FR2411876A1 - USE OF PHOSPHORUS COMPOUNDS AS ANTI-CLOUDING AGENTS IN CRACKING KILNS FOR ETHYLENE PRODUCTION - Google Patents

USE OF PHOSPHORUS COMPOUNDS AS ANTI-CLOUDING AGENTS IN CRACKING KILNS FOR ETHYLENE PRODUCTION

Info

Publication number
FR2411876A1
FR2411876A1 FR7825021A FR7825021A FR2411876A1 FR 2411876 A1 FR2411876 A1 FR 2411876A1 FR 7825021 A FR7825021 A FR 7825021A FR 7825021 A FR7825021 A FR 7825021A FR 2411876 A1 FR2411876 A1 FR 2411876A1
Authority
FR
France
Prior art keywords
clouding
kilns
cracking
phosphorus compounds
ethylene production
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7825021A
Other languages
French (fr)
Other versions
FR2411876B1 (en
Inventor
Billy W Weinland
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ChampionX LLC
Original Assignee
Nalco Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nalco Chemical Co filed Critical Nalco Chemical Co
Publication of FR2411876A1 publication Critical patent/FR2411876A1/en
Application granted granted Critical
Publication of FR2411876B1 publication Critical patent/FR2411876B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G9/00—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G9/14—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils in pipes or coils with or without auxiliary means, e.g. digesters, soaking drums, expansion means
    • C10G9/16—Preventing or removing incrustation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S585/00—Chemistry of hydrocarbon compounds
    • Y10S585/949—Miscellaneous considerations
    • Y10S585/95—Prevention or removal of corrosion or solid deposits

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Lubricants (AREA)
  • Detergent Compositions (AREA)
  • Cleaning By Liquid Or Steam (AREA)

Abstract

DES MONO ET DIESTERS DE TYPE PHOSPHATE ET PHOSPHITE, UTILISES EN PETITES QUANTITES, JOUENT LE ROLE D'ADDITIFS ANTI-ENCRASSEMENT DANS LES FOURS DE CRAQUAGE DE L'ETHYLENE QUI SONT SOUMIS A DES TEMPERATURES ELEVEES D'ENVIRON 260 A 930 C. LORS DU FONCTIONNEMENT DE CES FOURS, IL SE PRODUIT DES SUBSTANCES QUI SE DEPOSENT ET QUI S'ACCUMULENT SUR LES SERPENTINS DES FOURS ET LES ECHANGEURS DES CONDUITES DE TRANSFERT. LES PRESENTS ADDITIFS ANTI-ENCRASSEMENT INHIBENT ET SUPPRIMENT L'ENCRASSEMENT ET PERMETTENT EGALEMENT UN MEILLEUR NETTOYAGE DES SURFACES PREALABLEMENT ENCRASSEES.PHOSPHATE AND PHOSPHITE MONO AND DIESTERS, USED IN SMALL QUANTITIES, PLAY THE ROLE OF ANTI-CLOUDING ADDITIVES IN ETHYLENE CRACKING OVENS WHICH ARE SUBJECT TO HIGH TEMPERATURES OF APPROXIMATELY 260 TO 930 C. DURING THE IN THE OPERATION OF THESE OVENS, SUBSTANCES OCCUR THAT DEPOSIT AND ACCUMULATE ON THE OVEN COILS AND THE TRANSFER DUCT EXCHANGERS. ANTI-CLOUDING ADDITIVES INHIBIT AND REMOVE CLOUDING AND ALSO ALLOW BETTER CLEANING OF PREVIOUSLY CLOUDED SURFACES.

