FR2413396A1 - Procede de production de composes en n-phosphinylmethylglycine et nouveaux produits ainsi obtenus, utiles comme intermediaire pour des herbicides - Google Patents
Procede de production de composes en n-phosphinylmethylglycine et nouveaux produits ainsi obtenus, utiles comme intermediaire pour des herbicidesInfo
- Publication number
- FR2413396A1 FR2413396A1 FR7900054A FR7900054A FR2413396A1 FR 2413396 A1 FR2413396 A1 FR 2413396A1 FR 7900054 A FR7900054 A FR 7900054A FR 7900054 A FR7900054 A FR 7900054A FR 2413396 A1 FR2413396 A1 FR 2413396A1
- Authority
- FR
- France
- Prior art keywords
- phosphinylmethylglycine
- compounds
- production
- new products
- mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000004009 herbicide Substances 0.000 title abstract 2
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- OKBOBMRVKOVTJG-UHFFFAOYSA-N [PH2](=O)CNCC(=O)O Chemical class [PH2](=O)CNCC(=O)O OKBOBMRVKOVTJG-UHFFFAOYSA-N 0.000 title 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 4
- 239000000203 mixture Substances 0.000 abstract 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 2
- -1 N-phosphinylmethylglycine compound Chemical class 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 150000001768 cations Chemical group 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 239000007789 gas Substances 0.000 abstract 1
- XDDAORKBJWWYJS-UHFFFAOYSA-N glyphosate Chemical compound OC(=O)CNCP(O)(O)=O XDDAORKBJWWYJS-UHFFFAOYSA-N 0.000 abstract 1
- 230000002363 herbicidal effect Effects 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 229910052703 rhodium Inorganic materials 0.000 abstract 1
- 239000010948 rhodium Substances 0.000 abstract 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/48—Phosphonous acids [RP(OH)2] including [RHP(=O)(OH)]; Thiophosphonous acids including [RP(SH)2], [RHP(=S)(SH)]; Derivatives thereof
- C07F9/4808—Phosphonous acids [RP(OH)2] including [RHP(=O)(OH)]; Thiophosphonous acids including [RP(SH)2], [RHP(=S)(SH)]; Derivatives thereof the acid moiety containing a substituent or structure which is considered as characteristic
- C07F9/4816—Acyclic saturated acids or derivatices which can have further substituents on alkyl
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/46—Ruthenium, rhodium, osmium or iridium
- B01J23/464—Rhodium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/745—Iron
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Procédé de préparation de composé de N-phosphinylméthylglycine et nouveaux produits ainsi obtenus. Ces composés ont la formule : où M est l'hydrogène ou un cation et M1 est l'hydrogène ou un cation de métal alcalin, qui consiste à former un mélange d'un acide N-phosphinylméthylminodiacétique ayant la formule : où M et M1 sont tels que définis ci-dessus, avec de l'eau et un catalyseur se composant de carbone activé contenant 300 à 700 parties par million de fer, de rhodium sur du carbone activé ou sur de l'alumine, en maintenant ce mélange entre 15 et 45 C et en mettant en contact le mélange avec un gaz contenant de l'oxygène libre. La présente invention qui est un intermédiaire dans la production de N-phosphonométhylglycine employée comme herbicide.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US86666978A | 1978-01-03 | 1978-01-03 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| FR2413396A1 true FR2413396A1 (fr) | 1979-07-27 |
Family
ID=25348116
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR7900054A Withdrawn FR2413396A1 (fr) | 1978-01-03 | 1979-01-02 | Procede de production de composes en n-phosphinylmethylglycine et nouveaux produits ainsi obtenus, utiles comme intermediaire pour des herbicides |
Country Status (13)
| Country | Link |
|---|---|
| JP (1) | JPS54100325A (fr) |
| AR (1) | AR218097A1 (fr) |
| AU (1) | AU4304879A (fr) |
| BE (1) | BE873198A (fr) |
| BR (1) | BR7900008A (fr) |
| DD (1) | DD141024A5 (fr) |
| DE (1) | DE2900024A1 (fr) |
| ES (1) | ES476483A1 (fr) |
| FR (1) | FR2413396A1 (fr) |
| GB (1) | GB2011907A (fr) |
| IL (1) | IL56361A0 (fr) |
| NL (1) | NL7812636A (fr) |
