FR2369997A1 - ALUMINOSILICATE TYPE CRYSTALLINE ZEOLITE - Google Patents

ALUMINOSILICATE TYPE CRYSTALLINE ZEOLITE

Info

Publication number
FR2369997A1
FR2369997A1 FR7732986A FR7732986A FR2369997A1 FR 2369997 A1 FR2369997 A1 FR 2369997A1 FR 7732986 A FR7732986 A FR 7732986A FR 7732986 A FR7732986 A FR 7732986A FR 2369997 A1 FR2369997 A1 FR 2369997A1
Authority
FR
France
Prior art keywords
crystalline zeolite
type crystalline
aluminosilicate type
aluminosilicate
zeolite
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7732986A
Other languages
French (fr)
Other versions
FR2369997B1 (en
Inventor
Edwin Neil Givens
Edward Joseph Rosinski
Charles Joseph Plank
Mae Koenig Rubin
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Oil Corp
Original Assignee
Mobil Oil Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US05/738,773 external-priority patent/US4079096A/en
Priority claimed from US05/738,771 external-priority patent/US4086186A/en
Application filed by Mobil Oil Corp filed Critical Mobil Oil Corp
Publication of FR2369997A1 publication Critical patent/FR2369997A1/en
Application granted granted Critical
Publication of FR2369997B1 publication Critical patent/FR2369997B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/30—Erionite or offretite type, e.g. zeolite T
    • C01B39/305—Erionite or offretite type, e.g. zeolite T using at least one organic template directing agent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/50—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the erionite or offretite type, e.g. zeolite T, as exemplified by patent document US2950952
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7049—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/12—Catalytic processes with crystalline alumino-silicates or with catalysts comprising molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C4/00—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms
    • C07C4/02—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by cracking a single hydrocarbon or a mixture of individually defined hydrocarbons or a normally gaseous hydrocarbon fraction
    • C07C4/06—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
    • C10G11/04—Oxides
    • C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/26—After treatment, characterised by the effect to be obtained to stabilize the total catalyst structure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/36—Steaming
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/50—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the eroionite or offretite type, e.g. zeolite T

Abstract

La présente invention a pour objet une zéolite cristalline de type aluminosilicate ayant la composition suivante, exprimée en rapports molaires d'oxydes :The present invention relates to a crystalline zeolite of aluminosilicate type having the following composition, expressed in molar ratios of oxides:

FR7732986A 1976-11-04 1977-11-03 ALUMINOSILICATE TYPE CRYSTALLINE ZEOLITE Granted FR2369997A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US05/738,773 US4079096A (en) 1976-11-04 1976-11-04 Manufacture of light olefins
US05/738,771 US4086186A (en) 1976-11-04 1976-11-04 Crystalline zeolite ZSM-34 and method of preparing the same

Publications (2)

Publication Number Publication Date
FR2369997A1 true FR2369997A1 (en) 1978-06-02
FR2369997B1 FR2369997B1 (en) 1982-02-05

Family

ID=27113414

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7732986A Granted FR2369997A1 (en) 1976-11-04 1977-11-03 ALUMINOSILICATE TYPE CRYSTALLINE ZEOLITE

Country Status (8)

Country Link
JP (1) JPS5914407B2 (en)
AU (1) AU510040B2 (en)
DE (1) DE2749024A1 (en)
FR (1) FR2369997A1 (en)
GB (1) GB1589856A (en)
IT (1) IT1087929B (en)
NL (1) NL181921C (en)
NZ (1) NZ185397A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2440914A1 (en) * 1978-11-10 1980-06-06 Mobil Oil Corp Metal-contg. ZSM-5 type zeolites - useful as hydrocarbon conversion catalysts
EP0083160A2 (en) * 1981-12-30 1983-07-06 Mobil Oil Corporation Catalyst and process for light olefin production
EP0106643A2 (en) * 1982-10-08 1984-04-25 Tosoh Corporation Novel zeolite and process for preparation thereof
FR2565575A1 (en) * 1984-06-07 1985-12-13 Inst Francais Du Petrole ZEOLITE OF THE OFFERING FAMILY AND METHOD OF MANUFACTURE
EP0203619A1 (en) * 1985-05-29 1986-12-03 Showa Shell Sekiyu Kabushiki Kaisha Production of liquid hydrocarbon from gas containing lower hydrocarbon

