FR2398697A1 - Procede de preparation de silicates finement divises, insolubles dans l'eau, rendus aptes a l'echange de cations - Google Patents
Procede de preparation de silicates finement divises, insolubles dans l'eau, rendus aptes a l'echange de cationsInfo
- Publication number
- FR2398697A1 FR2398697A1 FR7822205A FR7822205A FR2398697A1 FR 2398697 A1 FR2398697 A1 FR 2398697A1 FR 7822205 A FR7822205 A FR 7822205A FR 7822205 A FR7822205 A FR 7822205A FR 2398697 A1 FR2398697 A1 FR 2398697A1
- Authority
- FR
- France
- Prior art keywords
- preparation
- water
- cation exchange
- made suitable
- finally divided
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000005341 cation exchange Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 238000002360 preparation method Methods 0.000 title abstract 2
- XLYOFNOQVPJJNP-PWCQTSIFSA-N Tritiated water Chemical compound [3H]O[3H] XLYOFNOQVPJJNP-PWCQTSIFSA-N 0.000 title 1
- 150000004760 silicates Chemical class 0.000 title 1
- 229910000323 aluminium silicate Inorganic materials 0.000 abstract 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 abstract 1
- 229910004742 Na2 O Inorganic materials 0.000 abstract 1
- 229910001424 calcium ion Inorganic materials 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 229910052681 coesite Inorganic materials 0.000 abstract 1
- 229910052906 cristobalite Inorganic materials 0.000 abstract 1
- 239000003599 detergent Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 235000012239 silicon dioxide Nutrition 0.000 abstract 1
- 229910052682 stishovite Inorganic materials 0.000 abstract 1
- 229910052905 tridymite Inorganic materials 0.000 abstract 1
- 238000005406 washing Methods 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/20—Silicates
- C01B33/26—Aluminium-containing silicates, i.e. silico-aluminates
- C01B33/28—Base exchange silicates, e.g. zeolites
- C01B33/2807—Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures
- C01B33/2815—Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures of type A (UNION CARBIDE trade name; corresponds to GRACE's types Z-12 or Z-12L)
- C01B33/2823—Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures of type A (UNION CARBIDE trade name; corresponds to GRACE's types Z-12 or Z-12L) from aqueous solutions of an alkali metal aluminate and an alkali metal silicate excluding any other source of alumina or silica
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/128—Aluminium silicates, e.g. zeolites
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S423/00—Chemistry of inorganic compounds
- Y10S423/24—LTA, e.g. A, alpha, ZK-4, ZK-21, ZK-22
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Detergent Compositions (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
Abstract
Procédé de préparation d'aluminosilicates finement divisés, insolubles dans l'eau, aptes à l'échange de cations et de formule générale : (Na2 O)0,8-1,3 . (A1 2 O3 ) . (SiO2 )1,75-2,0 Les aluminosilicates selon l'invention sont caractérisés par leur aptitude remarquable à la fixation par échange des ions calcium. Ces aluminosilicates conviennent bien pour la fabrication d'agents de lavage et de détergents.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19772734296 DE2734296A1 (de) | 1977-07-29 | 1977-07-29 | Verfahren zur herstellung von feinteiligen, zum kationenaustausch befaehigten wasserunloeslichen silikaten |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2398697A1 true FR2398697A1 (fr) | 1979-02-23 |
FR2398697B1 FR2398697B1 (fr) | 1981-07-24 |
