FR2492819A1 - Activeur d'agent de blanchiment apte a liberer de l'oxygene actif - Google Patents
Activeur d'agent de blanchiment apte a liberer de l'oxygene actif Download PDFInfo
- Publication number
- FR2492819A1 FR2492819A1 FR8022754A FR8022754A FR2492819A1 FR 2492819 A1 FR2492819 A1 FR 2492819A1 FR 8022754 A FR8022754 A FR 8022754A FR 8022754 A FR8022754 A FR 8022754A FR 2492819 A1 FR2492819 A1 FR 2492819A1
- Authority
- FR
- France
- Prior art keywords
- active oxygen
- activator
- bleaching
- hydrogen
- amidine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000012190 activator Substances 0.000 title abstract description 18
- 229910052760 oxygen Inorganic materials 0.000 title abstract description 14
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title abstract description 13
- 239000001301 oxygen Substances 0.000 title abstract description 13
- 239000003795 chemical substances by application Substances 0.000 title abstract description 6
- 206010033546 Pallor Diseases 0.000 title 1
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 abstract description 23
- 150000001409 amidines Chemical group 0.000 abstract description 16
- 239000007844 bleaching agent Substances 0.000 abstract description 12
- 239000007787 solid Substances 0.000 abstract description 10
- 229910052500 inorganic mineral Inorganic materials 0.000 abstract description 8
- 239000011707 mineral Substances 0.000 abstract description 8
- 239000002253 acid Substances 0.000 abstract description 5
- 229910052736 halogen Inorganic materials 0.000 abstract description 5
- 150000002367 halogens Chemical class 0.000 abstract description 5
- 239000001257 hydrogen Substances 0.000 abstract description 5
- 229910052739 hydrogen Inorganic materials 0.000 abstract description 5
- 239000007788 liquid Substances 0.000 abstract description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical group [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract description 3
- 238000004900 laundering Methods 0.000 abstract description 3
- 239000002689 soil Substances 0.000 abstract description 2
- 238000004061 bleaching Methods 0.000 description 16
- 239000000203 mixture Substances 0.000 description 16
- 238000005406 washing Methods 0.000 description 9
- 150000001875 compounds Chemical class 0.000 description 8
- 238000012360 testing method Methods 0.000 description 8
- BGRWYDHXPHLNKA-UHFFFAOYSA-N Tetraacetylethylenediamine Chemical compound CC(=O)N(C(C)=O)CCN(C(C)=O)C(C)=O BGRWYDHXPHLNKA-UHFFFAOYSA-N 0.000 description 7
- -1 cetylethylene diamine Chemical class 0.000 description 7
- 239000003599 detergent Substances 0.000 description 7
- 230000004913 activation Effects 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 235000010755 mineral Nutrition 0.000 description 6
- 241001122767 Theaceae Species 0.000 description 5
- 150000002978 peroxides Chemical class 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- 229960001922 sodium perborate Drugs 0.000 description 5
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 4
- 125000003118 aryl group Chemical group 0.000 description 4
- 239000000460 chlorine Substances 0.000 description 4
- 125000000753 cycloalkyl group Chemical group 0.000 description 4
- 239000004744 fabric Substances 0.000 description 4
- 229920000742 Cotton Polymers 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 3
- 229920000388 Polyphosphate Polymers 0.000 description 3
- 230000003213 activating effect Effects 0.000 description 3
- 239000008186 active pharmaceutical agent Substances 0.000 description 3
- 125000002877 alkyl aryl group Chemical group 0.000 description 3
- 239000012736 aqueous medium Substances 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 238000001802 infusion Methods 0.000 description 3
- 150000007522 mineralic acids Chemical class 0.000 description 3
- 239000001205 polyphosphate Substances 0.000 description 3
- 235000011176 polyphosphates Nutrition 0.000 description 3
- 229920002994 synthetic fiber Polymers 0.000 description 3
- 230000002087 whitening effect Effects 0.000 description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- 229910002651 NO3 Inorganic materials 0.000 description 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- 125000002252 acyl group Chemical group 0.000 description 2
- 239000012670 alkaline solution Substances 0.000 description 2
- 125000000320 amidine group Chemical group 0.000 description 2
