FR2443489A1 - Composition antioxydante normalement liquide a base de composes o-hydrocarbylphenoliques et son application a la protection d'une matiere organique contre la degradation par oxydation - Google Patents
Composition antioxydante normalement liquide a base de composes o-hydrocarbylphenoliques et son application a la protection d'une matiere organique contre la degradation par oxydationInfo
- Publication number
- FR2443489A1 FR2443489A1 FR7929771A FR7929771A FR2443489A1 FR 2443489 A1 FR2443489 A1 FR 2443489A1 FR 7929771 A FR7929771 A FR 7929771A FR 7929771 A FR7929771 A FR 7929771A FR 2443489 A1 FR2443489 A1 FR 2443489A1
- Authority
- FR
- France
- Prior art keywords
- hydrocarbylphenolic
- oxidation
- protection
- organic material
- application
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K15/00—Anti-oxidant compositions; Compositions inhibiting chemical change
- C09K15/04—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds
- C09K15/06—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing oxygen
- C09K15/08—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing oxygen containing a phenol or quinone moiety
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/06—Well-defined aromatic compounds
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
- C10M2205/028—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers containing aliphatic monomers having more than four carbon atoms
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
- C10M2207/024—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings having at least two phenol groups but no condensed ring
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
- C10M2207/026—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with tertiary alkyl groups
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/281—Esters of (cyclo)aliphatic monocarboxylic acids
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- C10M2207/282—Esters of (cyclo)aliphatic oolycarboxylic acids
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
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- C10M2207/283—Esters of polyhydroxy compounds
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- C10M2207/28—Esters
- C10M2207/286—Esters of polymerised unsaturated acids
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- C10M2207/287—Partial esters
- C10M2207/289—Partial esters containing free hydroxy groups
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- C10M2207/30—Complex esters, i.e. compounds containing at leasst three esterified carboxyl groups and derived from the combination of at least three different types of the following five types of compounds: monohydroxyl compounds, polyhydroxy xompounds, monocarboxylic acids, polycarboxylic acids or hydroxy carboxylic acids
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- C10M2207/30—Complex esters, i.e. compounds containing at leasst three esterified carboxyl groups and derived from the combination of at least three different types of the following five types of compounds: monohydroxyl compounds, polyhydroxy xompounds, monocarboxylic acids, polycarboxylic acids or hydroxy carboxylic acids
- C10M2207/304—Complex esters, i.e. compounds containing at leasst three esterified carboxyl groups and derived from the combination of at least three different types of the following five types of compounds: monohydroxyl compounds, polyhydroxy xompounds, monocarboxylic acids, polycarboxylic acids or hydroxy carboxylic acids derived from the combination of monohydroxy compounds, dihydroxy compounds and dicarboxylic acids only and having no free hydroxy or carboxyl groups
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
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- C10M2207/34—Esters having a hydrocarbon substituent of thirty or more carbon atoms, e.g. substituted succinic acid derivatives
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
- C10M2209/084—Acrylate; Methacrylate
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/26—Amines
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- C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2217/046—Polyamines, i.e. macromoleculars obtained by condensation of more than eleven amine monomers
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- C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
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- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/046—Overbasedsulfonic acid salts
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
- C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
