FR2377225A1 - Procede de production d'une composition de phosphate de vanadium (iv) a surface active intrinseque amelioree - Google Patents

Procede de production d'une composition de phosphate de vanadium (iv) a surface active intrinseque amelioree

Info

Publication number
FR2377225A1
FR2377225A1 FR7700903A FR7700903A FR2377225A1 FR 2377225 A1 FR2377225 A1 FR 2377225A1 FR 7700903 A FR7700903 A FR 7700903A FR 7700903 A FR7700903 A FR 7700903A FR 2377225 A1 FR2377225 A1 FR 2377225A1
Authority
FR
France
Prior art keywords
vanadium
production
active surface
phosphate
composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7700903A
Other languages
English (en)
Other versions
FR2377225B1 (fr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Chevron USA Inc
Original Assignee
Chevron Research and Technology Co
Chevron Research Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to BE173951A priority Critical patent/BE850222A/fr
Priority to DE2700635A priority patent/DE2700635B2/de
Application filed by Chevron Research and Technology Co, Chevron Research Co filed Critical Chevron Research and Technology Co
Priority to FR7700903A priority patent/FR2377225A1/fr
Priority to NL7700339A priority patent/NL7700339A/xx
Priority to GB2416/77A priority patent/GB1567073A/en
Publication of FR2377225A1 publication Critical patent/FR2377225A1/fr
Application granted granted Critical
Publication of FR2377225B1 publication Critical patent/FR2377225B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B25/00—Phosphorus; Compounds thereof
    • C01B25/16—Oxyacids of phosphorus; Salts thereof
    • C01B25/26—Phosphates
    • C01B25/37—Phosphates of heavy metals
    • C01B25/372—Phosphates of heavy metals of titanium, vanadium, zirconium, niobium, hafnium or tantalum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/20—Vanadium, niobium or tantalum
    • B01J23/22—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
    • B01J27/198—Vanadium
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B25/00—Phosphorus; Compounds thereof
    • C01B25/16—Oxyacids of phosphorus; Salts thereof
    • C01B25/26—Phosphates
    • C01B25/37—Phosphates of heavy metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/215—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of saturated hydrocarbyl groups

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Furan Compounds (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

L'invention concerne la fabrication de phosphate de vanadium cristallin d'une surface active supérieure à 10 m**2/g. On obtient ce produit, conformément à l'invention, en faisant réagir de l'acide orthophosphorique sur un composé oxygéné du vanadium IV. Le composé de vanadium est mis en suspension dans un milieu organique approprié, par exemple, l'isobutanol et mis en contact avec l'acide à une température variant de 20 degrés C à 210 degrés C, jusqu'à ce que la réaction soit achevée. Le catalyseur ainsi obtenu sert à la production d'anhydride maléique à partir de n-butane
FR7700903A 1977-01-07 1977-01-13 Procede de production d'une composition de phosphate de vanadium (iv) a surface active intrinseque amelioree Granted FR2377225A1 (fr)

Priority Applications (5)

Application Number Priority Date Filing Date Title
BE173951A BE850222A (fr) 1977-01-07 1977-01-07 Procede de preparation d'une composition de phosphate de vanadium (iv) a surface active intrinseque elevee
DE2700635A DE2700635B2 (de) 1977-01-07 1977-01-08 Kristallines Vanadium(IV)-phosphat mit einer inneren Oberfläche von 10 bis 100 m2 / g, Verfahren zu seiner Herstellung sowie seine Verwendung
FR7700903A FR2377225A1 (fr) 1977-01-07 1977-01-13 Procede de production d'une composition de phosphate de vanadium (iv) a surface active intrinseque amelioree
NL7700339A NL7700339A (nl) 1977-01-07 1977-01-13 Werkwijze ter bereiding van vana- dium-(iv)-fosfaatsamenstellingen met een hoog in- trinsiek specifiek oppervlak en werkwijze ter be- reiding van maleinezuuranhydride uit n-butaan met toepassing van een aldus bereide katalysator.
GB2416/77A GB1567073A (en) 1977-01-07 1977-01-20 Oxidation catalyst material

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
BE173951A BE850222A (fr) 1977-01-07 1977-01-07 Procede de preparation d'une composition de phosphate de vanadium (iv) a surface active intrinseque elevee
DE2700635A DE2700635B2 (de) 1977-01-07 1977-01-08 Kristallines Vanadium(IV)-phosphat mit einer inneren Oberfläche von 10 bis 100 m2 / g, Verfahren zu seiner Herstellung sowie seine Verwendung
FR7700903A FR2377225A1 (fr) 1977-01-07 1977-01-13 Procede de production d'une composition de phosphate de vanadium (iv) a surface active intrinseque amelioree
NL7700339A NL7700339A (nl) 1977-01-07 1977-01-13 Werkwijze ter bereiding van vana- dium-(iv)-fosfaatsamenstellingen met een hoog in- trinsiek specifiek oppervlak en werkwijze ter be- reiding van maleinezuuranhydride uit n-butaan met toepassing van een aldus bereide katalysator.
GB2416/77A GB1567073A (en) 1977-01-07 1977-01-20 Oxidation catalyst material

