FR2405913A1 - Procede de preparation de polyalcools et de derives de ceux-ci et catalyseur utilisable a cet effet - Google Patents

Procede de preparation de polyalcools et de derives de ceux-ci et catalyseur utilisable a cet effet

Info

Publication number
FR2405913A1
FR2405913A1 FR7828843A FR7828843A FR2405913A1 FR 2405913 A1 FR2405913 A1 FR 2405913A1 FR 7828843 A FR7828843 A FR 7828843A FR 7828843 A FR7828843 A FR 7828843A FR 2405913 A1 FR2405913 A1 FR 2405913A1
Authority
FR
France
Prior art keywords
polyalcools
derivatives
preparing
catalyst used
cluster
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7828843A
Other languages
English (en)
Other versions
FR2405913B1 (fr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Union Carbide Corp
Original Assignee
Union Carbide Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Union Carbide Corp filed Critical Union Carbide Corp
Publication of FR2405913A1 publication Critical patent/FR2405913A1/fr
Application granted granted Critical
Publication of FR2405913B1 publication Critical patent/FR2405913B1/fr
Granted legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0239—Quaternary ammonium compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0204—Ethers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0237—Amines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0271—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds also containing elements or functional groups covered by B01J31/0201 - B01J31/0231
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20—Carbonyls
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/1512—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by reaction conditions
    • C07C29/1514—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by reaction conditions the solvents being characteristic
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/153—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
    • C07C29/156—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing iron group metals, platinum group metals or compounds thereof
    • C07C29/157—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing iron group metals, platinum group metals or compounds thereof containing platinum group metals or compounds thereof
    • C07C29/158—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing iron group metals, platinum group metals or compounds thereof containing platinum group metals or compounds thereof containing rhodium or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0202—Polynuclearity
    • B01J2531/0211—Metal clusters, i.e. complexes comprising 3 to about 1000 metal atoms with metal-metal bonds to provide one or more all-metal (M)n rings, e.g. Rh4(CO)12
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/226—Sulfur, e.g. thiocarbamates
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)

Abstract

La présente invention concerne un nouveau procédé de préparation de polyalcools à partir de gaz de synthèse. Ce procédé repose sur l'utilisation d'un nouveau catalyseur qui est constitué par un cluster de rhodium-carbonyle/soufre. L'anion de ce cluster répond notamment à la formule brute suivante :
FR7828843A 1977-10-11 1978-10-10 Procede de preparation de polyalcools et de derives de ceux-ci et catalyseur utilisable a cet effet Granted FR2405913A1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US05/840,866 US4115433A (en) 1977-10-11 1977-10-11 Catalyst and process for producing polyhydric alcohols and derivatives

Publications (2)

Publication Number Publication Date
FR2405913A1 true FR2405913A1 (fr) 1979-05-11
FR2405913B1 FR2405913B1 (fr) 1982-07-02

Family

ID=25283423

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7828843A Granted FR2405913A1 (fr) 1977-10-11 1978-10-10 Procede de preparation de polyalcools et de derives de ceux-ci et catalyseur utilisable a cet effet

Country Status (8)

Country Link
US (2) US4115433A (fr)
JP (1) JPS5471098A (fr)
BE (1) BE871128A (fr)
CA (1) CA1120686A (fr)
DE (1) DE2844131A1 (fr)
FR (1) FR2405913A1 (fr)
GB (1) GB2006202B (fr)
NL (1) NL7810205A (fr)