- C10M2219/085—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing carboxyl groups; Derivatives thereof
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
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- C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
- C10M2219/087—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Derivatives thereof, e.g. sulfurised phenols
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- C10M2219/088—Neutral salts
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- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
- C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
- C10M2219/087—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Derivatives thereof, e.g. sulfurised phenols
- C10M2219/089—Overbased salts
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- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
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- C10M2223/045—Metal containing thio derivatives
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/04—Groups 2 or 12
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/08—Resistance to extreme temperature
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/12—Gas-turbines
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/12—Gas-turbines
- C10N2040/13—Aircraft turbines
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Anti-Oxidant Or Stabilizer Compositions (AREA)
- Lubricants (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Fats And Perfumes (AREA)
- Fodder In General (AREA)
- Edible Oils And Fats (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
L'invention concerne une composition antioxydante. Une matière organique est stabilisée contre la dégradation par voie d'oxydation par l'addition d'une petite quantité d'un composé antioxydant ou d'un mélange de composés antioxydants renfermant un segment central formé d'un à environ dix groupes o-hydrocarbylphénoliques divalents (par exemple o-tertio-butylphénol) liés entre eux par un pont méthylénique et portant à chaque extrémité des groupes 3,5-dihydrocarbyl-4-hydroxybenzyle terminaux. On les obtient en condensant d'abord un o-hydrocarbylphénol avec la formaldéhyde, puis en faisant réagir le produit intermédiaire avec un 2,6-dihydrocarbylphénol et le formaldéhyde Application à la protection d'un huile lubrifiante contre une dégradation graduelle par voie d'oxydation.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US05/966,028 US4222884A (en) | 1978-12-04 | 1978-12-04 | Antioxidant |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2443489A1 true FR2443489A1 (fr) | 1980-07-04 |
FR2443489B1 FR2443489B1 (fr) | 1985-03-15 |
Family
ID=25510836
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7929771A Granted FR2443489A1 (fr) | 1978-12-04 | 1979-12-04 | Composition antioxydante normalement liquide a base de composes o-hydrocarbylphenoliques et son application a la protection d'une matiere organique contre la degradation par oxydation |
Country Status (6)
Country | Link |
---|---|
US (1) | US4222884A (fr) |
JP (1) | JPS5589384A (fr) |
CA (1) | CA1120703A (fr) |
DE (1) | DE2948764C2 (fr) |
FR (1) | FR2443489A1 (fr) |
GB (1) | GB2041357B (fr) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0047649A2 (fr) * | 1980-09-08 | 1982-03-17 | The Electricity Council | Procédé de préparation d'un antioxydant; composition de polyoléfine ou de caoutchouc le contenant et câbles électriques formés à partir de celle-ci |
FR2551062A1 (fr) * | 1983-08-24 | 1985-03-01 | Ciba Geigy Ag | Polyphenols a liaisons en ortho, leur application en tant que stabilisants de matieres organiques, et compositions stabilisees renfermant de tels polyphenols |
Families Citing this family (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4278554A (en) * | 1978-12-04 | 1981-07-14 | Ethyl Corporation | Antioxidant |
US4532059A (en) * | 1982-11-25 | 1985-07-30 | Ciba-Geigy Corporation | Benzylated phenols |
US5039437A (en) * | 1987-10-08 | 1991-08-13 | Exxon Chemical Patents, Inc. | Alkyl phenol-formaldehyde condensates as lubricating oil additives |
US5213701A (en) * | 1989-03-16 | 1993-05-25 | Imperial Chemical Industries Plc | Composition containing an oligomeric 1,2,3-trihydroxybenzene additive |
US5024775A (en) * | 1989-11-06 | 1991-06-18 | Ethyl Corporation | Alkyl phenol stabilizer compositions for fuels and lubricants |
WO1993003123A1 (fr) * | 1991-08-09 | 1993-02-18 | The Lubrizol Corporation | Fluide fonctionnel comportant des triglycerides, des additifs inhibiteurs de detergents et des additifs de modification de la viscosite |