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4247416A (en) * 1979-02-28 1981-01-27 Mobil Oil Corporation Crystalline zeolite ZSM-25
NL7902021A (en) * 1979-03-14 1980-09-16 Shell Int Research METHOD FOR THE PREPARATION OF METHANE AND / OR ETHANE.
JPS577817A (en) * 1980-06-13 1982-01-16 Idemitsu Kosan Co Ltd Manufacture of crystalline zeolite
DE3134317A1 (en) * 1981-08-31 1983-03-10 Hoechst Ag, 6000 Frankfurt BORO ALUMOSILICATES WITH ZEOLITE STRUCTURE AND METHOD FOR THE PRODUCTION THEREOF
DE3136684A1 (en) * 1981-09-16 1983-04-21 Hoechst Ag, 6230 Frankfurt "GALLIUM- AND / OR INDIUM-CONTAINING ZEOLITES AND METHOD FOR THE PRODUCTION THEREOF AND THEIR USE"
DE3217322A1 (en) * 1982-05-08 1983-11-10 Hoechst Ag, 6230 Frankfurt CRYSTALLINE ALUMINOSILICATE ZEOLITE, METHOD FOR THE PRODUCTION THEREOF AND THEIR USE
DE3217324A1 (en) * 1982-05-08 1983-11-10 Hoechst Ag, 6230 Frankfurt TITANIUM-CONTAINING ZEOLITES AND METHOD FOR THE PRODUCTION THEREOF AND THEIR USE
DE3217323A1 (en) * 1982-05-08 1983-11-10 Hoechst Ag, 6230 Frankfurt ZIRCON AND / OR HAFNIUM-CONTAINING ZEOLITES AND METHOD FOR THE PRODUCTION THEREOF AND THEIR USE
DE3240870A1 (en) * 1982-11-05 1984-05-10 Hoechst Ag, 6230 Frankfurt ZEOLITES CONTAINING TITANIUM, ZIRCONIUM AND / OR HAFNIUM AND METHOD FOR THE PRODUCTION THEREOF AND THEIR USE
US4496786A (en) * 1983-09-30 1985-01-29 Chevron Research Company Selective conversion of methanol to low molecular weight olefins over high silica SSZ-13 zeolite
JPH0342097Y2 (en) * 1985-10-31 1991-09-04
EP1742874B1 (en) * 2004-04-20 2012-08-15 Uop Llc Uzm-16: a crystalline aluminosilicate zeolitic material
JP5902682B2 (en) * 2010-07-15 2016-04-13 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ Copper-containing ZSM-34, OFF and / or ERI zeolitic materials for selective reduction of NOx

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1592354A (en) * 1958-05-08 1970-05-11
US3578398A (en) * 1968-04-01 1971-05-11 Mobil Oil Corp Synthetic crystalline zeolite and preparation thereof
FR2066124A5 (en) * 1969-10-16 1971-08-06 Mobil Oil Corp
FR2078973A5 (en) * 1970-02-25 1971-11-05 Shell Int Research
GB1299016A (en) * 1970-06-12 1972-12-06 Bp Chem Int Ltd Hydrocarbon separation process
FR2156001A1 (en) * 1971-10-04 1973-05-25 Ici Ltd
US3758539A (en) * 1971-03-09 1973-09-11 Air Prod & Chem Offretite synthesis from minerals
FR2228721A1 (en) * 1973-05-07 1974-12-06 Mobil Oil ZSM-21 synthetic crystalline aluminosilicate zeolites - for use as hydrocarbon conversion catalysts
DE2511975A1 (en) * 1974-03-20 1975-09-25 Grace W R & Co PROCESS FOR MANUFACTURING ZEOLIGHEN WITH OPEN LATTICE STRUCTURE
BE840748A (en) * 1976-04-07 1976-10-14 NEW FORMS OF ZSM-4 ZEOLITES

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1592354A (en) * 1958-05-08 1970-05-11
US3578398A (en) * 1968-04-01 1971-05-11 Mobil Oil Corp Synthetic crystalline zeolite and preparation thereof
FR2066124A5 (en) * 1969-10-16 1971-08-06 Mobil Oil Corp
FR2078973A5 (en) * 1970-02-25 1971-11-05 Shell Int Research
GB1299016A (en) * 1970-06-12 1972-12-06 Bp Chem Int Ltd Hydrocarbon separation process
US3758539A (en) * 1971-03-09 1973-09-11 Air Prod & Chem Offretite synthesis from minerals
FR2156001A1 (en) * 1971-10-04 1973-05-25 Ici Ltd
FR2228721A1 (en) * 1973-05-07 1974-12-06 Mobil Oil ZSM-21 synthetic crystalline aluminosilicate zeolites - for use as hydrocarbon conversion catalysts
DE2511975A1 (en) * 1974-03-20 1975-09-25 Grace W R & Co PROCESS FOR MANUFACTURING ZEOLIGHEN WITH OPEN LATTICE STRUCTURE
BE840748A (en) * 1976-04-07 1976-10-14 NEW FORMS OF ZSM-4 ZEOLITES

