FR2384864A1 - ELECTROLYTICAL NICKEL EXTRACTION PROCESS - Google Patents
ELECTROLYTICAL NICKEL EXTRACTION PROCESSInfo
- Publication number
- FR2384864A1 FR2384864A1 FR7807646A FR7807646A FR2384864A1 FR 2384864 A1 FR2384864 A1 FR 2384864A1 FR 7807646 A FR7807646 A FR 7807646A FR 7807646 A FR7807646 A FR 7807646A FR 2384864 A1 FR2384864 A1 FR 2384864A1
- Authority
- FR
- France
- Prior art keywords
- nickel
- anode
- lead
- manganese
- electrolytical
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C7/00—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells
- C25C7/02—Electrodes; Connections thereof
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C1/00—Electrolytic production, recovery or refining of metals by electrolysis of solutions
- C25C1/06—Electrolytic production, recovery or refining of metals by electrolysis of solutions or iron group metals, refractory metals or manganese
- C25C1/08—Electrolytic production, recovery or refining of metals by electrolysis of solutions or iron group metals, refractory metals or manganese of nickel or cobalt
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electrolytic Production Of Metals (AREA)
- Extraction Or Liquid Replacement (AREA)
Abstract
L'invention concerne l'industrie de l'électrolyse. Extraction électrolytique de nickel d'un électrolyte dans une cellule comportant une cathode insoluble et une anode insoluble, celle-ci étant caractérisée en ce qu'elle comporte un substrat de titane, zirconium ou tantale, qui porte successivement un voile d'un métal du groupe du platine et une couche de bioxyde de plomb, l'électrolyte étant caractérisé en ce qu'il contient en solution, outre le nickel, un composé de manganèse en une quantité correspondant à au moins 0,1 g/l de manganèse. Le bioxyde de manganèse qui se forme à l'anode inhibe la dissolution du plomb de l'anode et la contamination par le plomb du dépôt de nickel électrolytique.The invention relates to the electrolysis industry. Electrolytic extraction of nickel from an electrolyte in a cell comprising an insoluble cathode and an insoluble anode, the latter being characterized in that it comprises a substrate of titanium, zirconium or tantalum, which successively carries a veil of a metal from platinum group and a layer of lead dioxide, the electrolyte being characterized in that it contains in solution, in addition to nickel, a manganese compound in an amount corresponding to at least 0.1 g / l of manganese. The manganese dioxide that forms at the anode inhibits the dissolution of lead from the anode and the lead contamination of the electrolytic nickel deposit.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA274,343A CA1074250A (en) | 1977-03-21 | 1977-03-21 | Anodic deposition of manganese dioxide during electrowinning |
Publications (1)
Publication Number | Publication Date |
---|---|
FR2384864A1 true FR2384864A1 (en) | 1978-10-20 |
Family
ID=4108202
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7807646A Pending FR2384864A1 (en) | 1977-03-21 | 1978-03-16 | ELECTROLYTICAL NICKEL EXTRACTION PROCESS |
Country Status (7)
Country | Link |
---|---|
JP (1) | JPS53116217A (en) |
AU (1) | AU515429B2 (en) |
CA (1) | CA1074250A (en) |
FI (1) | FI780821A (en) |
FR (1) | FR2384864A1 (en) |
NO (1) | NO780918L (en) |
ZA (1) | ZA781431B (en) |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3392094A (en) * | 1963-08-08 | 1968-07-09 | Cominco Ltd | Process for preconditioning lead or lead-alloy electrodes |
FR2236027A1 (en) * | 1973-06-12 | 1975-01-31 | Titanium Metals Corp | Insoluble anode with good electrical characteristics - comprises a sintered titanium substrate with separately deposited manganese dioxide coatings |
FR2289635A1 (en) * | 1974-11-04 | 1976-05-28 | Int Nickel Canada | ELECTROLYTIC METAL EXTRACTION AND ANODE INTENDED FOR THIS PURPOSE |
-
1977
- 1977-03-21 CA CA274,343A patent/CA1074250A/en not_active Expired
-
1978
- 1978-03-10 ZA ZA00781431A patent/ZA781431B/en unknown
- 1978-03-14 AU AU34093/78A patent/AU515429B2/en not_active Expired
- 1978-03-15 FI FI780821A patent/FI780821A/en not_active Application Discontinuation
- 1978-03-15 NO NO780918A patent/NO780918L/en unknown
- 1978-03-16 FR FR7807646A patent/FR2384864A1/en active Pending
- 1978-03-22 JP JP3281678A patent/JPS53116217A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3392094A (en) * | 1963-08-08 | 1968-07-09 | Cominco Ltd | Process for preconditioning lead or lead-alloy electrodes |
FR2236027A1 (en) * | 1973-06-12 | 1975-01-31 | Titanium Metals Corp | Insoluble anode with good electrical characteristics - comprises a sintered titanium substrate with separately deposited manganese dioxide coatings |
FR2289635A1 (en) * | 1974-11-04 | 1976-05-28 | Int Nickel Canada | ELECTROLYTIC METAL EXTRACTION AND ANODE INTENDED FOR THIS PURPOSE |
Also Published As
Publication number | Publication date |
---|---|
FI780821A (en) | 1978-09-22 |
ZA781431B (en) | 1979-02-28 |
AU515429B2 (en) | 1981-04-02 |
NO780918L (en) | 1978-09-22 |
AU3409378A (en) | 1979-09-20 |
CA1074250A (en) | 1980-03-25 |
JPS53116217A (en) | 1978-10-11 |
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