent/FR2514756B1/fr
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
    • C07C57/02—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
    • C07C57/03—Monocarboxylic acids
    • C07C57/04—Acrylic acid; Methacrylic acid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
    • B01J27/18—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr with metals other than Al or Zr
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
    • B01J27/18—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr with metals other than Al or Zr
    • B01J27/1802—Salts or mixtures of anhydrides with compounds of other metals than V, Nb, Ta, Cr, Mo, W, Mn, Tc, Re, e.g. phosphates, thiophosphates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/185—Phosphorus; Compounds thereof with iron group metals or platinum group metals
    • B01J27/1853—Phosphorus; Compounds thereof with iron group metals or platinum group metals with iron, cobalt or nickel
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
    • C07C51/377—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
FR8119520A 1980-02-25 1981-10-16 Procede de conversion catalytique de l'acide butyrique ou d'un de ses equivalents fonctionnels en le derive a insaturation a,b-ethylenique correspondant par oxydeshydrogenation Expired FR2514756B1 (fr)

Priority Applications (12)

Application Number Priority Date Filing Date Title
US06/124,030 US4298755A (en) 1980-02-25 1980-02-25 Catalytic oxydehydrogenation process
SE8105937A SE435925B (sv) 1980-02-25 1981-10-07 Forfarande for katalytisk omvandling av isosmorsyra eller metylisobutyrat
GB08130549A GB2107305A (en) 1980-02-25 1981-10-09 Catalytic oxydehydrogenation
CA000387725A CA1162936A (en) 1980-02-25 1981-10-09 Oxydehydrogenation catalyst
ZA817089A ZA817089B (en) 1980-02-25 1981-10-14 Oxydehydrogenation catalyst
FR8119520A FR2514756B1 (fr) 1980-02-25 1981-10-16 Procede de conversion catalytique de l'acide butyrique ou d'un de ses equivalents fonctionnels en le derive a insaturation a,b-ethylenique correspondant par oxydeshydrogenation
CH6706/81A CH653005A5 (en) 1980-02-25 1981-10-20 Oxydehydrogenation catalyst, and process for the catalytic conversion of isobutyric acid or functional derivatives thereof into corresponding alpha, beta-unsaturated compounds
JP56166520A JPS5872537A (ja) 1980-02-25 1981-10-20 イソ酪酸またはイソ酪酸メチルを接触的に転化する方法
NL8104803A NL8104803A (nl) 1980-02-25 1981-10-23 Werkwijze voor de katalytische omzetting van isoboterzuur of een functioneel equivalent tot het overeenkomstige alfa, beta- ethenisch onverzadigde derivaat.
DD81234498A DD201999A5 (de) 1980-02-25 1981-10-30 Verfahren zur katalytischen umwandlung von isobuttersaeure in das entsprechende alpha, beta-aethylenisch ungesaettigte derivat
BR8107073A BR8107073A (pt) 1980-02-25 1981-10-30 Processo para a conversao catalitica do acido isobutirico
DE3143152A DE3143152C2 (de) 1980-02-25 1981-10-30 Verfahren zur Umwandlung von Isobuttersäure oder einem Isobuttersäure-Niederalkylester in die entsprechenden α,β-äthylenisch ungesättigten Derivate durch Oxydehydrierung

Applications Claiming Priority (12)