GB9810994D0 (en) * | 1998-05-22 | 1998-07-22 | Exxon Chemical Patents Inc | Additives and oil compositions |
US20050223631A1 (en) * | 2004-04-07 | 2005-10-13 | Graham Jackson | Fuel oil compositions |
EP1584673A1 (fr) * | 2004-04-07 | 2005-10-12 | Infineum International Limited | Compositions de carburants |
JP2009507837A (ja) * | 2005-09-12 | 2009-02-26 | フジフィルム・エレクトロニック・マテリアルズ・ユーエスエイ・インコーポレイテッド | 環状アルケン誘導体の分解を防止する添加剤 |
US7883639B2 (en) * | 2005-09-12 | 2011-02-08 | Fujifilm Electronic Materials, U.S.A., Inc. | Additives to prevent degradation of cyclic alkene derivatives |
DE102007031461A1 (de) * | 2007-07-05 | 2009-01-08 | Sappok, Manfred, Dipl.-Phys. Dr. | Verfahren zum Stabilisieren von Heizöl oder Dieselöl, insbesondere aus der Depolimerisation von kohlenwasserstoffhaltigen Rückständen |
EP2318477B1 (fr) * | 2008-07-08 | 2019-06-05 | FujiFilm Electronic Materials USA, Inc. | Additifs permettant de prévenir la dégradation des dérivés alcène cycliques |
US20150225660A1 (en) | 2011-11-23 | 2015-08-13 | Greenville Environmental Company Limited | Hydrocarbon fuel antioxidant and method of application thereof |
CN102746919B (zh) * | 2012-07-17 | 2014-04-02 | 黄河三角洲京博化工研究院有限公司 | 一种汽油辛烷值提升剂及其制备方法 |
KR102046699B1 (ko) | 2015-03-24 | 2019-11-19 | 코니카 미놀타 가부시키가이샤 | 폴리이미드계 광학 필름, 그의 제조 방법 및 유기 일렉트로루미네센스 디스플레이 |
US20190292362A1 (en) * | 2016-06-29 | 2019-09-26 | Holland Novochem Technical Coatings B.V. | Catalytically Active Radical Scavengers Based on Benzylic and Allylic Functionalities |
US20190256734A1 (en) * | 2016-06-29 | 2019-08-22 | Holland Novochem Technical Coatings B.V. | Adhesion promoter for coatings on metal surfaces |
Citations (3)
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US3255255A (en) * | 1961-12-04 | 1966-06-07 | Ethyl Corp | Preparation of phenolic compounds |
US3297575A (en) * | 1961-06-27 | 1967-01-10 | Ethyl Corp | Novel trinuclear phenols and compositions stabilized therewith |
US4053428A (en) * | 1975-01-13 | 1977-10-11 | The Lubrizol Corporation | Hydrocarbon-substituted methylol phenols |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2899394A (en) * | 1954-12-03 | 1959-08-11 | Composite antioxidants and process of | |
NL131910C (fr) * | 1960-07-11 | |||
NL266894A (fr) * | 1960-07-11 | |||
GB928169A (en) * | 1960-12-02 | 1963-06-06 | Distillers Co Yeast Ltd | Trinuclear phenol antioxidants |
DE1197469B (de) * | 1962-09-19 | 1965-07-29 | Bayer Ag | Verfahren zur Herstellung von mehrkernigen Polyphenolen |
US3211652A (en) * | 1962-12-03 | 1965-10-12 | Ethyl Corp | Phenolic compositions |
SU732232A1 (ru) * | 1976-06-14 | 1980-05-05 | Научно-исследовательский институт резиновых и латексных изделий | Способ получени пространственно- затрудненных бис- или полифенолов |
-
1978
- 1978-12-04 US US05/966,028 patent/US4222884A/en not_active Expired - Lifetime
-
1979
- 1979-11-21 CA CA000340260A patent/CA1120703A/fr not_active Expired
- 1979-12-03 JP JP15670779A patent/JPS5589384A/ja active Granted
- 1979-12-04 DE DE2948764A patent/DE2948764C2/de not_active Expired
- 1979-12-04 FR FR7929771A patent/FR2443489A1/fr active Granted
- 1979-12-04 GB GB7941894A patent/GB2041357B/en not_active Expired
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3297575A (en) * | 1961-06-27 | 1967-01-10 | Ethyl Corp | Novel trinuclear phenols and compositions stabilized therewith |
US3255255A (en) * | 1961-12-04 | 1966-06-07 | Ethyl Corp | Preparation of phenolic compounds |
US4053428A (en) * | 1975-01-13 | 1977-10-11 | The Lubrizol Corporation | Hydrocarbon-substituted methylol phenols |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0047649A2 (fr) * | 1980-09-08 | 1982-03-17 | The Electricity Council | Procédé de préparation d'un antioxydant; composition de polyoléfine ou de caoutchouc le contenant et câbles électriques formés à partir de celle-ci |
EP0047649A3 (en) * | 1980-09-08 | 1982-03-24 | The Electricity Council | Process for preparing an antioxidant, polyolefin or rubber composition including prepared antioxidant and electric cable formed therefrom |
FR2551062A1 (fr) * | 1983-08-24 | 1985-03-01 | Ciba Geigy Ag | Polyphenols a liaisons en ortho, leur application en tant que stabilisants de matieres organiques, et compositions stabilisees renfermant de tels polyphenols |
Also Published As
Publication number | Publication date |
---|---|
JPS5754069B2 (fr) | 1982-11-16 |
DE2948764C2 (de) | 1986-09-25 |
US4222884A (en) | 1980-09-16 |
GB2041357B (en) | 1983-05-25 |
GB2041357A (en) | 1980-09-10 |
DE2948764A1 (de) | 1980-06-12 |
FR2443489B1 (fr) | 1985-03-15 |
CA1120703A (fr) | 1982-03-30 |
JPS5589384A (en) | 1980-07-05 |
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