FR2375983A1 - Styrene! polymer and metal composite material - using polydiene polyvinyl aromatic block copolymer adhesives, for structural applications - Google Patents
Styrene! polymer and metal composite material - using polydiene polyvinyl aromatic block copolymer adhesives, for structural applicationsInfo
- Publication number
- FR2375983A1 FR2375983A1 FR7700070A FR7700070A FR2375983A1 FR 2375983 A1 FR2375983 A1 FR 2375983A1 FR 7700070 A FR7700070 A FR 7700070A FR 7700070 A FR7700070 A FR 7700070A FR 2375983 A1 FR2375983 A1 FR 2375983A1
- Authority
- FR
- France
- Prior art keywords
- block copolymer
- composite material
- polydiene
- polymer
- structural applications
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
- B32B15/082—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising vinyl resins; comprising acrylic resins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/302—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising aromatic vinyl (co)polymers, e.g. styrenic (co)polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J151/00—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
- C09J151/006—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers grafted on to block copolymers containing at least one sequence of polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/40—Symmetrical or sandwich layers, e.g. ABA, ABCBA, ABCCBA
Abstract
A composite material comprises styrene polymer layer(s) bonded to metal layer(s) by an adhesive consisting of a block copolymer A-B-A, where block B comprises polydiene units of mol. wt. 10,000-100,000 and blocks A are polyvinyl-aromatic units of mol. wt. 5000-50,000. Block B is modified with a 3-6C ethylenically unsatd. carboxylic acid (anhydride). The block copolymer may be used in combination with any compatible polymer. Used for structural applications involving high stresses. The composite shows higher mechanical strength (40-80 kg/cm2) than similar materials involving conventional adhesives.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7700070A FR2375983A1 (en) | 1977-01-04 | 1977-01-04 | Styrene! polymer and metal composite material - using polydiene polyvinyl aromatic block copolymer adhesives, for structural applications |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7700070A FR2375983A1 (en) | 1977-01-04 | 1977-01-04 | Styrene! polymer and metal composite material - using polydiene polyvinyl aromatic block copolymer adhesives, for structural applications |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2375983A1 true FR2375983A1 (en) | 1978-07-28 |
FR2375983B1 FR2375983B1 (en) | 1981-06-19 |
Family
ID=9185106
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7700070A Granted FR2375983A1 (en) | 1977-01-04 | 1977-01-04 | Styrene! polymer and metal composite material - using polydiene polyvinyl aromatic block copolymer adhesives, for structural applications |
Country Status (1)
Country | Link |
---|---|
FR (1) | FR2375983A1 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0173379A1 (en) * | 1984-08-30 | 1986-03-05 | Shell Internationale Researchmaatschappij B.V. | Process for bonding polymeric and/or metal materials |
EP0389094A2 (en) * | 1989-03-09 | 1990-09-26 | Morton International, Inc. | Adhesive blend of polyolefins and grafted block copolymer of polystyrene |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4341837A (en) | 1978-08-11 | 1982-07-27 | Kureha Kagaku Kogyo Kabushiki Kaisha | Laminar thermoplastic resin structure |
JPS5587551A (en) | 1978-12-27 | 1980-07-02 | Asahi Chemical Ind | Original laminated piece |
-
1977
- 1977-01-04 FR FR7700070A patent/FR2375983A1/en active Granted
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0173379A1 (en) * | 1984-08-30 | 1986-03-05 | Shell Internationale Researchmaatschappij B.V. | Process for bonding polymeric and/or metal materials |
EP0389094A2 (en) * | 1989-03-09 | 1990-09-26 | Morton International, Inc. | Adhesive blend of polyolefins and grafted block copolymer of polystyrene |
EP0389094A3 (en) * | 1989-03-09 | 1992-01-15 | Morton International, Inc. | Adhesive blend of polyolefins and grafted block copolymer of polystyrene |
Also Published As
Publication number | Publication date |
---|---|
FR2375983B1 (en) | 1981-06-19 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
ST | Notification of lapse |