FR7825021A 1977-12-15 1978-08-30 USE OF PHOSPHORUS COMPOUNDS AS ANTI-CLOUDING AGENTS IN CRACKING KILNS FOR ETHYLENE PRODUCTION Granted FR2411876A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US05/860,793 US4105540A (en) 1977-12-15 1977-12-15 Phosphorus containing compounds as antifoulants in ethylene cracking furnaces

Publications (2)

Publication Number Publication Date
FR2411876A1 true FR2411876A1 (en) 1979-07-13
FR2411876B1 FR2411876B1 (en) 1982-04-16

Family

ID=25334025

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7825021A Granted FR2411876A1 (en) 1977-12-15 1978-08-30 USE OF PHOSPHORUS COMPOUNDS AS ANTI-CLOUDING AGENTS IN CRACKING KILNS FOR ETHYLENE PRODUCTION

Country Status (14)

Country Link
US (1) US4105540A (en)
JP (1) JPS54108808A (en)
AU (1) AU502063B1 (en)
BE (1) BE870102A (en)
BR (1) BR7806541A (en)
CA (1) CA1088959A (en)
DE (1) DE2836853C2 (en)
ES (1) ES472967A1 (en)
FR (1) FR2411876A1 (en)
GB (1) GB2010316B (en)
IT (1) IT1106771B (en)
NL (1) NL7808994A (en)
SE (1) SE430422B (en)
ZA (1) ZA784488B (en)