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4115428A (en) * 1977-09-29 1978-09-19 Union Carbide Corporation Catalyst and process for producing polyhydric alcohols and derivatives
US4115433A (en) * 1977-10-11 1978-09-19 Union Carbide Corporation Catalyst and process for producing polyhydric alcohols and derivatives
US4197253A (en) * 1978-06-30 1980-04-08 Union Carbide Corporation Catalytic process for producing polyhydric alcohols
US4257972A (en) * 1978-11-07 1981-03-24 Union Carbide Corporation Catalyst for producing polyhydric alcohols and derivatives
US4333854A (en) * 1979-06-04 1982-06-08 Uop Inc. Sulfided superactive multimetallic catalytic composite
US4363765A (en) * 1979-08-27 1982-12-14 Union Carbide Corporation Rhodium recovery process
US4288380A (en) * 1979-11-01 1981-09-08 Union Carbide Corporation Heteronuclear-bridged rhodium clusters
US4348539A (en) * 1979-11-01 1982-09-07 Union Carbide Corporation Heteronuclear-bridged rhodium clusters
US4302400A (en) * 1979-12-10 1981-11-24 Exxon Research & Engineering Co. Heteronuclear noble metal cluster catalysts
US4342838A (en) * 1980-03-31 1982-08-03 Exxon Research & Engineering Co. Bimetallic clusters of ruthenium with copper, silver and gold
US4301086A (en) * 1980-03-31 1981-11-17 Exxon Research & Engineering Co. Bimetallic clusters of ruthenium with copper, silver and gold
US4320064A (en) * 1980-03-31 1982-03-16 Union Carbide Corporation Polynuclear rhodium carbonyl complexes
DE3121927A1 (de) * 1981-06-03 1982-12-23 Wacker-Chemie GmbH, 8000 München Verfahren zur herstellung von uebergangsmetall-komplexen
US4590314A (en) 1983-12-30 1986-05-20 Union Carbide Corporation Catalytic process for the production of alcohols from carbon monoxide, hydrogen and olefins
US4605751A (en) * 1984-01-17 1986-08-12 The Board Of Regents Acting For And On Behalf Of The University Of Michigan Bimetallic cluster catalysts
DE3683556D1 (de) * 1985-07-31 1992-03-05 Fuji Photo Film Co Ltd Verfahren zur generierung von alkali.
US5068375A (en) * 1990-10-01 1991-11-26 Exxon Research & Engineering Company Substituted noble metal xanthates
US6149782A (en) * 1999-05-27 2000-11-21 De Nora S.P.A Rhodium electrocatalyst and method of preparation
US9566574B2 (en) * 2010-07-04 2017-02-14 Dioxide Materials, Inc. Catalyst mixtures
US10774431B2 (en) 2014-10-21 2020-09-15 Dioxide Materials, Inc. Ion-conducting membranes
US10975480B2 (en) 2015-02-03 2021-04-13 Dioxide Materials, Inc. Electrocatalytic process for carbon dioxide conversion

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4115433A (en) * 1977-10-11 1978-09-19 Union Carbide Corporation Catalyst and process for producing polyhydric alcohols and derivatives

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3907847A (en) * 1970-04-27 1975-09-23 Ethyl Corp Compound and method
DE2045416C3 (de) * 1970-09-15 1979-10-25 Basf Ag, 6700 Ludwigshafen Verfahren zur Elution von Rhodium, das als Rhodiumcarbonylat auf einem basischen Ionenaustauscher gebunden ist
GB1448826A (en) * 1973-02-07 1976-09-08 Dow Corning Ltd Rhodium complexes containing sulphur and use as catalysts
US3878292A (en) * 1973-06-19 1975-04-15 Union Carbide Corp Monovalent metal salts of dodecarhodiumtriaconta carbonyls
US3878214A (en) * 1973-06-19 1975-04-15 Union Carbide Corp Trivalent metal salts of dodecarhodiumtriaconta carbonyls
US3957857A (en) * 1973-06-19 1976-05-18 Union Carbide Corporation Catalytic process for polyhydric alcohols and derivatives
US3989799A (en) * 1974-03-27 1976-11-02 Union Carbide Corporation Divalent metal salts of dodecametal triaconta carbonyls
US3948965A (en) * 1974-07-12 1976-04-06 Union Carbide Corporation Catalytic process for polyhydric alcohols and derivatives
US3968136A (en) * 1974-07-12 1976-07-06 Union Carbide Corporation Catalytic process for polyhydric alcohols and derivatives
US4115428A (en) * 1977-09-29 1978-09-19 Union Carbide Corporation Catalyst and process for producing polyhydric alcohols and derivatives

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4115433A (en) * 1977-10-11 1978-09-19 Union Carbide Corporation Catalyst and process for producing polyhydric alcohols and derivatives

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
EXBK/78 *

Also Published As

Publication number Publication date
GB2006202B (en) 1982-04-07
FR2405913B1 (fr) 1982-07-02
CA1120686A (fr) 1982-03-30
GB2006202A (en) 1979-05-02
JPS5471098A (en) 1979-06-07
US4199520A (en) 1980-04-22
BE871128A (fr) 1979-04-10
US4115433A (en) 1978-09-19
DE2844131A1 (de) 1979-04-12
NL7810205A (nl) 1979-04-17

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