FR2514034A1 - Procede de traitement de surface d'aciers contre l'usure et revetement obtenu - Google Patents
Procede de traitement de surface d'aciers contre l'usure et revetement obtenu Download PDFInfo
- Publication number
- FR2514034A1 FR2514034A1 FR8118780A FR8118780A FR2514034A1 FR 2514034 A1 FR2514034 A1 FR 2514034A1 FR 8118780 A FR8118780 A FR 8118780A FR 8118780 A FR8118780 A FR 8118780A FR 2514034 A1 FR2514034 A1 FR 2514034A1
- Authority
- FR
- France
- Prior art keywords
- layer
- wear
- molybdenum
- chromium
- sulfur
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000576 coating method Methods 0.000 title abstract description 20
- 239000011248 coating agent Substances 0.000 title abstract description 18
- 238000000034 method Methods 0.000 title abstract description 17
- 230000008569 process Effects 0.000 title abstract description 12
- 229910052717 sulfur Inorganic materials 0.000 abstract description 19
- 239000011593 sulfur Substances 0.000 abstract description 19
- 238000011282 treatment Methods 0.000 abstract description 19
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract description 18
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 9
- 229910052799 carbon Inorganic materials 0.000 abstract description 9
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 abstract description 5
- 239000005557 antagonist Substances 0.000 abstract description 4
- 239000012808 vapor phase Substances 0.000 abstract description 4
- 229910052976 metal sulfide Inorganic materials 0.000 abstract description 3
- 239000010410 layer Substances 0.000 description 43
- 229910000831 Steel Inorganic materials 0.000 description 23
- 239000010959 steel Substances 0.000 description 23
- 229910052750 molybdenum Inorganic materials 0.000 description 20
- 239000011651 chromium Substances 0.000 description 18
- 239000011733 molybdenum Substances 0.000 description 18
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 17
- 229910052804 chromium Inorganic materials 0.000 description 15
- 150000001247 metal acetylides Chemical class 0.000 description 13
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 12
- 238000000151 deposition Methods 0.000 description 10
- 239000012071 phase Substances 0.000 description 10
- 230000008021 deposition Effects 0.000 description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 7
- 239000000758 substrate Substances 0.000 description 7
- UFGZSIPAQKLCGR-UHFFFAOYSA-N chromium carbide Chemical compound [Cr]#C[Cr]C#[Cr] UFGZSIPAQKLCGR-UHFFFAOYSA-N 0.000 description 6
- DBULDCSVZCUQIR-UHFFFAOYSA-N chromium(3+);trisulfide Chemical compound [S-2].[S-2].[S-2].[Cr+3].[Cr+3] DBULDCSVZCUQIR-UHFFFAOYSA-N 0.000 description 6
- 239000002344 surface layer Substances 0.000 description 6
- 229910003470 tongbaite Inorganic materials 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 5
- 238000009826 distribution Methods 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- 241000920340 Pion Species 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- DSMZRNNAYQIMOM-UHFFFAOYSA-N iron molybdenum Chemical compound [Fe].[Fe].[Mo] DSMZRNNAYQIMOM-UHFFFAOYSA-N 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 description 3
- 239000002966 varnish Substances 0.000 description 3
- 229910000975 Carbon steel Inorganic materials 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 239000010962 carbon steel Substances 0.000 description 2
- 239000004568 cement Substances 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- ADULOCGXJMPDRK-UHFFFAOYSA-N iron;sulfanylidenemolybdenum Chemical compound [Fe].[Mo]=S ADULOCGXJMPDRK-UHFFFAOYSA-N 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 230000003068 static effect Effects 0.000 description 2
- PTISTKLWEJDJID-UHFFFAOYSA-N sulfanylidenemolybdenum Chemical compound [Mo]=S PTISTKLWEJDJID-UHFFFAOYSA-N 0.000 description 2
- 150000004763 sulfides Chemical group 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229910001149 41xx steel Inorganic materials 0.000 description 1
- 101100361281 Caenorhabditis elegans rpm-1 gene Proteins 0.000 description 1
- 229910000640 Fe alloy Inorganic materials 0.000 description 1
- MBMLMWLHJBBADN-UHFFFAOYSA-N Ferrous sulfide Chemical compound [Fe]=S MBMLMWLHJBBADN-UHFFFAOYSA-N 0.000 description 1
- 101100009348 Mus musculus Depp1 gene Proteins 0.000 description 1
- 101100009350 Rattus norvegicus Depp gene Proteins 0.000 description 1
- 229910001315 Tool steel Inorganic materials 0.000 description 1
- XTEFNZKRAXWISF-UHFFFAOYSA-N [Mo+4].[S-2].[Cr+3] Chemical compound [Mo+4].[S-2].[Cr+3] XTEFNZKRAXWISF-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- -1 chromium carbides Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 238000005088 metallography Methods 0.000 description 1
- 229910052982 molybdenum disulfide Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 238000000682 scanning probe acoustic microscopy Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- RPBNQQGUJBCUGO-UHFFFAOYSA-N sulfanylidenechromium Chemical compound [S].[Cr] RPBNQQGUJBCUGO-UHFFFAOYSA-N 0.000 description 1
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 238000005496 tempering Methods 0.000 description 1
- 230000003313 weakening effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C12/00—Solid state diffusion of at least one non-metal element other than silicon and at least one metal element or silicon into metallic material surfaces
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12535—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.] with additional, spatially distinct nonmetal component
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12535—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.] with additional, spatially distinct nonmetal component
- Y10T428/12576—Boride, carbide or nitride component
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12535—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.] with additional, spatially distinct nonmetal component
- Y10T428/12597—Noncrystalline silica or noncrystalline plural-oxide component [e.g., glass, etc.]
