FR2444030A1 - Procede de carboxylation reductrice de composes heterocycliques azotes et nouveaux composes heterocycliques a groupes carboxylates - Google Patents

Procede de carboxylation reductrice de composes heterocycliques azotes et nouveaux composes heterocycliques a groupes carboxylates

Info

Publication number
FR2444030A1
FR2444030A1 FR7835491A FR7835491A FR2444030A1 FR 2444030 A1 FR2444030 A1 FR 2444030A1 FR 7835491 A FR7835491 A FR 7835491A FR 7835491 A FR7835491 A FR 7835491A FR 2444030 A1 FR2444030 A1 FR 2444030A1
Authority
FR
France
Prior art keywords
contg
electrolysis
oxide
carbon
aprotic solvent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7835491A
Other languages
English (en)
Other versions
FR2444030B3 (fr
Inventor
Daniel Michelet
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rhone Poulenc Industries SA
Original Assignee
Rhone Poulenc Industries SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rhone Poulenc Industries SA filed Critical Rhone Poulenc Industries SA
Priority to FR7835491A priority Critical patent/FR2444030A1/fr
Publication of FR2444030A1 publication Critical patent/FR2444030A1/fr
Application granted granted Critical
Publication of FR2444030B3 publication Critical patent/FR2444030B3/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/78—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
    • C07D213/79—Acids; Esters
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D215/00—Heterocyclic compounds containing quinoline or hydrogenated quinoline ring systems
    • C07D215/02—Heterocyclic compounds containing quinoline or hydrogenated quinoline ring systems having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen atoms or carbon atoms directly attached to the ring nitrogen atom
    • C07D215/16—Heterocyclic compounds containing quinoline or hydrogenated quinoline ring systems having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen atoms or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D215/48—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen
    • C07D215/50—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen attached in position 4
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D241/00—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings
    • C07D241/02—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings not condensed with other rings
    • C07D241/06—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings not condensed with other rings having one or two double bonds between ring members or between ring members and non-ring members
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D241/00—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings
    • C07D241/36—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings condensed with carbocyclic rings or ring systems
    • C07D241/38—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings condensed with carbocyclic rings or ring systems with only hydrogen or carbon atoms directly attached to the ring nitrogen atoms
    • C07D241/40—Benzopyrazines
    • C07D241/44—Benzopyrazines with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to carbon atoms of the hetero ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/04—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings directly linked by a ring-member-to-ring-member bond
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00—Electrolytic production of organic compounds
    • C25B3/20—Processes
    • C25B3/25—Reduction

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)

Abstract

Procédé de carboxylation réductrice de composés hétérocycliques azotés comportant au moins un atome d'azote triplement lié dans l'hétérocycle caractérisé en ce que l'on électrolyse ledit composé hétérocyclique dans le compartiment cathodique d'une cellule d'électrolyse divisée en deux compartiments par un diaphragme, entre les électrodes de laquelle est établie une différence de potentiel, au sein d'un électrolyte constitué par une solution d'un sel conducteur dans un solvant aprotique et en présence de gaz carbonique. Ce procédé permet de preparer des composés hétérocycliques azotés à groupes carboxyliques utilisables en synthèse organique.
FR7835491A 1978-12-12 1978-12-12 Procede de carboxylation reductrice de composes heterocycliques azotes et nouveaux composes heterocycliques a groupes carboxylates Granted FR2444030A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
FR7835491A FR2444030A1 (fr) 1978-12-12 1978-12-12 Procede de carboxylation reductrice de composes heterocycliques azotes et nouveaux composes heterocycliques a groupes carboxylates

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7835491A FR2444030A1 (fr) 1978-12-12 1978-12-12 Procede de carboxylation reductrice de composes heterocycliques azotes et nouveaux composes heterocycliques a groupes carboxylates

Publications (2)

Publication Number Publication Date
FR2444030A1 true FR2444030A1 (fr) 1980-07-11
FR2444030B3 FR2444030B3 (fr) 1981-09-04

Family

ID=9216230

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7835491A Granted FR2444030A1 (fr) 1978-12-12 1978-12-12 Procede de carboxylation reductrice de composes heterocycliques azotes et nouveaux composes heterocycliques a groupes carboxylates

Country Status (1)

Country Link
FR (1) FR2444030A1 (fr)

Also Published As

Publication number Publication date
FR2444030B3 (fr) 1981-09-04

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Legal Events

Date Code Title Description
ST Notification of lapse