FR2411879A1 - CATALYTIC PROCESS FOR THE PREPARATION OF COMBUSTIBLE GAS FROM COAL - Google Patents

CATALYTIC PROCESS FOR THE PREPARATION OF COMBUSTIBLE GAS FROM COAL

Info

Publication number
FR2411879A1
FR2411879A1 FR7835607A FR7835607A FR2411879A1 FR 2411879 A1 FR2411879 A1 FR 2411879A1 FR 7835607 A FR7835607 A FR 7835607A FR 7835607 A FR7835607 A FR 7835607A FR 2411879 A1 FR2411879 A1 FR 2411879A1
Authority
FR
France
Prior art keywords
coal
sites
preparation
group
combustible gas
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
FR7835607A
Other languages
French (fr)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
Exxon Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US05/861,826 external-priority patent/US4200439A/en
Priority claimed from US05/861,824 external-priority patent/US4204843A/en
Application filed by Exxon Research and Engineering Co filed Critical Exxon Research and Engineering Co
Publication of FR2411879A1 publication Critical patent/FR2411879A1/en
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72—Other features
    • C10J3/725—Redox processes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72—Other features
    • C10J3/78—High-pressure apparatus
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/093—Coal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/0946—Waste, e.g. MSW, tires, glass, tar sand, peat, paper, lignite, oil shale
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0956—Air or oxygen enriched air
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0959—Oxygen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0966—Hydrogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0969—Carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0973—Water
    • C10J2300/0976—Water as steam
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0983—Additives
    • C10J2300/0986—Catalysts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0983—Additives
    • C10J2300/0996—Calcium-containing inorganic materials, e.g. lime
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
    • C10J2300/1846—Partial oxidation, i.e. injection of air or oxygen only

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Industrial Gases (AREA)
  • Catalysts (AREA)

Abstract

L'INVENTION CONCERNE UN PROCEDE DE PRODUCTION DE GAZ COMBUSTIBLE PAR CATALYSE. ON TRAITE LE CHARBON QUE L'ON UTILISE POUR LA PREPARATION DE GAZ EN PRESENCE DE VAPEUR D'EAU, A L'AIDE D'UN COMPOSE DE METAL DU GROUPE II-A DU SYSTEME PERIODIQUE DES ELEMENTS, AFIN DE CREER DES SITES D'ECHANGE IONIQUE, ET ENSUITE AVEC UN SEL METALLIQUE DU GROUPE I-A, LES COMPOSES METALLIQUES SE TROUVANT EN SOLUTIONS AQUEUSES, OU BIEN ON OXYDE AU PREALABLE LE CHARBON POUR FORMER LES SITES D'ECHANGE IONIQUE ET ON EFFECTUE L'ECHANGE D'UN METAL DU GROUPE II SUR LES SITES ACTIFS AINSI CREES. APPLICATION NOTAMMENT A LA GAZEIFICATION DE CHARBONS DE HAUTE QUALITE, EN PARTICULIER DE CHARBONS DEFICIENTS EN SITES NATURELS D'ECHANGES IONIQUE.THE INVENTION RELATES TO A PROCESS FOR THE PRODUCTION OF COMBUSTIBLE GAS BY CATALYSIS. THE COAL THAT IS USED FOR THE PREPARATION OF GAS IN THE PRESENCE OF WATER VAPOR IS TREATED BY A METAL COMPOUND FROM GROUP II-A OF THE PERIODIC SYSTEM OF ELEMENTS, IN ORDER TO CREATE SITES OF IONIC EXCHANGE, AND THEN WITH A METAL SALT FROM GROUP IA, THE METAL COMPOUNDS ARE IN AQUEOUS SOLUTIONS, OR THE CARBON IS PREVIOUSLY OXIDATED TO FORM THE IONIC EXCHANGE SITES AND THE EXCHANGE OF A GROUP'S METAL II ON THE ACTIVE SITES THUS CREATED. APPLICATION IN PARTICULAR TO THE GASIFICATION OF HIGH QUALITY COAL, IN PARTICULAR DEFICIENT COAL IN NATURAL IONIC EXCHANGE SITES.