Families Citing this family (48)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2026319B2 (en) * 1970-05-29 1979-02-01 Exxon Research And Engineering Co., Linden, N.J. (V.St.A.) Process for the thermal cracking of a petroleum fraction
US4511405A (en) * 1982-09-30 1985-04-16 Reed Larry E Antifoulants for thermal cracking processes
US4614229A (en) * 1983-06-20 1986-09-30 Exxon Research & Engineering Co. Method and apparatus for efficient recovery of heat from hot gases that tend to foul heat exchanger tubes
US4542253A (en) * 1983-08-11 1985-09-17 Nalco Chemical Company Use of phosphate and thiophosphate esters neutralized with water soluble amines as ethylene furnace anti-coking antifoulants
US4724064A (en) * 1983-11-17 1988-02-09 Betz Laboratories, Inc. Composition and method for coke retardant during hydrocarbon processing
US4636297A (en) * 1984-08-16 1987-01-13 Hakuto Chemical Co., Ltd. Method for preventing coking in hydrocarbon treatment process
JPS61166882A (en) * 1985-01-18 1986-07-28 Hakutou Kagaku Kk Method of preventing coking of hydrocarbon treatment process
US4775459A (en) * 1986-11-14 1988-10-04 Betz Laboratories, Inc. Method for controlling fouling deposit formation in petroleum hydrocarbons or petrochemicals
US4804456A (en) * 1986-12-18 1989-02-14 Betz Laboratories, Inc. Method for controlling fouling deposit formation in petroleum hydrocarbons or petrochemicals
US4927561A (en) * 1986-12-18 1990-05-22 Betz Laboratories, Inc. Multifunctional antifoulant compositions
US4775458A (en) * 1986-12-18 1988-10-04 Betz Laboratories, Inc. Multifunctional antifoulant compositions and methods of use thereof
US4752374A (en) * 1987-04-20 1988-06-21 Betz Laboratories, Inc. Process for minimizing fouling of processing equipment
US4842716A (en) * 1987-08-13 1989-06-27 Nalco Chemical Company Ethylene furnace antifoulants
US4927519A (en) * 1988-04-04 1990-05-22 Betz Laboratories, Inc. Method for controlling fouling deposit formation in a liquid hydrocarbonaceous medium using multifunctional antifoulant compositions
US4835332A (en) * 1988-08-31 1989-05-30 Nalco Chemical Company Use of triphenylphosphine as an ethylene furnace antifoulant
US4900426A (en) * 1989-04-03 1990-02-13 Nalco Chemical Company Triphenylphosphine oxide as an ethylene furnace antifoulant
US5000836A (en) * 1989-09-26 1991-03-19 Betz Laboratories, Inc. Method and composition for retarding coke formation during pyrolytic hydrocarbon processing
US4962264A (en) * 1989-10-23 1990-10-09 Betz Laboratories, Inc. Methods for retarding coke formation during pyrolytic hydrocarbon processing
US5258113A (en) * 1991-02-04 1993-11-02 Mobil Oil Corporation Process for reducing FCC transfer line coking
US5221462A (en) * 1991-03-27 1993-06-22 Betz Laboratories, Inc. Methods for retarding coke formation during pyrolytic hydrocarbon processing
US5360531A (en) * 1992-12-10 1994-11-01 Nalco Chemical Company Phosphoric triamide coking inhibitors
US5314643A (en) * 1993-03-29 1994-05-24 Betz Laboratories, Inc. High temperature corrosion inhibitor
US5354450A (en) * 1993-04-07 1994-10-11 Nalco Chemical Company Phosphorothioate coking inhibitors
US5779881A (en) * 1994-02-03 1998-07-14 Nalco/Exxon Energy Chemicals, L.P. Phosphonate/thiophosphonate coking inhibitors
US5445743A (en) * 1994-02-10 1995-08-29 Nalco Chemical Company Methacrylate polymers as antifoulants in quench water systems
US5427690A (en) * 1994-02-10 1995-06-27 Nalco Chemical Company α-olefin/maleic anhydride copolymers as antifoulants in quench water systems
DE4405883C1 (en) * 1994-02-21 1995-08-10 Gerhard Prof Dr Zimmermann Process for the preparation of thermally cracked products and application of the process for reducing the coking of heat exchange surfaces
US5500107A (en) * 1994-03-15 1996-03-19 Betz Laboratories, Inc. High temperature corrosion inhibitor
US5593568A (en) * 1994-05-13 1997-01-14 Nalco Chemical Company Coker/visbreaker and ethylene furnace antifoulant
US5552085A (en) * 1994-08-31 1996-09-03 Nalco Chemical Company Phosphorus thioacid ester inhibitor for naphthenic acid corrosion
US5460712A (en) * 1994-11-30 1995-10-24 Nalco Chemical Company Coker/visbreaker and ethylene furnace antifoulant
US5733438A (en) * 1995-10-24 1998-03-31 Nalco/Exxon Energy Chemicals, L.P. Coke inhibitors for pyrolysis furnaces
US5863416A (en) * 1996-10-18 1999-01-26 Nalco/Exxon Energy Chemicals, L.P. Method to vapor-phase deliver heater antifoulants
US5954943A (en) * 1997-09-17 1999-09-21 Nalco/Exxon Energy Chemicals, L.P. Method of inhibiting coke deposition in pyrolysis furnaces
US6482311B1 (en) 2000-08-01 2002-11-19 Tda Research, Inc. Methods for suppression of filamentous coke formation
US6706669B2 (en) 2001-07-13 2004-03-16 Exxonmobil Research And Engineering Company Method for inhibiting corrosion using phosphorous acid
CN1305786C (en) * 2004-08-13 2007-03-21 北京斯伯乐科学技术研究院 Antisludging agent used in cracking gas compressor in an ethylene apparatus and its using method
CN100352899C (en) * 2005-10-11 2007-12-05 杭州市化工研究院有限公司 Ethene compressor cleaning media
JP5713669B2 (en) * 2007-03-30 2015-05-07 ドルフ ケタール ケミカルズ （インディア）プライヴェート リミテッド Prevention of high temperature naphthenic acid corrosion using organophosphorus sulfur compounds and combinations thereof
CN101688118B (en) * 2007-04-04 2014-10-29 多尔夫凯塔尔化学制品（I）私人有限公司 Naphthenic acid corrosion inhibition using new synergetic combination of phosphorus compounds
PL2193179T3 (en) * 2007-09-14 2017-07-31 Dorf Ketal Chemicals (I) Private Limited A novel additive for naphthenic acid corrosion inhibition and method of using the same
US8057707B2 (en) * 2008-03-17 2011-11-15 Arkems Inc. Compositions to mitigate coke formation in steam cracking of hydrocarbons
PL2340296T3 (en) * 2008-08-26 2015-03-31 Dorf Ketal Chemicals I Private Ltd A new additive for inhibiting acid corrosion and method of using the new additive
PE20110787A1 (en) * 2008-08-26 2011-10-31 Dorf Ketal Chemicals India Private Ltd A NOVEL AND AFFECTIVE POLYMER ADDITIVE TO INHIBIT THE CORROSION OF NAPHENIC ACIDS AND METHODS FOR THE USE OF THE SAME
AU2010238162B2 (en) 2009-04-15 2014-05-15 Dorf Ketal Chemicals (I) Pvt. Ltd. An effective novel non - polymeric and non - fouling additive for inhibiting high - temperature naphthenic acid corrosion and method of using the same
CN102732290A (en) * 2011-04-08 2012-10-17 新疆独山子天利实业总公司 Anti-yellowing processing method for long-placed solvent naphtha
TWI711586B (en) * 2015-12-28 2020-12-01 美商藝康美國公司 Method to disperse byproducts formed in dilution steam systems
JP2023503945A (en) * 2019-11-27 2023-02-01 エコラボ ユーエスエー インコーポレイティド Anti-pollution composition for use in crude oil production and processing