| ZA (1) | ZA787348B (fr) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101824049B (zh) * | 2009-03-08 | 2013-05-29 | 李坚 | 磷化氢或次磷酸盐或亚磷酸盐在制备草甘膦中的应用 |
-
1978
- 1978-12-28 JP JP16599878A patent/JPS54100325A/ja active Pending
- 1978-12-28 ZA ZA00787348A patent/ZA787348B/xx unknown
- 1978-12-29 BE BE192663A patent/BE873198A/fr unknown
- 1978-12-29 NL NL7812636A patent/NL7812636A/xx not_active Application Discontinuation
- 1978-12-29 ES ES476483A patent/ES476483A1/es not_active Expired
-
1979
- 1979-01-02 FR FR7900054A patent/FR2413396A1/fr not_active Withdrawn
- 1979-01-02 IL IL56361A patent/IL56361A0/xx unknown
- 1979-01-02 GB GB7934A patent/GB2011907A/en not_active Withdrawn
- 1979-01-02 DD DD79210299A patent/DD141024A5/de unknown
- 1979-01-02 AR AR275037A patent/AR218097A1/es active
- 1979-01-02 BR BR7900008A patent/BR7900008A/pt unknown
- 1979-01-02 AU AU43048/79A patent/AU4304879A/en not_active Abandoned
- 1979-01-02 DE DE19792900024 patent/DE2900024A1/de not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| BE873198A (fr) | 1979-06-29 |
| AU4304879A (en) | 1979-07-12 |
| DE2900024A1 (de) | 1979-07-12 |
| JPS54100325A (en) | 1979-08-08 |
| ES476483A1 (es) | 1979-04-16 |
| NL7812636A (nl) | 1979-07-05 |
| GB2011907A (en) | 1979-07-18 |
| IL56361A0 (en) | 1979-03-12 |
| DD141024A5 (de) | 1980-04-09 |
| ZA787348B (en) | 1979-12-27 |
| AR218097A1 (es) | 1980-05-15 |
| BR7900008A (pt) | 1979-08-07 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| FR2374328A1 (fr) | Procede de production de sels de n-phosphonomethylglycine et nouveaux produits ainsi obtenus | |
| CA1204759A (fr) | Allyl amine inhibitrice de la mao | |
| FR2433500A1 (fr) | Procede de preparation du tetrafluorethane | |
| FR2429772A1 (fr) | Procede pour l'obtention d'acides arylpyruviques | |
| FR2395224A1 (fr) | Procede de fabrication de chlore | |
| FR2435460A1 (fr) | Procede pour preparer des composes biphenyliques | |
| FR2395246A1 (fr) | Procede d'hydroformylation catalytique | |
| FR2370228A1 (fr) | Procede de stockage de l'hydrogene sur un compose de nickel-calcium | |
| FR2444659A1 (fr) | Procede pour la preparation de la methacroleine | |
| FR2413396A1 (fr) | Procede de production de composes en n-phosphinylmethylglycine et nouveaux produits ainsi obtenus, utiles comme intermediaire pour des herbicides | |
| EP0337839B1 (fr) | Procédé de fabrication des dialkyldisulfures inférieurs | |
| FR2446816A1 (fr) | Procede pour la production d'acides diperoxyalcanedioiques stables au stockage et desensibilises, et compositions les contenant | |
| FR2356619A1 (fr) | Procede de purification du dibenzylidenesorbitol brut | |
| FR811736A (fr) | Procédé pour la préparation d'hydrogène par réaction d'oxyde de carbone ou de mélanges gazeux contenant de l'oxyde de carbone avec de la vapeur d'eau | |
| FR2428624A1 (fr) | Procede pour l'alkylation de composes phenoliques pour produire des phenols ortho- et para-mono-alkyles et des phenols 2,4 et 2,6 dialkyles | |
| FR2390417A1 (fr) | Procede de production de vinylcyclopropanecarboxylates de benzyle substitues | |
| FR2384733A1 (fr) | Procede de production de composes aromatiques a substituant nucleophile sur un noyau | |
| FR2434115A1 (fr) | Procede de separation du chlorure d'hydrogene et du bromure d'hydrogene | |
| FR2382438A1 (fr) | Procede de production de thiophenols et nouveaux produits ainsi obtenus | |
| FR2432476A1 (fr) | Procede d'obtention de chlorure d'hydrogene a partir d'acide chlorhydrique aqueux dilue | |
| FR2446251A1 (fr) | Production de production d'acide halogene par reaction d'halogene gazeux avec de l'eau en presence de carbone non graphitise ou d'un catalyseur du type titane associe a du ruthenium ou titane platine | |
| BE904662A (fr) | Derive antipsychotique du benzisothiazole s-oxyde. | |
| FR2429200A1 (fr) | Procede pour preparer du dimethylformamide | |
| FR2361355A1 (fr) | Procede pour l'obtention de nitriles d'acides alcoxymethylene-maloniques | |
| FR2368461A1 (fr) | Procede de preparation d'oxalates a partir d'oxyde de carbone et d'un alcoxycycloalcene |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| ST | Notification of lapse |