- 239000007853 buffer solution Substances 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- RYTLGWCJESCDMY-UHFFFAOYSA-N carbamimidoyl chloride Chemical compound NC(Cl)=N RYTLGWCJESCDMY-UHFFFAOYSA-N 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 150000002431 hydrogen Chemical group 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 229910052740 iodine Inorganic materials 0.000 description 2
- 238000010409 ironing Methods 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 235000017550 sodium carbonate Nutrition 0.000 description 2
- 229940045872 sodium percarbonate Drugs 0.000 description 2
- 238000006467 substitution reaction Methods 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- 235000014101 wine Nutrition 0.000 description 2
- CNPURSDMOWDNOQ-UHFFFAOYSA-N 4-methoxy-7h-pyrrolo[2,3-d]pyrimidin-2-amine Chemical compound COC1=NC(N)=NC2=C1C=CN2 CNPURSDMOWDNOQ-UHFFFAOYSA-N 0.000 description 1
- MVXMNHYVCLMLDD-UHFFFAOYSA-N 4-methoxynaphthalene-1-carbaldehyde Chemical compound C1=CC=C2C(OC)=CC=C(C=O)C2=C1 MVXMNHYVCLMLDD-UHFFFAOYSA-N 0.000 description 1
- OQLZINXFSUDMHM-UHFFFAOYSA-N Acetamidine Chemical compound CC(N)=N OQLZINXFSUDMHM-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 1
- 102100031680 Beta-catenin-interacting protein 1 Human genes 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- PNKUSGQVOMIXLU-UHFFFAOYSA-N Formamidine Chemical compound NC=N PNKUSGQVOMIXLU-UHFFFAOYSA-N 0.000 description 1
- 101000993469 Homo sapiens Beta-catenin-interacting protein 1 Proteins 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-N Hydrogen bromide Chemical compound Br CPELXLSAUQHCOX-UHFFFAOYSA-N 0.000 description 1
- KQJQICVXLJTWQD-UHFFFAOYSA-N N-Methylthiourea Chemical compound CNC(N)=S KQJQICVXLJTWQD-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- XPOLVIIHTDKJRY-UHFFFAOYSA-N acetic acid;methanimidamide Chemical compound NC=N.CC(O)=O XPOLVIIHTDKJRY-UHFFFAOYSA-N 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 150000004982 aromatic amines Chemical class 0.000 description 1
- 150000001642 boronic acid derivatives Chemical class 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 239000000872 buffer Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- YPNWGLNCDBBKNX-UHFFFAOYSA-N carbamimidoyl bromide Chemical compound NC(Br)=N YPNWGLNCDBBKNX-UHFFFAOYSA-N 0.000 description 1
- YDNRLDHAFJJVLQ-UHFFFAOYSA-N carbamimidoyl chloride;sulfuric acid Chemical compound NC(Cl)=N.OS(O)(=O)=O YDNRLDHAFJJVLQ-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000002361 compost Substances 0.000 description 1
- 229920001577 copolymer Chemical group 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- WCQOBLXWLRDEQA-UHFFFAOYSA-N ethanimidamide;hydrochloride Chemical compound Cl.CC(N)=N WCQOBLXWLRDEQA-UHFFFAOYSA-N 0.000 description 1
- DLFVBJFMPXGRIB-UHFFFAOYSA-M ethanimidate Chemical compound CC([O-])=N DLFVBJFMPXGRIB-UHFFFAOYSA-M 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 125000001841 imino group Chemical group [H]N=* 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- MRJONIFKDTYEKI-UHFFFAOYSA-N n-chloroformamide;hydrochloride Chemical compound Cl.ClNC=O MRJONIFKDTYEKI-UHFFFAOYSA-N 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 125000005429 oxyalkyl group Chemical group 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 235000020095 red wine Nutrition 0.000 description 1
- 230000009919 sequestration Effects 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- MBEGFNBBAVRKLK-UHFFFAOYSA-N sodium;iminomethylideneazanide Chemical compound [Na+].[NH-]C#N MBEGFNBBAVRKLK-UHFFFAOYSA-N 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 239000004758 synthetic textile Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 125000004001 thioalkyl group Chemical group 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
- 238000003911 water pollution Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3907—Organic compounds
- C11D3/3917—Nitrogen-containing compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR8022754A FR2492819A1 (fr) | 1980-10-24 | 1980-10-24 | Activeur d'agent de blanchiment apte a liberer de l'oxygene actif |
| US06/309,503 US4451384A (en) | 1980-10-24 | 1981-10-07 | Haloformamidines bleaching agent activator functioning to release active oxygen |
| EP81401576A EP0051508B1 (fr) | 1980-10-24 | 1981-10-13 | Compositions de blanchiment |