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3516922A (en) * 1966-03-09 1970-06-23 Du Pont Method of inhibiting corrosion
US3558470A (en) * 1968-11-25 1971-01-26 Exxon Research Engineering Co Antifoulant process using phosphite and ashless dispersant
FR2092626A1 (en) * 1970-06-02 1972-01-28 Exxon Research Engineering Co Cracking petroleum-steam mixture - with addn of phosphorus or bismuth cpd to suppress coking and carbon monoxide formation
US3645886A (en) * 1970-05-15 1972-02-29 Exxon Research Engineering Co Reducing fouling deposits in process equipment
US4024050A (en) * 1975-01-07 1977-05-17 Nalco Chemical Company Phosphorous ester antifoulants in crude oil refining

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2899387A (en) * 1959-08-11 Process for preventing corrosion during
US3261774A (en) * 1965-09-01 1966-07-19 Nalco Chemical Co Reducing fouling in refining of petroleum products
US3647677A (en) * 1969-06-11 1972-03-07 Standard Oil Co Retardation of coke formation
DE2026319B2 (en) * 1970-05-29 1979-02-01 Exxon Research And Engineering Co., Linden, N.J. (V.St.A.) Process for the thermal cracking of a petroleum fraction
US3776835A (en) * 1972-02-23 1973-12-04 Union Oil Co Fouling rate reduction in hydrocarbon streams
US4024048A (en) * 1975-01-07 1977-05-17 Nalco Chemical Company Organophosphorous antifoulants in hydrodesulfurization
US4024051A (en) * 1975-01-07 1977-05-17 Nalco Chemical Company Using an antifoulant in a crude oil heating process
US4024049A (en) * 1975-01-07 1977-05-17 Nalco Chemical Company Mono and di organophosphite esters as crude oil antifoulants

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3516922A (en) * 1966-03-09 1970-06-23 Du Pont Method of inhibiting corrosion
US3558470A (en) * 1968-11-25 1971-01-26 Exxon Research Engineering Co Antifoulant process using phosphite and ashless dispersant
US3645886A (en) * 1970-05-15 1972-02-29 Exxon Research Engineering Co Reducing fouling deposits in process equipment
FR2092626A1 (en) * 1970-06-02 1972-01-28 Exxon Research Engineering Co Cracking petroleum-steam mixture - with addn of phosphorus or bismuth cpd to suppress coking and carbon monoxide formation
US4024050A (en) * 1975-01-07 1977-05-17 Nalco Chemical Company Phosphorous ester antifoulants in crude oil refining

Also Published As

Publication number Publication date
GB2010316B (en) 1982-04-21
IT1106771B (en) 1985-11-18
CA1088959A (en) 1980-11-04
NL7808994A (en) 1979-06-19
DE2836853A1 (en) 1979-06-21
JPS54108808A (en) 1979-08-25
ES472967A1 (en) 1979-10-16
AU502063B1 (en) 1979-07-12
SE430422B (en) 1983-11-14
GB2010316A (en) 1979-06-27
FR2411876B1 (en) 1982-04-16
US4105540A (en) 1978-08-08
SE7809031L (en) 1979-06-16
ZA784488B (en) 1979-07-25
BE870102A (en) 1979-02-28
DE2836853C2 (en) 1986-05-07
BR7806541A (en) 1979-08-14
IT7850902A0 (en) 1978-08-30

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