FR2408625A1 - PROCESS FOR THE POLYMERIZATION OF OLEFINS USING ZIEGLER-TYPE CATALYSTS - Google Patents
PROCESS FOR THE POLYMERIZATION OF OLEFINS USING ZIEGLER-TYPE CATALYSTSInfo
- Publication number
- FR2408625A1 FR2408625A1 FR7831954A FR7831954A FR2408625A1 FR 2408625 A1 FR2408625 A1 FR 2408625A1 FR 7831954 A FR7831954 A FR 7831954A FR 7831954 A FR7831954 A FR 7831954A FR 2408625 A1 FR2408625 A1 FR 2408625A1
- Authority
- FR
- France
- Prior art keywords
- halogenide
- catalyst
- manganese
- polymerization
- olefins
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000003054 catalyst Substances 0.000 title abstract 5
- 238000006116 polymerization reaction Methods 0.000 title abstract 3
- 150000001336 alkenes Chemical class 0.000 title abstract 2
- 238000000034 method Methods 0.000 title 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 abstract 3
- 229910052748 manganese Inorganic materials 0.000 abstract 3
- 239000011572 manganese Substances 0.000 abstract 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 150000002367 halogens Chemical group 0.000 abstract 2
- 229910052749 magnesium Inorganic materials 0.000 abstract 2
- 239000011777 magnesium Substances 0.000 abstract 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Substances 0.000 abstract 1
- YZCKVEUIGOORGS-UHFFFAOYSA-N Hydrogen atom Chemical compound [H] YZCKVEUIGOORGS-UHFFFAOYSA-N 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000003609 titanium compounds Chemical class 0.000 abstract 1
- 150000003682 vanadium compounds Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/02—Carriers therefor
- C08F4/022—Magnesium halide as support anhydrous or hydrated or complexed by means of a Lewis base for Ziegler-type catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
PROCEDE DE POLYMERISATION DES OLEFINES PAR APPLICATION D'UN CATALYSEUR DU TYPE ZIEGLER CONSTITUE D'UN PREMIER ET D'UN SECOND CATALYSEUR. LE PREMIER CATALYSEUR EST FORME DES TROIS COMPOSANTS SUIVANTS: A)UN HALOGENURE CHOISI PARMI LE GROUPE CONSTITUE PAR L'HALOGENURE DE MAGNESIUM, L'HYDROXYHALOGENURE DE MAGNESIUM, L'HALOGENURE DE MANGANESE ET L'HYDROXYHALOGENURE DE MANGANESE; B)UN COMPOSE DE TITANE CONTENANT DES ATOMES D'HALOGENE OU UN COMPOSE DE VANADIUM CONTENANT DES ATOMES D'HALOGENE; ET C)UN COMPOSE DONNEUR D'ELECTRONS. LE SECOND CATALYSEUR EST FORME D'UN COMPOSE EXPRIME PAR LA FORMULE GENERALE: (CF DESSIN DANS BOPI) M REPRESENTE NA OU K;M EST UN ELEMENT ALCALINO-TERREUX CHOISI PARMI LE GROUPE CONSTITUE PAR CA, SR, BA ET MG; ETCHACUN DES RADICAUX R, R, R ET R EST UN ATOME D'HYDROGENE OU UN RADICAL HYDROCARBURE CONTENANT DE1 A 20ATOMES DE CARBONE. APPLICATION A LA POLYMERISATION DE L'ETHYLENE ET DU PROPYLENE.OLEFINS POLYMERIZATION PROCESS BY APPLYING A ZIEGLER TYPE CATALYST CONSTITUTES A FIRST AND A SECOND CATALYST. THE FIRST CATALYST CONSISTS OF THE FOLLOWING THREE COMPONENTS: A) A HALOGENIDE CHOSEN FROM THE GROUP CONSTITUTING MAGNESIUM HALOGENIDE, MAGNESIUM HYDROXYHALOGENIDE, MANGANESE HALOGENIDE AND MANGANESE HALOGENIDE AND MANGANESE HYDROXYHALOGENIDE; (B) A TITANIUM COMPOUND CONTAINING HALOGEN ATOMS OR A VANADIUM COMPOUND CONTAINING HALOGEN ATOMS; AND C) AN ELECTRON DONOR COMPOUND. THE SECOND CATALYST IS IN THE FORM OF A COMPOUND EXPRESSED BY THE GENERAL FORMULA: (CF DRAWING IN BOPI) M REPRESENTS NA OR K; M IS AN ALKALINO-EARTH ELEMENT CHOSEN FROM THE GROUP CONSTITUTED BY CA, SR, BA AND MG; EACH OF THE R, R, R AND R RADICALS IS A HYDROGEN ATOM OR A HYDROCARBON RADICAL CONTAINING 1 TO 20ATOMS OF CARBON. APPLICATION TO THE POLYMERIZATION OF ETHYLENE AND PROPYLENE.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13622277A JPS5469194A (en) | 1977-11-15 | 1977-11-15 | Polymerization of olefin |
| JP4285878A JPS54134790A (en) | 1978-04-12 | 1978-04-12 | Polymerization of olefin |
| JP7805978A JPS5813081B2 (en) | 1978-06-29 | 1978-06-29 | Production method of alpha olefin polymer |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| FR2408625A1 true FR2408625A1 (en) | 1979-06-08 |
Family
ID=27291369
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR7831954A Withdrawn FR2408625A1 (en) | 1977-11-15 | 1978-11-13 | PROCESS FOR THE POLYMERIZATION OF OLEFINS USING ZIEGLER-TYPE CATALYSTS |