Application Number Priority Date Filing Date Title
US06/124,030 US4298755A (en) 1980-02-25 1980-02-25 Catalytic oxydehydrogenation process
SE8105937A SE435925B (sv) 1980-02-25 1981-10-07 Forfarande for katalytisk omvandling av isosmorsyra eller metylisobutyrat
GB08130549A GB2107305A (en) 1980-02-25 1981-10-09 Catalytic oxydehydrogenation
CA000387725A CA1162936A (en) 1980-02-25 1981-10-09 Oxydehydrogenation catalyst
ZA817089A ZA817089B (en) 1980-02-25 1981-10-14 Oxydehydrogenation catalyst
FR8119520A FR2514756B1 (fr) 1980-02-25 1981-10-16 Procede de conversion catalytique de l'acide butyrique ou d'un de ses equivalents fonctionnels en le derive a insaturation a,b-ethylenique correspondant par oxydeshydrogenation
CH6706/81A CH653005A5 (en) 1980-02-25 1981-10-20 Oxydehydrogenation catalyst, and process for the catalytic conversion of isobutyric acid or functional derivatives thereof into corresponding alpha, beta-unsaturated compounds
JP56166520A JPS5872537A (ja) 1980-02-25 1981-10-20 イソ酪酸またはイソ酪酸メチルを接触的に転化する方法
NL8104803A NL8104803A (nl) 1980-02-25 1981-10-23 Werkwijze voor de katalytische omzetting van isoboterzuur of een functioneel equivalent tot het overeenkomstige alfa, beta- ethenisch onverzadigde derivaat.
DD81234498A DD201999A5 (de) 1980-02-25 1981-10-30 Verfahren zur katalytischen umwandlung von isobuttersaeure in das entsprechende alpha, beta-aethylenisch ungesaettigte derivat
BR8107073A BR8107073A (pt) 1980-02-25 1981-10-30 Processo para a conversao catalitica do acido isobutirico
DE3143152A DE3143152C2 (de) 1980-02-25 1981-10-30 Verfahren zur Umwandlung von Isobuttersäure oder einem Isobuttersäure-Niederalkylester in die entsprechenden α,β-äthylenisch ungesättigten Derivate durch Oxydehydrierung

Publications (2)

Publication Number Publication Date
FR2514756A1 FR2514756A1 (fr) 1983-04-22
FR2514756B1 true FR2514756B1 (fr) 1986-12-26

Family

ID=27582860

Family Applications (1)

Application Number Title Priority Date Filing Date
FR8119520A Expired FR2514756B1 (fr) 1980-02-25 1981-10-16 Procede de conversion catalytique de l'acide butyrique ou d'un de ses equivalents fonctionnels en le derive a insaturation a,b-ethylenique correspondant par oxydeshydrogenation

Country Status (12)

Country Link
US (1) US4298755A (enExample)
JP (1) JPS5872537A (enExample)
BR (1) BR8107073A (enExample)
CA (1) CA1162936A (enExample)
CH (1) CH653005A5 (enExample)
DD (1) DD201999A5 (enExample)
DE (1) DE3143152C2 (enExample)
FR (1) FR2514756B1 (enExample)
GB (1) GB2107305A (enExample)
NL (1) NL8104803A (enExample)
SE (1) SE435925B (enExample)
ZA (1) ZA817089B (enExample)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4742035A (en) * 1980-12-31 1988-05-03 The Standard Oil Co. Mixed metal phosphorus oxide catalysts for the oxidative dehydrogenation of carboxylic acids
US4864057A (en) * 1980-12-31 1989-09-05 Pedersen S Erik Dehydrogenation of carboxylic acids with mixed metal phosphorus oxide catalysts
GB2090589B (en) * 1981-01-07 1985-01-23 Ashland Oil Inc Catalytic oxydehydrogenation of isobutyric acid to methacrylic acid
US4355176A (en) * 1981-11-09 1982-10-19 Ashland Oil, Inc. Oxydehydrogenation process for preparing methacrylic acid and its lower alkyl esters
US4390725A (en) * 1981-11-19 1983-06-28 Ashland Oil, Inc. Oxydehydrogenation process for preparing methacrylic acid and its lower alkyl esters
US4410728A (en) * 1982-04-19 1983-10-18 Ashland Oil, Inc. Oxydehydrogenation process
US4638124A (en) * 1984-09-21 1987-01-20 Itt Corporation Key telephone system with distributed control
FR2635521B1 (fr) * 1988-08-16 1991-02-22 Norsolor Sa Procede perfectionne pour la fabrication de methacrylate de methyle a partir d'acide isobutyrique
US5001102A (en) * 1989-01-11 1991-03-19 Pq Corporation Heterogeneous catalysts
US7495132B2 (en) * 2004-01-30 2009-02-24 Basf Aktiengesellschaft Catalytically active composition and the use thereof in dehydration methods
FR2921361B1 (fr) * 2007-09-20 2012-10-12 Arkema France Procede de fabrication d'acroleine a partir de glycerol
EP2179981A1 (en) 2008-10-24 2010-04-28 Arkema France Process for manufacturing acrolein from glycerol

