FR2372826A1 - Imidazolium pyridinium carbaldoxime double salts - for treatment of poisoning by phosphorus pesticides - Google Patents

Imidazolium pyridinium carbaldoxime double salts - for treatment of poisoning by phosphorus pesticides

Info

Publication number
FR2372826A1
FR2372826A1 FR7636169A FR7636169A FR2372826A1 FR 2372826 A1 FR2372826 A1 FR 2372826A1 FR 7636169 A FR7636169 A FR 7636169A FR 7636169 A FR7636169 A FR 7636169A FR 2372826 A1 FR2372826 A1 FR 2372826A1
Authority
FR
France
Prior art keywords
carbaldoxime
pyridinium
imidazolium
alkyl
double salts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7636169A
Other languages
French (fr)
Other versions
FR2372826B1 (en
Inventor
Daniel Kiffer
Michel Coq
Huguette Coq
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Etat Francais
Original Assignee
Etat Francais
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Etat Francais filed Critical Etat Francais
Priority to FR7636169A priority Critical patent/FR2372826A1/en
Publication of FR2372826A1 publication Critical patent/FR2372826A1/en
Application granted granted Critical
Publication of FR2372826B1 publication Critical patent/FR2372826B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/12—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
    • C07D233/54—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members
    • C07D233/56—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, attached to ring carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D249/00—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms
    • C07D249/02—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms not condensed with other rings
    • C07D249/08—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles

Abstract

Imidazolium-pyridinium carbaldoxime double salts of formula (I) are new:- In (I) the carbaldoxime gp. (syn or anti form may be in position 2,3 or 4 of the pyridine ring; (R)p is -(alkyl)m or (CH2OCH2)n; m=3-6; n=1 or 2;R1 is 1-4C alkyl which may opt. branched, (un)satd. hydroxyalkyl, carboxyalkyl, carbonitrile or carbaldoxime; R2R3 and R4 are each H, 1-4C alkyl which may be opt. branched, or (un)satd., hydroxyalkyl, carboxyalkyl, carbonitrile or carbaldoxime; X- and Y- are each halide anions or phosphoric, sulphuric, methane sulphonic, succinic, maleic tartaric or phthalic anions. (I) are used for the therapeutic and/or prophylactic treatment of toxicity caused by phosphorus derivs. esp. pesticides. A typical cpd. is 1-(1-methyl imidazolium)-3-(4-carbaldoxime pyridinium) propane dibromide. This was prepd. by dissolving 18.3 g 3(1-bromo-3-propyl)-1-methyl imidaolium bromide was heated with 7.8g pyridine-4-carbaldoxime in acetonitrile.
FR7636169A 1976-12-01 1976-12-01 Imidazolium pyridinium carbaldoxime double salts - for treatment of poisoning by phosphorus pesticides Granted FR2372826A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
FR7636169A FR2372826A1 (en) 1976-12-01 1976-12-01 Imidazolium pyridinium carbaldoxime double salts - for treatment of poisoning by phosphorus pesticides

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7636169A FR2372826A1 (en) 1976-12-01 1976-12-01 Imidazolium pyridinium carbaldoxime double salts - for treatment of poisoning by phosphorus pesticides

Publications (2)

Publication Number Publication Date
FR2372826A1 true FR2372826A1 (en) 1978-06-30
FR2372826B1 FR2372826B1 (en) 1980-03-28

Family

ID=9180517

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7636169A Granted FR2372826A1 (en) 1976-12-01 1976-12-01 Imidazolium pyridinium carbaldoxime double salts - for treatment of poisoning by phosphorus pesticides

Country Status (1)

Country Link
FR (1) FR2372826A1 (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0023378A1 (en) * 1979-07-26 1981-02-04 Nederlandse Organisatie voor toegepast-natuurwetenschappelijk onderzoek TNO 1-substituted hydroxyiminomethyl-pyridinium salts, a process for the production of said compounds, compositions with an activity against organophosphate poisonings, and a process for the preparation of such compositions
FR2517307A1 (en) * 1981-11-27 1983-06-03 France Etat Alkyl imidazolium di:methyl carbamoyl pyridinium double salts - for prevention of phosphorus pesticide intoxication
US4865837A (en) * 1987-07-28 1989-09-12 Sri International Aldoxime-substituted triazolium compounds useful in the treatment of poisoning by phosphorus-containing chemicals
JP2008507556A (en) * 2004-07-23 2008-03-13 シグマ−アルドリッチ・カンパニー Highly stable diionic liquid salt
US8168830B2 (en) * 2004-07-23 2012-05-01 Sigma-Aldrich Co. Llc High stability diionic liquid salts
US8481722B2 (en) 2007-01-31 2013-07-09 Sigma-Aldrich Co. Llc High stability polyionic liquid salts

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0023378A1 (en) * 1979-07-26 1981-02-04 Nederlandse Organisatie voor toegepast-natuurwetenschappelijk onderzoek TNO 1-substituted hydroxyiminomethyl-pyridinium salts, a process for the production of said compounds, compositions with an activity against organophosphate poisonings, and a process for the preparation of such compositions
FR2517307A1 (en) * 1981-11-27 1983-06-03 France Etat Alkyl imidazolium di:methyl carbamoyl pyridinium double salts - for prevention of phosphorus pesticide intoxication
US4865837A (en) * 1987-07-28 1989-09-12 Sri International Aldoxime-substituted triazolium compounds useful in the treatment of poisoning by phosphorus-containing chemicals
JP2008507556A (en) * 2004-07-23 2008-03-13 シグマ−アルドリッチ・カンパニー Highly stable diionic liquid salt
US8168830B2 (en) * 2004-07-23 2012-05-01 Sigma-Aldrich Co. Llc High stability diionic liquid salts
AU2005267033B2 (en) * 2004-07-23 2012-05-10 Sigma-Aldrich Co. Llc High stability diionic liquid salts
US8182581B2 (en) 2004-07-23 2012-05-22 Sigma-Aldrich Co. Llc High stability diionic liquid salts
US8956445B2 (en) 2004-07-23 2015-02-17 Sigma-Aldrich Co. High stability diionic liquid salts
US8481722B2 (en) 2007-01-31 2013-07-09 Sigma-Aldrich Co. Llc High stability polyionic liquid salts

Also Published As

Publication number Publication date
FR2372826B1 (en) 1980-03-28

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