FR2440914A1 - Metal-contg. ZSM-5 type zeolites - useful as hydrocarbon conversion catalysts - Google Patents

Metal-contg. ZSM-5 type zeolites - useful as hydrocarbon conversion catalysts

Info

Publication number
FR2440914A1
FR2440914A1 FR7831803A FR7831803A FR2440914A1 FR 2440914 A1 FR2440914 A1 FR 2440914A1 FR 7831803 A FR7831803 A FR 7831803A FR 7831803 A FR7831803 A FR 7831803A FR 2440914 A1 FR2440914 A1 FR 2440914A1
Authority
FR
France
Prior art keywords
zeolites
metal
zsm
contg
useful
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7831803A
Other languages
French (fr)
Other versions
FR2440914B1 (en
Inventor
Roger Allan Morrison
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Oil Corp
Original Assignee
Mobil Oil Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mobil Oil Corp filed Critical Mobil Oil Corp
Priority to FR7831803A priority Critical patent/FR2440914A1/en
Publication of FR2440914A1 publication Critical patent/FR2440914A1/en
Application granted granted Critical
Publication of FR2440914B1 publication Critical patent/FR2440914B1/fr
Granted legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0254—Nitrogen containing compounds on mineral substrates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/405—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • B01J29/44—Noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/48—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing arsenic, antimony, bismuth, vanadium, niobium tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2702—Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously
    • C07C5/2708—Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously with crystalline alumino-silicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/08—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond
    • C07C6/12—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring
    • C07C6/123—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring of only one hydrocarbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/37—Acid treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/40—Special temperature treatment, i.e. other than just for template removal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0239—Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Catalysts (AREA)

Abstract

New zeolites are characterised by their molar compsn. and by their X-ray diffraction pattern (which is characteristic of ZSM-5 zeolites). The molar compsn. in the anhydrous state is (R2O,M2'/nO)w:(Al2O3)x:(SiO2)y:(M"2/nO)z (where 0.5 w/y 3;y/x> 20;0 z/x 100; R is a N-contg. cation, pref. tetra (2-5C alkyl)ammonium; M' is an alkali metal; M" is In, B, Ru, Pt, Cr, a rare earth metal, V, Pd, Mo, Hg, Te and/or Ag; n is the valence of M' or M"). Also claimed are zeolites with the above compsn. in which R and/or M' are replaced by alkylammonium, metal, NH4 and/or H cations, as well as products obtd. by heat treating these zeolites at >260 degrees C. The zeolites are useful as hydrocarbon conversion catalysts, e.g. for cracking, hydrocracking, isomerisation, olefin polymerisation, reforming, alkylation, toluene disproportion, and conversion of methanol to hydrocarbons (esp. p-xylene). They have high selectivity and stability.
FR7831803A 1978-11-10 1978-11-10 Metal-contg. ZSM-5 type zeolites - useful as hydrocarbon conversion catalysts Granted FR2440914A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
FR7831803A FR2440914A1 (en) 1978-11-10 1978-11-10 Metal-contg. ZSM-5 type zeolites - useful as hydrocarbon conversion catalysts

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7831803A FR2440914A1 (en) 1978-11-10 1978-11-10 Metal-contg. ZSM-5 type zeolites - useful as hydrocarbon conversion catalysts

Publications (2)

Publication Number Publication Date
FR2440914A1 true FR2440914A1 (en) 1980-06-06
FR2440914B1 FR2440914B1 (en) 1984-01-20

Family

ID=9214707

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7831803A Granted FR2440914A1 (en) 1978-11-10 1978-11-10 Metal-contg. ZSM-5 type zeolites - useful as hydrocarbon conversion catalysts

Country Status (1)

Country Link
FR (1) FR2440914A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0434052A2 (en) * 1989-12-22 1991-06-26 Haldor Topsoe A/S Modified crystalline aluminosilicate and method of preparing the same
FR2688775A1 (en) * 1992-03-20 1993-09-24 Elf Aquitaine MFI TYPE ZEOLITHE COMPRISING VANADIUM SA SYNTHESIS AND ITS USE AS AN OXIDATION CATALYST.

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3687839A (en) * 1970-12-22 1972-08-29 Mobil Oil Corp Conversion with synthetic crystalline zeolite
FR2272034A1 (en) * 1973-09-28 1975-12-19 Shell Int Research
FR2369997A1 (en) * 1976-11-04 1978-06-02 Mobil Oil ALUMINOSILICATE TYPE CRYSTALLINE ZEOLITE
US4105541A (en) * 1977-06-20 1978-08-08 Mobil Oil Corporation Hydrocarbon conversion over zsm-38

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3687839A (en) * 1970-12-22 1972-08-29 Mobil Oil Corp Conversion with synthetic crystalline zeolite
FR2272034A1 (en) * 1973-09-28 1975-12-19 Shell Int Research
FR2369997A1 (en) * 1976-11-04 1978-06-02 Mobil Oil ALUMINOSILICATE TYPE CRYSTALLINE ZEOLITE
US4105541A (en) * 1977-06-20 1978-08-08 Mobil Oil Corporation Hydrocarbon conversion over zsm-38

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0434052A2 (en) * 1989-12-22 1991-06-26 Haldor Topsoe A/S Modified crystalline aluminosilicate and method of preparing the same
EP0434052A3 (en) * 1989-12-22 1991-12-04 Haldor Topsoe A/S Modified crystalline aluminosilicate and method of preparing the same
AU626485B2 (en) * 1989-12-22 1992-07-30 Haldor Topsoe A/S Modified crystalline aluminosilicate and method of preparing the same
FR2688775A1 (en) * 1992-03-20 1993-09-24 Elf Aquitaine MFI TYPE ZEOLITHE COMPRISING VANADIUM SA SYNTHESIS AND ITS USE AS AN OXIDATION CATALYST.
WO1993019008A1 (en) * 1992-03-20 1993-09-30 Societe Nationale Elf Aquitaine Vanadium-containing mfi zeolite

Also Published As

Publication number Publication date
FR2440914B1 (en) 1984-01-20

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