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
EXBK/70 *

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2440914A1 (en) * 1978-11-10 1980-06-06 Mobil Oil Corp Metal-contg. ZSM-5 type zeolites - useful as hydrocarbon conversion catalysts
EP0083160A2 (en) * 1981-12-30 1983-07-06 Mobil Oil Corporation Catalyst and process for light olefin production
EP0083160A3 (en) * 1981-12-30 1985-05-22 Mobil Oil Corporation Catalyst and process for light olefin production
EP0106643A2 (en) * 1982-10-08 1984-04-25 Tosoh Corporation Novel zeolite and process for preparation thereof
EP0106643A3 (en) * 1982-10-08 1984-09-12 Toyo Soda Manufacturing Co., Ltd. Novel zeolite and process for preparation thereof
US4687653A (en) * 1982-10-08 1987-08-18 Toyo Soda Manufacturing Co., Ltd. Process for preparation of zeolite OE having an offretite type structure
FR2565575A1 (en) * 1984-06-07 1985-12-13 Inst Francais Du Petrole ZEOLITE OF THE OFFERING FAMILY AND METHOD OF MANUFACTURE
EP0203619A1 (en) * 1985-05-29 1986-12-03 Showa Shell Sekiyu Kabushiki Kaisha Production of liquid hydrocarbon from gas containing lower hydrocarbon

Also Published As

Publication number Publication date
DE2749024A1 (en) 1978-05-24
JPS5358499A (en) 1978-05-26
FR2369997B1 (en) 1982-02-05
JPS5914407B2 (en) 1984-04-04
GB1589856A (en) 1981-05-20
NL181921C (en) 1987-12-01
NL7712165A (en) 1978-05-08
AU510040B2 (en) 1980-06-05
NZ185397A (en) 1979-12-11
DE2749024C2 (en) 1987-03-26
NL181921B (en) 1987-07-01
AU3030077A (en) 1979-05-10
IT1087929B (en) 1985-06-04

Similar Documents

Publication Publication Date Title
FR2369997A1 (en) ALUMINOSILICATE TYPE CRYSTALLINE ZEOLITE
DE69020811D1 (en) Particulate detergent composition additive.
IT1168206B (en) SUBSTANTIALLY AMORPHOUS FORM OF ESTER OF CEFUROSSIMA, PROCEDURE TO PRODUCE IT WITH THE COMPOSITION THAT CONTAINS IT
DK202477A (en) LITTLE HYGIENE BIND
DE3887020D1 (en) Detergent compositions.
ATE37392T1 (en) DETERGENT COMPOSITIONS.
ATE54935T1 (en) DETERGENT COMPOSITIONS.
DE3585261D1 (en) FIXED DETERGENT COMPOSITIONS.
DE3874447D1 (en) ORAL ANTI-BACTERIAL TO BIGUANIDOHEXANE COMPOSITION.
AU2676977A (en) Manufacturing high corrosion resistant cement compositions
BR8804923A (en) DETERGENT COMPOSITION
IT8024827A0 (en) USE OF PYRIDOXINE ALPHA-KETOGLUTARATE IN THE PROPHYLAXIS OF HYPERLACTACIDEMIA.
DE3583608D1 (en) DIVISION OF AMORPHOUS ALLOYS BY HEAT.
BR8805250A (en) DETERGENT COMPOSITION
AU6422380A (en) Particulate alkaline detergent composition
EP0462598A3 (en) Transition metal-containing zeolite having high hydrothermal stability, production method thereof and method of using same
BR8805900A (en) DETERGENT COMPOSITION
GB2043051B (en) Intermediates useful in the synthesis of chemiluminescent naphthalene-1,2-dicarboxylic acid hydrazide-labelled conjugates
MX151812A (en) ALKALINE STRUCTURER-FREE DETERGENT COMPOSITION
DE3681213D1 (en) DETERGENT COMPOSITIONS.
DK245585A (en) PARTICULATE, BUILD-CONTAINING, NON-IONOGENT, SYNTHETIC DETERGENT
UA32404C2 (en) synthetic crystalline aluminum silicate
BR8400240A (en) DETERGENT COMPOSITION
DE68909615T2 (en) PHOSPHATE-FREE FULL DETERGENT COMPOSITION.
BE833909A (en) COMPOSITIONS FOR ORAL HYGIENE