| DE8181401576T DE3166859D1 (en) | 1980-10-24 | 1981-10-13 | Bleaching compositions |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR8022754A FR2492819A1 (fr) | 1980-10-24 | 1980-10-24 | Activeur d'agent de blanchiment apte a liberer de l'oxygene actif |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2492819A1 true FR2492819A1 (fr) | 1982-04-30 |
| FR2492819B1 FR2492819B1 (Direct) | 1983-09-16 |
Family
ID=9247266
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR8022754A Granted FR2492819A1 (fr) | 1980-10-24 | 1980-10-24 | Activeur d'agent de blanchiment apte a liberer de l'oxygene actif |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US4451384A (Direct) |
| EP (1) | EP0051508B1 (Direct) |
| DE (1) | DE3166859D1 (Direct) |
| FR (1) | FR2492819A1 (Direct) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4847089A (en) * | 1986-07-16 | 1989-07-11 | David N. Kramer | Cleansing and distinfecting compositions, including bleaching agents, and sponges and other applicators incorporating the same |
| US5584888A (en) * | 1994-08-31 | 1996-12-17 | Miracle; Gregory S. | Perhydrolysis-selective bleach activators |
| US5686015A (en) * | 1994-08-31 | 1997-11-11 | The Procter & Gamble Company | Quaternary substituted bleach activators |
| US5460747A (en) * | 1994-08-31 | 1995-10-24 | The Procter & Gamble Co. | Multiple-substituted bleach activators |
| US5653910A (en) * | 1995-06-07 | 1997-08-05 | Lever Brothers Company, Division Of Conopco Inc. | Bleaching compositions containing imine, hydrogen peroxide and a transition metal catalyst |
| DE19801049A1 (de) * | 1998-01-14 | 1999-07-15 | Clariant Gmbh | Verwendung von Formamidinium-Salzen als Bleichaktivatoren |
| DE102006018345A1 (de) * | 2006-04-19 | 2007-10-25 | Henkel Kgaa | Aufhell- und/oder Färbemittel mit Amidinen |
| DE102006028019A1 (de) * | 2006-06-14 | 2007-12-20 | Henkel Kgaa | Aufhell- und/oder Färbemittel mit Acetamidinen |
| DE102007058846A1 (de) * | 2007-12-05 | 2009-06-10 | Henkel Ag & Co. Kgaa | Wasch- oder Reinigungsmittel mit Amidinverbindungen und/oder Amidiniumbicarbonaten |
| CN108124902B (zh) * | 2017-11-24 | 2020-12-01 | 中国人民解放军陆军防化学院 | 复配型低腐蚀性生化消毒剂及其使用方法和应用 |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2147401A (en) * | 1933-11-09 | 1939-02-14 | Gen Aniline Works Inc | Water-soluble salts of amidines and derivatives thereof |
| US2211280A (en) * | 1937-07-08 | 1940-08-13 | Geigy Ag J R | Water-soluble nitrogenous compounds and a process for their manufacture |
| US2816077A (en) * | 1950-11-22 | 1957-12-10 | Saint Gobain | Method of cleaning deposits from hard surfaces |
| US2727922A (en) * | 1953-03-25 | 1955-12-20 | American Cyanamid Co | Halo-formamidine salts and method of preparation |
| US2845458A (en) * | 1956-05-21 | 1958-07-29 | American Cyanamid Co | C-chloro-n, n, n'-trimethylformamidine hydrochloride |
| US3487156A (en) * | 1962-03-08 | 1969-12-30 | Ciba Ltd | Combating insects,their eggs,or acarids on plants |
| US3299081A (en) * | 1963-09-13 | 1967-01-17 | Merck & Co Inc | Chemical processes for preparing nu-substituted amidines |
| US3445517A (en) * | 1966-06-03 | 1969-05-20 | Lilly Co Eli | Aryl acetamidines |
| US3428681A (en) * | 1966-09-01 | 1969-02-18 | Ansul Co | N-halotrichloroacetamidines |
| DE1915668A1 (de) * | 1969-03-27 | 1970-10-08 | Sueddeutsche Kalkstickstoff | Verfahren zur Herstellung von Halogenformamidiniumhalogeniden |
| JPS5088044A (Direct) * | 1973-12-01 | 1975-07-15 | ||
| US3986973A (en) * | 1975-10-24 | 1976-10-19 | American Cyanamid Company | Cyanoformates and cyanoformamides as bleach activators |
| US4202786A (en) * | 1978-12-22 | 1980-05-13 | Fmc Corporation | Peroxygen bleaching and compositions therefor |
| US4210551A (en) * | 1979-03-01 | 1980-07-01 | Fmc Corporation | Peroxygen bleaching and compositions therefor |
-
1980
- 1980-10-24 FR FR8022754A patent/FR2492819A1/fr active Granted
-
1981
- 1981-10-07 US US06/309,503 patent/US4451384A/en not_active Expired - Fee Related
- 1981-10-13 DE DE8181401576T patent/DE3166859D1/de not_active Expired
- 1981-10-13 EP EP81401576A patent/EP0051508B1/fr not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| EP0051508B1 (fr) | 1984-10-24 |
| EP0051508A1 (fr) | 1982-05-12 |
| DE3166859D1 (en) | 1984-11-29 |
| FR2492819B1 (Direct) | 1983-09-16 |
| US4451384A (en) | 1984-05-29 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| ST | Notification of lapse |