Publications (2)

Publication Number Publication Date
FR2377225A1 true FR2377225A1 (fr) 1978-08-11
FR2377225B1 FR2377225B1 (fr) 1979-04-20

Family

ID=27507574

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7700903A Granted FR2377225A1 (fr) 1977-01-07 1977-01-13 Procede de production d'une composition de phosphate de vanadium (iv) a surface active intrinseque amelioree

Country Status (5)

Country Link
BE (1) BE850222A (fr)
DE (1) DE2700635B2 (fr)
FR (1) FR2377225A1 (fr)
GB (1) GB1567073A (fr)
NL (1) NL7700339A (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2469207A1 (fr) * 1979-08-27 1981-05-22 Monsanto Co Procede de preparation de catalyseurs complexes au phosphore-vanadium-oxygene et de precurseurs de ces catalyseurs et nouveaux produits ainsi obtenus
EP0050402A2 (fr) * 1980-10-22 1982-04-28 The Standard Oil Company Préparation de catalyseurs vanadium phosphore et leur application dans la production d'anhydride maléique
FR2496493A1 (fr) * 1980-12-22 1982-06-25 Monsanto Co Procede de preparation de catalyseurs complexes au phosphore-vanadium-oxygene, avec mise en contact des precurseurs catalytiques avec un solvant non aqueux

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4361501A (en) * 1980-12-29 1982-11-30 The Standard Oil Company Preparation of vanadium phosphorus catalysts using a mixed phosphorus source
CA1202950A (fr) * 1981-12-28 1986-04-08 The Standard Oil Company Activation in-situ de catalyseurs d'oxydation a lit fluidise
DE69702728T2 (de) * 1996-04-01 2001-02-01 Nippon Catalytic Chem Ind Vanadium-Phosphoroxid, Verfahren zu dessen Herstellung, aus dem Oxid hergestellter Katalysator für die Dampfphasenoxidation und Verfahren für die Dampfphasenteiloxidation von Kohlenwasserstoffen
DE19840224C2 (de) * 1998-09-03 2002-09-12 Consortium Elektrochem Ind Verfahren zur Herstellung von Katalysatoren für die Synthese von Maleinsäureanhydrid durch Gasphasenoxidation
GB9921116D0 (en) * 1999-09-07 1999-11-10 Univ Cardiff Metal phosphates
WO2009061167A1 (fr) * 2007-11-09 2009-05-14 Universiti Putra Malaysia Procédé amélioré pour produire des catalyseurs à base de nanoparticules d'oxyde de vanadium et phosphore ayant une grande surface active et produits obtenus par ce procédé

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2276874A1 (fr) * 1974-07-01 1976-01-30 Mobil Oil Procede en un stade pour preparer un complexe catalytique d'oxydation a base de vanadium et de phosphore
FR2304402A1 (fr) * 1975-03-17 1976-10-15 Petro Tex Chem Corp Catalyseur et procede pour preparer de l'anhydride maleique a partir d'hydrocarbures ayant 4 atomes de carbone

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2276874A1 (fr) * 1974-07-01 1976-01-30 Mobil Oil Procede en un stade pour preparer un complexe catalytique d'oxydation a base de vanadium et de phosphore
FR2304402A1 (fr) * 1975-03-17 1976-10-15 Petro Tex Chem Corp Catalyseur et procede pour preparer de l'anhydride maleique a partir d'hydrocarbures ayant 4 atomes de carbone

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2469207A1 (fr) * 1979-08-27 1981-05-22 Monsanto Co Procede de preparation de catalyseurs complexes au phosphore-vanadium-oxygene et de precurseurs de ces catalyseurs et nouveaux produits ainsi obtenus
EP0050402A2 (fr) * 1980-10-22 1982-04-28 The Standard Oil Company Préparation de catalyseurs vanadium phosphore et leur application dans la production d'anhydride maléique
EP0050402A3 (en) * 1980-10-22 1982-06-16 The Standard Oil Company Preparation of vanadium phosphorus catalysts and use thereof in production of maleic anhydride
FR2496493A1 (fr) * 1980-12-22 1982-06-25 Monsanto Co Procede de preparation de catalyseurs complexes au phosphore-vanadium-oxygene, avec mise en contact des precurseurs catalytiques avec un solvant non aqueux

Also Published As

Publication number Publication date
BE850222A (fr) 1977-05-02
DE2700635A1 (de) 1978-07-13
NL7700339A (nl) 1978-07-17
FR2377225B1 (fr) 1979-04-20
GB1567073A (en) 1980-05-08
DE2700635B2 (de) 1979-02-01

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