Family
ID=6015178
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7822205A Granted FR2398697A1 (fr) | 1977-07-29 | 1978-07-27 | Procede de preparation de silicates finement divises, insolubles dans l'eau, rendus aptes a l'echange de cations |
Country Status (14)
Country | Link |
---|---|
US (1) | US4271135A (fr) |
JP (1) | JPS6049133B2 (fr) |
AT (1) | AT366013B (fr) |
BE (1) | BE869348A (fr) |
BR (1) | BR7804876A (fr) |
CA (1) | CA1117733A (fr) |
CH (1) | CH637352A5 (fr) |
DE (1) | DE2734296A1 (fr) |
ES (1) | ES472171A1 (fr) |
FR (1) | FR2398697A1 (fr) |
GB (1) | GB2002335B (fr) |
IT (1) | IT1097166B (fr) |
NL (1) | NL7807197A (fr) |
SE (1) | SE437977B (fr) |
Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5710392Y2 (fr) * | 1977-07-04 | 1982-02-27 | ||
US4576986A (en) * | 1978-01-31 | 1986-03-18 | J. M. Huber Corporation | Rubber compositions containing small particle size zeolites and mixtures |
US4612342A (en) * | 1978-12-20 | 1986-09-16 | J. M. Huber Corporation | Rubber compositions containing small particle size zeolites |
US4888378A (en) * | 1978-12-20 | 1989-12-19 | J. M. Huber Corporation | Plastic compositions containing small particle size zeolites and mixtures |
DE3007080A1 (de) * | 1980-02-26 | 1981-09-10 | Degussa Ag, 6000 Frankfurt | Verfahren zur herstellung von kristallinem zeolithpulver des typs a |
DE3007044A1 (de) * | 1980-02-26 | 1981-09-10 | Degussa Ag, 6000 Frankfurt | Verfahren zur herstellung von kristallinem zeolith a |
DE3007087A1 (de) * | 1980-02-26 | 1981-09-10 | Degussa Ag, 6000 Frankfurt | Verfahren zur herstellung von zeolith a |
DE3007123A1 (de) * | 1980-02-26 | 1981-09-10 | Degussa Ag, 6000 Frankfurt | Verfahren zur herstellung von zeolith a |
FR2528722A1 (fr) * | 1982-06-18 | 1983-12-23 | Rhone Poulenc Chim Base | Zeolite comme auxiliaire de detergence |
US4540559A (en) * | 1983-08-22 | 1985-09-10 | Rhone-Poulenc Specialites Chimiques | Preparation of type Y zeolites |
DE3444311A1 (de) * | 1984-12-05 | 1986-06-05 | Degussa Ag, 6000 Frankfurt | Waessrige stabile suspension wasserunloeslicher, zum binden von calciumionen befaehigter silikate und deren verwendung zur herstellung von wasch- und reinigungsmitteln |
DE3806932A1 (de) * | 1988-03-03 | 1989-09-14 | Vaw Ver Aluminium Werke Ag | Verfahren zur modifizierung eines zeoliths |
US5443812A (en) * | 1989-04-24 | 1995-08-22 | Kanebo Ltd. | Stabilized synthetic zeolite and a process for the preparation thereof |
JPH0318146U (fr) * | 1990-04-11 | 1991-02-22 | ||
DE4309656A1 (de) * | 1993-03-25 | 1994-09-29 | Henkel Kgaa | Verfahren zur Herstellung von feinstteiligen zeolithischen Alkalimetallaluminiumsilicaten |
FR2750973B1 (fr) * | 1996-07-12 | 1998-10-30 | Ceca Sa | Utilisation d'un reacteur agite par un systeme du type vis d'archimede pour la synthese de faujasite lsx |
US6413492B1 (en) * | 2000-03-23 | 2002-07-02 | Engelhard Corporation | Method of forming high aluminum aluminosilicate zeolites |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1240756A (fr) * | 1958-10-03 | 1960-09-09 | Bayer Ag | Procédé de préparation de zéolite sodique synthétique |
FR1536947A (fr) * | 1967-03-01 | 1968-09-02 | Mines Domaniales De Potasse | Zéolites synthétiques et leur procédé de fabrication |
FR2318823A1 (fr) * | 1975-07-25 | 1977-02-18 | Huber Corp J M | Matiere minerale cristalline d'echange de bases et son procede de production |
FR2340128A1 (fr) * | 1976-02-06 | 1977-09-02 | Henkel & Cie Gmbh | Procede de preparation de suspensions aqueuses de silicates insolubles en fines particules echangeurs de cations, produits obtenus et leur utilisation pour la fabrication de produits de lavage et de nettoyage |
