FR2384864A1 - ELECTROLYTICAL NICKEL EXTRACTION PROCESS - Google Patents

ELECTROLYTICAL NICKEL EXTRACTION PROCESS

Info

Publication number
FR2384864A1
FR2384864A1 FR7807646A FR7807646A FR2384864A1 FR 2384864 A1 FR2384864 A1 FR 2384864A1 FR 7807646 A FR7807646 A FR 7807646A FR 7807646 A FR7807646 A FR 7807646A FR 2384864 A1 FR2384864 A1 FR 2384864A1
Authority
FR
France
Prior art keywords
nickel
anode
lead
manganese
electrolytical
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
FR7807646A
Other languages
French (fr)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Vale Canada Ltd
Original Assignee
Vale Canada Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Vale Canada Ltd filed Critical Vale Canada Ltd
Publication of FR2384864A1 publication Critical patent/FR2384864A1/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25CPROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C7/00Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells
    • C25C7/02Electrodes; Connections thereof
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25CPROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C1/00Electrolytic production, recovery or refining of metals by electrolysis of solutions
    • C25C1/06Electrolytic production, recovery or refining of metals by electrolysis of solutions or iron group metals, refractory metals or manganese
    • C25C1/08Electrolytic production, recovery or refining of metals by electrolysis of solutions or iron group metals, refractory metals or manganese of nickel or cobalt

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Electrolytic Production Of Metals (AREA)
  • Extraction Or Liquid Replacement (AREA)

Abstract

L'invention concerne l'industrie de l'électrolyse. Extraction électrolytique de nickel d'un électrolyte dans une cellule comportant une cathode insoluble et une anode insoluble, celle-ci étant caractérisée en ce qu'elle comporte un substrat de titane, zirconium ou tantale, qui porte successivement un voile d'un métal du groupe du platine et une couche de bioxyde de plomb, l'électrolyte étant caractérisé en ce qu'il contient en solution, outre le nickel, un composé de manganèse en une quantité correspondant à au moins 0,1 g/l de manganèse. Le bioxyde de manganèse qui se forme à l'anode inhibe la dissolution du plomb de l'anode et la contamination par le plomb du dépôt de nickel électrolytique.The invention relates to the electrolysis industry. Electrolytic extraction of nickel from an electrolyte in a cell comprising an insoluble cathode and an insoluble anode, the latter being characterized in that it comprises a substrate of titanium, zirconium or tantalum, which successively carries a veil of a metal from platinum group and a layer of lead dioxide, the electrolyte being characterized in that it contains in solution, in addition to nickel, a manganese compound in an amount corresponding to at least 0.1 g / l of manganese. The manganese dioxide that forms at the anode inhibits the dissolution of lead from the anode and the lead contamination of the electrolytic nickel deposit.

FR7807646A 1977-03-21 1978-03-16 ELECTROLYTICAL NICKEL EXTRACTION PROCESS Pending FR2384864A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CA274,343A CA1074250A (en) 1977-03-21 1977-03-21 Anodic deposition of manganese dioxide during electrowinning

Publications (1)

Publication Number Publication Date
FR2384864A1 true FR2384864A1 (en) 1978-10-20

Family

ID=4108202

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7807646A Pending FR2384864A1 (en) 1977-03-21 1978-03-16 ELECTROLYTICAL NICKEL EXTRACTION PROCESS

Country Status (7)

Country Link
JP (1) JPS53116217A (en)
AU (1) AU515429B2 (en)
CA (1) CA1074250A (en)
FI (1) FI780821A (en)
FR (1) FR2384864A1 (en)
NO (1) NO780918L (en)
ZA (1) ZA781431B (en)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3392094A (en) * 1963-08-08 1968-07-09 Cominco Ltd Process for preconditioning lead or lead-alloy electrodes
FR2236027A1 (en) * 1973-06-12 1975-01-31 Titanium Metals Corp Insoluble anode with good electrical characteristics - comprises a sintered titanium substrate with separately deposited manganese dioxide coatings
FR2289635A1 (en) * 1974-11-04 1976-05-28 Int Nickel Canada ELECTROLYTIC METAL EXTRACTION AND ANODE INTENDED FOR THIS PURPOSE

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3392094A (en) * 1963-08-08 1968-07-09 Cominco Ltd Process for preconditioning lead or lead-alloy electrodes
FR2236027A1 (en) * 1973-06-12 1975-01-31 Titanium Metals Corp Insoluble anode with good electrical characteristics - comprises a sintered titanium substrate with separately deposited manganese dioxide coatings
FR2289635A1 (en) * 1974-11-04 1976-05-28 Int Nickel Canada ELECTROLYTIC METAL EXTRACTION AND ANODE INTENDED FOR THIS PURPOSE

Also Published As

Publication number Publication date
FI780821A (en) 1978-09-22
ZA781431B (en) 1979-02-28
AU515429B2 (en) 1981-04-02
NO780918L (en) 1978-09-22
AU3409378A (en) 1979-09-20
CA1074250A (en) 1980-03-25
JPS53116217A (en) 1978-10-11

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