- Y10T428/12604—Film [e.g., glaze, etc.]
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physical Vapour Deposition (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR8118780A FR2514034A1 (fr) | 1981-10-06 | 1981-10-06 | Procede de traitement de surface d'aciers contre l'usure et revetement obtenu |
| US06/428,661 US4435227A (en) | 1981-10-06 | 1982-09-30 | Method of treating steel surfaces to prevent wear, and coating obtained thereby |
| EP82401774A EP0076745B1 (fr) | 1981-10-06 | 1982-09-30 | Procédé de traitement de surface d'aciers contre l'usure et revêtement obtenu |
| DE8282401774T DE3267828D1 (en) | 1981-10-06 | 1982-09-30 | Process for treating the surfaces of steels against wear, and coating obtained |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR8118780A FR2514034A1 (fr) | 1981-10-06 | 1981-10-06 | Procede de traitement de surface d'aciers contre l'usure et revetement obtenu |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2514034A1 true FR2514034A1 (fr) | 1983-04-08 |
| FR2514034B1 FR2514034B1 (enExample) | 1984-07-20 |
Family
ID=9262784
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR8118780A Granted FR2514034A1 (fr) | 1981-10-06 | 1981-10-06 | Procede de traitement de surface d'aciers contre l'usure et revetement obtenu |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US4435227A (enExample) |
| EP (1) | EP0076745B1 (enExample) |
| DE (1) | DE3267828D1 (enExample) |
| FR (1) | FR2514034A1 (enExample) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6042949A (en) * | 1998-01-21 | 2000-03-28 | Materials Innovation, Inc. | High strength steel powder, method for the production thereof and method for producing parts therefrom |
| CN114196954A (zh) * | 2021-12-07 | 2022-03-18 | 中国第一汽车股份有限公司 | 一种复合渗硫层及其制备方法和应用 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH365921A (de) * | 1958-11-04 | 1962-11-30 | Berghaus Elektrophysik Anst | Verfahren zur Behandlung der Oberfläche von Metallkörpern |
| FR1535457A (fr) * | 1966-11-30 | 1968-08-09 | Applic Des Traitements De Surf | Bains ignés pour le traitement des surfaces métalliques |
| FR2093559A5 (enExample) * | 1970-05-21 | 1972-01-28 | Kito Kk |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2243787A (en) | 1938-06-30 | 1941-05-27 | Allegheny Ludlum Steel | Colored steel |
| US3769098A (en) | 1971-05-19 | 1973-10-30 | Kito Kk | Process of manufacturing fine powders of metal halide |
| US3987222A (en) | 1975-06-20 | 1976-10-19 | Petr Mikhailovich Verkhovykh | Method of surface-strengthening of steel parts working in abrasion |
-
1981
- 1981-10-06 FR FR8118780A patent/FR2514034A1/fr active Granted
-
1982
- 1982-09-30 EP EP82401774A patent/EP0076745B1/fr not_active Expired
- 1982-09-30 US US06/428,661 patent/US4435227A/en not_active Expired - Lifetime
- 1982-09-30 DE DE8282401774T patent/DE3267828D1/de not_active Expired
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH365921A (de) * | 1958-11-04 | 1962-11-30 | Berghaus Elektrophysik Anst | Verfahren zur Behandlung der Oberfläche von Metallkörpern |
| FR1535457A (fr) * | 1966-11-30 | 1968-08-09 | Applic Des Traitements De Surf | Bains ignés pour le traitement des surfaces métalliques |
| FR2093559A5 (enExample) * | 1970-05-21 | 1972-01-28 | Kito Kk |
Also Published As
| Publication number | Publication date |
|---|---|
| US4435227A (en) | 1984-03-06 |
| EP0076745B1 (fr) | 1985-12-04 |
| DE3267828D1 (en) | 1986-01-16 |
| FR2514034B1 (enExample) | 1984-07-20 |
| EP0076745A1 (fr) | 1983-04-13 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| ST | Notification of lapse |