FR2370693A1 (fr) * | 1976-11-11 | 1978-06-09 | Degussa | Poudre de zeolite cristallisee de type a |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2882243A (en) * | 1953-12-24 | 1959-04-14 | Union Carbide Corp | Molecular sieve adsorbents |
US3058805A (en) * | 1958-10-03 | 1962-10-16 | Bayer Ag | Process for the production of sodium zeolite a |
AR208392A1 (es) * | 1973-05-07 | 1976-12-27 | Henkel & Cie Gmbh | Composicion para lavar blanquear o limpiar materiales resistentes especialmente textiles adicional a la patente no 201687 adicional a la no 253286 |
US3985669A (en) * | 1974-06-17 | 1976-10-12 | The Procter & Gamble Company | Detergent compositions |
US4102977A (en) * | 1975-11-18 | 1978-07-25 | Mizusawa Kagaku Kogyo Kabushiki Kaisha | Process for the preparation of alkali aluminosilicate detergent builder |
-
1977
- 1977-07-29 DE DE19772734296 patent/DE2734296A1/de active Granted
-
1978
- 1978-07-03 NL NL7807197A patent/NL7807197A/xx not_active Application Discontinuation
- 1978-07-03 SE SE7807490A patent/SE437977B/sv not_active IP Right Cessation
- 1978-07-17 IT IT25781/78A patent/IT1097166B/it active
- 1978-07-25 CA CA000308064A patent/CA1117733A/fr not_active Expired
- 1978-07-27 FR FR7822205A patent/FR2398697A1/fr active Granted
- 1978-07-28 ES ES472171A patent/ES472171A1/es not_active Expired
- 1978-07-28 CH CH816878A patent/CH637352A5/de not_active IP Right Cessation
- 1978-07-28 JP JP53093084A patent/JPS6049133B2/ja not_active Expired
- 1978-07-28 GB GB7831471A patent/GB2002335B/en not_active Expired
- 1978-07-28 BE BE189563A patent/BE869348A/fr not_active IP Right Cessation
- 1978-07-28 AT AT0549678A patent/AT366013B/de not_active IP Right Cessation
- 1978-07-28 BR BR7804876A patent/BR7804876A/pt unknown
-
1979
- 1979-10-04 US US06/081,824 patent/US4271135A/en not_active Expired - Lifetime
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1240756A (fr) * | 1958-10-03 | 1960-09-09 | Bayer Ag | Procédé de préparation de zéolite sodique synthétique |
FR1536947A (fr) * | 1967-03-01 | 1968-09-02 | Mines Domaniales De Potasse | Zéolites synthétiques et leur procédé de fabrication |
FR2318823A1 (fr) * | 1975-07-25 | 1977-02-18 | Huber Corp J M | Matiere minerale cristalline d'echange de bases et son procede de production |
FR2340128A1 (fr) * | 1976-02-06 | 1977-09-02 | Henkel & Cie Gmbh | Procede de preparation de suspensions aqueuses de silicates insolubles en fines particules echangeurs de cations, produits obtenus et leur utilisation pour la fabrication de produits de lavage et de nettoyage |
FR2370693A1 (fr) * | 1976-11-11 | 1978-06-09 | Degussa | Poudre de zeolite cristallisee de type a |
Also Published As
Publication number | Publication date |
---|---|
DE2734296A1 (de) | 1979-02-08 |
IT7825781A0 (it) | 1978-07-17 |
BE869348A (fr) | 1979-01-29 |
IT1097166B (it) | 1985-08-26 |
SE437977B (sv) | 1985-03-25 |
BR7804876A (pt) | 1979-04-24 |
ES472171A1 (es) | 1979-02-16 |
AT366013B (de) | 1982-03-10 |
ATA549678A (de) | 1981-07-15 |
CA1117733A (fr) | 1982-02-09 |
US4271135A (en) | 1981-06-02 |
JPS5426299A (en) | 1979-02-27 |
JPS6049133B2 (ja) | 1985-10-31 |
DE2734296C2 (fr) | 1988-05-11 |
GB2002335B (en) | 1982-03-03 |
NL7807197A (nl) | 1979-01-31 |
FR2398697B1 (fr) | 1981-07-24 |
CH637352A5 (de) | 1983-07-29 |
GB2002335A (en) | 1979-02-21 |
SE7807490L (sv) | 1979-01-30 |
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