FR7835607A 1977-12-19 1978-12-18 CATALYTIC PROCESS FOR THE PREPARATION OF COMBUSTIBLE GAS FROM COAL Withdrawn FR2411879A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US86182577A 1977-12-19 1977-12-19
US05/861,826 US4200439A (en) 1977-12-19 1977-12-19 Gasification process using ion-exchanged coal
US05/861,824 US4204843A (en) 1977-12-19 1977-12-19 Gasification process

Publications (1)

Publication Number Publication Date
FR2411879A1 true FR2411879A1 (en) 1979-07-13

Family

ID=27420416

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7835607A Withdrawn FR2411879A1 (en) 1977-12-19 1978-12-18 CATALYTIC PROCESS FOR THE PREPARATION OF COMBUSTIBLE GAS FROM COAL

Country Status (8)

Country Link
JP (1) JPS54122304A (en)
AU (1) AU531755B2 (en)
BR (1) BR7808431A (en)
CA (1) CA1115522A (en)
DE (1) DE2854908A1 (en)
FR (1) FR2411879A1 (en)
GB (1) GB2010315B (en)
ZA (1) ZA787109B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2395779A1 (en) * 1977-07-01 1979-01-26 Exxon Research Engineering Co PROCESS FOR THE TRANSFORMATION OF COAL USING AN ION EXCHANGE WITH A METAL CATION

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4336034A (en) * 1980-03-10 1982-06-22 Exxon Research & Engineering Co. Process for the catalytic gasification of coal
JPS56157493A (en) * 1980-05-08 1981-12-04 Yoshiyuki Nishiyama Catalytic gasification of carbonaceous material
JP2015030739A (en) * 2013-07-31 2015-02-16 三菱重工業株式会社 Coal for boiler fuel
JP7280718B2 (en) * 2018-03-09 2023-05-24 大阪瓦斯株式会社 Gasification method of carbonaceous material
CN113233416B (en) * 2021-05-13 2023-05-12 内蒙古工业大学 Method for preparing hydrogen-rich synthetic gas

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR417930A (en) * 1910-01-10 1910-11-25 Otto Dieffenbach Hydrogen manufacturing process
FR2306255A1 (en) * 1975-03-31 1976-10-29 Battelle Memorial Institute SOLID FUELS TREATMENT PROCESS BY A GASING CATALYST

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE303992C (en) *
JPS51127102A (en) * 1975-04-28 1976-11-05 Mitsubishi Heavy Ind Ltd A method of gasification of a solid carbon-compound
ZA763382B (en) * 1975-06-18 1977-05-25 Battelle Memorial Institute Converting fuels
DE2530600C2 (en) * 1975-07-09 1984-02-02 Kraftwerk Union AG, 4330 Mülheim Process for the catalytic pressure gasification of fossil fuels with water vapor
GB1599932A (en) * 1977-07-01 1981-10-07 Exxon Research Engineering Co Distributing coal-liquefaction or-gasifaction catalysts in coal

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR417930A (en) * 1910-01-10 1910-11-25 Otto Dieffenbach Hydrogen manufacturing process
FR2306255A1 (en) * 1975-03-31 1976-10-29 Battelle Memorial Institute SOLID FUELS TREATMENT PROCESS BY A GASING CATALYST

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
CATAL. REV.-SCI.ENG., volume 14, no. 1, 1976, (US) J.L. JOHNSON "The use of catalysts in coal gasification", pages 131-152 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2395779A1 (en) * 1977-07-01 1979-01-26 Exxon Research Engineering Co PROCESS FOR THE TRANSFORMATION OF COAL USING AN ION EXCHANGE WITH A METAL CATION

Also Published As

Publication number Publication date
DE2854908A1 (en) 1979-06-28
AU531755B2 (en) 1983-09-08
ZA787109B (en) 1980-08-27
BR7808431A (en) 1979-08-21
AU4277878A (en) 1979-06-28
GB2010315A (en) 1979-06-27
JPS54122304A (en) 1979-09-21
GB2010315B (en) 1982-05-26
CA1115522A (en) 1982-01-05

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Legal Events

Date Code Title Description
RE Withdrawal of published application