Country Status (4)
| Country | Link |
|---|---|
| DE (1) | DE2849391A1 (en) |
| FR (1) | FR2408625A1 (en) |
| GB (1) | GB2008131B (en) |
| IT (1) | IT1109292B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3724240A1 (en) * | 2017-12-14 | 2020-10-21 | Basell Poliolefine Italia S.r.l. | Magnesium dichloride-alcohol adducts and catalyst components obtained therefrom |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR68927E (en) * | 1954-12-27 | 1958-07-23 | Process for the preparation of high molecular weight polyethylenes which can be used as synthetic products and catalysts for carrying out this process | |
| FR1353224A (en) * | 1962-04-16 | 1964-02-21 | Solvay | Olefin polymerization process |
| FR2283909A1 (en) * | 1974-09-03 | 1976-04-02 | Mitsui Petrochemical Ind | PROCESS FOR PREPARING A HIGHLY CRYSTALLINE OLEFINE POLYMER OR COPOLYMER |
| FR2338077A1 (en) * | 1975-11-25 | 1977-08-12 | Ici Ltd | TRANSITIONAL METAL COMPOSITION |
-
1978
- 1978-11-07 GB GB7843524A patent/GB2008131B/en not_active Expired
- 1978-11-13 FR FR7831954A patent/FR2408625A1/en not_active Withdrawn
- 1978-11-14 DE DE19782849391 patent/DE2849391A1/en not_active Ceased
- 1978-11-15 IT IT51903/78A patent/IT1109292B/en active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR68927E (en) * | 1954-12-27 | 1958-07-23 | Process for the preparation of high molecular weight polyethylenes which can be used as synthetic products and catalysts for carrying out this process | |
| FR1353224A (en) * | 1962-04-16 | 1964-02-21 | Solvay | Olefin polymerization process |
| FR2283909A1 (en) * | 1974-09-03 | 1976-04-02 | Mitsui Petrochemical Ind | PROCESS FOR PREPARING A HIGHLY CRYSTALLINE OLEFINE POLYMER OR COPOLYMER |
| FR2338077A1 (en) * | 1975-11-25 | 1977-08-12 | Ici Ltd | TRANSITIONAL METAL COMPOSITION |
Also Published As
| Publication number | Publication date |
|---|---|
| DE2849391A1 (en) | 1979-05-17 |
| IT1109292B (en) | 1985-12-16 |
| IT7851903A0 (en) | 1978-11-15 |
| GB2008131B (en) | 1982-06-30 |
| GB2008131A (en) | 1979-05-31 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| FR2392037A1 (en) | CATALYSTS FOR THE POLYMERIZATION OF OLEFINS | |
| DE3876585T2 (en) | CATALYST FOR OLEFIN POLYMERIZATION. | |
| GB1444010A (en) | Preparation of catalytic complexes for the -co- 'polymerisation of alpha-olefins | |
| SE7606505L (en) | CATALYST FOR OLEFINER POLYMERIZATION AND CATALYST PREPARATION PROCEDURE | |
| FR2418242A1 (en) | PROCESS FOR THE PRODUCTION OF A-OLEFINIC POLYMERS OF HIGH STEREOREGULARITY | |
| KR930701496A (en) | Method for producing poly-1-olefin | |
| GB1482669A (en) | Olefin polymerization catalyst | |
| ATE10374T1 (en) | CATALYST FOR THE POLYMERIZATION OF OLEFINS AND OLEFIN POLYMERIZATION PROCESSES USING THEM. | |
| ES485256A1 (en) | Catalyst components and catalysts for polymerizing olefins | |
| RU95116378A (en) | METHOD FOR POLYMERIZATION OF OLEFINS | |
| FR2393010A1 (en) | PROCESS FOR PREPARING OLEFIN POLYMERS | |
| FR2408625A1 (en) | PROCESS FOR THE POLYMERIZATION OF OLEFINS USING ZIEGLER-TYPE CATALYSTS | |
| FR2423259A1 (en) | A-OLEFINS POLYMERIZATION PROCESS | |
| JPS5578005A (en) | Polymerization of olefin | |
| FR2391229A1 (en) | PROCESS FOR POLYMERIZING ALPHA-OLEFINS HAVING AT LEAST 3 CARBON ATOMS, AND CATALYST TO BE USED IN THIS PROCESS | |
| GB887314A (en) | Polymerisation catalysts | |
| DE2017841A1 (en) | Catalyst for olefin reactions and process for its use | |
| JPS55133408A (en) | Polymerization of olefin | |
| FR2399990A1 (en) | OLEFINS ISOMERIZATION PROCESS | |
| GB997462A (en) | Improvements in or relating to crystalline polyolefines | |
| GB1473048A (en) | Process for polymerizing olefin | |
| GB1464451A (en) | Solid catalytic complexes and their use in olefin polymerization | |
| SE8100744L (en) | CHEMICAL COMPOSITION AND APPLICATION THEREOF FOR HOMO- AND CO-POLYMERIZATION OF UNSATURED SOCIETIES | |
| GB894804A (en) | Method of polymerizing olefine hydrocarbons and catalyst therefor | |
| GB1511958A (en) | Preparation of titanium chloride based catalyst components and use thereof in olefine(co)polymerisation |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| ST | Notification of lapse |