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3855279A (en) * 1973-10-26 1974-12-17 Eastman Kodak Co Catalytic process for the manufacture of unsaturated acids and esters
US3917673A (en) * 1973-10-26 1975-11-04 Eastman Kodak Co Catalytic process for the manufacture of unsaturated acids and esters
JPS5949214B2 (ja) * 1976-11-24 1984-12-01 三菱レイヨン株式会社 不飽和カルボン酸またはそのエステルの製法

Also Published As

Publication number Publication date
US4298755A (en) 1981-11-03
GB2107305A (en) 1983-04-27
DE3143152C2 (de) 1985-07-25
NL8104803A (nl) 1983-05-16
SE435925B (sv) 1984-10-29
FR2514756A1 (fr) 1983-04-22
JPS5872537A (ja) 1983-04-30
ZA817089B (en) 1982-09-29
DE3143152A1 (de) 1983-05-11
DD201999A5 (de) 1983-08-24
CH653005A5 (en) 1985-12-13
SE8105937L (sv) 1983-04-08
BR8107073A (pt) 1983-05-31
CA1162936A (en) 1984-02-28
JPH0219813B2 (enExample) 1990-05-07

Similar Documents

Publication Publication Date Title
FR2564859B1 (fr) Procede de preparation d'acide hyaluronique par fermentation.
FR2343712A1 (fr) Procede pour la preparation de l'acide acrylique a partir du propylene
BE834848A (fr) Procede de separation de citrate ou d'acide citrique a partir de solutions de fermentation
FR2302993A1 (fr) Procede par catalyse de preparation d'un acide carboxylique insature
BE880571A (fr) Procede de production de l'acide methacrylique et catalyseur approprie
FR2514756B1 (fr) Procede de conversion catalytique de l'acide butyrique ou d'un de ses equivalents fonctionnels en le derive a insaturation a,b-ethylenique correspondant par oxydeshydrogenation
RO79394A (ro) Procedeu pentru purificarea acidului fosforic
OA07001A (fr) Procédé de préparation d'acide phosphorique.
BE877243A (fr) Procede de preparation de l'o-methallyloxyphenol par monoetherification selective de la pyrocatechine
PT73314A (fr) Procede pour la fabrication de l'acide beta-hydroxybutyrique etde ses oligocondensats
FR2504918B1 (fr) Procede de preparation de l'acide d-2-(6-methoxy-2-naphtyl)-propionique
RO74500A (ro) Procedeu pentru purificarea de acid tereftalic
BE880865A (fr) Procede de purification d'acides dicarboxyliques obtenus par fermentation
FR2540861B1 (fr) Procede de preparation catalytique d'un acide carboxylique par carbonylation d'un alcool
RO82537A (ro) Procedeu pentru prepararea acidului diacetoncetugulonic
BE878774A (fr) Procede de preparation d'acides carboxyliques, principalement w (w -1) dihydroxyles
BE890350A (fr) Procede de production d'acide 0-(2,6-dichloranilino)phenylacetique
BE861693A (fr) Procede de reduction de l'acide 2,5-dicetogluconique
BE889169A (fr) Procede de preparation d'acide 2-methoxy-3-6-dichloro-benzoique
BE875593A (fr) Procede de purification d'olefines
BE880848A (fr) Catalyseur et procede de production d'acide methacrylique
BE876162A (fr) Procede de preparation de l'acide alpha-4-(4-chlorobenzoylamino-ethyl)-phenoxy)-isobutyrique
BE889661A (fr) Procede de preparation d'acide phosphorique par voie humide a teneur accrue en uranium
PT74813B (fr) Procede de preparation de derives de l'acide 1,4-thiazane-carboxylique
RO84498A (ro) Procedeu de obtinere a gazolinei din amestecurile apoase care le contin

Legal Events

Date Code Title Description
ST Notification of lapse
TP Transmission of property
AR Application made for restoration
BR Restoration of rights
ST Notification of lapse