FR2442835A1 - Nouveaux complexes peroxydiques du platine et du palladium, leur procede de fabrication et leur utilisation comme reactifs selectifs d'oxydation et de deshydrogenation oxydante - Google Patents
Nouveaux complexes peroxydiques du platine et du palladium, leur procede de fabrication et leur utilisation comme reactifs selectifs d'oxydation et de deshydrogenation oxydanteInfo
- Publication number
- FR2442835A1 FR2442835A1 FR7834052A FR7834052A FR2442835A1 FR 2442835 A1 FR2442835 A1 FR 2442835A1 FR 7834052 A FR7834052 A FR 7834052A FR 7834052 A FR7834052 A FR 7834052A FR 2442835 A1 FR2442835 A1 FR 2442835A1
- Authority
- FR
- France
- Prior art keywords
- platinum
- oxidant
- manufacture
- complexes
- selective oxidation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 title abstract 6
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical class [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 title abstract 5
- 229910052697 platinum Inorganic materials 0.000 title abstract 3
- 239000003153 chemical reaction reagent Substances 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 230000003647 oxidation Effects 0.000 title abstract 2
- 238000007254 oxidation reaction Methods 0.000 title abstract 2
- 150000002978 peroxides Chemical class 0.000 title abstract 2
- 238000006356 dehydrogenation reaction Methods 0.000 title 1
- 238000004519 manufacturing process Methods 0.000 title 1
- 239000007800 oxidant agent Substances 0.000 title 1
- 230000001590 oxidative effect Effects 0.000 title 1
- 238000006243 chemical reaction Methods 0.000 abstract 2
- 229910052763 palladium Inorganic materials 0.000 abstract 2
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- 150000001336 alkenes Chemical class 0.000 abstract 1
- 150000001450 anions Chemical class 0.000 abstract 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 abstract 1
- 150000003997 cyclic ketones Chemical class 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002576 ketones Chemical class 0.000 abstract 1
- 238000005839 oxidative dehydrogenation reaction Methods 0.000 abstract 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical compound OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
- C07F15/0013—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
- C07C37/06—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by conversion of non-aromatic six-membered rings or of such rings formed in situ into aromatic six-membered rings, e.g. by dehydrogenation
- C07C37/07—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by conversion of non-aromatic six-membered rings or of such rings formed in situ into aromatic six-membered rings, e.g. by dehydrogenation with simultaneous reduction of C=O group in that ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/28—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of CHx-moieties
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/30—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with halogen containing compounds, e.g. hypohalogenation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
- C07C45/65—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by splitting-off hydrogen atoms or functional groups; by hydrogenolysis of functional groups
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Abstract
L'invention concerne des nouveaux complexes peroxydiques du platine et du palladium ainsi qu'une méthode de préparation de ces nouveaux complexes. Les nouveaux complexes ont pour formule : ØØAõM-O-O-Rõ n dans laquelle ØAõ est un anion d'un acide carboxylique ou sulfonique, M est le platine ou le palladium, R est un radical hydrocarboné et n un nombre entier égal à 1, 2 ou 3. Ces complexes peuvent notamment être utilisés comme réactifs dans les réactions d'oxydation d'oléfines en cétones et dans les réactions de deshydrogénation oxydante de cétones cycliques.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7834052A FR2442835A1 (fr) | 1978-11-30 | 1978-11-30 | Nouveaux complexes peroxydiques du platine et du palladium, leur procede de fabrication et leur utilisation comme reactifs selectifs d'oxydation et de deshydrogenation oxydante |
GB7941206A GB2036742B (en) | 1978-11-30 | 1979-11-29 | Peroxide complexes of platinum and palladium their production and their use as selective oxidation dehydrogenation reagents |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7834052A FR2442835A1 (fr) | 1978-11-30 | 1978-11-30 | Nouveaux complexes peroxydiques du platine et du palladium, leur procede de fabrication et leur utilisation comme reactifs selectifs d'oxydation et de deshydrogenation oxydante |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2442835A1 true FR2442835A1 (fr) | 1980-06-27 |
FR2442835B1 FR2442835B1 (fr) | 1981-07-10 |
Family
ID=9215634
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7834052A Granted FR2442835A1 (fr) | 1978-11-30 | 1978-11-30 | Nouveaux complexes peroxydiques du platine et du palladium, leur procede de fabrication et leur utilisation comme reactifs selectifs d'oxydation et de deshydrogenation oxydante |
Country Status (2)
Country | Link |
---|---|
FR (1) | FR2442835A1 (fr) |
GB (1) | GB2036742B (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0053847A1 (fr) * | 1980-12-04 | 1982-06-16 | Stamicarbon B.V. | Procédé pour la préparation du cyclohexanol et/ou du cyclohexanone |
-
1978
- 1978-11-30 FR FR7834052A patent/FR2442835A1/fr active Granted
-
1979
- 1979-11-29 GB GB7941206A patent/GB2036742B/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0053847A1 (fr) * | 1980-12-04 | 1982-06-16 | Stamicarbon B.V. | Procédé pour la préparation du cyclohexanol et/ou du cyclohexanone |
Also Published As
Publication number | Publication date |
---|---|
FR2442835B1 (fr) | 1981-07-10 |
GB2036742A (en) | 1980-07-02 |
GB2036742B (en) | 1983-03-09 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
ST | Notification of lapse |